Introduction To Ammonia Production - AIChE
Introduction To Ammonia Production - AIChE
BACK TO BASICS
SEPTEMBER 2016
Most people associate the pungent smell of ammonia (NH3) with cleaners or
smelling salts. However, the use of ammonia in these two products represents only
a small fraction of the total global ammonia production, which was around 176
million metric tons in 2014 (1). To appreciate where the industry and technology are
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Ammonia has been known for more than 200 years. Joseph Priestley, an English
chemist, first isolated gaseous ammonia in 1774. Its composition was ascertained by
French chemist Claude Louis Berthollet in 1785. In 1898, Adolph Frank and
Nikodem Caro found that N2 could be fixed by calcium carbide to form calcium
cyanamide, which could then be hydrolyzed with water to form ammonia (2):
CaO + 3C ↔ CaC2 + CO
CaC2 + N2 ↔ CaCN2 + C
did not occur until the early 20th century. Because this process required large
amounts of energy, scientists focused their efforts on reducing energy requirements.
German chemist Fritz Haber performed some of the most important work in the
development of the modern ammonia industry. Working with a student at the Univ.
of Karlsruhe, he synthesized ammonia in the laboratory from N2 and H2.
iron catalyst at 1,000°C and 75 barg pressure. He was able to produce larger
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Nonetheless, both Haber and Nernst pursued the high-pressure route to produce
Haber realized that the amount of ammonia formed in a single pass through a
converter was far too low to be of commercial interest. To produce more ammonia
from the makeup gas, he proposed a recycle system, and received a patent for the
After testing more than 2,500 different catalysts, Carl Bosch, Alvin Mittasch, and
other BASF chemists developed a promoted iron catalyst for the production of
ammonia in 1910. Developing equipment that could withstand the necessary high
temperatures and pressure was an even more difficult task. An early mild steel
reactor lasted only 80 hours before failure due to decarbonization. Lining mild steel
reactors with soft iron (which was not vulnerable to decarbonization) and adding
grooves between the two liners to release hydrogen that had diffused through the
soft iron liner solved
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The first commercial ammonia plant based on the Haber-Bosch process was built by
BASF at Oppau, Germany. The plant went on-stream on Sept. 9, 1913, with a
▲Figure 1. This is a simplified flowsheet of the first commercial ammonia plant by BASF.
Figure 1 is a flowsheet of the first commercial ammonia plant. The reactor contained
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▲Figure 2. Worldwide ammonia production has steadily increased from 1946 to 2014.
Ammonia production has become one of the most important industries in the
world. Without the crop yield made possible by ammonia-based fertilizers and
chemicals, the global population would be at least two to three billion less than it is
today (3). Ammonia production has increased steadily since 1946 (Figure 2), and it
is estimated that the annual production of ammonia is worth more than $100
billion, with some plants producing more than 3,000 m.t./day of NH3.
In 1983, on the occasion of the 75th anniversary of AIChE’s founding, a blue ribbon
world’s ten greatest chemical engineering achievements (4). Embracing such feats
as wonder drugs, synthetic fibers, and atomic energy, the citation also included the
breakthrough
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Within the past decades, chemical engineers have succeeded in creating processes
that make vast amounts of ammonia at relatively low costs. As recently as 80 years
ago, the total annual production of synthesized ammonia was just over 300,000
of fertilizer. Most of the remainder goes into the production of formaldehyde. China
produced about 32.6% of the global production in 2014, while Russia, India, and the
U.S. produced 8.1%, 7.6%, and 6.4%, respectively (1). While most of the global
quantities are produced by coal gasification; most of the gasification plants are
located in China.
unrelated units, such as gas preparation, gas purification, gas compression, and
ammonia synthesis. New innovations and an integral design tied process units
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▲Figure 3. KBR designed one of the first single-train, large-capacity ammonia plants.
In the mid-1960s, the American Oil Co. installed a single-converter ammonia plant
engineered by M.W. Kellogg (MWK) at Texas City, TX, with a capacity of 544
pressure of 152 bar, and final compression to an operating pressure of 324 bar
occurred in a reciprocating compressor. Centrifugal compressors for the synthesis
loop and refrigeration services were also implemented, which provided significant
cost savings.
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The key differences between the MWK process and the processes used in previous
ammonia plants included:
generating steam from the waste heat for use in steam turbine drivers
Most plants built between 1963 and 1993 had large single-train designs with
synthesis gas production at 25–35 bar and ammonia synthesis at 150–200 bar.
Another variation by Braun (now KBR) offered slight modifications to the basic
design. The Braun Purifier process plants utilized a primary or tubular reformer
with a low outlet temperature and high methane leakage to reduce the size and cost
of the reformer. Excess air was added to the secondary reformer to reduce the
methane content of the primary reformer exit stream to 1–2%. Excess nitrogen and
other impurities were removed downstream of the methanator. Because the
synthesis gas was essentially free of impurities, two axial-flow ammonia converters
were used to achieve a high ammonia conversion.
Some recently built plants have a synthesis gas generation system with only one
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reformer (no secondary reformer), a pressure-swing adsorption (PSA) system for
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H2 recovery, and an air separation plant as the source of N2. Improvements in
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converter design, such as radial and horizontal catalyst beds, internal heat
efficiency. Most modern plants can produce ammonia with an energy consumption
of 28 GJ/m.t.
reduced. When the first single-train plant was built in the 1960s, it contained a
high-pressure synthesis loop. In 1962, MWK received an inquiry from Imperial
Because the development of kinetic data for the ammonia reaction at 152 bar would
take more time than MWK had to respond to the ICI inquiry, they contacted Haldor
Topsøe to support their plans. Topsøe had data covering the entire pressure range
of interest to MWK. In addition, they had a computer program for calculating the
quantity of catalyst that was required at the lower operating pressure. Even though
ICI chose Bechtel to design the plant, MWK was able to develop a flowsheet for a
544-m.t./day design with centrifugal compressors and a low-pressure synthesis
loop, which some people consider the single most important event in the
development ofuse
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Approximately twice as much catalyst was required at 152 bar as at 324 bar, an
increase that seemed economically feasible. Although the converter would need
twice the volume, the lower operating pressure would reduce the required thickness
of the pressure shell. As a result, the weight of metal required for the converter plus
the catalyst remained about the same. The lower-pressure synthesis loop also
During the first few years of the 21st century, many improvements were made in
ammonia plant technology that allow existing plants to increase production rates
and new plants to be built with larger and larger capacities. Competition between
technology suppliers is quite fierce. Three technology licensors — KBR (Kellogg
Brown and Root), Haldor Topsøe, and ThyssenKrupp Industrial Solutions (TKIS) —
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▲Figure 4. Modern ammonia plants designed by KBR employ its proprietary Purifier design.
Most of the ammonia plants recently designed by KBR utilize its Purifier process
(Figure 4), which combines low-severity reforming in the primary reformer, a liquid
N2 wash purifier downstream of the methanator to remove impurities and adjust
the H2:N2 ratio, a proprietary waste-heat boiler design, a unitized chiller, and a
impurities suchtoas
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use of 4, and argon from the synthesis gas while adjusting the
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H2:N2 ratio of the makeup gas in the ammonia loop to the optimum level. The
ammonia concentration exiting the low-pressure-drop horizontal converter is 20–
21%, which reduces energy requirements for the recycle compressor. KBR also
offers a low-pressure ammonia loop that employs a combination of magnetite
catalyst and its proprietary ruthenium catalyst.
▲Figure 5. Haldor Topsøe offers an ammonia plant design that has a proprietary side-fired
reformer in which radiant burners supply heat for the reforming reaction.
The syngas generation section (or front end) of a Haldor Topsøe-designed plant
reformer, which uses radiant burners to supply heat for the reforming reaction.
Haldor Topsøe also offers a proprietary iron-based synthesis catalyst, radial-flow
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converters consisting of one, two, or three beds, and a proprietary
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waste-heat boiler. More recent developments include the S-300 and S-350
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ammonia conversion.
pressure ammonia synthesis loop. Today, a production rate of 3,300 m.t./day can
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▲Figure 7. The Linde Ammonia Concept (LAC) features a pressure-swing adsorption unit for
high-purity hydrogen production and an air separation unit for high-purity nitrogen production.
with over 25 years of operating experience in plants with capacities from 200
m.t./day to over 1,750 m.t./day. The LAC process scheme (Figure 7) replaces the
costly and complex front end of a conventional ammonia plant with two well-
PSA purification
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▲Figure 8. Ammonia Casale’s process employs a catalyst bed that harnesses axial-radial
technology, which has a lower pressure drop and higher efficiency than standard catalyst beds.
Ammonia Casale’s plant design has a production rate of 2,000 m.t./day. One of the
key features of this design is axial-radial technology in the catalyst bed (Figure 8).
In an axial-radial catalyst bed, most of the synthesis gas passes through the catalyst
bed in a radial direction, creating a very low pressure drop. The rest of the gas
passes down through a top layer of catalyst in an axial direction, eliminating the
need for a top cover on the catalyst bed. Casale’s axial-radial catalyst bed technology
is used in both high-temperature and low-temperature shift converters, as well as in
Other technologies
Some technology suppliers have offered gas-heated reformers (GHRs) for the
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production of ammonia in small-capacity plants or for capacity Unlike
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operating in series, plants with GHRs use the hot process gas from the secondary
reformer to supply heat to the primary reformer. This reduces the size of the
primary reformer and eliminates CO2 emissions from the primary reformer stack,
ammonia in small ammonia plants, most companies prefer to build large facilities
near cheap raw material sources and transport the product by ship, rail, or pipeline
to the consumers.
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China produces more ammonia than any other country, and produces the majority
The basic processing units in a coal-based ammonia plant are the ASU for the
separation of O2 and N2 from air, the gasifier, the sour gas shift (SGS) unit, the acid
gas removal unit (AGRU), and the ammonia synthesis unit. Oxygen from the ASU is
fed to the gasifier to convert coal into synthesis gas (H2, CO, CO2) and CH4. There
are many gasifier designs, but most modern gasifiers are based on fluidized beds
that operate above atmospheric pressure and have the ability to utilize different coal
feeds. Depending on the design, CO levels of 30–60% by volume may be produced.
After gasification, any particulate matter in the synthesis gas is removed and steam
is added to the SGS unit. The SGS process typically utilizes a cobalt and
molybdenum (CoMo) catalyst specially designed for operation in a sulfur
environment.
After reducing the CO concentration in the synthesis gas to less than 1 vol%, the
Rectisol) removes CO2 and sulfur from the synthesis gas. The CO2 overhead is either
vented or fed to a urea plant. The sulfur outlet stream is fed to a sulfur recover unit
(SRU).
Syngas that passes through the AGRU is typically purified by one of two methods:
aOur
nitrogen wash
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Closing thoughts
During the past 60 years, ammonia process technology has improved drastically.
Plant layouts evolved from multi-train designs, often with different numbers of
trains in the front end and synthesis loop, to single-train designs. Synthesis gas
preparation in the front end of the plant increased from atmospheric pressure to
30–50 barg pressure. Capacities increased from 100 m.t./day to as much as 3,300
based plants to 30–40 GJ/m.t. in the first single-train plants. Modern plants have
added heat recovery by steam production at pressures as high as 125 barg in both
Designers have tapped into hydrogen recovery from purge gas (in units such as PSA
systems) to enhance production or reduce the plant energy consumption. Designers
have also implemented hot feed gas desulfurization systems. There have been
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To improve process control and safety, distributed control systems (DCSs) for
advanced process control, as well as safety-instrumented systems (SISs), are now
standard in ammonia plants. Before any process goes online, hazard and operability
(HAZOP) studies and layer of protection analyses (LOPAs) are performed. Advances
in training simulators and education practices ensure that operators and engineers
These are just a few of the thousands of improvements in technology and safety that
have been implemented to make the ammonia industry one of the most productive
Literature Cited
2. Slack, A. V., and G. R. James (eds.), “Ammonia,” Parts I, II, and III,
3. Smil, V., “Enriching the Earth – Fritz Haber, Carl Bosch, and the
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Acknowledgments
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