Annexure 1: P&ID of City Gate Station

Annexure 1: P&ID of City Gate Station
NODE-1
NODE-2
Annexure 2: SCADA controlled CNG Stations
Annexure 2: SCADA controlled CNG Stations
Sr. No. Name of Retail outlets Sr. No. Name of Retail outlets
1 BPCL COCO Belapur 51 Vashi Petroleum, Vashi

2 Gurukripa Automobiles-Sanapada 52 Airoli Service Station, Airoli
3 Dashmesh Automobiles-Sanpada 53 Suburban Auto, Bandra
4 Vashi Fuel Centre 54 A.D. Adjania, Grant Road
5 Radhakrishna Automobiles-Thane 55 Worliway Auto, Worli
6 Aiki Automobiles-Thane 56 Bajrang Auto, Marol
7 Jaimal Singh Automobiles-Thane 57 Gupta Auto, Saki Naka
8 Dashmesh Automobiles-Kurla 58 Charkop Auto, Kandivali
9 Indus Filling Station-Wadala 59 Pratiksha Nagar Depot, Wadala
10 Taj Automobiles 60 MGL TMT Depot (Outside)
11 Golden Automobiles 61 Raj Auto, Vile Parle
12 H.Irani-Byculla 62 Amar Auto, Matunga
13 Patel Brothers 63 IBP Malad
14 Tardeo Service Station 64 MGL RTO Tardeo
15 BEST Deonar Bus Depot (Captive) 65 MGL BKC House
16 BEST Deonar Bus Depot (Outside) 66 Ganesh Auto, Thane
17 New Bombay Auto 67 MSRTC Khopat (Captive)
18 CGS-Mahape Cascade Filling Station 68 Madhav Motors, Andheri
19 New Modern, Grant Road 69 Carcare Auto, Gaoregoan
20 NMMT Turbhe Captive 70 Oshiwara S.S
21 NMMT Turbhe Outside 71 Satya Shanti Auto, Dahisar
22 City Service, Prabhadevi 72 Samrudh Auto, Kurla
23 Prakash Automobiles, Juhu 73 Laxmi Auto, Thane
24 Gurunanak Auto, Andheri (E) 74 K.M Suchak, Gansoli
25 Radiant Auto Chembur 75 Gulati Auto, Vikhroli
26 Hind Automobiles, King's Circle 76 Ketki Auto, Dahisar
27 Bharat Garage , Ghatkopar (W) 77 Goregaon Auto
28 Borivali Petrol Supply Co., Borivali (W) 78 K.K Brothers, Andheri
29 National Petroleum, Dadar (W) 79 Kapadia Brothers, Malad
30 Shetkari Sahakari Sangh Ltd., Parel (E) 80 Bon Bon Auto, Andheri
31 Lakhbir Auto, Kalina 81 Bharat Coal Tar, Goregaon
32 Universal Auto, Thane 82 Jai Shri Enterprise, Badlapur
33 Dinesh Auto, Ghatkopar 83 Raj Auto, Turbhe
34 Diamond Auto, Chembur 84 Bright Brothers, Saki Naka
35 Sanjeev Auto, Deonar 85 Excel Service Station
36 Mastakar Auto, Andheri (W) 86 Highway Auto, Ghatkopar
37 MGL Dindoshi Depot (Outside), Goregaon (E) 87 Global Automobiles
38 Mahavir Auto, Kurla
39 Uganda Auto, Wadala
40 Mahavir Auto, Bhandup
41 Kaka Auto, Bhandup
42 Hind Auto, Parel
43 United Motors, Thane
44 Chamundi Auto, Borilvali
45 MGL Magathane Depot (Outside)- Dispensers only
46 MGL Owale CNG Station

47 Palm Beach CNG Outlet , Vashi
48 Mecloid's Garage, S.V. Road Khar
49 Mukund Auto, Jogeshwari
50 MGL Taloja
Annexure 3: Risk Register
Installation - City Gate Station
Risk 1 - Loss of containment of Gas in CGS Terminal
Type of Risk Risk
Applicable
Haz Type of Activity - Rating Acceptable / Classification
Hazard Description Existing Controls Legal I L
No. Hazard Routine/ Non Not Of Risk
Requirement IXL
Routine Acceptable
a) Material selection & Corrosion allowance
considered in design and maximum flow capacity
considered.
Material Corrosion/ Process b) Periodic monitoring of Corrosion coupons / Sr. No. 1, Risk
1 Routine C 0 C0 Low
Erosion Safety probe schedule 1F Acceptable
c) Regular UT measurement of pipelines and
vessels
d) External protective painting & coating
Unathorized entry to a) CGS is fenced.
Process Risk
2 CGS (Sabotage, Routine b) 20 hour security / access control at CGS Sr. no. 2 C 0 C0 Low
Safety Acceptable
Terrorist attack) c) CCTV monitoring
Breaking into the a) Clear procedure are in place for specific
process ( opening Process operations (PTW, TBT, LOTO) Sr. No. 1, Risk
3 Routine C 2 C2 Medium
pressurize equipment or Safety b) Communication schedule 1E Acceptable
piping) by error c) Blinds & plugs present on open ended valves
a) Material selection, welding procedure RT

considered in design and construction.
Failure of flange joints & Process Sr. No. 1, Risk
4 Routine b) Hydrotest, leak test & RT as per procedure. C 2 C2 Medium
valves Safety schedule 1 Acceptable
c) Flange management
d) QA/QC in place.
Incorrect installation of Process a) Pre installation equipment audit Sr. No. 1, Risk
equipment Safety b) Hydrotest, leak test & RT as per procedure. schedule 1 Acceptable
a) High pressure Alarm & shutdown (GAIL)
b) Relef valve to protect downstream over
High Pressure gas Process Sr. No. 1, Risk
6 Routine pressure C 2 C2 Medium
received from GAIL Safety schedule 1 Acceptable
c) Relieving devices installed releases extra
pressure (GAIL)
Injury due to over a) Provision of safety relief valves on the
Process Sr. No.10, Risk
7 Pressure Routine compressor. C 2 C2 Medium
Safety Rule No.15 Acceptable
Development b)Auto Tripping also provided.
Injury due to operation / Process a) STC training of compressor operator Sr. No.10, Risk
Staff In competency Safety b) Competency test at the training institute Rule No 9A Acceptable
a) Gas detectors & flame detectors are provided in

the compressor.
Gas release from Process b) CO2 Flooding system installed in compressor. Sr. No.3, Section Risk
9 Routine C 3 C3 ALARP
Compressor Safety c) Isolation of gas inventories and compressor trip 38 Acceptable
by pressing Ememrgency Isolation Switch.
d) Excess pressure vented to Blowdown vessel.
a) Vehicle impact restricted to designated areas in

Process Sr. No. 15, Risk
10 Vehicle impact Routine CGS B 3 B3 Medium
Safety section a Acceptable
b) Company driving Safety Policy.
a) PTW for load lifting

b) All lifting equipment is tested and certified from
third party ( MPI & Loat test)
11 Dropped object Routine b) Training and competency of crane opeartor B 3 B3 Medium
Safety schedule 1F Acceptable
banks man.
c) Lifting plans ( for critical lifts) and lay down SOP
followed.
a) Seismic and Meteriological data considered

Process Risk
12 Flood and Earthquake Routine during design of the plant. Sr. no. 2 B 3 B3 Medium
Safety Acceptable
b) Action as per COP/SOP contained in ERP.
Risk 2 - Loss of containment of Gas in Compressor

Type of Risk Risk
Applicable
Haz Type of Activity - Acceptable / Classification of
Hazard Description Existing Controls Legal I L Rating
No. Hazard Routine/Non Not Risk
Requirement IXL
Routine Acceptable
Failure of gas hose/
1 tubing or seal failure Routine a) Regular condition monitoring & PM C 2 C2 Medium
Safety schedule 1 Acceptable
(Gas/coolant)
2 Filter casing crack Routine a) PM and inspection of filter casing C 2 C2 Medium
Reverse flow from Process a) NRV provided on the discharge line on each Sr. No. 1, Risk
discharge header Safety stage of compressor schedule 1 Acceptable
a) Regular condition monitoring & PM
High vibration lead to Process b) High vibration trip of compressor Sr. No. 1, Risk
compressor failure Safety c) Overspeed trip of compressor schedule 1 Acceptable
d) Daily surveillance by the operators
Material Corrosion/ Process considered. Sr. No. 1, Risk
Erosion Safety b) Regaular UT measurement of pipelines and schedule 1F Acceptable
vessels
c) External protective painting
Process Risk
7 CGS (Sabotage, Routine b) 20 hour security / access control at CGS Sr. No. 2 C 0 C0 Low
Safety Acceptable
Failure of flange a) Material selection, welding procedure RT

joints & valves (also considered in design and construction.
8 in the fuel line of Routine b) Hydrotest, leak test & RT as per procedure. C 2 C2 Medium
Engine driven c) Flange management
compressor) d) QA/QC in place.

11 Dropped object Non Routine b) Training and competency of crane opeartor B 3 B3 Medium
banks man.
followed.
Process Risk
Safety Acceptable
Risk 3 - Fire/Explosion in Process Area (including compressor)

Type of Risk Risk
Applicable
Haz Type of Activity - Rating Acceptable / Classification of
Hazard Description Existing Controls Legal I L
Requirement IXL
Routine Acceptable
a) Gas detectors & flame detectors are provided in

the compressor.
b) CO2 Flooding system installed in compressor.
Gas release from Process Sr. No.3, Section Risk
1 Routine c) Isolation of gas inventories and compressor trip C 3 C3 ALARP
Compressor Safety 38 Acceptable
by pressing Ememrgency Isolation Switch.
e) Reducing probabilty of ignition
a) Gas Detection system

Gas release from Process b) Shutdown of gas inventory from GAIL's station Sr. No.3, Section Risk
process area Safety isolation valve from GAIL's remote control room 38 Acceptable
c) Reducing probabilty of ignition
a) Identify & isolate damage component of leakage
inventories and area barricaded.
Fire / Missile generation Process Sr. No.3, Section Risk
3 Routine b) Immediately stop all gas filling operations & LCV C 4 C4 ALARP
of cascades Safety 38 Acceptable
movement as per ERP
Loss of containment of Process B) Containment of inventory in the dyke area by Sr. No. 1, Risk
4 Routine D 4 D4 High
odorant Safety damming. schedule 1 Acceptable
C) Reponse clean up by absorbing with neutralizing
agent
a) CGS is fenced.
b) 20 hour security / access control at CGS
Terrorist attack / Bomb Process Risk
5 Routine c) CCTV monitoring Sr. No. 2 B 5 B5 ALARP
blast in CGS Safety Acceptable
d) Appropriate actions as per MGL Security's ERP
implemented.
Risk 4 - Loss of containment of Gas from cascades & LCV filling area
Type of Risk
Applicable Risk
Requirement IXL
Routine Acceptable
Failure of high pressure Process a)Isolation of gas inventories and compressor trip Sr. No.3, Section Risk
tubing / fittings Safety by pressing Ememrgency Isolation Switch. 38 Acceptable
Rupture of Safety disc in

Process a) Identify and close the valve of that particular Risk
2 stationary / mobile Routine C 2 C2 Medium
Safety cylinder Acceptable
cascade



banks man.
followed.
Process a)Isolation of gas inventories and compressor trip Sr. No. 1, Risk
7 Failure of filling hose Routine C 2 C2 Medium
Safety by pressing Ememrgency Isolation Switch. schedule 1 Acceptable
Missile genaration due

Process a) Location of stationary & mobile cascade loading Sr. No.3, Section Risk
8 to BLEVE in odorant Routine D 4 D4 ALARP
Safety area is designed keeping adequate distance 38 Acceptable
tank
Risk 5 - Fire / Missile generation of pressurized cylinder & cascades
Type of Risk Risk
Applicable
Requirement IXL
Routine Acceptable
Gas release from a)Isolation of gas inventories and compressor trip

Process Sr. No.3, Section Risk
1 cascades & LCV filling Routine by pressing Ememrgency Isolation Switch. C 4 C4 ALARP
Safety 38 Acceptable
area at CGS b) Reducing probabilty of ignition
a) CGS is fenced.
b) 20 hour security / access control at CGS
Terrorist attack / Bomb Process Risk
2 Routine c) CCTV monitoring Sr. No. 2 B 5 B5 ALARP
blast in CGS Safety Acceptable
d) Appropriate actions as per MGL Security's ERP
implemented.
Risk 6 - Loss of containment of odourant (from tank, during transfer, etc.)

Type of Risk
Applicable Risk
Requirement IXL
Routine Acceptable
Operational erros
a)Wedges at the wheel to stop movement
overfill of Odorant
Process b)Clear procedure are in place for specific Sr. No.14, Rule Risk
1 storage tank, tanker Routine C 2 C2 Medium
Safety operations (PTW, TBT, LOTO) no. 18 Acceptable
moves accidently during
c) Communication
filling, etc.
Malfunction of nitrogen
Process Risk
2 Regulator / hoseetc. In Routine a) Use of certified equipment NA B 3 B3 Medium
Safety Acceptable
the SBC
Buckling of odorant
storage tank due to low Process a) Natural gas blanketing provided on the Odorant Sr. No. 1, Risk
3 Routine B 3 B3 Medium
pressure during Safety Storage tank schedule 1 Acceptable
pumping
a) High Pressure alarm

Development of vapour
Process b) Scrubbing unit neutralizes the released odorant Risk
4 pressure in tank due to Routine Sr. no. 14 C 3 C3 ALARP
Safety c) Relieving devics installed releases extra pressure Acceptable
fire in vicinity
d) Automated sprinklers provided for cooling
considered.
Material Corrosion/ Process b) Periodic monitoring of Corrosion coupons / Sr. No. 1, Risk
Erosion Safety probe schedule 1F Acceptable
c) Regaular UT measurement of pipelines and
vessels
Process Risk
6 CGS (Sabotage, Routine b) 20 hour security / access control at CGS Sr. no. 2 C 0 C0 Low
Safety Acceptable
Failure of flange joints & Process Sr. No. 1, Risk
7 Routine b) Hydrotest, leak test & RT as per procedure. C 2 C2 Medium
valves Safety schedule 1 Acceptable
d) QA/QC in place.

banks man.
followed.

Process Risk
Safety Acceptable
Risk 7 - Occupational accidents

Type of Risk
Applicable Risk
Requirement IXL
Routine Acceptable
a)ELCB installed in circuit
b) Qulaified electrician / electrical license to
operate electrical equipment Sr. No.17
Risk
1 Electrocution Health Safety Routine c) PTW is issued at every work Rule No.36 C 2 C2 Medium
Acceptable
d) Use of safeguards, insulation resistance
measurement, ensuring earth fault protection
before energizing the electrical system
a) MGL approved SOP followed for working at

Sr. No.16, Risk
2 Working at hieght Health Safety Routine hieght. C 2 C2 Medium
Section 2(1)(d) Acceptable
B) PTW and use of proper harness
a) Housekeeping as per HSE policy Sr. No.3 Risk
3 Slip/trip while at work Health Safety Routine C 2 C2 Medium
b) Use of certified & complete PPE Section 41B Acceptable
Bees, bugs & reptile a) Housekeeping as per HSE policy Risk
4 Health Safety Routine - C 2 C2 Medium
bites b) Snake repellent avavilble at site Acceptable
Working in extreme a) MGL approved SOP followed for Working in Risk
5 Health Safety Routine Sr. no. 2 B 3 B3 Medium
climatic condition extreme climatic condition Acceptable
Sr. No. 16
a) PTW issused for work Risk
6 Confined entry space Health Safety Routine Section 2(1)(d) C 3 C3 ALARP
b) Working in buddy system Acceptable
a) Regular measurment of noise

Sr. No. 3
b) Warning signs/ personnel access restricted to Risk
7 Heavy noise exposure Health Safety Routine SCHEDULE XXIV C 1 C1 Medium
noise areas Acceptable
c) use of hearing protection
Sr. No.15
Sr. No.13
Working on Odorant a) PTW issused for work Risk
8 Health Safety Routine Section 4 D 4 D4 High
system b) Working in buddy system Acceptable
Sr. No. 3
Section 41B
a) Mandatory odorant awareness and escape

traing for all personnel at site
b) Emergency alarm/ siren
c) Up wind mustering with the help of wind sock to Sr. no. 3 Section Risk
9 Inhalation of toxic gas Health Safety Routine B 4 B4 ALARP
the nearest assebley point & head count 36 Acceptable
d) Search and rescue of the missing personnel &
identify the point of leakage with the help of self
contained Breathing Apparatus (SCBA)
Installation - CNG Station
Risk 1 - Loss of containment of Gas (including Compressor & Dispenser)
Risk
Type of Type of Activity -Routine/ Applicable Legal Rating Risk Acceptable / Classificatio
Haz No. Hazard Description Existing Controls I L
Hazard Non Routine Requirement Not Acceptable n Of Risk
IXL
Failure of high pressure tubing / a)Isolation of gas inventories and compressor trip by Sr. No.1, Schedule
1 Process Safety Routine C 3 C3 Risk Acceptable ALARP
fittings pressing EmergencyIsolation Switch. 1C
a)Isolation of gas inventories and compressor trip by

pressingEmergencyIsolation Switch.
Sr. No.1, Schedule
2 Failure of filling hose Process Safety Routine 'b) Breakaway coupling provided to isolate dispenser C 3 C3 Risk Acceptable ALARP
1C
during accidental pulling of hose during filling
c) Periodic replacement of hose

Failure of gas hose / tubing or Seal Sr. No.1, Schedule
3 Process Safety Routine pressingEmergencyIsolation Switch. C 3 C3 Risk Acceptable ALARP
failure ( Gas/coolant) 1C
B) Periodic replacement of Dispensing (filling) probe seal
Vehicle impact ( Dispensing a) Vehicle movvement restricted to designated areas in

4 Process Safety Routine Sr.no 15 C 3 C3 Risk Acceptable ALARP
operation) CNG Station
a) Vehicle movvement restricted to designated areas in
5 Vehicle impact (by LCV) Process Safety Routine CNG Station Sr.no 15 C 3 C3 Risk Acceptable ALARP
b) Company drving Safety policy
a) Clear procedure are in place for specific operations
Breaking into the process ( opening (PTW, TBT, LOTO)
Sr. No. 1, schedule
6 pressurize equipment or piping) by Process Safety Routine b)24 hour monitoring of operating conditions of CNG C 2 C2 Risk Acceptable LOW
1E
error Station by SCADA
c)Communication
Rupture of Safety disc in
7 Process Safety Routine a) Identify and close the valve of that particular cylinder Sr. no 14 C 3 C3 Risk Acceptable ALARP
stationery/mobile cascade
a) Regular condition monitoring & PM
High vibration lead to compressor b) High vibration trip of compressor Sr. no. 3 Section 73-
8 Process Safety Routine C 2 C2 Risk Acceptable Medium
failure c) Gas Detector in the air inlet Z
d) Daily surveillance by the operator
a) NRV provided on the discharge line of each stage of
compressor
9 Reverse flow from discharge header Process Safety Routine Sr. no. 3 C 2 C2 Risk Acceptable Medium
b) Actiuator operated ball valves on the inlet of cascades
stops reverse flow
a) Material selection, welding procedure RT considered
in design and construction.
Sr. No. 1, schedule
10 Failure of flange joints & valves Process Safety Routine b) Hydrotest, leak test & RT as per procedure. C 2 C2 Risk Acceptable Medium
1
d) QA/QC in place.
a) Pre installation equipment audit Sr. no. 1 Schedule
11 Incorrect installation of equipment Process Safety Routine C 3 C3 Risk Acceptable ALARP
b) Hydrotest, leak test & RT as per procedure 1D
b) All lifting equipment is tested and certified from third
party ( MPI & Loat test)
Sr. No. 1, schedule
12 Dropped object Process Safety Routine b) Training and competency of crane opeartor banks B 3 B3 Risk Acceptable LOW
1F
man.
followed.
a) Regular UT measurement of pipelines and vessels Sr. No. 1, schedule
13 Material Corrosion/ Erosion Process Safety Routine C 0 C0 Risk Acceptable LOW
b) External protective painting & coating 1F
a) Seismic and Meteriological data considered during
14 Flood and Earthquake Process Safety Routine design of the plant. Sr. no. 2 B 3 B3 Risk Acceptable Medium
Risk 2 - Fire/Explosion at Compressor, Dispenser area, etc.

Risk
IXL
a) Gas detectors & flame detectors are provided in the

compressor.
b) CO2 Flooding system installed in compressor.
c) Isolation of gas inventories and compressor trip by
Gas release from
1 Process Safety Routine pressingEmergencyIsolation Switch. Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
Compressor/Dispensing area
e) Identify & isloate damage component of leakage
invetories and area barricaded.
f) Reducing probabilty of ignition.
a) Overfill protection through electronically programmed
microprocessors with 2 nos. of pressure limiting device
Loss of containment of gas in per filling line
2 dispensing area due to overfilling of Process Safety Routine b) Return vent line hose for safe venting of gas in Sr. No.3, Section 39 C 4 C4 Risk Acceptable ALARP
gas in vehicle dispenser
c) Easily accessible emergency shut off valve on each
filling line of dispenser
3 Fire / Missile generation of cascades Process Safety Routine b) Immediately stop all gas filling operations & LCV Sr. No.3, Section 38 C 5 C5 Risk Acceptable ALARP
movement as per ERP

pressingEmergencyIsolation Switch.
4 Fire in adjoining petrol pump Process Safety Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
B) Shut down of Gas inventory from dispenser & /or
Compressor Isolation valve and cordon off the area
a) CCTV monitoring at MGl owned CNG station

Terrorist attack / Bomb blast in CNG
5 Process Safety Routine b) Appropriate actions as per MGL Security's ERP Sr. No. 2 B 5 B5 Risk Acceptable ALARP
Station
implemented.
Explosion during gas filling in the
6 Process Safety Routine a) No plate No gas policy Sr. no. 3 C 3 C3 Risk Acceptable ALARP
spurious cylinder of vehicle
Risk 3 - Loss of containment of Gas from cascades & LCV filling area
Risk
Type of Type of Activity - Applicable Legal Risk Acceptable / Classificatio
Haz No. Hazard Description Existing Controls I L Rating
Hazard Routine/Non Routine Requirement Not Acceptable n of Risk
IXL
Failure of high pressure tubing / a)Isolation of gas inventories and compressor trip by
1 Process Safety Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
fittings pressingEmergencyIsolation Switch.
Rupture of Safety disc in stationary /

2 Process Safety Routine a) Identify and close the valve of that particular cylinder Sr. No. 14 C 2 C2 Risk Acceptable Medium
mobile cascade
a) Pre installation equipment audit Sr. No. 1, schedule
3 Incorrect installation of equipment Process Safety Routine C 2 C2 Risk Acceptable Medium
b) Hydrotest, leak test & RT as per procedure. 1
a) Clear procedure are in place for specific operations
Breaking into the process ( opening
(PTW, TBT, LOTO) Sr. No. 1, schedule
4 pressurize equipment or piping) by Process Safety Routine C 2 C2 Risk Acceptable Medium
b) Communication 1E
error
c) Blinds & plugs present on open ended valves
a) Vehicle impact restricted to designated areas in CGS

5 Vehicle impact Process Safety Routine Sr. No. 15, section a B 3 B3 Risk Acceptable Medium

b) All lifting equipment is tested and certified from third
party ( MPI & Loat test)
Sr. No. 1, schedule
6 Dropped object Process Safety Routine b) Training and competency of crane opeartor banks B 3 B3 Risk Acceptable Medium
1F
man.
followed.
a)Isolation of gas inventories and compressor trip by Sr. No. 1, schedule

7 Failure of filling hose Process Safety Routine C 2 C2 Risk Acceptable Medium
pressingEmergencyIsolation Switch. 1
Risk 4 - Fire / Missile generation of pressurized cylinder & cascades

Risk
Type of Type of Activity - Applicable Legal Risk Acceptable / Classificatio
Haz No. Hazard Description Existing Controls I L Rating
Hazard Routine/Non Routine Requirement Not Acceptable n of Risk
IXL

pressing Emergency Isolation Switch.
Gas release from cascades & LCV b) Reducing probabilty of ignition
1 Process Safety Routine Sr. No.3, Section 38 C 4 C4 Risk Acceptable ALARP
filling area at CGS c) Identify & isloate damage component of leakage

2 Terrorist attack / Bomb blast in CGS Process Safety Routine b) Appropriate actions as per MGL Security's ERP Sr. No. 2 B 5 B5 Risk Acceptable ALARP
implemented.
Risk 5 - Inhalation of odorized Gas
Risk
IXL
a) Odorant injection in gas at CGS within the specified

limi
b)Isolation of gas inventories and compressor trip by
pressing Emergency Isolation Switch.
Gas release from
1 Process Safety Routine C) Shut down of Gas inventory from dispenser & /or Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
Compressor/Dispensing area
Compressor Isolation valve and cordon off the area
d) Identify & isloate damage component of leakage
e) Regular sampling of gas for odorant PPM check at the
extreme end of the network
Installation -DRS
Risk 1 - Loss of containment of Gas in DRS
Risk Rating
Type of Type of Activity - Applicable Legal Risk Acceptable / Not Classification
Hazard Routine/ Non Routine Requirement IXL Acceptable Of Risk
Process a)Location of DRS is finalized after consulation with

1 Vehicle impact Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
Safety consumer keeping in mind minimal vehicle
movement in the vicinity

Process considered.
2 Material Corrosion/ Erosion Routine Sr. No. 1, schedule 1F C 0 C0 Risk Acceptable Low
Safety b) Periodic monitoring of Corrosion coupons / probe
c) Regular UT measurement of pipelines and vessels
a) Clear procedure are in place for specific

Breaking into the process ( opening Process operations (PTW, TBT, LOTO)
3 Routine Sr. No. 1, schedule 1E C 2 C2 Risk Acceptable Medium
pressurize equipment or piping) by error Safety b) Communication
c) MRS is kept locked to avoid unintended access
Process
4 Failure of flange joints & valves Routine b) Hydrotest, leak test & RT as per procedure. Sr. No. 1, schedule 1 C 2 C2 Risk Acceptable Medium
Safety
d) QA/QC in place.
Process a) Pre installation equipment audit
5 Incorrect installation of equipment Routine Sr. No. 1, schedule 1 C 2 C2 Risk Acceptable Medium
Safety b) Hydrotest, leak test & RT as per procedure.
a)Awareness Campaign to avoid lifiting operations
Process in areas near SR & MRS
6 Dropped object Routine Sr. No. 1, schedule 1F B 3 B3 Risk Acceptable Medium
Safety b) Clear procedure are in place for specific
operations (PTW, TBT, LOTO)
a) High Pressure Alarm & Shutdown
Process
7 High Pressure Gas Routine b) Relieving devices installed relaeases extra Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
Safety
pressure
Process
8 Flood and Earthquake Routine a) Shut down of system Sr. no. 2 B 3 B3 Risk Acceptable Medium
Safety
Process
9 Terrorist Attack / Bomb blast Routine a) Regular Patrolling Sr. No. 2 B 5 B5 Risk Acceptable ALARP
Safety
Process a) Regular Patrolling
10 Encroachment including Sabotage Routine Sr. No. 2 C 3 C3 Risk Acceptable ALARP
Safety b) Inform authorities for removal of encroachment

Risk Rating
a) Odorant injection in gas at CGS within the
specified limit
b) Shut down of Gas inventory from dispenser & /or
Process Compressor Isolation valve and cordon off the area
1 Gas release at DRS Routine Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
Safety c) Identify & isloate damage component of leakage
d) Regular sampling of gas for odorant PPM check at
the extreme end of the network
e)Gas detection System
Risk 3 - Fire/Explosion at DRS

Risk Rating
a) Identify & isloate damage component of leakage

b) Reducing probabilty of ignition.
Process C) Shut down of Gas inventory nearest valve and
1 Gas release at DRS Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
Safety cordon off the area
d) Emergency Communication to MGL for necessary
action
e) Gas Detection System
a)Awareness campaign to civilians to keep watch of
Process
2 Fire in nearby area Routine unsafe acts in and around DRS ( MGL Sahayogi) Sr. No.3, Section 38 C 4 C4 Risk Acceptable ALARP
Safety
b) Regular Patroling

Process
4 Terrorist attack / Bomb blast in DRS Routine b) Appropriate actions as per MGL Security's ERP Sr. No. 2 B 5 B5 Risk Acceptable ALARP
Safety
implemented.
Installation - MRS
Risk 1 - Loss of containment of Gas in MRS
Risk Rating
Hazard Type of Type of Activity - Applicable Legal Risk Acceptable / Not Classification
Haz No. Existing Controls I L
Description Hazard Routine/ Non Routine Requirement IXL Acceptable Of Risk
Process a)Location of MRS is finalized after consulation

1 Vehicle impact Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
Safety with consumer keeping in mind minimal vehicle
considered.
Material
Process b) Periodic monitoring of Corrosion coupons /
2 Corrosion/ Routine Sr. No. 1, schedule 1F C 0 C0 Risk Acceptable Low
Safety probe
Erosion
c) Regaular UT measurement of pipelines and
vessels
Breaking into
the process ( a) Clear procedure are in place for specific
opening Process operations (PTW, TBT, LOTO)
3 Routine Sr. No. 1, schedule 1E C 2 C2 Risk Acceptable Medium
pressurize Safety b) Communication
equipment or c) MRS is kept locked to avoid unintended access
piping) by error
Failure of considered in design and construction.
Process
4 flange joints & Routine b) Hydrotest, leak test & RT as per procedure. Sr. No. 1, schedule 1 C 2 C2 Risk Acceptable Medium
Safety
valves c) Flange management
d) QA/QC in place.
Incorrect
5 installation of Routine Sr. No. 1, schedule 1 C 2 C2 Risk Acceptable Medium
equipment
Process in areas near SR & MRS
6 Dropped object Routine Sr. No. 1, schedule 1F B 3 B3 Risk Acceptable Medium
Safety b) Clear procedure are in place for specific
a) High Pressure Alarm & Shutdown
High Pressure Process
7 Routine b) Relieving devices installed relaeases extra Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
Gas Safety
pressure
Flood and Process
8 Routine a) Shut down of system Sr. no. 2 B 3 B3 Risk Acceptable Medium
Earthquake Safety

Risk Rating
specified limit
b) Shut down of Gas inventory from dispenser & /or
Gas release at Process
1 Routine Compressor Isolation valve and cordon off the area Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
MRS Safety
c) Identify & isloate damage component of leakage
e) Regular sampling of gas for odorant PPM check
at the extreme end of the network
Risk 3 - Fire/Explosion at MRS/SR

Risk Rating

Gas release at Process
1 Routine C) Shut down of Gas inventory nearest valve and Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
MRS Safety
cordon off the area
d) Emergency Communication to MGL for
necessary action
Terrorist attack
Process a) Unathorized entry not permitted
2 / Bomb blast in Routine Sr. No. 2 B 5 B5 Risk Acceptable ALARP
Safety b) MRS is kept locked to avoid unintended access
MRS
Process a) Shut down of Gas inventory nearest valve and
3 Fire in MRS Routine Sr. No.3, Section 38 C 4 C4 Risk Acceptable ALARP
Safety cordon off the area
Installation - SR & Domestic consumers
Risk 1 - Loss of containment of Gas in DRS
Risk Rating
Type of Activity -
Haz No. Hazard Description Type of Hazard Existing Controls Applicable Legal Requirement I L Risk Acceptable / Not Acceptable Classification Of Risk
Routine/ Non Routine IXL
a) High/low pressure shut off at Service

Regulator
b) Meter regualtor lock up pressure to 30mbar
to stop downstream piping and apparatus from
1 High Pressure Gas Process Safety Routine over pressurization Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
c) Meter regulator has inbuilt low pressure shut
off which cuts the supply through the regualtor
when the inlet pressure falls to as low as 11-15
mbar
a)Location of DRS is finalized after consulation with

2 Vehicle impact Process Safety Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
consumer keeping in mind minimal vehicle
considered.
Material Corrosion/
3 Process Safety Routine b) Periodic monitoring of Corrosion coupons / Sr. No. 1, schedule 1F C 0 C0 Risk Acceptable Low
Erosion
probe
c) Regular UT measurement of pipelines and vessels

process ( opening operations (PTW, TBT, LOTO)
4 Process Safety Routine Sr. No. 1, schedule 1E C 2 C2 Risk Acceptable Medium
pressurize equipment b) Communication
or piping) by error c) MRS is kept locked to avoid unintended access
Failure of flange joints
5 Process Safety Routine b) Hydrotest, leak test & RT as per procedure. Sr. No. 1, schedule 1 C 2 C2 Risk Acceptable Medium
& valves
d) QA/QC in place.
Incorrect installation of a) Pre installation equipment audit
6 Process Safety Routine Sr. No. 1, schedule 1 C 2 C2 Risk Acceptable Medium
equipment b) Hydrotest, leak test & RT as per procedure.
in areas near SR & MRS
7 Dropped object Process Safety Routine Sr. No. 1, schedule 1F B 3 B3 Risk Acceptable Medium
b) Clear procedure are in place for specific
9 Flood and Earthquake Process Safety Routine a) Shut down of system Sr. no. 2 B 3 B3 Risk Acceptable Medium
Terrorist Attack / Bomb
10 Process Safety Routine a) Regular Patrolling Sr. No. 2 B 5 B5 Risk Acceptable ALARP
blast
Encroachment a) Regular Patrolling
11 Process Safety Routine Sr. No. 2 C 3 C3 Risk Acceptable ALARP
including Sabotage b) Inform authorities for removal of encroachment

Risk Rating
Type of Activity -
specified limit
b) Shut down of Gas inventory from dispenser &
/or Compressor Isolation valve and cordon off the
area
1 Gas release at SR Process Safety Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
c) Identify & isloate damage component of leakage
d) Regular sampling of gas for odorant PPM check
at the extreme end of the network
e)Gas detection System
Risk 3 - Fire/Explosion at DRS

Risk Rating
Type of Activity -

C) Shut down of Gas inventory nearest valve and
1 Gas release at SR Process Safety Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
cordon off the area
d) Emergency Communication to MGL for
necessary action
e) Gas Detection System
a)Awareness campaign to civilians to keep watch of
2 Fire in nearby area Process Safety Routine unsafe acts in and around DRS ( MGL Sahayogi) Sr. No.3, Section 38 C 4 C4 Risk Acceptable ALARP
b) Regular Patroling
Installation - Pipeline & Valve Chamber
Risk 1 - Loss of containment of Gas from Steel Pipeline/Valve Chamber
Type of Activity - Risk Rating
Type of Applicable Legal
Haz No. Hazard Description Routine/ Non Existing Controls I L Risk Acceptable / Not Acceptable Classification Of Risk
Hazard Requirement IXL
Routine
a) Material selection /welding procedure & RT considered in design &
construction
b) Hydrotest, leak test & RT as per procedure
Failure/Leakage from valve/weld Process c) No flange joints in the interfield pipelines & in the valve chambers to
1 Routine Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
joints/flanges Safety avoid failure
d) QA/QC
e) Periodic maintenance & greasing of valves in valve chamber
f) Regular leak survey
a) Material selection & Corrosion allowance considered in design and
maximum flow capacity considered.
b) Periodic monitoring of Corrosion coupons / probe
Process c) Regular UT measurement of pipelines
2 Material Corrosion/ Erosion Routine Sr. No. 1, schedule 1F C 0 C0 Risk Acceptable Low
Safety d) External protective painting & coating
e) Cathodic Protection
f) Inspection of cut out section of pipeline ( opportunity based
inspections)
Breaking into the process ( opening a) Clear procedure are in place for specific operations (PTW, TBT, LOTO)
Process
3 pressurize equipment or piping) by Routine b) Communication Sr. No. 1, schedule 1E C 2 C2 Risk Acceptable Medium
Safety
error c) Pipeline laid underground with the top cover of 1.2 m.
a) Clear procedure are in place for specific operations (PTW, TBT, LOTO)
b) Awareness campaign to avoid lifting/removal of cover of valve
Process
4 Dropped object in valve chamber Routine chamber without MGL approval Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety
c) Use of approved hand tools
d) Lifting plan & lay down SOP followed
Risk 2 - Loss of containment of Gas from PE Pipeline/Valve Chamber

Routine
a) PE network designed as per IGE TD 3 & has high peiod life period of
50 years
b) Pneumatic test as per procedure
Failure/Leakage from valve/weld Process
1 Routine c) 100% leak proof joints in PE line by elctrofusion Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
joints/flanges Safety
d) QA/QC
e) Regular Leak survey
f) Condition assessment check of PE pipeline
Breaking into the process ( opening
a) Clear procedure are in place for specific operations (PTW, TBT, LOTO)
pressurize equipment or piping, Process
2 Routine b) Communication Sr. No. 1, schedule 1E C 2 C2 Risk Acceptable Medium
puncturing of pipe during excavation) Safety
c) Pipeline laid underground with the top cover of 1 m.
by error
Safety b)Leak test as per procedure.
Puncture of PE pipeline due to power Process a) 300 mm Clearance maintained during pipeline laying & separation
4 Routine Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
cable Safety tiles in place.
Risk 3 - Fire explosion from Gas released /Valve Chamber

Routine
a) Odorized gas easily detected by human nose
b) Emergency commnunication to MGL for necessary actions
d) c) Identify & isloate damage component of leakage invetories and
Gas release from Pipeline / valve Process area barricaded.
1 Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
chamber of steel pipeline Safety d) Regular sampling of gas for odorant PPM check at the extreme end
of the network
e) Isolation of gas from nearest isolation valve & vent the trap gas to
enable prompt depressurization of the affected zone.
a) Odorized gas easily detected by human nose
b) Emergency commnunication to MGL for necessary actions
d) c) Identify & isloate damage component of leakage invetories and
Gas release from Pipeline / valve Process area barricaded.
2 Routine Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
chamber of PE pipeline Safety d) Regular sampling of gas for odorant PPM check at the extreme end
of the network
e) Isolation of gas from nearest isolation valve/DRS by squeezing & vent
the trap gas to enable prompt depressurization of the affected zone.
Risk 4 - Occupational Accidents

Routine
Process a) Housekeeping as per HSE policy

1 Bees, bugs & Reptile bite Routine Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety b) Snake repellent available with the emergency repsonse team
Process a) PTW issued for work
2 Confined Sapce entry Routine Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety b) Work in buddy system
Process a) Housekeeping as per HSE policy
3 Slip/trip while at work Routine Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety b) Use of certified and complete PPE
a) SOP on working on pressurized system
Process
4 Working wit pressurized system Routine b) Use of certified and complete PPE Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety
c) Tool box talk
Working in extreme climatic Process
5 Routine SOP on Working in extreme climatic conditions Sr. No. 3 C 2 C2 Risk Acceptable Medium
conditions Safety
a) Safety briefing meeting to RT crew prior to job
Process
6 Radiation exposure Routine b) Warning signboards/access restriction to areas of radiation Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety
c) STC trained personnel
Process a) Area Barricaded with visible markers
7 Accident by vehicle to workers Routine Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety b) Working in buddy system
Process a) SOP on Working in extreme climatic conditions
8 Working at height Routine Sr. No. 3 C 2 C2 Risk Acceptable Medium
Safety b) PTW and use of proper harness
Installation - Logistics
Risk 1 - Loss of containment of Gas from cascades during transportation
Applicable Legal
Haz No. Hazard Description Type of Hazard Routine/ Non Existing Controls I L Risk Acceptable / Not Acceptable Classification Of Risk
Requirement IXL
Routine
a)Combine driving safety policy
b) Route Risk Assessment
1 Vehicle impact Process Safety Routine c) Preventive Maintainance of vehicles to maintain Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
healthiness
d) LCVs fitted with IVMS
Failure of high pressure

2 Process Safety Routine PM of tubing / fitting of mobile cascades for healthiness Sr. No.1, Schedule 1C C 3 C3 Risk Acceptable ALARP
tubing / fittings
a) Periodic replacement of rupture disc

Rupture of safety disc
3 Process Safety Routine b) common vent releases the gas to safe area Sr. No. 14 C 2 C2 Risk Acceptable Medium
in mobile cascade
c) Identify & close the valve of that particular cylinder
Dropped object during a) Dropped object protection on casade

4 Process Safety Routine Sr. No. 15 C 3 C3 Risk Acceptable ALARP
transportation b) Route Risk Assessment
Risk 2 - Fire / Missile generation from cascades during transportation

Applicable Legal
Haz No. Hazard Description Type of Hazard Routine/ Non Existing Controls I L Risk Acceptable / Not Acceptable Classification Of Risk
Requirement IXL
Routine
a) Park the LCV on left side of the road upon detectionof
Gas release from gas leakage during transportation
1 cascades during Process Safety Routine b) Close all the cylinder valves & wait till the gas release is Sr. No.3, Section 38 C 3 C3 Risk Acceptable ALARP
transportation completely vented from tubes
c) reducing probabilty of ignition
Annexure 4: Material Safety Data Sheet
MATERIAL SAFETY DATA SHEET
1. ETHYL MERCAPTAN
SECTION I: PHYSICAL DATA
Density (20 o C=68 o F)------------------------------------------------------------------------------------0.84

Viscosity at 20 o C----------------------------------------------------------------------------- 0.29 map.s
Flash Point (Open cup) ----------------------------------------------------------------------------- -53.7 oC
Vapour Pressure 20 oC------------------------------------------------------------------------- 577mbar
Vapour Pressure 50 o C----------------------------------------------------------------------- 1800mbar
Boiling Point--------------------------------------------------------------------------------------------34.7 oC
Meling Point------------------------------------------------------------------------------------------ -148 oC
Decomposition temperarure--------------------------------------------------------------------------425 o C
Lower explosive limit (Volume in air) --------------------------------------------------------------- 2.8%
Upper explosive limit (Volume in air )---------------------------------------------------------------- 18%
Autoignition temperature------------------------------------------------------------------------------300 o C
SECTION II : HAZARDS IDENTIFICATION
MOST IMPORTANT HAZARDS
HEALTH EFFECTS Harmful by inhalation and if swallowed

ENVIRONMENTAL EFFECTS Very toxic to daphnia
PHYSICAL AND CHEMICAL HAZARDS Highly flammable
Thermal decomposition giving flammable and
Toxic products.:
Hydrogen Sulphide, Oxides of Sulphur,
Oxides of carbon
SPECIFIC HAZARDS Harmful by inhalation.
Vapours may form explosive mixture with air.
Possible re-ignition of vapors from a distance.
Hazards of over pressurization in containers .
. exposed to heat explosion risk
SECTION III: FIRST AID MEASURES
GENERAL ADVICE Take off immediately all contaminated clothing

INHALATION Move to fresh air
Oxygen or artificial respiration if needed.
SKIN CONTACT Wash immediately and abundantly with soap and
Water
EYE CONTACT Wash immediately abundantly and thoroughly with
Water
INGESTION Do not induce vomiting
Hospitalize
PROTECTION OF FIRST-AIDERS In case of insufficient ventilation, wear suitable
Respiratory equipment
SECTION IV: FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Foam

Dry powder
Carbon dioxide (CO2)
SPECIFIC METHODS Cool containers / tanks with water spray.
Prohibit all sources of sparks and ignition –Do not
Smoke
SPECIAL PROTECTIVE
EQUIPMENT OR FIREGIGHTERS : In case of fire. Wear a self contained breathing apparatus.
Impermeable clothing
SECTION V: ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTION : Evacuate non-essential staff and those not

equipped with protection apparatus.
: Prohibit all sources of sparks and ignition- Do not smoke.
: Avoid contact with skin and eyes and inhalation of
Vapours
: Wear personal protective equipment
In case of leak wear a self contained breathing apparatus
ENVIRONMENTAL PROTECTION: Do not release in to the environment

: Do not let product enter into drains
: Contain by damming.
METHODS FOR CLEANING UP
Recovery Pump into an inert labelled emergency container
Absorb the remainder with an inert absorbent material.
Disposal Destroy product by oxidation with dilute solution of
Hydrogen peroxide
Sodium hypochloride
Or
Destroy the product by incineration
SECTION VI : HANDLING AND STORAGE

HANDLING
Safe handling advice keep well away from naked flames
Prohibit sources of sparks and ignition-Do not smoke
Avoid accumulation of static discharges
Use product only in a closed system.
Open drum carefully as contents may be under pressure.
Do not used air for transfer.
STORAGE
Technical measures Keep containers tightly closed in a cool well-ventilated place
/Storage condition Store away from heat and ignition sources.
Keep at temperatures below 50 °C.

Provide electrical earthling of equipment and electrical
equipment usable in explosive atmospheres.
Natural Gas
SECTION I: MATERIAL INDENTIFICATION & USE
Material: Natural Gas

Supplier’s Name: Mahanagar Gas Limited
Address: City Gate Station
City: Mumbai (Sion)
State: Maharashtra
Postal Code: 400 022
Emergency Telephone No. 4012400
Chemical Name : Natural gas

Chemical Identity : Aliphatic Mixture
Trade Name and Synonymas : Natural Gas
Product Use : Domestic/ Industrial/ Commercial
Codes / Labels : Flammable Gas – Class 2
Hazchem code : 2S–E
SECTION II: HAZARDOUS INGREDIENTS OF MATERIAL
Hazardous Ingredients Approximate Concentration

Methane (CH4) 88 – 98 % v/v
Ethane (C2H6) 2 – 8 % v/v
Other Higher Hydrocarbons < 2 % v/v
SECTION III : PHYSICAL DATA FOR MATERIAL
Physical State : Gas

Appearance : Colourless
Odour : Odourless. Ethyl Mercaptan
(C2H5SH) is added for odourisation.
Specific Gravity : 0.55-0.65
Solubility in Water at 30oC : Soluble
pH : Not Pertinent
Boiling Point : 161.5 oC
Melting Point : - 182.6 oC
SECTION IV: REACTIVITY DATA
Chemical Stability : Stable

Incompatibility with other substances : Strong Oxidisers.
Reactivity and under what conditions : No reaction with common material but may
react with oxidising agent.
-Page 1 of 3 -
SECTION V: FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability : Highly Flammable

Means of Extinction : CO2, DCP Type Fire
Extinguisher & Water Spray.
Special Procedures : Keep spraying water to cool
Upper Explosive Limit (UEL) : 15 % Volume of Gas in Air
Lower Explosive Limit (LEL) : 5 % Volume of Gas in Air
Flash Point (UEL) : -222.5 oC (CC)
Auto-ignition Temperature : 540 oC
Hazardous Combustion Products : CO2 + Traces of oxides
Explosion Data
Sensitivity to chemical Impact : May explode
Sensitivity to Static Discharge : May explode
SECTION VI: TOXICOLOGICAL PROPERTIES OF MATERIAL
Nontoxic
Skin Contact : Yes
Eye Contact : Yes
Inhalation : Yes
Effects of Exposure to human : Dizziness & Eye irritation, Ashyxition at higher
concentration.
SECTION VII: PREVENTIVE MEASURES
Personnel : Avoid direct contact

Protective Equipments : Provide self contained breathing apparatus for
higher concentrations, provide overclothing,
hand gloves, safety goggles & shoes.
Leak and Spill Procedures : Shut down all the Valve and allow proper
ventilation.
Waste Disposal : Allow the gas to burn under control.
SECTION VIII: FIRST AID MEASURES
First Aid Measures : If inhaled, remove the person to fresh air and
offer artificial respiration if required. In case of
skin contact, wash the skin with plenty of water
& soap.
Additional Information : Wash the eye with cold water in case of contact
with eyes.
- Page 2 of 3 -
SECTION IX: DISCLAMER
Information contained in this Material Safety Data Sheet (MSRDS) is believed to be reliable but
no representation, guarantee or warranties of any kind are made as to accuracy, suitability for a
particular application or results to be obtained from them. It is upto the manufacturer / seller to
ensure that the information contained in the MSDS is relevant to the product manufactured/
handled or sold by him, as the case may be. Makes no warranties expressed or implied in respect
of the adequacy of this document for any particular purpose.
- Page 3 of 3 -
A
SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006
Product: SPOTLEAK® 1007 Page: 1 / 10
SDS No.: 002027-001 (Version 2.0 ) Date 27.06.2012 (Cancel and replace : 26.06.2009)
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Identification of the product
Identification of the mixture: SPOTLEAK® 1007
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture :
Sector of use : Product category :

PC0: Strong-smelling additive for natural gas PC28: Perfumes, fragrances
SU23: Electricity, steam, gas water supply and sewage treatment
1.3. Details of the supplier of the safety data sheet
Supplier Arkema
THIOCHIMIE
420 rue d’Estienne d'Orves
92705 Colombes Cedex, France
Téléphone : +33 (0)1 49 00 80 80
Télécopie : +33 (0)1 49 00 83 96
http://www.arkema.com
E-mail address pars-drp-fds@arkema.com
E-mail address : Exposure scenario ARKEMA-THIOCHEM-REACH-USES@arkema.com
1.4. Emergency telephone number
+33 1 49 00 77 77
European emergency phone number : 112
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (Regulation (EC) No 1272/2008):

Flammable liquids, 2, H225
Eye irritation, 2, H319
Skin sensitization, 1B, H317
Chronic aquatic toxicity, 2, H411
Classification according to EU Directives 1999/45/EC :
F; R11
Xi; R43
N; R51/53
Additional information:
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.
2.2. Label elements
ARKEMA 420 rue d’Estienne d'Orves - 92700 Colombes – FRANCE

Label elements (REGULATION (EC) No 1272/2008):
Hazardous components which must be listed on the label:

2-Methylpropane-2-thiol
Hazard pictograms:
Signal word: Danger
Hazard statements:
H225 : Highly flammable liquid and vapour.
H317 : May cause an allergic skin reaction.
H319 : Causes serious eye irritation.
H411 : Toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention:
P210 : Keep away from open flames/hot surfaces. - No smoking.
P273 : Avoid release to the environment.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P303 + P361 + P353 : IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
Storage:
P403 + P235 : Store in a well-ventilated place. Keep cool.
2.3. Other hazards
Potential health effects:
May cause sensitization by skin contact. Severe eye irritation
Environmental Effects:
Harmful to algae. Harmful to fish. Toxic to daphnia. Not readily biodegradable. Slightly bioaccumulable.
Physical and chemical hazards:

Highly flammable Thermal decomposition giving flammable and toxic products
Decomposition products: See chapter 10
Other:
Results of PBT and vPvB assessment : According to REACH regulation, annex XIII, this mixture contains no substance meeting PBT and
vPvB criteria.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
1
Chemical nature of the mixture :
Hazardous components (according to Regulation (EC) No. 1907/2006) :
Classification
1 2 Classification
Chemical Name & REACH Registration Number EC-No. CAS-No. Concentration Directive
Regulation (EC) No 1272/2008
67/548/EEC
2-Methylpropane-2-thiol (01-2119491288-26) 200-890-2 75-66-1 > 50 % F; R11 Flam. Liq. 2; H225
Xi; R43 Skin Sens. 1B; H317
N; R51/53 Aquatic Chronic 2; H411
Ethyl methyl sulphide 210-868-4 624-89-5 10 - 20% F; R11 Flam. Liq. 2; H225
R52/53 Eye Irrit. 2; H319
Aquatic Chronic 3; H412

Hazardous impurities :
Classification
1 Classification
Chemical Name EC-No. CAS-No. Concentration Directive
Regulation (EC) No 1272/2008
67/548/EEC
Methanol 200-659-6 67-56-1 < 0,5 % T; R23/24/25- Flam. Liq. 2; H225
R39/23/24/25 Acute Tox. 3 (Oral); H301
F; R11 Acute Tox. 3 (Dermal); H311
Acute Tox. 3 (Inhalation); H331
STOT SE 1 (Oral / Dermal /
Inhalation); H370
1
: See chapter 14 for Proper Shipping Name
2
:See the text of the regulation for applicable exceptions or provisions : The transition time according to REACH Regulation, Article 23, is still
not expired.
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1. & 4.2. Description of necessary first-aid measures & Most important symptoms/effects, acute and delayed:
General advice:
Take off immediately all contaminated clothing.
Inhalation:
Move to fresh air. Oxygen or artificial respiration if needed. In case of persistent problems : Consult a physician.
Skin contact:
Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician.
Eye contact:
Wash immediately, abundantly and thoroughly with water. If irritation persists, consult an ophthalmologist.
Ingestion:
In case of problems : Consult a doctor.
Protection of first-aiders:
Confined space : risk of hypoxia. If entering a saturated atmosphere, wear a self contained breathing apparatus.
4.3.Indication of immediate medical attention and special treatment needed, if necessary : No data available.
5. FIREFIGHTING MEASURES
5.1.Extinguishing media
Suitable extinguishing media: Foam, Dry powder, Carbon dioxide (CO2)
Unsuitable extinguishing media: High volume water jet
5.2. Special hazards arising from the substance or mixture:

Flammable liquid, Vapours may form explosive mixture with air., Possible re-ignition of vapours from a distance, Hazards of
overpressurization in containers exposed to heat : explosion risk., Thermal decomposition giving flammable and toxic products, Hydrogen
sulphide, Sulphur oxides, Carbon oxides
5.3. Advice for firefighters:
Specific methods:
Cool containers / tanks with water spray.
Special protective actions for fire-fighters:

Wear self-contained breathing apparatus and protective suit.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures:

Evacuate non-essential staff and those not equipped with individual protection apparatus. Prohibit all sources of sparks and ignition - Do not
smoke. Prohibit contact with skin and eyes and inhalation of vapours. Use personal protective equipment. In case of leak, wear a self-
contained breathing apparatus.

6.2. Environmental precautions:

Do not release into the environment. Do not let product enter drains. Dam up with sand or inert earth (do not use combustible materials).
6.3. Methods and materials for containment and cleaning up:
Recovery:
Pump into a labelled inert emergency tank. Absorb the remainder with an inert absorbent material. Rinse with water. Recover waste water for
processing later.
Elimination:
Destroy product by oxidation with dilute solutions of : Hydrogen peroxide sodium hypochlorite or Destroy the product by incineration (in
accordance with local and national regulations).
6.4. Reference to other sections: None.
7. HANDLING AND STORAGE
7.1. Precautions for safe handling:
Technical measures/Precautions:
Storage and handling precautions applicable to products: Liquid. Highly flammable With vapours explosive in air. Sensitizing. Dangerous for
the environment. Provide appropriate exhaust ventilation at machinery. Provide showers, eye-baths. Provide self-contained breathing
apparatus nearby. Well ventilate empty vats and tanks before entering.
Safe handling advice:

Keep well away from naked flames. Take precautionary measures against static discharges. Prohibit all sources of sparks and ignition - Do
not smoke. Use product only in closed system. Do not use air for transfers. Open drum carefully as content may be under pressure.
Hygiene measures:
Prohibit contact with skin and eyes and inhalation of vapours. Remove and wash contaminated clothing before re-use. When using do not eat,
drink or smoke.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
7.2. Conditions for safe storage, including any incompatibilities:

Keep containers tightly closed in a cool, well-ventilated place. Store away from heat and ignition sources. Provide a catch-tank in a bunded
area. Provide electrical earthing of equipment and electrical equipment usable in explosive atmospheres.
Incompatible products:
Strong oxidizing agents, Acids, Bases, Reducing agents, Alkali metals
Packaging material:
Recommended: Carbon steel, Steel in absence of moisture, Stainless steel, Joints : polyethylene, Rilsan ®, polytetrafluoroethylene
(PTFE)
To be avoided: Copper and copper alloys
7.3. Specific end uses: None.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters:
Exposure Limit Values
Methanol
Source Date Value type Value Value Remarks
(ppm) (mg/m3)
EU ELV 12 2009 STEL 200 260 Indicative value, Can be absorbed through the skin.
EU ELV 12 2009 TWA 200 260 Indicative
ACGIH (US) 2007 TWA 200 – –
ACGIH (US) 2007 STEL 250 – –
ACGIH (US) 2007 SKIN – – Can be absorbed through the skin.
Derived No Effect Level (DNEL): 2-METHYLPROPANE-2-THIOL :

End Use Inhalation Ingestion Skin contact

Workers 14,5 mg/m3 (LT, SE) 2,06 mg/kg bw/day (LT, SE)
18,6 mg/m3 (LT, LE)
Consumers 2,57 mg/m3 (LT, SE) 0,74 mg/kg bw/day (LT, SE)
3,3 mg/m3 (LT, LE)
LE : Local effects, SE : Systemic effecs, LT : Long term, ST : Short term
Predicted No Effect Concentration (PNEC): 2-METHYLPROPANE-2-THIOL :
Compartment: Value:
Water 0,0067 mg/l
Marine water 0,00067 mg/l
Water (Intermittent release) 0,067 mg/l
Effects on waste water treatment plants 0,1 mg/l
Sediment 0,0535 mg/kg dw
Marine sediment 0,00535 mg/kg dw
Soil 0,00782 mg/kg dw
8.2. Exposure controls:
General protective measures: Ensure sufficient air exchange and/or exhaust in work areas
Personal protective equipment:

Respiratory protection: Self contained Breathing Apparatus
Hand protection: Splash contact, intermittent and prolonged Gloves nitrile rubber Glove thickness: 0,75 mm
Eye/face protection: Safety glasses with side-shields
Skin and body protection: At the workplace : Combination with delayed penetration
Intervention at incident: anti-acid suit
Environmental exposure controls: See chapter 6
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance:
Physical state (20°C): liquid
Colour: colourless
Odour: strong, stinging
Olfactory threshold: approximately 0,1 ppb
pH: No data available.
crystallization temperature : < -10 °C
Cloud point : < -30 °C (Standard : NF T 60 105)
Boiling point/boiling range : 64 °C
Flash point: closed cup: approx. -26 °C (Standard ASTM D 3278)
Evaporation rate: No data available.
Flammability (solid, gas):
Lower flammable limit : ETHYL METHYL SULPHIDE : 1,7 %(V)
Upper flammable limit : ETHYL METHYL SULPHIDE : 9,6 %(V)
Vapour pressure: 151 hPa , at 15 °C (calculated)
Relative vapour density: 3 Reference substance: Air=1
Density: 808 kg/m3 , at 20 °C (standard : NF 12 185)
Relative density (Water=1): 0,808 at 20 °C
Water solubility: insoluble at 20 °C
Partition coefficient: n-octanol/water: 2-METHYLPROPANE-2-THIOL : log Kow : 2,14 (calculated)
ETHYL METHYL SULPHIDE : log Kow : = 1,54 (measured)
Autoignition temperature: 238 °C (Standard NF T 60 118)
Decomposition temperature: 450 °C
Viscosity, dynamic: 0,546 mPa.s , at 20 °C (Standard ISO 3105)
Explosive properties:

Explosivity: Not relevant (due to the chemical structure)

Oxidizing properties: Not relevant (due to the chemical structure)
9.2. Other data:
Solubility in other solvents: Soluble in: Ethyl ether , Alcohol , Hydrocarbons

Refractive index: 1,427 at 20 °C
10. STABILITY AND REACTIVITY
10.1. & 10.2. Reactivity & Chemical stability:

This material is chemically stable under normal and anticipated storage, handling and processing conditions.
10.3. Possibility of hazardous reactions: No data available.
10.4. Conditions to avoid:

Keep away from heat and sources of ignition. To avoid thermal decomposition, do not overheat.
10.5. Incompatible materials to avoid:

• Reacts violently with :, Strong oxidizing agents, Hydrogen peroxide, Nitric acid, Hypochlorites, Acids, Bases, Reducing agents, Alkali metals,
Release of : sulphur dioxide
10.6. Hazardous decomposition products:
Thermal decomposition:
Decomposition temperature: 450 °C
Thermal decomposition giving flammable and toxic products, hydrogen sulfide, sulfur oxides, Carbon oxides
11. TOXICOLOGICAL INFORMATION
All available data on this product and/or the components quoted in section 3 and/or the analogue substances/metabolites have been taken
into account for the hazard assessment.
11.1. Information on toxicological effects:
Acute toxicity:
Inhalation: According to its composition, can be considered as : Slightly harmful by inhalation

2-METHYLPROPANE-2-THIOL :
• In animals : LC50/4 h/rat: 82 - 98 mg/l (Method: OECD Test Guideline 403) (vapour)
ETHYL METHYL SULPHIDE :
• In animals : No mortality/4 h/rat: 21,7 mg/l ( 6988 ppm) (Method: OECD Test Guideline 403) (vapour)
Ingestion: According to its composition, can be considered as : Slightly harmful by ingestion

• In animals : LD50/rat: 4.729 mg/kg
• In animals : LD50/rat: > 5.000 mg/kg (Method: OECD Test Guideline 401)
Dermal: According to its composition, can be considered as : Slightly harmful in contact with skin
• In animals : No mortality/rabbit: 2.000 mg/kg
• In animals : No mortality/rat: 2.000 mg/kg (Method: OECD Test Guideline 402)
Local effects ( Corrosion / Irritation / Serious eye damage ):
Skin contact: According to its composition, can be considered as : Slightly irritating to skin.
• In animals : No skin irritation (after occlusive contact, rabbit, Exposure time: 4 h)
• In animals : Mild skin irritation (OECD Test Guideline 404, rabbit, Exposure time: 4 h)
Eye contact: From its composition, it must be considered as: Irritating to eyes.


• In animals : Eye irritation (OECD Test Guideline 405, rabbit)
May be considered as comparable to a similar product for which experimental results are:
PROPANE-2-THIOL :
• In animals : Not irritating to the eyes. (rabbit)
Respiratory or skin sensitization:
Inhalation: No data available.
Skin contact: From its composition, it must be considered as: Skin sensitizer
• In animals : Weak sensitizing effects by skin contact. (Method : OECD Test Guideline 429 LLNA: Local Lymph
Node Assay, mouse)
• In animals : No skin allergy was observed (Method : OECD Test Guideline 406 Guinea pig maximization test)
CMR effects :
Mutagenicity: According to its composition, can be considered as : Not genotoxic
In vitro
Ames test in vitro: Inactive (Method: OECD Test Guideline 471)
In vitro gene mutations test on mammalian cells: Inactive (Method: OECD Test Guideline 476)
Ames test in vitro: Inactive
In vitro chromosomal abnormality test on human lymphocytes: Inactive
Through anology with a comparable product :
DIMETHYL SULPHIDE :
Ames test: Inactive (Method: OECD Test Guideline 471)
In vitro gene mutations test on mammalian cells: Inactive (Method: OECD Test Guideline 476)
In vivo
Micronucleus test in vivo rat: Inactive (Method: OECD Test Guideline 474)
Carcinogenicity: No data available.
Reproductive toxicity:
Fertility: Based on the available data, the substance is not suspected of having reprotoxic potential.
• In animals : Reproduction Test (Method: OECD Test Guideline 422, rat, By oral route)
At high dose :, Absence of toxic effects on fertility, Effects on offspring

NOAEL ( Parent ): 200 mg/kg
NOAEL ( F1 ): 50 mg/kg
DIMETHYL SULPHIDE :
• In animals : Repeated administration: Absence of toxic effects upon the reproductive system
NOAEL ( Parent ): 250 mg/kg bw/d (rat, By oral route, 14 Sem.)
Must be regarded as assimilable to its principal metabolite in vivo:
DIMETHYL SULFOXIDE :
• In animals : Reproduction Test, NOAEL: 1000 mg/kg (Method: OECD Test Guideline 421, rat, By oral route)
Foetal development: Based on the available data, the substance is not suspected of having developmental toxicity
potential.

• In animals : Exposure during pregnancy: Absence of toxic effects for foetal development. (Method: OECD Test
Guideline 414, rat, mouse, By inhalation)
NOAEL: > 195 ppm
Maternal concentration without effect: > 195 ppm

DIMETHYL SULPHIDE :
• In animals : Exposure during pregnancy: Absence of toxic effects for foetal development. (Method: OECD Test
Guideline 414, rat, By oral route)
NOAEL: 1000 mg/kg bw/jour
Maternal concentration without effect: 1.000 mg/kg
Specific target organ toxicity :

Single exposure :
Inhalation:
Olfactory threshold: approximately 0,1 ppb
At high concentrations , Risk of irritation of eyes and respiratory system
Repeated exposure: The substance or mixture is not classified as specific target organ toxicant, repeated exposure.
• In animals : By inhalation: No toxic effect directly extrapolated to humans
NOAEL= 196 ppm (Method: OECD Test Guideline 413, rat, 13 Weeks)
By oral route: Haematological problems, NOAEL= 50 mg/kg (Method: OECD Test Guideline 422, rat,
6 Weeks)
DIMETHYL SULPHIDE :
• In animals : By oral route: No adverse effects reported.
NOAEL= 250 mg/kg bw/jour (Method: OECD Test Guideline 408, rat, 14 Weeks)
Aspiration hazard: Not applicable
12. ECOLOGICAL INFORMATION
Ecotoxicology Assessment: All available data on this product and/or the components quoted in section 3 and/or the analogue
substances/metabolites have been taken into account for the hazard assessment.
12.1. Toxicity
Fish: Based on the available information, it is not possible to conclude on the hasard potential of this
mixture.
LC50, 96 h (Oncorhynchus mykiss) : = 34 mg/l (Method: OECD Test Guideline 203, pH: 7,9 - 8,4, Test
substance: Active ingredient)
Aquatic invertebrates: According to its composition, can be considered as : Toxic to daphnia.

EC50, 48 h (Daphnia) : 6,7 mg/l (Method: OECD Test Guideline 202, pH: 7,8 - 7,9, Immobilization,
Test substance: Active ingredient)
EC50, 48 h (Daphnia magna (Water flea)) : = 16 mg/l (Method: OECD Test Guideline 202,
Immobilization)
Aquatic plants: According to its composition, can be considered as : Harmful to algae.

ErC50, 72 h (Pseudokirchneriella subcapitata) : 24 mg/l (Method: OECD Test Guideline 201, pH: 7,0 -
7,8, growth rate, Test substance: Active ingredient)
ErC50, 72 h (Pseudokirchneriella subcapitata) : > 500 mg/l (Method: OECD Test Guideline 201, growth
rate)
Aquatic toxicity / Long term toxicity:

Aquatic plants:
NOEC r, 72 h (Pseudokirchneriella subcapitata (green algae)) : 6,41 mg/l (Method: OECD Test
Guideline 201, growth rate)

12.2. Persistence and degradability :
Biodegradation (In water): According to its composition, can be considered as : Not readily biodegradable.
Aerobic primary degradation: Biochemical oxygen demand 6 % after 63 d (Method: OECD Test
Guideline 301 D)

Not readily biodegradable.
41 % after 28 d (Method: OECD Test Guideline 301 D)
Photodegradation (In air):

Degradation by radicals OH: Overall half-life time: 1,9 Days, (estimation)
12.3. Bioaccumulative potential :
Bioaccumulation: According to its composition, can be considered as : Not bioaccumulable

Partition coefficient: n-octanol/water: log Kow : 2,14 (Method: calculated)
Partition coefficient: n-octanol/water: log Kow : = 1,54 (Method: measured)
12.4. Mobility in soil - Distribution among environmental compartments: No data available.
12.5. Results of PBT and vPvB assessment :
According to REACH regulation, annex XIII, this mixture contains no substance meeting PBT and vPvB criteria.
12.6. Other adverse effects: None known.
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment:
Disposal of product: Destroy product by oxidation with dilute solutions of : Hydrogen peroxide sodium hypochlorite or
Destroy the product by incineration (in accordance with local and national regulations).
14. TRANSPORT INFORMATION
UN Environmentally
Regulation
number
Proper shipping name Class Label PG
hazardous
Other information
MERCAPTANS, LIQUID, FLAMMABLE, N.O.S.(t-
yes
ADR 3336 BUTYLMERCAPTAN, METHYL ETHYL 3 3 II
SULPHIDE)
RID 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. (t- 3 3 II yes

BUTYLMERCAPTAN, METHYL ETHYL
SULPHIDE)
IATA Cargo 3336 Mercaptans, liquid, flammable, n.o.s. (t- 3 3 II yes
Butylmercaptan, Methylethyl sulfide)
IATA Passenger 3336 Mercaptans, liquid, flammable, n.o.s. (t- 3 3 II yes
Butylmercaptan, Methylethyl sulfide)
IMDG 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. (t- 3 3 II Marine pollutant EmS Number: F-E, S-D
BUTYLMERCAPTAN, METHYL ETHYL Mark: MP
SULPHIDE)
15. REGULATORY INFORMATION
Safety data sheets: according to Regulation (EC) No. 1907/2006

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:
15.2. Chemical Safety Assessment:

A Chemical Safety Assessment has been carried out for this substance. (2-Methylpropane-2-thiol)
INVENTORIES:
EINECS: Conforms to
TSCA: Conforms to
AICS: Conforms to
DSL: All components of this product are on the Canadian DSL list.
ENCS (JP): Conforms to
KECI (KR): Conforms to
PICCS (PH): Conforms to
IECSC (CN): Conforms to
NZIOC: Conforms to
16. OTHER INFORMATION
Full text of R, H, EUH-phrases referred to under sections 2 and 3
R11 Highly flammable.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
H225 Highly flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H370 Causes damage to organs.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Further information When used in formulations, contact us for labelling.

Update:
Safety datasheet sections which have been updated: Type:

2 Classification and labelling, Potential health effects, Environmental Effects Additions, Revisions
3 REACH Registration Number Additions
8 Derived No Effect Level (DNEL), Predicted No Effect Concentration (PNEC), Exposure controls, Eye Additions, Revisions
protection
9 Explosive properties, Oxidizing properties Revisions
11 Germ cell mutagenicity, Foetal development, Specific Target Organ Toxicant, Reproductive toxicity, Additions, Revisions
Carcinogenicity, Aspiration hazard
12 Aquatic toxicity, Biodegradation, Bioaccumulative potential, Distribution among environmental Revisions
compartments, PBT assessment
14 Transport information Revisions
15 Prescribed processes, Chemical Safety Assessment Additions
Thesaurus:
NOAEL : No Observed Adverse Effect Level (NOAEL)
LOAEL : Lowest Observed Adverse Effect Level (LOAEL)
bw : Body weight
food : oral feed
dw : Dry weight
vPvB : very Persistent and very Bioaccumulative
PBT : Persistent, Bioaccumulative and Toxic
This information applies to the PRODUCT AS SUCH and conforming to specifications of ARKEMA. In case of formulations or mixtures, it is
necessary to ascertain that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of
publishing and it is given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was
not intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and
codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of
the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product
to pass on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the
totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of
environment.
NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).

Annexure 5: HSE Policy
Technical Director Managing Director
Health, Safety &
Environmental Policy
Date: 21.06.2016
MGL believes that outstanding business performance requires outstanding HSE performance in the protection
of the health and safety of our people, those affected by our operations, our physical assets, our reputation
and the environment.
Our Goal is zero injuries because we believe they are all preventable. We conduct our business in a
responsible manner and to internationally accepted good practice. HSE performance is everyone’s
responsibility and we each have a duty to intervene to prevent unsafe actions and to reinforce good behavior
through demonstrating HSE leadership. Safety in all our operations is a critical success factor for our
business.
In implementing this policy we will ensure that:
§ Management decisions reflect our HSE intentions.
§ Our HSE management system reflects best industry practice and is properly resourced.
§ Continuously improve our HSE performance by acting on lessons learnt ;
§ to avoid work related ill health, accidents, and incidents,
§ to prevent pollution and
§ to minimize environmental emissions, waste and energy use.
§ Ensure and maintain compliance with all legal requirements as well as MGL Life Savers to operate our
business and which relate to its environmental aspects and OH&S risks.
§ Provide direction, education, training and supervision to ensure all employees are competent and
understand their accountabilities, the required behavior and the consequences of non compliance.
§ Ensure that our contractors and suppliers understand their HSE accountabilities and required behavior,
share our aspirations and are aware of the consequences of non compliance. We will share and learn
from each other’s experiences.
§ Work with our partners to achieve internationally accepted good practice in HSE and learn continually
from each other’s experiences.
§ Adopt a risk based approach to the design, construction and operation of our facilities across their life
cycles.
§ Educate frontline contracted staff through ‘No Safety & Technical Competency (STC) No Work’ system.
§ Involve and consult all our Stakeholders and take into account their concerns on HSE.
§ Report on our HSE objectives together with our performance and work with industry and government
agencies to improve HSE practices.
§ Our policy is used as a framework for setting and reviewing Environmental and OH&S objectives and
targets.
NB: The Policy is made available to the public and interested parties.

Annexure 6: Asset Integrity Policy
Annexure 7: AI & HSE KPIs
MGL HSSE report for the period [Month]
Report Issue date – [Monthly on 7th of each month]

Note: Report Any Fatality, LTI, Tier 1 and RAM 4+ incidents immediately
Key Highlights for the Period

1.0
Incident summaries since last report
Dashboard KPI’s For the Month YTD (Jan.17- YTD Incident Listing # / Remarks
(Mar.17) Mar.17) (April.16 –
Mar.17)
Fatality
Exposure Hours
(Million Man hours)
Lost Time Injury (LTI)/ Lost

Working Day (LWC)
LTIF
Total Recordable Cases

(MTC/RWC)
TRCF
HIPO
*API Tier1 (>500 kg)
*API Tier 2 (>50 kg)
Total damage (Steel line)
Third Party damage (Steel

line)
Total damage (MP line)(PE)
Third Party Damage ( MP

Line) (PE)
Total damage (LP line) (PE)
Third Party Damage ( LP

Line) (PE)
Total Damage (LP – GI)
Third Party Damage (LP-GI)
Total Gas leakage (Steel) –

Split for third party and
others [provide in Scm &
kgs]
Total Gas leakage (MP) –

Split for third party and
others [provide in Scm &
kgs]
Dashboard KPI’s For the Month YTD (Jan.17- YTD Incident Listing # / Remarks
(Mar.17) Mar.17) (April.16 –
Mar.17)
Total Gas leakage (LP) –
split for third party and others
[provide in scm & kgs]
Total Gas leakage (GI) –

split for third party and others
[provide in scm & kgs]
Total Kms driven
Motor Vehicle Incident (MVI)
RAM 4+ potential incidents

( Other than Pipeline
damages)
Total RAM 1 incidents – Pipe

damages

damages

damages

damages

damages
# Incident Listings; for example TRC, include date/time/location of incident & action taken; PSE, include
date/time/location of incident, action taken, LOPC quantity in (scm & Kg), chemical composition leak rate per
hour . RAM 1-5 pipeline incidents as per agreed RAM matrix
*Process Safety events: API Tier -1 - An unplanned or uncontrolled release of any (including non-toxic and non-flammable)
material at an hourly rate above a threshold quantity defined in API 754. API Tier-2 - An unplanned or controlled release of
any (including non-toxic and non-flammable) material at an hourly rate above a threshold quantity but not meeting the
requirements of a Tier-1 event.
LEADING INDICATORS
SR.
TARGET MONTH
NO. LEADING INDICATORS
1 Closure of Incident Investigation Recommendations
2 Closure of Shell HSSE audit
Number of Near misses, Hazards and Suggestions
3
reported
4 HSE Training Man days
5 HSE Key Contractor Performance Evaluation (CPE)
6 Senior Management Tours (SMT)
Other Details for the Month (not reported above) – (Personal Safety, AIPSM, and Environment & General)
Please provide details of key events/ issues only
Personal Safety
AIPSM
Environment
General
Annexure 8: List of Safety Critical Elements with Performance Standards
Grouping of SCEs for Performance Standards Rev-01
Corrosion Odorant Injection Electrical & Ignition First Aid & Fire Suppression
Containment Alarm & Shut Down Relieving Devices Fire & Gas Detection Security Communication
Management System Control Escape System
PS No. 01 PS No. 02 PS No. 03 PS No. 04 PS No. 05 PS No. 06 PS No. 07 PS No. 08 PS No. 09 PS No. 10 PS No. 11
Actuator operated ball valves Cathodic protection Compressor trip logic Level Transmitter in Fire detector in Access control Overload Protection & Emergency CO2 Flooding unit
Creep relief valves in SR First Aid Kit
of cascades system System Odorant Tank compressor system Earth Fault Relays Alarm/Siren for compressor
Junction Boxes &

Diode stations/
Blinds & Plugs for open Domestic/ Meter PSV/SRV (Including of Odorant Injection Electrical Equipment Fire Hydrants &
devices for electrical Gas detector CCTV Stretcher SCADA system
ended valves Regulator GAIL) pump (Classified Electrical Hoses
Continuity
Equipment)
Corrosion coupon and Emergency shutoff valve Small Bulk Container
Break away coupling Rupture disc CGS fencing Circuit Breaker Fire Blanket Fire Monitors
Probes on filling line (SBC)
Scrubbing unit for
Remote monitoring TR ESD switch / Emergency Chain link fencing /
Cylinder valve neutralising odorant Emergency lighting SCBA Fire Water pump
unit Isolation Switch Boundary wall
vapour
Electronic Pressure Lock Lighting Panel &
Neutralising Agent Lock on DRS Shower & Eye Fire Water sprinkler
System to avoid accidental Emergency vehicle fixtures at classified
(ekoperl66) enclosures wash station on odorant tank
starting of LCV Area
Safety lock system PPE (including
Lightening Arrestor Portable Fire
Dyke wall & Dyke Wall valve Isolation Valve for LCV during Work Vest, High
(Protection) extinguishers
Filling of cascade Visibility Jacket)
Vehicle tracking Spark Arrestor of
NRV Over speed trip of Engine Wind Sock
Devices Vehicle
Dispensing hose & probe Pressure Transmitter
UPS Safety Signage
assembly (Including of GAIL)
Portable Electrical
Cascade protection guard SDV (GAIL)
Equipment
Concrete Block Service Regulator
Overfill Protection System
Crash Guard
in Dispenser
Slam Shut valves (SSA)
RCC Crimp Guard
(Including of GAIL)
Rodent Tape/Sleeve Vibration sensor/Switch
Fire Water Header
Wedges
Pressure Switch
Temperature Transmitter
in CNG Compressor

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Annexure 1: P&ID of City Gate Station

1 BPCL COCO Belapur 51 Vashi Petroleum, Vashi

45 MGL Magathane Depot (Outside)- Dispensers only

46 MGL Owale CNG Station

a) Material selection, welding procedure RT

a) Gas detectors & flame detectors are provided in

a) Vehicle impact restricted to designated areas in

a) PTW for load lifting

a) Seismic and Meteriological data considered

Risk 2 - Loss of containment of Gas in Compressor

Failure of flange a) Material selection, welding procedure RT

Breaking into the a) Clear procedure are in place for specific

Risk 3 - Fire/Explosion in Process Area (including compressor)

a) Gas detectors & flame detectors are provided in

a) Gas Detection system

Rupture of Safety disc in

Breaking into the a) Clear procedure are in place for specific

a) Vehicle impact restricted to designated areas in

a) PTW for load lifting

Missile genaration due

Gas release from a)Isolation of gas inventories and compressor trip

Risk 6 - Loss of containment of odourant (from tank, during transfer, etc.)

a) High Pressure alarm

a) PTW for load lifting

a) Seismic and Meteriological data considered

Risk 7 - Occupational accidents

a) MGL approved SOP followed for working at

a) Regular measurment of noise

a) Mandatory odorant awareness and escape

a)Isolation of gas inventories and compressor trip by

a)Isolation of gas inventories and compressor trip by

Vehicle impact ( Dispensing a) Vehicle movvement restricted to designated areas in

Risk 2 - Fire/Explosion at Compressor, Dispenser area, etc.

a) Gas detectors & flame detectors are provided in the

a)Isolation of gas inventories and compressor trip by

a) CCTV monitoring at MGl owned CNG station

Rupture of Safety disc in stationary /

a) Vehicle impact restricted to designated areas in CGS

a) PTW for load lifting

a)Isolation of gas inventories and compressor trip by Sr. No. 1, schedule

Risk 4 - Fire / Missile generation of pressurized cylinder & cascades

a)Isolation of gas inventories and compressor trip by

a) CCTV monitoring at MGl owned CNG station

a) Odorant injection in gas at CGS within the specified

Process a)Location of DRS is finalized after consulation with

a) Material selection & Corrosion allowance

a) Clear procedure are in place for specific

Risk 2 - Inhalation of odorized Gas

Risk 3 - Fire/Explosion at DRS

a) Identify & isloate damage component of leakage

a) CCTV monitoring at MGl owned CNG station

Process a)Location of MRS is finalized after consulation

Risk 2 - Inhalation of odorized Gas

Risk 3 - Fire/Explosion at MRS/SR

a) Identify & isloate damage component of leakage

a) High/low pressure shut off at Service

a)Location of DRS is finalized after consulation with

Breaking into the a) Clear procedure are in place for specific

Risk 2 - Inhalation of odorized Gas