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    Potentiometric Titration

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    Mahmood Ullah
    This document describes a potentiometric titration experiment to determine the concentration of ferrous ion using a potassium dichromate solution. The document discusses the objectives, principles, equipment, procedure, and data analysis of the titration experiment.

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    Potentiometric Titration

    Uploaded by

    Mahmood Ullah
    95 views13 pages
    This document describes a potentiometric titration experiment to determine the concentration of ferrous ion using a potassium dichromate solution. The document discusses the objectives, principles, equipment, procedure, and data analysis of the titration experiment.

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    Potentiometric titration

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    This document describes a potentiometric titration experiment to determine the concentration of ferrous ion using a potassium dichromate solution. The document discusses the objectives, principles, equipment, procedure, and data analysis of the titration experiment.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    95 views13 pages

    Potentiometric Titration

    Uploaded by

    Mahmood Ullah
    This document describes a potentiometric titration experiment to determine the concentration of ferrous ion using a potassium dichromate solution. The document discusses the objectives, principles, equipment, procedure, and data analysis of the titration experiment.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 13

    Exp No 05

    Potentiometric titration of ferrous ion with


    standard potassium dichromate solution

    Chem 352 © Department of Chemistry, BUET


    Objectives

    ➢ Understanding of redox reactions


    ➢ Develop understating about the electroanalytical techniques
    ➢ Determination of the concentration of analytes (iron) present in
    a sample

    Chem 352 © Department of Chemistry, BUET


    Potentiometry

    Chem 352 © Department of Chemistry, BUET


    Potentiometry

    ➢ In potentiometry, information of the sample composition is


    obtained from the potential develop between two electrodes.

    Chem 352 © Department of Chemistry, BUET


    Potentiometry

    ➢ It measures electrical potential develops by an electrode in an


    electrolyte solution at zero current flow.
    ➢ Nernst Equation is used to relate potential to concentration of
    the analyte in solution.

    Chem 352 © Department of Chemistry, BUET


    Types of Electrodes

    Reference electrode:
    ➢ It gives reference for potential measurement.
    ➢ The electrode is a stable reversible nonpolarizable electrode
    ➢ Shows little hysteresis with temperature.
    ➢ The high stability of the electrode potential is usually reached
    by employing a redox system with constant concentrations of
    each participants of the redox reaction.

    Chem 352 © Department of Chemistry, BUET


    Types of Electrodes

    Indicator/ working electrode:


    ➢ It responds to the analyte
    ➢ It could be metallic or membrane type
    ➢ Inert conductors that themselves do not engage in
    electrochemical reactions under the conditions in which a
    redox reaction of interest occurs.

    Chem 352 © Department of Chemistry, BUET


    Advantages of Potentiometric Titration

    Advantages of potentiometric titrations over 'classical' visual


    indicator methods are:
    1. Can be used for colored, turbid or fluorescent analyte solution.
    2. Can be used for titration of polyprotic acids, mixtures of acids,
    mixtures of bases or mixtures of halides.

    Chem 352 © Department of Chemistry, BUET


    Titration Process

    Chem 352 © Department of Chemistry, BUET


    Titration Curve

    Chem 352 © Department of Chemistry, BUET


    Nernst Equation

    Chem 352 © Department of Chemistry, BUET


    Conducting Experiment
    Procedure
    1. Take 20 mL Fe(II) solution or Mohr’s salt FeSO4.(NH4)2SO4.
    6H2O solution in a beaker.
    2. Add 10 mL H2SO4 solution (3 M)
    3. Fill up the burette with K2Cr2O7 (0.017 M ) 20 mL solution and
    drop wise add it.
    4. Record the potential at 0.5 mL interval when the change of
    potential is small
    5. Record the potential at 0.2 mL interval when the change of
    potential is becoming larger.
    6. Take of a graph and plot potential vs. volume of potassium
    dichromate added
    7. Draw first derivative and second derivative of the potential-
    volume curve.

    Chem 352 © Department of Chemistry, BUET


    Additional Processing

    E1/2 Calculation
    ➢ E1/2: Potential when half of the reactant converted to product

    Chem 352 © Department of Chemistry, BUET

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