MCQ Test-4, Unit 2, Engg - Chemistry, 2020-21

R.R.
INSTITUTE OF MODERN TECHNOLOGY

NH-24, Bakshi Ka Talab, Sitapur Road, Lucknow, Uttar Pradesh 226201
M C Q Test
Unit -4
(SESSION-: 2020-2021)
Subject Name:- Engg.Chemistry Subject Code:- KAS 202T
Course: B.Tech Branch:- CS,ME & CE
Semester : - 2 Section: A,A1& A2
[Time:-1/2 Hour
] [Total Marks: - 30]
Q.1. The different types of energies associated with a molecule are __________
a) Electronic energy
b) Vibrational energy
c) Rotational energy
d) All of the mentioned
Q.2 The correct order of different types of energies is __________
a) Eel >> Evib >> Erot >> E tr
b) Eel >> Erot >> Evib >> E tr
c) Eel >> Evib >> Etr >> E rot
d) Etr >> Evib >> Erot >> E el

Q.3. Which of the following is an application of molecular spectroscopy?
a) Structural investigation
b) Basis of understanding of colors
c) Study of energetically excited reaction products
d) All of the mentioned
Q.4. The transition zone for Raman spectra is __________
a) Between vibrational and rotational levels
b) Between electronic levels
c) Between magnetic levels of nuclei
d) Between magnetic levels of unpaired electrons
Q.5. Selection rule for Raman spectroscopy-
a) ∆J=±1
b) ∆J=0,±1, ±2…
c) ∆J=±2
d) ∆J=0
Q.6.Which of the following shift leads to the decreased intensity of

absorption?
a) Hypochromic
b) Hyper chromic
c) Hypsochromic
d) Bathochromic
Q 7. According to Beer’s law for a colored solution, which one of the following
statements is False?
(a) The percent transmission is not directly proportional to the concentration.
(b) The absorbance is directly proportional to the concentration.
(c) The absorbance does not change when the cell path length (cell
thickness) increases.
(d) When the concentration of the unknown sample is higher than the
highest concentration in the calibration range, the sample should be
diluted.
Q.8. Raman effect is scattering of ________
a) Atoms
b) Molecules
c) Protons
d) Photons
Q 9. The elastic scattering of photons is called as ______
a) Atmospheric scattering
b) Rayleigh Scattering
c) Conserved Scattering
d) Raman Scattering
Q10. How many degrees of freedom does a chemical compound of N atoms

have?
a) 2N
b) 2N + 1
c) 3N
d) 3N + 1
Q.11 In Raman spectroscopy, the radiation lies in the ________
a) Microwave Region
b) Visible Region
c) UV Region
d) X-ray Region
Q12. The Raman spectrum is said to consist of Strokes lines when ________
a) Δv > 0
b) Δv < 0
c) Δv = 0
d) Does not depend on Δv
Q13. Raman lines are ________

a) Weak
b) Strong
c) Curved
d) Blurry
Q 14. Which of the following lines are most intense?
a) Stokes lines
b) Rayleigh-scattered lines
c) Anti-strokes lines
d) All have same intensity
Q 15. For a particular vibrational mode to appear in the Raman spectrum, what
must change?
a) Frequency of radiation
b) Intensity of radiation
c) Molecule’s shape
d) Molecule’s polarizability
Q 16. IR spectrum is a plot of:
A. % Transmittance versus time
B. % Transmittance versus wavenumber
C. Peak area versus time
D. Peak area versus wavenumber

Q.17. Which of the following spectroscopy techniques is associated with
molecular
emission?
A. UV-Visible spectroscopy
B. IR spectroscopy
C. Fluorescence spectroscopy
D. X-ray diffraction
Q.18. Which of the following statements regarding IR spectroscopy is correct?
A. IR radiation is higher in energy than UV radiation
B. IR spectra records the scattering of the radiation
C. IR spectra gives information about the ƛmax of the molecule
D. IR radiation is higher in wavelength than UV radiation
Q 19.Which of the following shift leads to the increased intensity of

absorption?
a) Hypochromic
b) Hyper chromic
c) Hypsochromic
d) Bathochromic
Q 20. Which of the following shift leads to the decreased wave length of
absorption?
a) Hypochromic
b) Hyper chromic
c) Hypsochromic
d) Bathochromic
Q21. Which of the following shift leads to the increased wave length of
absorption?
a) Hypochromic
b) Hyper chromic
c) Hypsochromic
d) Bathochromic
Q 22 . Rotational energy of rotating diatomic molecule is ...
A. E= I ω 2 / 2. B.E = j( j+2)B. C. Both A&B. D. None
Q 23. In IR spectroscopy, the number of types of bending vibrations are...
A. 4. B. 5. C . 2. D3
Q 24. A compound having conc. ( 1/ 1000)g/ L resulted absorbance value 0. 20 at
maximum wave length 510 nm using 1 cm cell. What is absorptivity...
A. 200 L / g cm. B. 300 L / g cm C. 0.25 m / L D. None
Q25. Rotational spectra shows by molecule which must be exist in ... State.
A. Liquid. B. Solid. C. Gases D. None
Q 26. After absorption of light in UV spectroscopy ,electrons are exist as paired .

This state is called....
A. Excited singlet state
B. Excited triplet state
C. Excited doublet state
D. None
Q 27 In UV spectroscopy ,those transition required highest energy...
A. Sigma to sigma anti bonding molecular orbital
B. Pi BMO to pi ABMO
C. Non bonding to sigma ABMO
D. None
Q28. The structural group which is responsible for imparting colour to

compound called ...
A. Axochromophore
B. Chromophore
C. Hydroxy group
D. None
Q 29. The spectroscopy which distinct conjugated and non conjugatrd

compounds is ....
A. Microwave spectroscopy
B. I.R. spectroscopy
C. Raman spectroscopy
D. UV spectroscopy
Q30. The lines whose frequency lower than incident light are called....
A. Rayleigh line
B. Stokes line
C. Anti- Stoke's line
D. None
Answer: 1.D,2.A,3.D,4.A,5.A,6. A 7.B,8.D 9.B, 10.C ,11.B ,12. A ,13.A 14.B
15. D,16.B, 17.A , 18.D, 19. B, 20. C , 21. D 22. C,23. A , 24. A 25. C, 26.A,
27. A , 28. B , 29. D ,30. B

MCQ Test-4, Unit 2, Engg - Chemistry, 2020-21

Uploaded by

Copyright:

Available Formats

MCQ Test-4, Unit 2, Engg - Chemistry, 2020-21

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

MCQ Test-4, Unit 2, Engg - Chemistry, 2020-21

Uploaded by

Copyright:

Available Formats

R.R.

INSTITUTE OF MODERN TECHNOLOGY

Subject Name:- Engg.Chemistry Subject Code:- KAS 202T

Course: B.Tech Branch:- CS,ME & CE

Semester : - 2 Section: A,A1& A2

] [Total Marks: - 30]

d) All of the mentioned

Q.2 The correct order of different types of energies is __________

a) Eel >> Evib >> Erot >> E tr

b) Eel >> Erot >> Evib >> E tr

c) Eel >> Evib >> Etr >> E rot

d) Etr >> Evib >> Erot >> E el

b) Basis of understanding of colors

c) Study of energetically excited reaction products

d) All of the mentioned

Q.4. The transition zone for Raman spectra is __________

a) Between vibrational and rotational levels

b) Between electronic levels

c) Between magnetic levels of nuclei

d) Between magnetic levels of unpaired electrons

Q.5. Selection rule for Raman spectroscopy-

Q.6.Which of the following shift leads to the decreased intensity of

(a) The percent transmission is not directly proportional to the concentration.

(b) The absorbance is directly proportional to the concentration.

highest concentration in the calibration range, the sample should be

Q.8. Raman effect is scattering of ________

Q10. How many degrees of freedom does a chemical compound of N atoms

Q.11 In Raman spectroscopy, the radiation lies in the ________

d) Does not depend on Δv

Q13. Raman lines are ________

Q 14. Which of the following lines are most intense?

d) All have same intensity

Q 16. IR spectrum is a plot of:

A. % Transmittance versus time

B. % Transmittance versus wavenumber

C. Peak area versus time

D. Peak area versus wavenumber

Q.18. Which of the following statements regarding IR spectroscopy is correct?

A. IR radiation is higher in energy than UV radiation

B. IR spectra records the scattering of the radiation

C. IR spectra gives information about the ƛmax of the molecule

D. IR radiation is higher in wavelength than UV radiation

Q 19.Which of the following shift leads to the increased intensity of

Q 22 . Rotational energy of rotating diatomic molecule is ...

A. E= I ω 2 / 2. B.E = j( j+2)B. C. Both A&B. D. None

Q 23. In IR spectroscopy, the number of types of bending vibrations are...

A. 200 L / g cm. B. 300 L / g cm C. 0.25 m / L D. None

A. Liquid. B. Solid. C. Gases D. None

Q 26. After absorption of light in UV spectroscopy ,electrons are exist as paired .

A. Excited singlet state

B. Excited triplet state

C. Excited doublet state

Q 27 In UV spectroscopy ,those transition required highest energy...

A. Sigma to sigma anti bonding molecular orbital

C. Non bonding to sigma ABMO

Q28. The structural group which is responsible for imparting colour to

Q 29. The spectroscopy which distinct conjugated and non conjugatrd

C. Anti- Stoke's line

27. A , 28. B , 29. D ,30. B