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CHAPTER 2

MATTER AND SOLUTIONS



Solubility အေျခခံသေဘာတရားမ်ား

ေကာ္ဖီမစ္ + သၾကား + ေရေႏြး à ေကာ္ဖီ

1 ထုုပ္ + 2 ဇြန္း + 400ml à 1 ခြက ္

+ + à 2 ခြက ္
+ + à 3 ခြက ္
+ + à 4 ခြက ္
+ + à 5 ခြက ္
+ + à 10ခြက ္
+ + à 0.5ခြက ္

သၾကား + ေရ à သၾကားေပ်ာ္ရည္၂၀ါ
20g + 100g à 120g

40g + à
60g + à
80g + à
100g + à
200g + à
10g + à


ဆား + ေရ à ဆားးေပ်ာ္ရည္၂၀ ၂၀ါ
50g + 100g à 150g
+ à 300g
+ à 450g
+ à 600g
+ à 750g
+ à 1500g
+ à 75g

1





ေဆးမFႈုန္႔ + ေရ à ေဆးေပ်ာ္ရည္
10g + 100g à 110g
+ 200g à
+ 300g à
+ 400g à
+ 500g à
+ 1000g à
+ 50g à


Example 1
Solid A + water à Saturated solution
40g + 100g à 140g
20g ?
40g of solid A à 140g of saturated solution
20g of solid A à ?
!"# %& '%()* +
= x 140g of saturated solution
,"# %& '%()* +
= 70 g of saturated solution
Example 2
Solid A + water à Saturated solution
40g + 100g à 140g
20g ?









Example 3
Solid A + water à Saturated solution
40g + 100g à 140g
? 50g



2





Example 4
Solid A + water à Saturated solution
40g + 100g à 140g
50g ?







Example 5
Solid A + water à Saturated solution
40g + 100g à 140g
? 70g









Example 6
Solid A + water à Saturated solution
40g + 100g à 140g
? 70g











3





Example 7
Salt + water à Saturated solution
60g + 100g à 160g
120g ?







Example 8
Salt + water à Saturated solution
60g + 100g à 160g
120g ?









Example 9
Salt + water à Saturated solution
60g + 100g à 160g
? 200g











4





Example 10
Salt + water à Saturated solution
60g + 100g à 160g
200g ?








Example 11
Salt + water à Saturated solution
60g + 100g à 160g
? 320g









Example 12
Salt + water à Saturated solution
60g + 100g à 160g
? 320g










5





Exercise 2.1

1. The solubility of sodium nitrate at 40°C is 140g/100g water.
(a) How much sodium nitrate will be obtained if 25.5g of saturated solution at
40°C is evaporated to dryness?
(b) What is the maximum amount of solid that can be dissolved in 250g of
water at 40°C?
































6





2. The solubility of solid A at 60°C is 24g/100g water.
(a) What is the amount of solid required to saturated 30g of water at 60°C?
(b) What will be the amount of saturated solution obtained at 60°C when
12g of the solid A is used to prepare a saturated solution?



































7





3. 20g of a soluble substance is dissolved in water to from 100g of the solution.
25g of solution is taken and evaporated to dryness. How many grams of
the solid will be obtained?




































8





Temperature တိုးေလ်ွာ့လုပ္ေသာ Solubility အေျခခံေမးခြန္းမ်ား

Example 13


Temperature(°C) 0°C 10°C 20°C 30°C 40°C 50°C
Solubilities 15 30 40 55 75 65
(g/100g of water)

From 10°C to 30°C
30g – 55g = -22g
the amount of solid dissolved = 22g

From 20°C to 50°C




From 30°C to 0°C
55g-15g = 40g
The amount of solid come out = 40g


From 40°C to 50°C




From 50°C to 40°C




From 0°C to 30°C




9





Example 14


Temperature(°C) 0°C 20°C 40°C 60°C 80°C 100°C
Solubilities 5 15 25 50 40 30
(g/100g of water)

From 0°C to 40°C




From 60°C to 100°C




From 80°C to 40°C




From 60°C to 0°C




From 20°C to 80°C




From 40°C to 60°C





10





Exercise 2.2
1. The solubility (g/100g water) of three substances at different temperature
are given below.


Temperature(°C) 0 10 20 30 40 50 60 70 80
Potassium chlorate 3.3 5.0 7.3 10.0 14.0 18.5 24.0 30.2 37.5
Calcium hydroxide 0.13 0.13 0.12 0.11 0.10 0.00 0.08 0.06 -
Sodium sulphate 5.0 9.0 20.5 41.0 48.0 47.0 45.0 44.0 43.0

(a) Plot the solubility curve of each substance.
(b) Describe the change in solubility with the temperature for each substance.
(c) What is the solubility of each substance at 25°C?
(d) What happens when each solution at 70°C is cooled down to 30°C?

























11





2. The solubility of copper (II) sulphate at 60°C is 40g/100g and 90°C is 67.5g/100g.
A saturated solution of copper (II) sulphate in 100g of water at 90°C is cooled
to 60°C. Calculate the amount of copper (II) sulphate which would come out of
the solution.

































12





CHAPTER 3
THE ELECTRONIC STRUCTURES OF ATOMS
AND PERIODIC TABLE

ဒီဇယားကြက္ေလး အရင္ျဖည့္ၾကည့္။

Particle Symbol Relative mass Relative charge


Proton
Neutron
Electron

Example 1
What are the symbols, charges and masses of neutron and electron?

Particles Symbols Relative masses Relative charges

neutron
electron

ဒီဇယားကြက္ေလး အရင္ျဖည့္ၾကည့္။

𝟐𝟑 𝟑𝟓 𝟒𝟏 𝟏 𝟏𝟒 𝟑𝟗 𝟐𝟒 𝟒 𝟐𝟕 𝟑𝟏
𝟏𝟏 𝐍𝐚 𝟏𝟕𝐂𝐥 𝟐𝟎 𝐂𝐚 𝟏𝐇 𝟕𝐍 𝟏𝟗 𝐊 𝟏𝟐 𝐌𝐠 𝟐𝐇𝐞 𝟏𝟑𝐀𝐥 𝟏𝟓𝐏
Element Na
Mass number 23
Atomic number 11
Protons 11
Electrons 11
Neutrons 23-11 = 12
!,
Possible isotopes BBNa

13





Example 2
Determine the number of electrons, protons and neutrons for3517Cl.Write
down its possible isotopes.
number of electrons =
number of protons =
number of neutrons =
35
possible isotopesof 17Cl =

Example 3
Select the isotopes from the following and give reasons for your answer.
35 39 16 37 39
17Cl , 19K, 8O, 17Cl, 17Cl
………………..and ………………..are isotopes.
Because……………………………………………………………………………………………………….……
………………………………………………………………………………………

Example 4
Select the isobars from the following and give reasons for your answer.
35 23 40 37 39
17Cl , 11Na , 20Ca , 17Cl, 19K
………………..and ………………..are isobars.
Because……………………………………………………………………………………………………….……
………………………………………………………………………………………

Example 5
Write down the notation of isotopes for an element ‘X’. Express the
corresponding terms.
……………………………..
……………………………..
……………………………..

Example 6
In a neutral atom of an element, the number of a certain particle or particles
is equal to the atomic number. Name the particle or particles.
atomic number = ………………………………………….
atomic number = ………………………………………….

14





Exercise 3.1

1. What are the symbols, charges and relative masses of neutron and
protons.
particles symbols relative masses Relative charges

neutron
proton
2. What are the symbols, charges and relative masses of neutron and
electrons.
particles symbols relative masses Relative charges

neutron
electrons

3. Determine the number of electrons , protons and neutrons for 𝟑𝟕
𝟏𝟕𝑪𝒍.
number of electrons =
number of protons =
number of neutrons =

4. What are the number of protons, neutrons and electrons in the atom
of 𝟐𝟕
𝟏𝟑𝑨𝒍?.Write down its possible isotopes.
number of protons =
number of neutrons =
number of electrons =
𝟐𝟕
possible isotopes of 𝟏𝟑𝑨𝒍 =

5. Find the number of protons ,electrons and neutrons in 𝟒𝟎
𝟐𝟎𝑪𝒂 and give
possible isotopes.
number of protons =
number of electrons =
number of neutrons =
𝟒𝟎
possible isotopes of 𝟐𝟎𝑪𝒂 =

15





6. Determine the number of protons, electrons and neutrons in the atom of
element 'E' which has the atomic number of 18 and, mass of 40. Give
possible isotopes.
number of protons =
number of electrons =
number of neutrons =
𝟒𝟎
possible isotopes of 𝟏𝟖𝑬 =

7. Determine the number of protons, electrons and neutrons in the atom of
the element 'E' which has the atomic number 14 and mass number 28.
Give the possible isotopes.
number of protons =
number of electrons =
number of neutrons =
𝟐𝟖
possible isotopes of 𝟏𝟒𝑬 =

8. Fine the number of protons ,electrons and neutrons in 𝟏𝟐𝟔𝑪.
number of protons =
number of electrons =
number of neutrons =













16





ဒီဇယားကြက္ေလး အရင္ေလ့က်င့္ၾကည့္။

Shell no. Name Maximum number of electron (2n2)
1
2
3
4

Example 7
Give the maximum number of electrons in shell number 2 and 4.
Shell number Name Maximum number of electrons(2n2)
2

17





ဒီဇယားကြက္ေလး အရင္ေလ့က်င့္ၾကည့္။
Atomic Symbol Name IES CES EES G P V
number
1

10

11

12

13

14

15

16

17

18

19

20

18





Diagram ဆြဲက်င့္ၾကည့္ၾကစို႔။

1H 2He 3Li 4Be

5B 6C 7N 8O

9F 10Ne 11Na 12Mg

19





13Al 14Si 15P 16S

17Cl 18Ar 19K 20Ca

20





Example 8
Write down the complete and essential electronic structure of 11Na and 12Mg.

Complete electronic structure of 11Na =


Complete electronic structure of 12Mg =
Essential electronic structure of 11Na =
Essential electronic structure of 12Mg =

Example 9
Write down the group number , period number and chief valence of the following. 13Al ,
19K , 2He

Element Group number Period number Chief valence


13Al
19K
2He

Example 10
Write down

a) the complete electronic structure.


b) the essential electronic structure.
c) the group number.
d) the period number of the following element 12Mg and 17Cl.
(a) Complete electronic structure of Mg =
Complete electronic structure of Cl =
(b) essential electronic structure of Mg =
essential electronic structure of Cl =
(c) group number of Mg =
group number of Cl =
(d) period number of Mg =
period number of Cl =





21





ဒီဇယားကြက္ေလး အရင္ေလ့က်င့္ၾကည့္။

Group number Types of elements Name
I A Alkali metal Li , Na , K
II A
VII B
0

Example 11
Classify the following elements as alkali metal, alkaline earth metal , halogen and noble gas.
11Na, 17Cl , 10Ne, 12Mg

Alkali metal =
Alkaline earth metal =
Halogen =
Noble gas =

Example 12
Classify the following elements in their appropriate group number.
3Li, 17Cl, 20Ca, 8O, 11Na, 16S, 9F, 12Mg

Group IA =
Group IIA =
Group VIB =
Group VIIB =

22





Exercise3.2
1. Give the maximum number of electrons in shell number 1 and 3.
Shell number Name Maximum number of electrons(2n2)

1
3
2. Give the maximum number of electrons in L shell and M shell.
Shell number Name Maximum number of electrons(2n2)
L
M
3. Write down the complete and essential electronic structure of 7N and 20Ca.
Complete electronic structure of 7N =
Complete electronic structure of 20Ca =
Essential electronic structure of 7N =
Essential electronic structure of 20Ca =

4. Write down the complete and essential electronic structure of 1H and 18Ar.
Complete electronic structure of 1H =
Complete electronic structure of 18Ar =
Essential electronic structure of 1H =
Essential electronic structure of 18Ar =

5. Write down the complete and essential electronic structure of 14Si and 15P.
Complete electronic structure of 14Si =
Complete electronic structure of 15P =
Essential electronic structure of 14Si =
Essential electronic structure of 15P =

6. Write down the complete and essential electronic structure of 3Li and 2He.
Complete electronic structure of 3Li =
Complete electronic structure of 2He =
Essential electronic structure of 3Li =
Essential electronic structure of 2He =




23





7. Complete the following table;
Element Integer Complete Electronic Structure Essential Valence
Electronic Electronic
Structure Structure
Li 1s2 2s1 2s1
2 2 1
B 1s 2s 2p 3
1
Na 2.8.1 3s
2 2 6 2 1
Al 2.8.3 1s 2s 2p 3s 3p
1
2.8.8.1 4s
2.8.7 3s2 3p5

8. You are given the following elements; A to G represent unknown elements.
10A, 17B , 3C , 9D , 11E , 18F , 19G
(a) Write down the electronic structures of these elements.
(b) Which elements are alkali metals?
(c) Which elements are noble gases?
(d) Which elements are halogen?
(e) Which elements are s-block elements?

(a) Electronic structure of 10A=
Electronic structure of17B =
Electronic structure of3C =
Electronic structure of9D=
Electronic structure of11E=
Electronic structure of18F=
Electronic structure of19G=
(b) Elements ……………………………………… are alkali metals.
(c) Elements ……………………………………… are noble gases.
(d) Elements ……………………………………… are halogen.
(e) Elements ……………………………………… are s-block elements.

24





9. (a) How many electrons, neutrons and protons are there in the following elements?
Write down their complete electronic structures.
12 56 35 40 48 55 45
6C, 26Fe , 17Cl , 20Ca , 22Ti, 25Mn, 21Sc

1s 2s 2p 3s 3p 4s 3d 4p 5s ………..

Elements Number of Number of Number of Complete Electronic Structure
Electrons Neutrons Protons
12
6C
56
26Fe
35
17Cl
40
20Ca
48
22Ti
55
25Mn
45
21Sc

(b)Write the complete symbol for the atom with the given atomic number (Z) and
atomic mass (A).

(i) Z=17 , A = 35 (ii) Z=12 , A = 24 (iii) Z=4 , A = 9 (iv) Z=19 , A = 39

(b)(i)

(ii)

(iii)

(iv)

25





10. (a) Draw diagrammatic representation of the following atoms by using shell or energy
level:
(a) 49 Be (ii) 919 F (iii) 1428 Si (iv) 1939 K

(i) 49 Be (ii) 919 F (iii) 1428 Si (iv) 1939 K

(b) For the elements in above question, give the valence electrons and the number of

neutrons for each.

Elements Valence electrons Number of neutrons

(i) 49 Be

(ii) 919 F

(iii) 1428 Si

(iv) 1939 K

11. (a) Rewrite the correct complete electronic structures given below.

(i)1s2 2s2 2p4 3s2 (ii) 1s2 2s1 2p6 (iii) 1s2 2s2 2p6 3P3 3s2 (iv) 1s2 2s2 2p63s2 3P5 4s2

Given Complete Electronic Structure Correct Complete Electronic Structure

(i)1s2 2s2 2p4 3s2

(ii) 1s2 2s1 2p6

(iii) 1s2 2s2 2p6 3P3 3s2

(iv) 1s2 2s2 2p63s2 3P5 4s2

26





(b)What are the atomic numbers of elements whose outermost electrons are represented
by (i) 3s1 (ii) 2s22p3 (iii) 3s23p5 ?

(i) 3s1 =

(ii) 2s22p3 =

(iii) 3s23p5 =

12. Which atoms are indicated by the following configurations?


(a) [ He ] 2s1 (b) [ Ne ] 3s2 3p3 (c) [ Ar ] 4s2

Configurations Atoms

(a) [ He ] 2s1

(b) [ Ne ] 3s2 3p3


(c) [ Ar ] 4s2

13. (a) Write the complete and essential electronic structures using noble gases as a core
for Li, O, Mg, Al, Cl, Ca.

Elements Complete Electronic Structure with a noble gas core Essential Electronic
Structure

Li

Mg

Al

Cl

Ca

27





(b) Give the group ,period and valence of the above elements.

Elements Group Period Valence

Li

Mg

Al

Cl

Ca

(c) Which of the above element is in period 3 and group II?


……………………. is in period 3 and group II.

14. An element X in period 3 of the Periodic Table has six outer shell electrons.

(a) In which group of the Periodic Table is X?

(b) What is the name and symbol of X?

(c) How many electron shells are there in an atom of X?

(d) Is the element X a metal or non-metal?

(e) What is the atomic number of the element X?

(a) Element X is in group…………………….

(b) The name and symbol of X is ……………………

(c)There are ……………………………………….in an atom of X.

(d) The element X is a ……………………………

(e) The atomic number of the element X is………………………

28





15. Complete the following table and answer the following questions:

Element X Element Y Element Z

Atomic number 11 6 …………….

Number of protons ……………. ……………. 16

Number of neutrons 12 6 16

Mass number ……………. 12 32

Electronic structure 2.8.1 ……………. …………….

Valence ……………. 4 …………….

Position in Periodic Table ……………. ……………. group VI, period 3

(a) Which of the above elements X,Y and Z is a metal?


Element ………………….. is a metal.
(b) What type of bonding exists between X and Z?
Write down the most likely formula of this compound using the symbols X and Z.
………………………………. bonding exists between X and Z.
Formula =…………………………..
16. Classify the following elements as alkali metal,alkaline earth metal, halogen and noble
gas.
3Li, 12Mg, 9F, 4Be, 10Ne, 11Na, 17Cl, 2He.
Alkali metal =
Alkaline earth metal =
Halogen =
Noble gas =
17. Classify the following elements in their appropriate group number.
3Li, 17Cl, 20Ca, 8O, 11Na, 16S, 12Mg, 19K, 1H, 4Be, 9F, 2He, 10Ne, 7N, 14Si
Group IA =
Group IIA =
Group IIIB =
Group IVB =
Group VB =
Group VIB =
Group VIIB =
Group 0 =

29






Ionic size
Positive ion < Parent atom
Negative ion > Parent atom

Example 13
From the following groups, select the one which has the largest radius. Give reason.
(a) Fe 2+ , Fe 3+
(b) Cl , Cl-
(a) Fe 2+ , Fe 3+
Fe 2+ is formed by removal of two electrons from Fe atom.
Fe 3+ is formed by removal of three electrons from Fe atom.
They both have the same nuclear charges.
Number of electrons Fe2+ > Fe3+
Repulsion between electrons Fe2+ > Fe3+
Size Fe2+ > Fe3+
(b) Cl , Cl-
Cl – is formed by addition of one electron to Cl atom.
They both have the same nuclear charges.
Number of electrons Cl< Cl-
Repulsion between electrons Cl< Cl-
Size Cl< Cl-

Example 14
From the following elements, select the one which has the largest radius. Give
reasons.4Be , 12Mg, 20Ca and 6C, 7N, 9F.
4Be, 12Mg, 20Ca
They are in the same group.
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
Atomic radius ( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
Atomic radius è 4Be<12Mg< 20Ca
20Ca has the largest radius.

6C , 7N, 9F
They are in the same period.
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
Atomic radius ( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
Atomic radius è 6C>7N >9F
6C has the largest radius.

30





Exercise 3.3
1. Select the one which has the larger radius between Br and Br-. Give reason for your
answer.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
2. From the following , select the one which has the largest radius. Give reason for your
answer. Fe , Fe2+ , Fe3+.
………….. is formed by……………………. of ……….. electron to ………atom.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
3. From the following pair, select the one which has the largest radius. Give reason for
your choice. F and F-.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………

4. From the following element select the one which has the largest radius.
(i) 4Be, 12Mg, 20Ca (ii) 5B , 6C, 9F
(i) 4Be, 12Mg, 20Ca
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… ………………………………….
è
………………………..has the largest radius.
(ii) 5B , 6C, 9F
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… ………………………………….
è
………………………..has the largest radius.

31





5. In each of the following groups, select the one which has the largest radius.
(i) Fe, Fe2+, Fe3+ (ii) S, S2- (iii) Li, Na, K (iv) C, N,O
(i) Fe, Fe2+, Fe3+
………….. is formed by……………………. of ……….. electron to ………atom.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
(ii) S, S2-
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
(iii) Li, Na, K
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… è ………………………………….
………………………..has the largest radius.
(iv) C, N,O
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… è ………………………………….
………………………..has the largest radius.
6. From the following elements, select the one which has the lowest ionisation energy.
Give reason. 3Li, 9F, 10Ne.
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… è ………………………………….
………………………..has the lowest ionisation energy.
7. Explain which one has the largest ionisation energy : 2.8.1 , 2.8.5 , 2.8.7.
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… ………………………………….
è
………………………..has the largest ionisation energy.

32





8. Arrange which of the following elements in order to their increasing
electronegativity and give reason ; Oxygen, Carbon, Fluorine , Nitrogen
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.


XYZ[\]^XY_ \`\Za[bY\_]aXcXad
































33





Ionic bond
Ø Metals + Non-metals
(I,II) + (VI,VII)
Ø Complete transfer of electron(s)
Ø Formation of cation and anion
Ø Strong electrostatic attraction
Li F
Na Cl
K O
Mg S
Ca
LiF





Lithium Fluorine

(2.1) (2.7)

NaCl

KCl

34





NaF

KF

CaCl2

MgCl2

CaF2

MgF2

35





Covalent bond

Ø Non-metal + Non-metal
Ø Sharing of electron(s)
Ø Weak intermolecular forces
Ø 2 types
(Atoms of the same element) , (Atoms of different elements)
(e.g. H2,O2,N2,Cl2) (e.g. CO2, H2O, NH3,CH4)

Atoms of the same element

Cl2

H2

O2



N2


36





Atoms of different elements

CO2

H2O

NH3

CH4

37





Exercise 3.3
1. Lithium has the electronic structure 2.1. Fluorine has the electronic structure 2.7.
Lithium and fluorine react together to form an ionic lithium fluoride. Draw the
arrangement of electrons in fluorine and lithium. Explain how ionic bond is formed
in lithium fluoride.















2. Carbon has the electronic structure 2.4. Chlorine has the electronic structure 2.8.7.
Draw the structure of the compound formed between carbon and chlorine.

38





CHAPTER 4
THE QUANTITIES OF SUBSTANCES:
CHEMICAL CALCULATIONS


Group (I)

§ Molecular mass(amu)

§ Formula mass(amu)

§ Relative molecular mass(unitless)
§ Relative formula mass(unitless)

Example 1


What is the molecular mass of carbon dioxide , CO2 ? The relative atomic

mass of carbon and oxygen are 12 and 16 , respectively.

𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇𝑪𝑶𝟐 𝟏 𝒂𝒕𝒐𝒎 𝒐𝒇𝒄𝒂𝒓𝒃𝒐𝒏 𝟐 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 𝒐𝒙𝒚𝒈𝒆𝒏

= (1 x 12) + (2 x 16)

= 12 + 32

= 44 amu

Example 2

What is the relative molecular mass of carbon dioxide,CO2? The relative


atomic mass of carbon and oxygen are 12 and 16 , respectively.

𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆


𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪𝑶𝟐 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝟏 𝒂𝒕𝒐𝒎 𝒐𝒇𝒄𝒂𝒓𝒃𝒐𝒏 𝟐 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 𝒐𝒙𝒚𝒈𝒆𝒏

= (1 x 12) + (2 x 16)

= 12 + 32 = 44

39





Example 3


Calculate the formula mass of copper (II) sulphate, CuSO ?


4
(Given; Cu = 63.5amu, S=32amu, O=16amu)
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 𝑪𝒖𝑺𝑶𝟒 𝟏𝒂𝒕𝒐𝒎 𝒐𝒇 𝑪𝒖 𝟏𝒂𝒕𝒐𝒎 𝒐𝒇 𝑺 𝟒𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 𝑶

= ( 1 x 63.5) + ( 1x 32 ) + (4 x 16)

= 63.5 + 32 + 64

= 159.5 amu

Example 4


Calculate the relative formula mass of copper (II) sulphate, CuSO ?


4
(Given; Cu = 63.5amu, S=32amu, O=16amu)
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 𝑪𝒖𝑺𝑶𝟒 𝟏𝒂𝒕𝒐𝒎 𝒐𝒇 𝑪𝒖 𝟏𝒂𝒕𝒐𝒎 𝒐𝒇 𝑺 𝟒𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 𝑶

= ( 1 x 63.5) + ( 1x 32 ) + (4 x 16)

= 63.5 + 32 + 64

= 159.5 amu

40





Exercises (Group I)

1. Calculate the relative formula mass of sodium chloride,NaCl.(Na=23,


Cl=35.5)
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … . . … … … … 𝒂𝒕𝒐𝒎 𝒐𝒇 … … … . … … … … 𝒂𝒕𝒐𝒎 𝒐𝒇 … … … .

= ( ) + ( )

2. Calculate the relative formula mass of glucose, C6H12O6.(C=12,O=16,H=1)


𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆


𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … . . … … … … 𝒂𝒕𝒐𝒎 𝒐𝒇 … … … . … … … … 𝒂𝒕𝒐𝒎 𝒐𝒇 … … … . … … … … 𝒂𝒕𝒐𝒎 𝒐𝒇 … … … .

= ( ) + ( ) + ( )
=

3. Calculate the molecular mass of the following. (C=12,O=16,S=32,N=14,H=1)

(a) CO

𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(b) CO2


𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

41





(c) SO2


𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(d) SO3


𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(e) NO

𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(f) NO2
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

42





(g) NO
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(h) N2O
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(i)H2O
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(j)NH3
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

43





4. Calculate the relative molecular mass of the following.
(C=12,O=16,S=32,N=14,H=1)

(a) CO

𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(b) CO2


𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆


𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(c) SO2


𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆


𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(d) SO3


𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆


𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

44





(e) NO

𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(f) NO2
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(g) NO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(h) N2O
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂 𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

45





(i) H2O
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(j)NH3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

5. Calculate the formula mass of the following.


(Ca=40,C=12,O=16,Mg=24,S=32,K=39,Cl=35.5,Pb=207,N=14,Na=23)

(a) CaCO3
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(b)MgO

𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

46





(c)CaSO4
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(d)CaO

𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(e)KCl

𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(f) CaCl2

𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

47





(g)PbO

𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇


= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(h)MgSO4
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(i)KNO3
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(j)NaNO3
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

48





6. Calculate the relative formula mass of the following.
(Ca=40,C=12,O=16,Mg=24,S=32,K=39,Cl=35.5,Pb=207,N=14,Na=23)

(a) CaCO3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(b)MgO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(c)CaSO4
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(d)CaO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

49





(e)KCl
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(f) CaCl2

𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆


𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(g)PbO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( )

(h)MgSO4
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

50





(i)KNO3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

(j)NaNO3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …

= ( ) + ( ) + ( )

51





Group (II)

§ Average R.A.M(Relative Atomic Mass)


§ R.A.M(Relative Atomic Mass)

§ Composition by mass (%)

Average R.A.M. ေမးေသာေမးခြန္း

Example 5

Magnesium consists of three isotopes. One isotopes has the relative atomic mass 24 and
its relative abundance is 78.6%. The second isotope has relative mass 25 and its relative
abundance is 10.1%.The third isotopes has relative mass 26 and its relative abundance is
11.3%. Calculate the average relative atomic mass of magnesium.

Average R.A.M. of Mg = ( 24 x 78.6% ) + ( 25 x 10.1 ) + ( 26 x 11.3)


𝟕𝟖.𝟔 𝟏𝟎.𝟏 𝟏𝟏.𝟑
= (24 x ) + ( 25 x ) + ( 26 x )
𝟏𝟎𝟎 𝟏𝟎𝟎 𝟏𝟎𝟎

= 18.86 + 2.53 + 2.94 = 24.33

R.A.M(Relative Atomic Mass)
 ေမးေသာေမးခြန္း

𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕


Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐

Example 6


A magnesium atom has twice the mass of a 12C atom. What is the relative
atomic mass of magnesium? (C=12)
𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐

𝟐 𝒙 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐


Relative atomic mass of an magnesium = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐

! ~ B!
= • = 24
~ B!
•€

52





Composition by mass (%) ရွာေသာ ေမးခြန္းမ်ား

လို
% = စုု x 100%

Example 7


Calculate the percentage by mass of iron in iron(III) oxide(Fe2O3)


.(Fe=56,O=16)

Step 1 ;

Formula of iron (III) oxide = Fe2O3

Relative formula mass of Fe2O3 = (2 x Fe) + (3 x O)

= (2x 56) + (3x16) = 112 + 48 = 160

Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇 𝑭𝒆 𝒙 𝟐
% mass of iron = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑭𝒆𝟐𝑶𝟑

𝟓𝟔 𝒙 𝟐
= x 100% = 70%
𝟏𝟔𝟎

53





Example 8

Calculate the percent composition of magnesium nitrate,


Mg(NO3)2.(Mg=24,N=14,O=16)

Step 1 ;

Formula of magnesium nitrate = Mg(NO3)2

Relative formula mass of Mg(NO3)2 = (Mg) + (2 x N) + ( 6 x O)

= (24)+ (2x14)+ (6x 16) = 24 + 28 + 96 = 148

Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇 𝑴𝒈 𝒙 𝟏
% mass of Mg = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝐌𝐠(𝐍𝐎𝟑)𝟐

𝟐𝟒 𝒙 𝟏
= x 100% = 16.21 %
𝟏𝟒𝟖

𝑹.𝑨.𝑴 𝒐𝒇 𝑵 𝒙 𝟐
% mass of N = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝐌𝐠(𝐍𝐎𝟑)𝟐

𝟏𝟒𝒙 𝟐
= x 100% = 18.91 %
𝟏𝟒𝟖

𝑹.𝑨.𝑴 𝒐𝒇 𝑶 𝒙 𝟔
% mass of O = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝐌𝐠(𝐍𝐎𝟑)𝟐

𝟏𝟔 𝒙 𝟔
= x 100% = 64.86 %
𝟏𝟒𝟖

54





Exercises (Group II)

1. The isotopic masses of naturally occuring oxygen and their relative


abundance are as follows;
Isotopic mass Per cent relative abundance

16 99.76%

17 0.04%
18 0.2%

What is the average relative atomic mass of oxygen.


Average R.A.M. of Oxygen = ( x ) + ( x ) + ( x )

2. Chlorine has 2 isotopes. One isotope has the relative mass 35 and its
relative abundance is 75%. The other isotope has the relative mass 37 and
its relative abundance is 25%. Calculate the average relative atomic mass
of chlorine.


Average R.A.M. of Chlorine = ( x ) + ( x )

3. A titanium atom has 4 times the mass of 12C atom. What is the relative
atomic mass of titanium.(C=12)

𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐
Relative atomic mass of ………………… =

=


55





4. A nickel atom has 5 times the mass of 12C atom. What is the relative
atomic mass of nickel.(C=12)

𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐

Relative atomic mass of …………………=





5. An argon atom has 3 times the mass of 12C atom. What is the relative
atomic mass of argon.(C=12)
𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐
Relative atomic mass of …………………=

=



6. Calculate the percentage by mass of nitrogen in ammonium
nitrate(NH4NO3) fertiliser which is used by farmers to increase the yield of
crops.
(N=14, H=1, O=16)
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=



56





7. Calculate the percent of magnesium in magnesium oxide(MgO).
(Mg=24,O=16)
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
8. Calculate the percent of calcium in calcium carbonate, CaCO3. (Ca=
40,C=12,O=16)
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=

Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

57





9. Calculate the percentage of mass of elements in each of the followings.
(a) Sodium thiosulphate, Na S O 
(b) Iron II Sulphate, FeSO 

2 2 3 4
(c) Trilead tetroxide Pb3O4(Mg=24,O=16,N=14,Ca=40,C=12,Na=23,
S=32,Fe=56, Pb=207)

(a) Sodium thiosulphate, Na S O 

2 2 3
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=










58





(b) Iron II Sulphate, FeSO 

4
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
(c) Trilead tetroxide Pb3O4
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….

=

59





Group (III)

§ Empirical formula
§ Molecular formula

Empirical formula

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

Molecular formula

Step 1 empirical formula mass of

Step 2 divided the R.M.M by empirical formula mass

Step 3 multiply the number of atom in the empirical

60





Example 9

Calculate the formula of a compound in which 3g of carbon combines with 4g of oxygen.


(C=12, O=16)

C O

Step 1 the mass of each element 3 4


𝟑 𝟒
Step 2 divide by relative atomic masses
𝟏𝟐 𝟏𝟔

0.25 0.25
𝟎.𝟐𝟓 𝟎.𝟐𝟓
Step 3 divide by the lowest number
𝟎.𝟐𝟓 𝟎.𝟐𝟓

1 1

Step 4 empirical formula (must be in integers) CO

Example 10

When 1.55g of phosphorus is completely combusted, 3.55g of an oxide of phosphorus is


produced. Deduced the empirical formula of this oxide of phosphorus. (P=31,O=16)

P O

Step 1 the mass of each element 1.55 3.55-1.55=2


𝟏.𝟓𝟓 𝟐
Step 2 divide by relative atomic masses
𝟑𝟏 𝟏𝟔

0.05 0.125
𝟎.𝟎𝟓 𝟎.𝟏𝟐𝟓
Step 3 divide by the lowest number
𝟎.𝟎𝟓 𝟎.𝟎𝟓

1 2.5

1 x 2=2 2.5 x 2=5

Step 4 empirical formula (must be integers) P2 O5

61





Example 11

A compound of carbon and hydrogen contains 85.7% of carbon and 14.3% of


hydrogen by mass. Deduce the empirical formula of this hydrocarbon.
(H=1,C=12)

C H

Step 1 the % by mass 85.7 14.3


𝟖𝟓.𝟕 𝟏𝟒.𝟑
Step 2 divide by relative atomic masses
𝟏𝟐 𝟏

7.142 14.3
𝟕.𝟏𝟒𝟐 𝟏𝟒.𝟑
Step 3 divide by the lowest number
𝟕.𝟏𝟒𝟐 𝟕.𝟏𝟒𝟐

1 2

Step 4 empirical formula CH2

Example 12

A compound has the empirical formula CH2Br. Its relative molecular mass is
188. Deduce the molecular formula of this compound. (Br= 80 , C=12 , H=1)

Step 1 empirical formula mass of CH2Br = (12) + (2 x 1) + (80) = 94


𝟏𝟖𝟖
Step 2 divided the R.M.M by empirical formula mass =
𝟗𝟒

Step 3 multiply the number of atom in the empirical = 2 x CH2Br

formula by the number in step 2

So molecular formula is C2H4Br2.

62





Example 13

Write the empirical formulae of the following compounds.

Compound Empirical formula Molecular formula

Water H2O

Hydrogen peroxide H2O2

Sulphur dioxide SO2

Methane CH4

Cyclopropane C3H6

Butane C4H10

Exercises (Group III)

(1) The composition by mass of a hydrocarbon is 10% hydrogen and 90%


carbon. Deduce the empirical formula of this hydrocarbon.(C=12,H=1)

Step 1 the % by mass

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

63





(2) Calculate the formula of the following compounds.
(a)Sodium oxide in which 2.3g of sodium combines with 0.8g of oxygen.

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)


(b) Oxide of phosphorus in which 1.24g of phosphorus combines with
0.96g of oxygen.

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)


(c) Oxide of lead in which 2.07g of lead combines with 0.32g of oxygen.
(Na=23,O=16,P=31,Pb=207)

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

64





(3)Calculate the empirical formula of nitrogen oxide. It is found that 4.2g
of nitrogen is contained in 16.2g of nitrogen oxide.(N=14,O=16)

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

(4) Calculate the formula of the following compounds.


(a) 1.91g of oxide of sodium is formed from 1.42g of sodium

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

(b) 2.23g of oxide of lead is formed from 2.07g of lead

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

65





(c)16.04g of oxide of iron is formed from 11.22g of iron.

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

(d) 5g of oxide of copper is formed from 4g of copper.


(Na=23,O=16,P=31,Pb=207,Fe=56,Cu=64)

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

66





(5) In a compound of sulphur and chlorine, 6.4g of sulphur combines with
7.1g of chlorine. Calculate the empirical formula of the compound. Then
calculate the molecular formula of the following compound if the molecular
mass of the compound is 135amu. (S=32, Cl=35.5)

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

Step 1 empirical formula mass of

Step 2 divided the R.M.M by empirical formula mass

Step 3 multiply the number of atom in the empirical

(6)Calculate the empirical formula of the following compounds.


(a) A compound in which 3g of carbon combines with 4g of oxygen.

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

67





(b) Iron oxide in which the weight of iron is 77.7% and that of oxygen is
22.3%.

Step 1 the % by mass

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)


(c) Water in which hydrogen and oxygen combine in the proportion of 1:8 by
weight.(Fe=56,C=12,O=16,H=1)

Step 1 the mass of each element

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

68





(7) The empirical formulae and relative molecular masses of three
compounds, A,B,C are shown as follows.(C=12,Cl=35.5,H=1)
Compound Empirical formula Relative molecular mass
A C3H5 82
B CCl3 237
C CH2 112

For compound A

Step 1 empirical formula mass of

Step 2 divided the R.M.M by empirical formula mass

Step 3 multiply the number of atom in the empirical

For compound B

Step 1 empirical formula mass of

Step 2 divided the R.M.M by empirical formula mass

Step 3 multiply the number of atom in the empirical

For compound C

Step 1 empirical formula mass of

Step 2 divided the R.M.M by empirical formula mass

Step 3 multiply the number of atom in the empirical

69





(8) Vinegar which is used in our homes, is a dilute form of acetic acid. A
sample of acetic acid has the following percentage composition; 39.9%
carbon,6.7%hydrogen and 53.4% of oxygen.
(a) Determine the empirical formula of acetic acid.
(b)Determine the molecular formula of acetic acid if the molecular mass of
acetic acid is 60amu.(C=12,H=1,O=16)

(a) Step 1 the % by mass

Step 2 divide by relative atomic masses

Step 3 divide by the lowest number

Step 4 empirical formula (must be in integers)

(b)

Step 1 empirical formula mass of

Step 2 divided the R.M.M by empirical formula mass

Step 3 multiply the number of atom in the empirical

(9) Write the empirical formulae for (a) hydrazine,N2H4 (b) octane, C8H18 (c)
benzene, C6H6 (d) ammonia , NH3

Compound Empirical formula Molecular formula

Hydrazine N2 H4

Octane C8H18

Benzene C6 H6

Ammonia NH3

70





Group (IV) The mole concept
𝒎𝒂𝒔𝒔
Number of mole =
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔

𝒗𝒐𝒍𝒖𝒎𝒆
Number of mole =
𝒎𝒐𝒍𝒂𝒓 𝒗𝒐𝒍𝒖𝒎𝒆

Number of molecules = number of mole x 6.02 x 1023 molecules mol-1

Example 14

Calculate the volume of 0.5 mol of carbon dioxide at room temperature and
pressure (r.t.p.)

Volume = ?

Mole = 0.5 mol


𝒗𝒐𝒍𝒖𝒎𝒆
Number of mole =
𝒎𝒐𝒍𝒂𝒓 𝒗𝒐𝒍𝒖𝒎𝒆

Volume of CO2 = mole x molume volume(r.t.p.)

= 0.5 x 24 = 12 dm3

Example 15

How many moles of sodium chloride are present in 117.0 g of sodium


chloride,NaCl? (Na=23, Cl=35.5)

Mole = ?

Mass = 117 g

Molar mass of NaCl = Na + Cl

= 23 + 35.5 = 58.5 gmol-1


𝒎𝒂𝒔𝒔 𝟏𝟏𝟕
Number of mole = = = 2 mol
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝟓𝟖.𝟓

71





Example 16

What mass of sodium hydroxide, NaOH, is present in 0.25 mol of sodium


hydroxide? (H=1, Na=23 , O=16)

Mass = ?

Mole = 0.25 mol

Molar mass of NaOH = Na + O + H = 23 + 16+1= 40


gmol-1
𝒎𝒂𝒔𝒔
Number of mole =
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔

Mass = number of mole x molar mass

= 0.25 x 40 = 10 g

Example 17

Calculate the number of molecules in 7.10g of chlorine molecule(Cl2).

(Avogadro’s constant = 6.02 x 1023 mol-1 , Cl =35.5)

molar mass of CL2 = 2 x 35.5 = 71 g mol-1


𝒎𝒂𝒔𝒔 𝒐𝒇 𝒄𝒉𝒍𝒐𝒓𝒊𝒏𝒆 𝟕.𝟏 𝒈
number of mole of chlorine= = = 0.1 mol
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒄𝒉𝒍𝒐𝒓𝒊𝒏𝒆 𝟕𝟏 𝒈 𝒎𝒐𝒍}𝟏

number of molecule of Cl2 = number of moles of chlorine x 6.02 x 1023 molecules mol-1

= 0.1 mol x 6.02 x 1023 molecules mol-1

= 6.02 x 1022 molecules

72





Exercises (Group IV)

1. Calculate the amount of moles in 10.7 g of sulphur atoms. (S = 32)

2. What is the mass of 0.20 mol of carbon dioxide,CO2 ?(C =12,O=16)

73





3. You have a 56 g sample of iron (II) sulphide ,FeS.
(a) How many moles of FeS are there in the sample?
(b) How may molecules of FeS are there in the sample?
(Fe = 56,S=32,Avogadro’s constant = 6.02 x 10 23 mol -1 ).





























74





4. How many moles are present in the following volumes of gases at r.t.p?
(a) 1.2 dm3 of sulphur dioxide (SO2)
(b) 0.24 dm3 of methane (CH4)
(c) 120 cm3 of carbon dioxide (CO2)

75





5. A conical flask contains 68.4 g of octane C8H18 ).How many molecules of
octane are there in the flask ? (Avogadro’s constant = 6.02 x 10 23 mol -1
C =12, H=1).

6. Calculate the number of atoms in 4 g of bromine molecule (Br 2).


(Avogadro’s constant = 6.02 x 10 23 mol -1 Br=80).







76





7. Calculate the amount of substance in moles in each of the following.
(a) 64.2 of sulphur molecules (S8)
(b) 60.45 g of anhydrous iron (III) nitrate ,Fe (NO3)3 .
(Fe =56,N =14,O=16,S=32)

77





8. Calculate the mass in grams of the following.
(a) 0.050 moles of sodium carbonate,Na2 CO3
(b) 5.00 moles of iron (II) hydroxide ,Fe (OH2)
(C= 12,Fe = 56,H=1,O=16,Na =23)



























78





Group (V)

Calculations from equations

Example 18
C + O2 à CO2 (C=12,O=16)
6g ? g

Step 1 (သိတဲ့ေကာင္ရဲ႕ mole ရွာ)

Molar mass of C = (C) = 12gmol-1


𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪
Mole of C =
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪

𝟔 𝒈
= = 0.5 mol
𝟏𝟐 𝒈𝒎𝒐𝒍}𝟏

Step 2 (လို/သိ အခ်ိဳးခ်)

𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪𝑶𝟐 𝟏
=
𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪 𝟏

mole of CO2 = 1 x mole of C

= 1 x 0.5 mol = 0.5 mol

Step 3 (လိုခ်င္တာဆက္တြက္အေျဖထြက္)

Molar mass of CO2 = C + 2(O) = (12)+(2x16)= 44gmol-1


𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪𝑶𝟐
Mole of CO2 =
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪𝑶𝟐

Mass of CO2 = mole of CO2 x molar mass of CO2

= 0.5 mol x 44 gmol-1

= 22 g

79





Example 19
C + O2 à CO2 (C=12,O=16)
6g ? dm3

Step 1 (သိတဲ့ေကာင္ရဲ႕ mole ရွာ)

Molar mass of C = (C) = 12gmol-1


𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪 𝟔 𝒈
Mole of C = = = 0.5 mol
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑪 𝟏𝟐 𝒈𝒎𝒐𝒍}𝟏

Step 2 (လို/သိ အခ်ိဳးခ်)

𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪𝑶𝟐 𝟏
=
𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪 𝟏

mole of CO2 = 1 x mole of C

= 1 x 0.5 mol = 0.5 mol


Step 3 (လိုခ်င္တာဆက္တြက္အေျဖထြက္)

𝒗𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝑪𝑶𝟐
Mole of CO2 =
𝒎𝒐𝒍𝒂𝒓 𝒗𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝑪𝑶𝟐

Volume of CO2 = mole of CO2 x molar volume of CO2

= 0.5 mol x 24 dm3 mol-1 at r.t.p

= 12 dm3 at r.t.p

80





Example 20

Calculate the mass of water produced from the complete combustion of


0.25 mol of methane.

CH4 (g) + 2O2 (g) àCO2 (g) + 2 H2 O(I)

CH4 (g) + 2O2 (g) àCO2 (g) + 2 H2 O(I)


𝒎𝒐𝒍𝒆𝒔 𝒐𝒇 𝑯𝟐𝑶 𝟐
=
𝒎𝒐𝒍𝒆𝒔 𝒐𝒇 𝑪𝑯𝟒 𝟏

moles of H2 O = 2 x number of moles of CH4

= 2 x 0.25 mol = 0.5 mol

Molar mass of H2O = (2x1) + 16 = 18 g mol-1

Mass of H2O = moles of H2O x molar mass of H2 O

= 0.5 mol x 18g mol-1 = 9 g

81





Example 21

Magnesium reacts with hydrochloric acid according to the equation:

Mg(s) + 2HCI(aq) à MgCl2 (aq) + H2 (g)

Calculate the volume of hydrogen gas, measured at room conditions,


produced from the reaction of 14.6 g of hydrochloric acid.

Mg (s) + 2 HCI (aq) àMgCI2 (aq) + H2(g)

molar mass of HCI = 1 + 35.5 = 36.5 g mol-1


𝒎𝒂𝒔𝒔 𝒐𝒇 𝑯𝑪𝑰 (𝒈) 𝟏𝟒.𝟔
moles of HCI = = = 0.4 mol
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑯𝑪𝑰 (𝒈 𝒎𝒐𝒍}𝟏) 𝟑𝟔.𝟓

𝒎𝒐𝒍𝒆𝒔 𝒐𝒇 𝑯𝟐 𝟏
=
𝒎𝒐𝒍𝒆𝒔 𝒐𝒇 𝑯𝑪𝑰 𝟐

𝟏
moles of H2 = x number of mole of HCI
𝟐

𝟐
= x 0.4 mol =0.2 mol
𝟏

Volume of H2 = moles of H2 x molar volume of H2

= 0.2 x 24 dm3 = 4.8 dm3

82





Exercise (Group V)

1. Calculate the following.(C=12,S=32,O=16)


(b) C + O2 à CO2
3g ? g















(c) C + O2 à CO2
3g ? dm3











83





(d) C + O2 à CO2
3g ? g

















(e) C + O2 à CO2
3g ? dm3












84





(f) S + O2 à SO2
16g ?g

















(g) S + O2 à SO2
16g ?dm3












85





(h) S + O2 à SO2
16g ?g
















(i) S + O2 à SO2
16g ?dm3













86





2. Hydrogen peroxide decomposes according to the equation:

H2 O2 (I) à 2 H2 O(I) + O2 (g)

Calculate the volume of oxygen gas produced at r.t.p .when 1.7 g of


H2O2 is decomposed. (H=1,O=16)

87





3. Tin (IV) oxide is reduced to tin by heating with carbon. Carbon
monoxide is also formed.
Sn O2(s) + 2C (s) à Sn (s) + 2CO(g)

Calculate the mass of carbon that exactly reacts with 14 g of tin (IV) oxide.

(C= 12,O=16,Sn =119)

88

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