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FTIR Tables

This document provides a table summarizing characteristic infrared absorptions and the corresponding functional groups that produce them. It lists infrared frequency ranges in wavenumbers (cm-1) along with descriptions of bond vibrations and stretches for various functional groups including alcohols, amines, carboxylic acids, aldehydes, ketones, aromatics, alkenes, alkynes, esters, and others. The table acts as a reference for identifying functional groups based on their infrared absorption spectra.

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2K views

FTIR Tables

This document provides a table summarizing characteristic infrared absorptions and the corresponding functional groups that produce them. It lists infrared frequency ranges in wavenumbers (cm-1) along with descriptions of bond vibrations and stretches for various functional groups including alcohols, amines, carboxylic acids, aldehydes, ketones, aromatics, alkenes, alkynes, esters, and others. The table acts as a reference for identifying functional groups based on their infrared absorption spectra.

Uploaded by

vandykavidurga
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Table of Characteristic IR Absorptions

frequency, cm–1 bond functional group


3640–3610 (s, sh) O–H stretch, free hydroxyl alcohols, phenols
3500–3200 (s,b) O–H stretch, H–bonded alcohols, phenols
3400–3250 (m) N–H stretch 1˚, 2˚ amines, amides
3300–2500 (m) O–H stretch carboxylic acids
3330–3270 (n, s) –C≡C–H: C–H stretch alkynes (terminal)
3100–3000 (s) C–H stretch aromatics
3100–3000 (m) =C–H stretch alkenes
3000–2850 (m) C–H stretch alkanes
2830–2695 (m) H–C=O: C–H stretch aldehydes
2260–2210 (v) C≡N stretch nitriles
2260–2100 (w) –C≡C– stretch alkynes
1760–1665 (s) C=O stretch carbonyls (general)
1760–1690 (s) C=O stretch carboxylic acids
1750–1735 (s) C=O stretch esters, saturated aliphatic
1740–1720 (s) C=O stretch aldehydes, saturated aliphatic
1730–1715 (s) C=O stretch α, β–unsaturated esters
1715 (s) C=O stretch ketones, saturated aliphatic
1710–1665 (s) C=O stretch α, β–unsaturated aldehydes, ketones
1680–1640 (m) –C=C– stretch alkenes
1650–1580 (m) N–H bend 1˚ amines
1600–1585 (m) C–C stretch (in–ring) aromatics
1550–1475 (s) N–O asymmetric stretch nitro compounds
1500–1400 (m) C–C stretch (in–ring) aromatics
1470–1450 (m) C–H bend alkanes
1370–1350 (m) C–H rock alkanes
1360–1290 (m) N–O symmetric stretch nitro compounds
1335–1250 (s) C–N stretch aromatic amines
1320–1000 (s) C–O stretch alcohols, carboxylic acids, esters, ethers
1300–1150 (m) C–H wag (–CH2X) alkyl halides
1250–1020 (m) C–N stretch aliphatic amines
1000–650 (s) =C–H bend alkenes
950–910 (m) O–H bend carboxylic acids
910–665 (s, b) N–H wag 1˚, 2˚ amines
900–675 (s) C–H “oop” aromatics
850–550 (m) C–Cl stretch alkyl halides
725–720 (m) C–H rock alkanes
700–610 (b, s) –C≡C–H: C–H bend alkynes
690–515 (m) C–Br stretch alkyl halides

m=medium, w=weak, s=strong, n=narrow, b=broad, sh=sharp

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