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    Analytical Chemistry Activity

    Uploaded by

    Agyao Yam Faith
    1. The document provides examples of chemistry problems involving concentrations expressed in different units like ppm, % by volume, and mole fractions. 2. It also gives practice problems interconverting between concentration terms such as molarity, molality, and mole fractions. 3. The last section provides sample chemistry problems involving stoichiometry, titration, percent composition, empirical formulas, and vapor pressure depression.

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    © All Rights Reserved
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    Analytical Chemistry Activity

    Uploaded by

    Agyao Yam Faith
    174 views4 pages
    1. The document provides examples of chemistry problems involving concentrations expressed in different units like ppm, % by volume, and mole fractions. 2. It also gives practice problems interconverting between concentration terms such as molarity, molality, and mole fractions. 3. The last section provides sample chemistry problems involving stoichiometry, titration, percent composition, empirical formulas, and vapor pressure depression.

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    1. The document provides examples of chemistry problems involving concentrations expressed in different units like ppm, % by volume, and mole fractions. 2. It also gives practice problems interconverting between concentration terms such as molarity, molality, and mole fractions. 3. The last section provides sample chemistry problems involving stoichiometry, titration, percent composition, empirical formulas, and vapor pressure depression.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    174 views4 pages

    Analytical Chemistry Activity

    Uploaded by

    Agyao Yam Faith
    1. The document provides examples of chemistry problems involving concentrations expressed in different units like ppm, % by volume, and mole fractions. 2. It also gives practice problems interconverting between concentration terms such as molarity, molality, and mole fractions. 3. The last section provides sample chemistry problems involving stoichiometry, titration, percent composition, empirical formulas, and vapor pressure depression.

    Copyright:

    © All Rights Reserved
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    Analytical Chemistry

    Name: IBUOS, JAMES VINCENT S. Date:


    Course & Year: BSED-2 SCIENCE Subject: Analytical Chemistry

    C. SEAT WORK
    1.Expressing Concentrations in Parts by mass, Parts by volume, and Mole fraction.

    a) Find the concentration of calcium (in ppm) in a 3.50-g pill that contains 40.5 mg of Ca.

    Given:
    Mass of solution=3.50 g
    Mass of calcium=40.5 mg

    Find: % by mass of calcium in ppm


    mass of solute
    Formula: ppm= ×1.0 ×106
    mass of solution
    Solution:
    g
    40.5 mgCa × 3
    10 mg
    × 106=1.16 × 104 ppm Ca
    3.5 g

    b) The label on a 0.750-L bottle of Italian chianti indicates “11.5% alcohol by volume” How many
    liters of alcohol does the wine contain?

    Given:
    Alcohol by volume=11.5%
    Bottle of Italian Chianti=0.750 L

    Find: The Number of liters of alcohol in a wine


    Solution:
    11.5 L alcohol
    0.750 L chianti × =0.0862 L alcohol
    100 L ch ianti

    c) A sample of rubbing alcohol contains 142 g of isopropyl alcohol (C 3 H 7 OH ¿ and 58.0 g of water.
    What are the mole fractions of alcohol and water?

    Given:
    Water (solvent)=58.0 g
    Isopropyl alcohol=142 g

    Find: Find for the mole of fraction in water and alcohol


    Solution:
    mole
    moles of ethelyne glycol=142 g =2.36 mol C 3 H 8 O
    60.09 g
    2.39 mol C3 H 8 O
    2.39 mol C3 H 8 O 2 +3.22 mol H 2 O
    ¿ 0.423 C2 H 6 O 2

    mole
    moles of water=38.0 g =3.22 mol H 2 O
    18.02 g
    3.22 mol H 2 O
    2.39 mol C3 H 8 O 2 +3.22 mol H 2 O
    ¿ 0.577 H 2 O
    2. Interconverting Concentration Terms

    a) Given:
    Solution by mass=30.0%
    Density of mass=1.11g/mL

    Find: Mass of solvent and Calculate its molality


    Solution:
    g of H 2 O=100 g solution−30.0 g H 2 O 2=70.0 g H 2 O
    mol H 2 O
    30.0 g H 2 O2 =0.882mol H 2 O2
    34.02 g H 2 O2
    Calculate its Molality
    Formula:
    no .of moles solute
    molality =
    Kilogram solvent
    Solution:
    0.882 mol H 2 O2
    Molality= =12.6 m H 2 O2
    1 kg
    70.0 g × 3
    10 g

    b) Given:
    Moles of solute fraction=70.0 g
    Mass percent=0.882 mol H2O2

    Find: Mole fractions of H 2 O2


    Formula:
    moles solut e
    mole fraction solute=
    moles solution
    moles solute
    mole fraction solvent=
    moles solution

    Solution:

    1mol H 2 O
    70.0 g H 2 O× =3.88 mol H 2 O
    18.02 g H 2 O
    0.882 mol H 2 O 2
    X H 2 O 2= =0.185
    3.88mol H 2 O+0.882 mol H 2 O 2

    c) Solution
    1 mL
    volume ( mL ) of solution=100.0 g × =90.1 mL
    1.11 g
    mol H 2 O2 0.882mol H 2 O2
    molarity= = =9.79 M H 2 O2
    L soln 1 L soln
    90.1 mL× 3
    10 mL
    Evaluation
    1.) What mass of CO is required to react with 25.13 g of Fe2O3 according to the equation
    Fe2O3+3CO⟶2Fe+3CO2?

    Given:

    Find:
    Formula:

    Solution:
    1 mol of Fe2 O3 3 mol of Co 28.01 g CO
    25.13 of Fe2 O3 × × × =13.22 g
    159.69 g of Fe2 O 3 1 mol of Fe 2 O3 1 mol of CO

    2.) A 20.00-mL sample of aqueous oxalic acid, H2C2O4, was titrated with a 0.09113-M solution of
    potassium permanganate, KMnO4.

    Given:

    Find:
    Formula:

    Solution:
    5 H 2 C 2 O 4+ 2¿
    0.02324 L ×0.09113 mol ¿ ¿

    3) What is the percent of chloride ion in a sample if 1.1324 g of the sample produces 1.0881 g of
    AgCl when treated with excess Ag+ ?

    Given:

    Find:
    Formula:

    Solution:
    g AgCl → moles AgCl →moles Cl−1 → g → %
    g
    MW AgCl=143.32
    mol
    g
    MW Cl−1=35.45
    mol
    1 mol AgCl 1mol Cl−1 35.4 g 100
    1.0881 g × × × × =23.76 %
    143.32 g 1 mol AgCl 1 mol Cl −1
    1.324 g
    4) A 0.00215-g sample of polystyrene, a polymer composed of carbon and hydrogen, produced
    0.00726 g of CO2 and 0.00148 g of H2O in a combustion analysis. What is the empirical formula
    for polystyrene?

    Given:

    Find:
    Formula:

    Solution:
    y
    C x H y ( s ) +O 2 ( g ) → x CO 2 ( g ) +
    H O ( g)
    2 2
    1 mol CO2 1 mol C
    0.00726 × ×
    43.99 g 1 mol CO 2=1.64 ×10−4 mol H
    1.64 ×10−4 mol H
    =1 so CH
    1.65 ×10−4 mol C

    5) A solution contains 5.00 g of urea, CO(NH2)2 (a nonvolatile solute) and 0.100 kg of water. If the
    vapor pressure of pure water at 25 °C is 23.7 torr, what is the vapor pressure of the solution
    assuming ideal behavior?

    Solution:

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