Microsoft Word - G10 Workbook - Docx 7
Microsoft Word - G10 Workbook - Docx 7
Microsoft Word - G10 Workbook - Docx 7
1
ေဆးမFႈုန္႔ + ေရ à ေဆးေပ်ာ္ရည္
10g + 100g à 110g
+ 200g à
+ 300g à
+ 400g à
+ 500g à
+ 1000g à
+ 50g à
Example 1
Solid A + water à Saturated solution
40g + 100g à 140g
20g ?
40g of solid A à 140g of saturated solution
20g of solid A à ?
!"# %& '%()* +
= x 140g of saturated solution
,"# %& '%()* +
= 70 g of saturated solution
Example 2
Solid A + water à Saturated solution
40g + 100g à 140g
20g ?
Example 3
Solid A + water à Saturated solution
40g + 100g à 140g
? 50g
2
Example 4
Solid A + water à Saturated solution
40g + 100g à 140g
50g ?
Example 5
Solid A + water à Saturated solution
40g + 100g à 140g
? 70g
Example 6
Solid A + water à Saturated solution
40g + 100g à 140g
? 70g
3
Example 7
Salt + water à Saturated solution
60g + 100g à 160g
120g ?
Example 8
Salt + water à Saturated solution
60g + 100g à 160g
120g ?
Example 9
Salt + water à Saturated solution
60g + 100g à 160g
? 200g
4
Example 10
Salt + water à Saturated solution
60g + 100g à 160g
200g ?
Example 11
Salt + water à Saturated solution
60g + 100g à 160g
? 320g
Example 12
Salt + water à Saturated solution
60g + 100g à 160g
? 320g
5
Exercise 2.1
1. The solubility of sodium nitrate at 40°C is 140g/100g water.
(a) How much sodium nitrate will be obtained if 25.5g of saturated solution at
40°C is evaporated to dryness?
(b) What is the maximum amount of solid that can be dissolved in 250g of
water at 40°C?
6
2. The solubility of solid A at 60°C is 24g/100g water.
(a) What is the amount of solid required to saturated 30g of water at 60°C?
(b) What will be the amount of saturated solution obtained at 60°C when
12g of the solid A is used to prepare a saturated solution?
7
3. 20g of a soluble substance is dissolved in water to from 100g of the solution.
25g of solution is taken and evaporated to dryness. How many grams of
the solid will be obtained?
8
Temperature တိုးေလ်ွာ့လုပ္ေသာ Solubility အေျခခံေမးခြန္းမ်ား
Example 13
Temperature(°C) 0°C 10°C 20°C 30°C 40°C 50°C
Solubilities 15 30 40 55 75 65
(g/100g of water)
From 10°C to 30°C
30g – 55g = -22g
the amount of solid dissolved = 22g
From 20°C to 50°C
From 30°C to 0°C
55g-15g = 40g
The amount of solid come out = 40g
From 40°C to 50°C
From 50°C to 40°C
From 0°C to 30°C
9
Example 14
Temperature(°C) 0°C 20°C 40°C 60°C 80°C 100°C
Solubilities 5 15 25 50 40 30
(g/100g of water)
From 0°C to 40°C
From 60°C to 100°C
From 80°C to 40°C
From 60°C to 0°C
From 20°C to 80°C
From 40°C to 60°C
10
Exercise 2.2
1. The solubility (g/100g water) of three substances at different temperature
are given below.
Temperature(°C) 0 10 20 30 40 50 60 70 80
Potassium chlorate 3.3 5.0 7.3 10.0 14.0 18.5 24.0 30.2 37.5
Calcium hydroxide 0.13 0.13 0.12 0.11 0.10 0.00 0.08 0.06 -
Sodium sulphate 5.0 9.0 20.5 41.0 48.0 47.0 45.0 44.0 43.0
(a) Plot the solubility curve of each substance.
(b) Describe the change in solubility with the temperature for each substance.
(c) What is the solubility of each substance at 25°C?
(d) What happens when each solution at 70°C is cooled down to 30°C?
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2. The solubility of copper (II) sulphate at 60°C is 40g/100g and 90°C is 67.5g/100g.
A saturated solution of copper (II) sulphate in 100g of water at 90°C is cooled
to 60°C. Calculate the amount of copper (II) sulphate which would come out of
the solution.
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CHAPTER 3
THE ELECTRONIC STRUCTURES OF ATOMS
AND PERIODIC TABLE
ဒီဇယားကြက္ေလး အရင္ျဖည့္ၾကည့္။
Example 1
What are the symbols, charges and masses of neutron and electron?
Particles Symbols Relative masses Relative charges
neutron
electron
ဒီဇယားကြက္ေလး အရင္ျဖည့္ၾကည့္။
𝟐𝟑 𝟑𝟓 𝟒𝟏 𝟏 𝟏𝟒 𝟑𝟗 𝟐𝟒 𝟒 𝟐𝟕 𝟑𝟏
𝟏𝟏 𝐍𝐚 𝟏𝟕𝐂𝐥 𝟐𝟎 𝐂𝐚 𝟏𝐇 𝟕𝐍 𝟏𝟗 𝐊 𝟏𝟐 𝐌𝐠 𝟐𝐇𝐞 𝟏𝟑𝐀𝐥 𝟏𝟓𝐏
Element Na
Mass number 23
Atomic number 11
Protons 11
Electrons 11
Neutrons 23-11 = 12
!,
Possible isotopes BBNa
13
Example 2
Determine the number of electrons, protons and neutrons for3517Cl.Write
down its possible isotopes.
number of electrons =
number of protons =
number of neutrons =
35
possible isotopesof 17Cl =
Example 3
Select the isotopes from the following and give reasons for your answer.
35 39 16 37 39
17Cl , 19K, 8O, 17Cl, 17Cl
………………..and ………………..are isotopes.
Because……………………………………………………………………………………………………….……
………………………………………………………………………………………
Example 4
Select the isobars from the following and give reasons for your answer.
35 23 40 37 39
17Cl , 11Na , 20Ca , 17Cl, 19K
………………..and ………………..are isobars.
Because……………………………………………………………………………………………………….……
………………………………………………………………………………………
Example 5
Write down the notation of isotopes for an element ‘X’. Express the
corresponding terms.
……………………………..
……………………………..
……………………………..
Example 6
In a neutral atom of an element, the number of a certain particle or particles
is equal to the atomic number. Name the particle or particles.
atomic number = ………………………………………….
atomic number = ………………………………………….
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Exercise 3.1
1. What are the symbols, charges and relative masses of neutron and
protons.
particles symbols relative masses Relative charges
neutron
proton
2. What are the symbols, charges and relative masses of neutron and
electrons.
particles symbols relative masses Relative charges
neutron
electrons
3. Determine the number of electrons , protons and neutrons for 𝟑𝟕
𝟏𝟕𝑪𝒍.
number of electrons =
number of protons =
number of neutrons =
4. What are the number of protons, neutrons and electrons in the atom
of 𝟐𝟕
𝟏𝟑𝑨𝒍?.Write down its possible isotopes.
number of protons =
number of neutrons =
number of electrons =
𝟐𝟕
possible isotopes of 𝟏𝟑𝑨𝒍 =
5. Find the number of protons ,electrons and neutrons in 𝟒𝟎
𝟐𝟎𝑪𝒂 and give
possible isotopes.
number of protons =
number of electrons =
number of neutrons =
𝟒𝟎
possible isotopes of 𝟐𝟎𝑪𝒂 =
15
6. Determine the number of protons, electrons and neutrons in the atom of
element 'E' which has the atomic number of 18 and, mass of 40. Give
possible isotopes.
number of protons =
number of electrons =
number of neutrons =
𝟒𝟎
possible isotopes of 𝟏𝟖𝑬 =
7. Determine the number of protons, electrons and neutrons in the atom of
the element 'E' which has the atomic number 14 and mass number 28.
Give the possible isotopes.
number of protons =
number of electrons =
number of neutrons =
𝟐𝟖
possible isotopes of 𝟏𝟒𝑬 =
8. Fine the number of protons ,electrons and neutrons in 𝟏𝟐𝟔𝑪.
number of protons =
number of electrons =
number of neutrons =
16
ဒီဇယားကြက္ေလး အရင္ေလ့က်င့္ၾကည့္။
Shell no. Name Maximum number of electron (2n2)
1
2
3
4
Example 7
Give the maximum number of electrons in shell number 2 and 4.
Shell number Name Maximum number of electrons(2n2)
2
17
ဒီဇယားကြက္ေလး အရင္ေလ့က်င့္ၾကည့္။
Atomic Symbol Name IES CES EES G P V
number
1
10
11
12
13
14
15
16
17
18
19
20
18
Diagram ဆြဲက်င့္ၾကည့္ၾကစို႔။
5B 6C 7N 8O
19
13Al 14Si 15P 16S
20
Example 8
Write down the complete and essential electronic structure of 11Na and 12Mg.
21
ဒီဇယားကြက္ေလး အရင္ေလ့က်င့္ၾကည့္။
Group number Types of elements Name
I A Alkali metal Li , Na , K
II A
VII B
0
Example 11
Classify the following elements as alkali metal, alkaline earth metal , halogen and noble gas.
11Na, 17Cl , 10Ne, 12Mg
Alkali metal =
Alkaline earth metal =
Halogen =
Noble gas =
Example 12
Classify the following elements in their appropriate group number.
3Li, 17Cl, 20Ca, 8O, 11Na, 16S, 9F, 12Mg
Group IA =
Group IIA =
Group VIB =
Group VIIB =
22
Exercise3.2
1. Give the maximum number of electrons in shell number 1 and 3.
Shell number Name Maximum number of electrons(2n2)
1
3
2. Give the maximum number of electrons in L shell and M shell.
Shell number Name Maximum number of electrons(2n2)
L
M
3. Write down the complete and essential electronic structure of 7N and 20Ca.
Complete electronic structure of 7N =
Complete electronic structure of 20Ca =
Essential electronic structure of 7N =
Essential electronic structure of 20Ca =
4. Write down the complete and essential electronic structure of 1H and 18Ar.
Complete electronic structure of 1H =
Complete electronic structure of 18Ar =
Essential electronic structure of 1H =
Essential electronic structure of 18Ar =
5. Write down the complete and essential electronic structure of 14Si and 15P.
Complete electronic structure of 14Si =
Complete electronic structure of 15P =
Essential electronic structure of 14Si =
Essential electronic structure of 15P =
6. Write down the complete and essential electronic structure of 3Li and 2He.
Complete electronic structure of 3Li =
Complete electronic structure of 2He =
Essential electronic structure of 3Li =
Essential electronic structure of 2He =
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7. Complete the following table;
Element Integer Complete Electronic Structure Essential Valence
Electronic Electronic
Structure Structure
Li 1s2 2s1 2s1
2 2 1
B 1s 2s 2p 3
1
Na 2.8.1 3s
2 2 6 2 1
Al 2.8.3 1s 2s 2p 3s 3p
1
2.8.8.1 4s
2.8.7 3s2 3p5
8. You are given the following elements; A to G represent unknown elements.
10A, 17B , 3C , 9D , 11E , 18F , 19G
(a) Write down the electronic structures of these elements.
(b) Which elements are alkali metals?
(c) Which elements are noble gases?
(d) Which elements are halogen?
(e) Which elements are s-block elements?
(a) Electronic structure of 10A=
Electronic structure of17B =
Electronic structure of3C =
Electronic structure of9D=
Electronic structure of11E=
Electronic structure of18F=
Electronic structure of19G=
(b) Elements ……………………………………… are alkali metals.
(c) Elements ……………………………………… are noble gases.
(d) Elements ……………………………………… are halogen.
(e) Elements ……………………………………… are s-block elements.
24
9. (a) How many electrons, neutrons and protons are there in the following elements?
Write down their complete electronic structures.
12 56 35 40 48 55 45
6C, 26Fe , 17Cl , 20Ca , 22Ti, 25Mn, 21Sc
1s 2s 2p 3s 3p 4s 3d 4p 5s ………..
Elements Number of Number of Number of Complete Electronic Structure
Electrons Neutrons Protons
12
6C
56
26Fe
35
17Cl
40
20Ca
48
22Ti
55
25Mn
45
21Sc
(b)Write the complete symbol for the atom with the given atomic number (Z) and
atomic mass (A).
(b)(i)
(ii)
(iii)
(iv)
25
10. (a) Draw diagrammatic representation of the following atoms by using shell or energy
level:
(a) 49 Be (ii) 919 F (iii) 1428 Si (iv) 1939 K
(b) For the elements in above question, give the valence electrons and the number of
(i) 49 Be
(ii) 919 F
(iii) 1428 Si
(iv) 1939 K
11. (a) Rewrite the correct complete electronic structures given below.
(i)1s2 2s2 2p4 3s2 (ii) 1s2 2s1 2p6 (iii) 1s2 2s2 2p6 3P3 3s2 (iv) 1s2 2s2 2p63s2 3P5 4s2
26
(b)What are the atomic numbers of elements whose outermost electrons are represented
by (i) 3s1 (ii) 2s22p3 (iii) 3s23p5 ?
(i) 3s1 =
(ii) 2s22p3 =
(iii) 3s23p5 =
Configurations Atoms
(a) [ He ] 2s1
(c) [ Ar ] 4s2
13. (a) Write the complete and essential electronic structures using noble gases as a core
for Li, O, Mg, Al, Cl, Ca.
Elements Complete Electronic Structure with a noble gas core Essential Electronic
Structure
Li
Mg
Al
Cl
Ca
27
(b) Give the group ,period and valence of the above elements.
Li
Mg
Al
Cl
Ca
28
15. Complete the following table and answer the following questions:
Number of neutrons 12 6 16
29
Ionic size
Positive ion < Parent atom
Negative ion > Parent atom
Example 13
From the following groups, select the one which has the largest radius. Give reason.
(a) Fe 2+ , Fe 3+
(b) Cl , Cl-
(a) Fe 2+ , Fe 3+
Fe 2+ is formed by removal of two electrons from Fe atom.
Fe 3+ is formed by removal of three electrons from Fe atom.
They both have the same nuclear charges.
Number of electrons Fe2+ > Fe3+
Repulsion between electrons Fe2+ > Fe3+
Size Fe2+ > Fe3+
(b) Cl , Cl-
Cl – is formed by addition of one electron to Cl atom.
They both have the same nuclear charges.
Number of electrons Cl< Cl-
Repulsion between electrons Cl< Cl-
Size Cl< Cl-
Example 14
From the following elements, select the one which has the largest radius. Give
reasons.4Be , 12Mg, 20Ca and 6C, 7N, 9F.
4Be, 12Mg, 20Ca
They are in the same group.
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
Atomic radius ( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
Atomic radius è 4Be<12Mg< 20Ca
20Ca has the largest radius.
6C , 7N, 9F
They are in the same period.
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
Atomic radius ( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
Atomic radius è 6C>7N >9F
6C has the largest radius.
30
Exercise 3.3
1. Select the one which has the larger radius between Br and Br-. Give reason for your
answer.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
2. From the following , select the one which has the largest radius. Give reason for your
answer. Fe , Fe2+ , Fe3+.
………….. is formed by……………………. of ……….. electron to ………atom.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
3. From the following pair, select the one which has the largest radius. Give reason for
your choice. F and F-.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
4. From the following element select the one which has the largest radius.
(i) 4Be, 12Mg, 20Ca (ii) 5B , 6C, 9F
(i) 4Be, 12Mg, 20Ca
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… ………………………………….
è
………………………..has the largest radius.
(ii) 5B , 6C, 9F
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… ………………………………….
è
………………………..has the largest radius.
31
5. In each of the following groups, select the one which has the largest radius.
(i) Fe, Fe2+, Fe3+ (ii) S, S2- (iii) Li, Na, K (iv) C, N,O
(i) Fe, Fe2+, Fe3+
………….. is formed by……………………. of ……….. electron to ………atom.
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
(ii) S, S2-
………….. is formed by……………………. of ……….. electron to ………atom.
They both have the same nuclear charges.
Number of electrons ………..
Repulsion between electrons …………
Size …………
(iii) Li, Na, K
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… è ………………………………….
………………………..has the largest radius.
(iv) C, N,O
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… è ………………………………….
………………………..has the largest radius.
6. From the following elements, select the one which has the lowest ionisation energy.
Give reason. 3Li, 9F, 10Ne.
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… è ………………………………….
………………………..has the lowest ionisation energy.
7. Explain which one has the largest ionisation energy : 2.8.1 , 2.8.5 , 2.8.7.
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
……………………… ………………………………….
è
………………………..has the largest ionisation energy.
32
8. Arrange which of the following elements in order to their increasing
electronegativity and give reason ; Oxygen, Carbon, Fluorine , Nitrogen
They are in the same …………………….
)JKLMN'M &L%O P%Q P% R%PP%O O%S)J# *%TJ N #L%UQ.
……………………………( )( )
*MKLMN'M &L%O (M&P P% L)#WP NKL%'' N QML)%*.
XYZ[\]^XY_ \`\Za[bY\_]aXcXad
33
Ionic bond
Ø Metals + Non-metals
(I,II) + (VI,VII)
Ø Complete transfer of electron(s)
Ø Formation of cation and anion
Ø Strong electrostatic attraction
Li F
Na Cl
K O
Mg S
Ca
LiF
Lithium Fluorine
(2.1) (2.7)
NaCl
KCl
34
NaF
KF
CaCl2
MgCl2
CaF2
MgF2
35
Covalent bond
Ø Non-metal + Non-metal
Ø Sharing of electron(s)
Ø Weak intermolecular forces
Ø 2 types
(Atoms of the same element) , (Atoms of different elements)
(e.g. H2,O2,N2,Cl2) (e.g. CO2, H2O, NH3,CH4)
Cl2
H2
O2
N2
36
Atoms of different elements
CO2
H2O
NH3
CH4
37
Exercise 3.3
1. Lithium has the electronic structure 2.1. Fluorine has the electronic structure 2.7.
Lithium and fluorine react together to form an ionic lithium fluoride. Draw the
arrangement of electrons in fluorine and lithium. Explain how ionic bond is formed
in lithium fluoride.
2. Carbon has the electronic structure 2.4. Chlorine has the electronic structure 2.8.7.
Draw the structure of the compound formed between carbon and chlorine.
38
CHAPTER 4
THE QUANTITIES OF SUBSTANCES:
CHEMICAL CALCULATIONS
Group (I)
§ Molecular mass(amu)
§ Formula mass(amu)
§ Relative molecular mass(unitless)
§ Relative formula mass(unitless)
Example 1
What is the molecular mass of carbon dioxide , CO2 ? The relative atomic
mass of carbon and oxygen are 12 and 16 , respectively.
= (1 x 12) + (2 x 16)
= 12 + 32
= 44 amu
Example 2
= (1 x 12) + (2 x 16)
= 12 + 32 = 44
39
Example 3
= ( 1 x 63.5) + ( 1x 32 ) + (4 x 16)
= 63.5 + 32 + 64
= 159.5 amu
Example 4
= ( 1 x 63.5) + ( 1x 32 ) + (4 x 16)
= 63.5 + 32 + 64
= 159.5 amu
40
Exercises (Group I)
= ( ) + ( )
= ( ) + ( ) + ( )
=
3. Calculate the molecular mass of the following. (C=12,O=16,S=32,N=14,H=1)
(a) CO
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(b) CO2
= ( ) + ( )
41
(c) SO2
= ( ) + ( )
(d) SO3
= ( ) + ( )
(e) NO
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(f) NO2
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
42
(g) NO
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(h) N2O
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(i)H2O
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(j)NH3
𝑴𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
43
4. Calculate the relative molecular mass of the following.
(C=12,O=16,S=32,N=14,H=1)
(a) CO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(b) CO2
= ( ) + ( )
(c) SO2
= ( ) + ( )
(d) SO3
= ( ) + ( )
44
(e) NO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(f) NO2
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(g) NO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(h) N2O
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂 𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
45
(i) H2O
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(j)NH3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(a) CaCO3
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(b)MgO
= ( ) + ( )
46
(c)CaSO4
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(d)CaO
= ( ) + ( )
(e)KCl
= ( ) + ( )
(f) CaCl2
= ( ) + ( )
47
(g)PbO
= ( ) + ( )
(h)MgSO4
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(i)KNO3
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(j)NaNO3
𝑭𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
= + +
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
48
6. Calculate the relative formula mass of the following.
(Ca=40,C=12,O=16,Mg=24,S=32,K=39,Cl=35.5,Pb=207,N=14,Na=23)
(a) CaCO3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(b)MgO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(c)CaSO4
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(d)CaO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
49
(e)KCl
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(f) CaCl2
= ( ) + ( )
(g)PbO
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( )
(h)MgSO4
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
50
(i)KNO3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
(j)NaNO3
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆
𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 = 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇 + 𝒂𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔 𝒐𝒇
𝒐𝒇 … … … … … … . 𝒂𝒕𝒐𝒎 𝒐𝒇 … … . . … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … … … . 𝒂𝒕𝒐𝒎𝒔 𝒐𝒇 … … …
= ( ) + ( ) + ( )
51
Group (II)
Example 5
Magnesium consists of three isotopes. One isotopes has the relative atomic mass 24 and
its relative abundance is 78.6%. The second isotope has relative mass 25 and its relative
abundance is 10.1%.The third isotopes has relative mass 26 and its relative abundance is
11.3%. Calculate the average relative atomic mass of magnesium.
Example 6
A magnesium atom has twice the mass of a 12C atom. What is the relative
atomic mass of magnesium? (C=12)
𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐
! ~ B!
= • = 24
~ B!
•€
52
Composition by mass (%) ရွာေသာ ေမးခြန္းမ်ား
လို
% = စုု x 100%
Example 7
Step 1 ;
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇 𝑭𝒆 𝒙 𝟐
% mass of iron = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝑭𝒆𝟐𝑶𝟑
𝟓𝟔 𝒙 𝟐
= x 100% = 70%
𝟏𝟔𝟎
53
Example 8
Step 1 ;
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇 𝑴𝒈 𝒙 𝟏
% mass of Mg = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝐌𝐠(𝐍𝐎𝟑)𝟐
𝟐𝟒 𝒙 𝟏
= x 100% = 16.21 %
𝟏𝟒𝟖
𝑹.𝑨.𝑴 𝒐𝒇 𝑵 𝒙 𝟐
% mass of N = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝐌𝐠(𝐍𝐎𝟑)𝟐
𝟏𝟒𝒙 𝟐
= x 100% = 18.91 %
𝟏𝟒𝟖
𝑹.𝑨.𝑴 𝒐𝒇 𝑶 𝒙 𝟔
% mass of O = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇 𝐌𝐠(𝐍𝐎𝟑)𝟐
𝟏𝟔 𝒙 𝟔
= x 100% = 64.86 %
𝟏𝟒𝟖
54
Exercises (Group II)
2. Chlorine has 2 isotopes. One isotope has the relative mass 35 and its
relative abundance is 75%. The other isotope has the relative mass 37 and
its relative abundance is 25%. Calculate the average relative atomic mass
of chlorine.
3. A titanium atom has 4 times the mass of 12C atom. What is the relative
atomic mass of titanium.(C=12)
𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐
Relative atomic mass of ………………… =
=
55
4. A nickel atom has 5 times the mass of 12C atom. What is the relative
atomic mass of nickel.(C=12)
𝒂𝒗𝒆𝒓𝒂𝒈𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒕𝒉𝒆 𝒆𝒍𝒆𝒎𝒆𝒏𝒕
Relative atomic mass of an element = 𝟏
𝒐𝒇 𝒕𝒉𝒆 𝒎𝒂𝒔𝒔 𝒐𝒇 𝒐𝒏𝒆 𝒂𝒕𝒐𝒎 𝒐𝒇 𝒄𝒂𝒓𝒃𝒐𝒏}𝟏𝟐
𝟏𝟐
56
7. Calculate the percent of magnesium in magnesium oxide(MgO).
(Mg=24,O=16)
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
8. Calculate the percent of calcium in calcium carbonate, CaCO3. (Ca=
40,C=12,O=16)
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
57
9. Calculate the percentage of mass of elements in each of the followings.
(a) Sodium thiosulphate, Na S O
(b) Iron II Sulphate, FeSO
2 2 3 4
(c) Trilead tetroxide Pb3O4(Mg=24,O=16,N=14,Ca=40,C=12,Na=23,
S=32,Fe=56, Pb=207)
(a) Sodium thiosulphate, Na S O
2 2 3
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
58
(b) Iron II Sulphate, FeSO
4
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
(c) Trilead tetroxide Pb3O4
Step 1 ;
Formula of ……………………… =
Relative formula mass of ………… =
=
Step 2 ;
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
𝑹.𝑨.𝑴 𝒐𝒇………….𝒙…………
% mass of ………….. = x 100%
𝑹𝒆𝒍𝒂𝒕𝒊𝒗𝒆 𝒇𝒐𝒓𝒎𝒖𝒍𝒂 𝒎𝒂𝒔𝒔 𝒐𝒇…….
=
59
Group (III)
§ Empirical formula
§ Molecular formula
Empirical formula
Molecular formula
60
Example 9
C O
0.25 0.25
𝟎.𝟐𝟓 𝟎.𝟐𝟓
Step 3 divide by the lowest number
𝟎.𝟐𝟓 𝟎.𝟐𝟓
1 1
Example 10
P O
0.05 0.125
𝟎.𝟎𝟓 𝟎.𝟏𝟐𝟓
Step 3 divide by the lowest number
𝟎.𝟎𝟓 𝟎.𝟎𝟓
1 2.5
61
Example 11
C H
7.142 14.3
𝟕.𝟏𝟒𝟐 𝟏𝟒.𝟑
Step 3 divide by the lowest number
𝟕.𝟏𝟒𝟐 𝟕.𝟏𝟒𝟐
1 2
Example 12
A compound has the empirical formula CH2Br. Its relative molecular mass is
188. Deduce the molecular formula of this compound. (Br= 80 , C=12 , H=1)
62
Example 13
Water H2O
Methane CH4
Cyclopropane C3H6
Butane C4H10
63
(2) Calculate the formula of the following compounds.
(a)Sodium oxide in which 2.3g of sodium combines with 0.8g of oxygen.
64
(3)Calculate the empirical formula of nitrogen oxide. It is found that 4.2g
of nitrogen is contained in 16.2g of nitrogen oxide.(N=14,O=16)
65
(c)16.04g of oxide of iron is formed from 11.22g of iron.
66
(5) In a compound of sulphur and chlorine, 6.4g of sulphur combines with
7.1g of chlorine. Calculate the empirical formula of the compound. Then
calculate the molecular formula of the following compound if the molecular
mass of the compound is 135amu. (S=32, Cl=35.5)
67
(b) Iron oxide in which the weight of iron is 77.7% and that of oxygen is
22.3%.
(c) Water in which hydrogen and oxygen combine in the proportion of 1:8 by
weight.(Fe=56,C=12,O=16,H=1)
68
(7) The empirical formulae and relative molecular masses of three
compounds, A,B,C are shown as follows.(C=12,Cl=35.5,H=1)
Compound Empirical formula Relative molecular mass
A C3H5 82
B CCl3 237
C CH2 112
For compound A
For compound B
For compound C
69
(8) Vinegar which is used in our homes, is a dilute form of acetic acid. A
sample of acetic acid has the following percentage composition; 39.9%
carbon,6.7%hydrogen and 53.4% of oxygen.
(a) Determine the empirical formula of acetic acid.
(b)Determine the molecular formula of acetic acid if the molecular mass of
acetic acid is 60amu.(C=12,H=1,O=16)
(b)
(9) Write the empirical formulae for (a) hydrazine,N2H4 (b) octane, C8H18 (c)
benzene, C6H6 (d) ammonia , NH3
Hydrazine N2 H4
Octane C8H18
Benzene C6 H6
Ammonia NH3
70
Group (IV) The mole concept
𝒎𝒂𝒔𝒔
Number of mole =
𝒎𝒐𝒍𝒂𝒓 𝒎𝒂𝒔𝒔
𝒗𝒐𝒍𝒖𝒎𝒆
Number of mole =
𝒎𝒐𝒍𝒂𝒓 𝒗𝒐𝒍𝒖𝒎𝒆
Example 14
Calculate the volume of 0.5 mol of carbon dioxide at room temperature and
pressure (r.t.p.)
Volume = ?
= 0.5 x 24 = 12 dm3
Example 15
Mole = ?
Mass = 117 g
71
Example 16
Mass = ?
= 0.25 x 40 = 10 g
Example 17
number of molecule of Cl2 = number of moles of chlorine x 6.02 x 1023 molecules mol-1
72
Exercises (Group IV)
73
3. You have a 56 g sample of iron (II) sulphide ,FeS.
(a) How many moles of FeS are there in the sample?
(b) How may molecules of FeS are there in the sample?
(Fe = 56,S=32,Avogadro’s constant = 6.02 x 10 23 mol -1 ).
74
4. How many moles are present in the following volumes of gases at r.t.p?
(a) 1.2 dm3 of sulphur dioxide (SO2)
(b) 0.24 dm3 of methane (CH4)
(c) 120 cm3 of carbon dioxide (CO2)
75
5. A conical flask contains 68.4 g of octane C8H18 ).How many molecules of
octane are there in the flask ? (Avogadro’s constant = 6.02 x 10 23 mol -1
C =12, H=1).
76
7. Calculate the amount of substance in moles in each of the following.
(a) 64.2 of sulphur molecules (S8)
(b) 60.45 g of anhydrous iron (III) nitrate ,Fe (NO3)3 .
(Fe =56,N =14,O=16,S=32)
77
8. Calculate the mass in grams of the following.
(a) 0.050 moles of sodium carbonate,Na2 CO3
(b) 5.00 moles of iron (II) hydroxide ,Fe (OH2)
(C= 12,Fe = 56,H=1,O=16,Na =23)
78
Group (V)
Example 18
C + O2 à CO2 (C=12,O=16)
6g ? g
𝟔 𝒈
= = 0.5 mol
𝟏𝟐 𝒈𝒎𝒐𝒍}𝟏
𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪𝑶𝟐 𝟏
=
𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪 𝟏
Step 3 (လိုခ်င္တာဆက္တြက္အေျဖထြက္)
= 22 g
79
Example 19
C + O2 à CO2 (C=12,O=16)
6g ? dm3
𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪𝑶𝟐 𝟏
=
𝒎𝒐𝒍𝒆 𝒐𝒇 𝑪 𝟏
Step 3 (လိုခ်င္တာဆက္တြက္အေျဖထြက္)
𝒗𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝑪𝑶𝟐
Mole of CO2 =
𝒎𝒐𝒍𝒂𝒓 𝒗𝒐𝒍𝒖𝒎𝒆 𝒐𝒇 𝑪𝑶𝟐
= 12 dm3 at r.t.p
80
Example 20
81
Example 21
𝒎𝒐𝒍𝒆𝒔 𝒐𝒇 𝑯𝟐 𝟏
=
𝒎𝒐𝒍𝒆𝒔 𝒐𝒇 𝑯𝑪𝑰 𝟐
𝟏
moles of H2 = x number of mole of HCI
𝟐
𝟐
= x 0.4 mol =0.2 mol
𝟏
82
Exercise (Group V)
83
(d) C + O2 à CO2
3g ? g
(e) C + O2 à CO2
3g ? dm3
84
(f) S + O2 à SO2
16g ?g
(g) S + O2 à SO2
16g ?dm3
85
(h) S + O2 à SO2
16g ?g
(i) S + O2 à SO2
16g ?dm3
86
2. Hydrogen peroxide decomposes according to the equation:
87
3. Tin (IV) oxide is reduced to tin by heating with carbon. Carbon
monoxide is also formed.
Sn O2(s) + 2C (s) à Sn (s) + 2CO(g)
Calculate the mass of carbon that exactly reacts with 14 g of tin (IV) oxide.
88