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10/4/21, 12:25 PM Introduction to Ammonia Production | AIChE

Home Publications CEP September 2016

Introduction to Ammonia Production

Introduction to Ammonia Production

BACK TO BASICS

SEPTEMBER 2016

VENKAT PATTABATHULA, JIM RICHARDSON

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Ammonia is critical in the manufacturing of fertilizers, and is one of the

largest-volume synthetic chemicals produced in the world. This article

explores the evolution of ammonia production and describes the


current manufacturing technologies.

Most people associate the pungent smell of ammonia (NH3) with cleaners or
smelling salts. However, the use of ammonia in these two products represents only

a small fraction of the total global ammonia production, which was around 176
million metric tons in 2014 (1). To appreciate where the industry and technology are
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Ammonia has been known for more than 200 years. Joseph Priestley, an English

chemist, first isolated gaseous ammonia in 1774. Its composition was ascertained by
French chemist Claude Louis Berthollet in 1785. In 1898, Adolph Frank and
Nikodem Caro found that N2 could be fixed by calcium carbide to form calcium

cyanamide, which could then be hydrolyzed with water to form ammonia (2):

CaO + 3C ↔ CaC2 + CO

CaC2 + N2 ↔ CaCN2 + C

CaCN2 + 3H2O ↔ CaCO3 + 2NH3

The production of significant quantities of ammonia using the cyanamide process

did not occur until the early 20th century. Because this process required large
amounts of energy, scientists focused their efforts on reducing energy requirements.

German chemist Fritz Haber performed some of the most important work in the

development of the modern ammonia industry. Working with a student at the Univ.
of Karlsruhe, he synthesized ammonia in the laboratory from N2 and H2.

Meanwhile, Walther Nernst, a professor of physical chemistry at the Univ. of Berlin,


developed a process to make ammonia by passing a mixture of N2 and H2 across an

iron catalyst at 1,000°C and 75 barg pressure. He was able to produce larger

quantities of ammonia at this pressure than earlier experiments by Haber and


others
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Nonetheless, both Haber and Nernst pursued the high-pressure route to produce

ammonia over a catalyst. Haber finally developed a process for producing


commercial quantities of ammonia, and in 1906 he was able to achieve a 6%

ammonia concentration in a reactor loaded with an osmium catalyst. This is

generally recognized as the turning point in the development of a practical process


for the production of ammonia in commercial quantities.

Haber realized that the amount of ammonia formed in a single pass through a

converter was far too low to be of commercial interest. To produce more ammonia
from the makeup gas, he proposed a recycle system, and received a patent for the

concept. Haber’s recycle idea changed the perception of process engineering as

static in favor of a more dynamic approach. In addition to the chemical reaction


equilibrium, Haber recognized that reaction rate was a determining factor. Instead

of simple yield in a once-through process, he concentrated on space-time yield in a

system with recycle.

BASF purchased Haber’s patents and started development of a commercial process.

After testing more than 2,500 different catalysts, Carl Bosch, Alvin Mittasch, and

other BASF chemists developed a promoted iron catalyst for the production of
ammonia in 1910. Developing equipment that could withstand the necessary high

temperatures and pressure was an even more difficult task. An early mild steel

reactor lasted only 80 hours before failure due to decarbonization. Lining mild steel

reactors with soft iron (which was not vulnerable to decarbonization) and adding

grooves between the two liners to release hydrogen that had diffused through the
soft iron liner solved
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The first commercial ammonia plant based on the Haber-Bosch process was built by

BASF at Oppau, Germany. The plant went on-stream on Sept. 9, 1913, with a

production capacity of 30 m.t./day.

▲Figure 1. This is a simplified flowsheet of the first commercial ammonia plant by BASF.

Figure 1 is a flowsheet of the first commercial ammonia plant. The reactor contained

an internal heat exchanger in addition to those shown on the schematic.

Global production rates

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▲Figure 2. Worldwide ammonia production has steadily increased from 1946 to 2014.

Ammonia production has become one of the most important industries in the

world. Without the crop yield made possible by ammonia-based fertilizers and

chemicals, the global population would be at least two to three billion less than it is

today (3). Ammonia production has increased steadily since 1946 (Figure 2), and it

is estimated that the annual production of ammonia is worth more than $100

billion, with some plants producing more than 3,000 m.t./day of NH3.

In 1983, on the occasion of the 75th anniversary of AIChE’s founding, a blue ribbon

panel of distinguished chemical engineers named what they believed to be the

world’s ten greatest chemical engineering achievements (4). Embracing such feats

as wonder drugs, synthetic fibers, and atomic energy, the citation also included the

breakthrough
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Within the past decades, chemical engineers have succeeded in creating processes
that make vast amounts of ammonia at relatively low costs. As recently as 80 years

ago, the total annual production of synthesized ammonia was just over 300,000

m.t. Thanks to chemical engineering breakthroughs, one modern ammonia plant

can produce more than 750,000 m.t./yr.

Approximately 88% of ammonia made annually is consumed in the manufacturing

of fertilizer. Most of the remainder goes into the production of formaldehyde. China
produced about 32.6% of the global production in 2014, while Russia, India, and the

U.S. produced 8.1%, 7.6%, and 6.4%, respectively (1). While most of the global

production of ammonia is based on steam reforming of natural gas, significant

quantities are produced by coal gasification; most of the gasification plants are

located in China.

Modern production processes

The tremendous increase in ammonia demand from 1950 to 1980 necessitated

larger, more-energy-efficient plants. Those decades also saw a change in design


philosophy. Until that time, an ammonia plant was regarded as an assembly of

unrelated units, such as gas preparation, gas purification, gas compression, and
ammonia synthesis. New innovations and an integral design tied process units

together in the most effective and efficient ways.

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▲Figure 3. KBR designed one of the first single-train, large-capacity ammonia plants.

In the mid-1960s, the American Oil Co. installed a single-converter ammonia plant
engineered by M.W. Kellogg (MWK) at Texas City, TX, with a capacity of 544

m.t./day. The single-train design concept (Figure 3) was so revolutionary that it


received the Kirkpatrick Chemical Engineering Achievement Award in 1967.

The plant used a four-case centrifugal compressor to compress the syngas to a

pressure of 152 bar, and final compression to an operating pressure of 324 bar
occurred in a reciprocating compressor. Centrifugal compressors for the synthesis
loop and refrigeration services were also implemented, which provided significant

cost savings.
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The key differences between the MWK process and the processes used in previous
ammonia plants included:

using a centrifugal compressor as part of the synthesis gas compression

maximizing the recovery of waste heat from the process

generating steam from the waste heat for use in steam turbine drivers

using the refrigeration compressor for rundown and atmospheric refrigeration.

An integrated scheme that balanced energy consumption, energy production,


equipment size, and catalyst volumes was incorporated throughout the plant.

Most plants built between 1963 and 1993 had large single-train designs with

synthesis gas production at 25–35 bar and ammonia synthesis at 150–200 bar.
Another variation by Braun (now KBR) offered slight modifications to the basic

design. The Braun Purifier process plants utilized a primary or tubular reformer
with a low outlet temperature and high methane leakage to reduce the size and cost
of the reformer. Excess air was added to the secondary reformer to reduce the

methane content of the primary reformer exit stream to 1–2%. Excess nitrogen and
other impurities were removed downstream of the methanator. Because the

synthesis gas was essentially free of impurities, two axial-flow ammonia converters
were used to achieve a high ammonia conversion.

Some recently built plants have a synthesis gas generation system with only one
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H2 recovery, and an air separation plant as the source of N2. Improvements in
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converter design, such as radial and horizontal catalyst beds, internal heat

exchangers, and synthesis gas treatment, helped increase ammonia concentrations


exiting the synthesis converter from about 12% to 19–21%. A higher conversion per
pass, along with more-efficient turbines and compressors, further reduced energy

consumption. More-efficient CO2 removal solutions, such as potassium carbonate


and methyldiethanolamine (MDEA), have contributed to improved energy

efficiency. Most modern plants can produce ammonia with an energy consumption
of 28 GJ/m.t.

In addition to the design, mechanical, and metallurgical improvements made


during this time, the operating pressure of the synthesis loop was significantly

reduced. When the first single-train plant was built in the 1960s, it contained a
high-pressure synthesis loop. In 1962, MWK received an inquiry from Imperial

Chemical Industries (ICI) for a proposal to build a 544-m.t./day plant at their


Severnside site. MWK proposed a 152-bar synthesis loop instead of a 324-bar loop.

Because the development of kinetic data for the ammonia reaction at 152 bar would
take more time than MWK had to respond to the ICI inquiry, they contacted Haldor

Topsøe to support their plans. Topsøe had data covering the entire pressure range
of interest to MWK. In addition, they had a computer program for calculating the

quantity of catalyst that was required at the lower operating pressure. Even though
ICI chose Bechtel to design the plant, MWK was able to develop a flowsheet for a
544-m.t./day design with centrifugal compressors and a low-pressure synthesis

loop, which some people consider the single most important event in the
development ofuse
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Approximately twice as much catalyst was required at 152 bar as at 324 bar, an
increase that seemed economically feasible. Although the converter would need

twice the volume, the lower operating pressure would reduce the required thickness
of the pressure shell. As a result, the weight of metal required for the converter plus
the catalyst remained about the same. The lower-pressure synthesis loop also

allowed the use of centrifugal compressors instead of reciprocating compressors.


Another improvement was recovering heat to generate high-pressure steam for

steam turbine drives.

Plant designs in the 21st century

During the first few years of the 21st century, many improvements were made in
ammonia plant technology that allow existing plants to increase production rates

and new plants to be built with larger and larger capacities. Competition between
technology suppliers is quite fierce. Three technology licensors — KBR (Kellogg
Brown and Root), Haldor Topsøe, and ThyssenKrupp Industrial Solutions (TKIS) —

currently dominate the market. Ammonia Casale, which offers an axial-radial


catalyst bed design, is a market leader in revamps of existing plants.

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▲Figure 4. Modern ammonia plants designed by KBR employ its proprietary Purifier design.

Most of the ammonia plants recently designed by KBR utilize its Purifier process

(Figure 4), which combines low-severity reforming in the primary reformer, a liquid
N2 wash purifier downstream of the methanator to remove impurities and adjust
the H2:N2 ratio, a proprietary waste-heat boiler design, a unitized chiller, and a

horizontal ammonia synthesis converter.

Depending on the configuration of the plant, energy consumption can be as low as


28 GJ/m.t. Because the secondary reformer uses excess air, the primary reformer

can be smaller than in conventional designs. The cryogenic purifier (shown in


Figure
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H2:N2 ratio of the makeup gas in the ammonia loop to the optimum level. The
ammonia concentration exiting the low-pressure-drop horizontal converter is 20–

21%, which reduces energy requirements for the recycle compressor. KBR also
offers a low-pressure ammonia loop that employs a combination of magnetite
catalyst and its proprietary ruthenium catalyst.

▲Figure 5. Haldor Topsøe offers an ammonia plant design that has a proprietary side-fired
reformer in which radiant burners supply heat for the reforming reaction.

The syngas generation section (or front end) of a Haldor Topsøe-designed plant

(Figure 5) is quite traditional with the exception of its proprietary side-fired

reformer, which uses radiant burners to supply heat for the reforming reaction.
Haldor Topsøe also offers a proprietary iron-based synthesis catalyst, radial-flow
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converter designs. The S-300 converter is a three-bed radial-flow configuration with


internal heat exchangers, while the S-350 design combines an S-300 converter with

an S-50 single-bed design with waste-heat recovery between converters to maximize

ammonia conversion.

▲Figure 6. ThyssenKrupp’s dual-pressure synthesis loop design features a once-through


reactor between syngas compressors.

ThyssenKrupp offers a conventional plant (Figure 6) with a unique secondary


reformer design, a proprietary waste-heat boiler, radial-flow converters, and a dual-

pressure ammonia synthesis loop. Today, a production rate of 3,300 m.t./day can

be achieved using the TKIS dual-pressure process.

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▲Figure 7. The Linde Ammonia Concept (LAC) features a pressure-swing adsorption unit for
high-purity hydrogen production and an air separation unit for high-purity nitrogen production.

The Linde Ammonia Concept (LAC) is an established technology process scheme

with over 25 years of operating experience in plants with capacities from 200
m.t./day to over 1,750 m.t./day. The LAC process scheme (Figure 7) replaces the

costly and complex front end of a conventional ammonia plant with two well-

proven, reliable process units:

production of ultra-high-purity hydrogen from a steam-methane reformer with

PSA purification

production of ultra-high-purity nitrogen by a cryogenic nitrogen generation

unit, also known as an air separation unit (ASU).

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▲Figure 8. Ammonia Casale’s process employs a catalyst bed that harnesses axial-radial
technology, which has a lower pressure drop and higher efficiency than standard catalyst beds.

Ammonia Casale’s plant design has a production rate of 2,000 m.t./day. One of the

key features of this design is axial-radial technology in the catalyst bed (Figure 8).

In an axial-radial catalyst bed, most of the synthesis gas passes through the catalyst
bed in a radial direction, creating a very low pressure drop. The rest of the gas

passes down through a top layer of catalyst in an axial direction, eliminating the

need for a top cover on the catalyst bed. Casale’s axial-radial catalyst bed technology
is used in both high-temperature and low-temperature shift converters, as well as in

the synthesis converter.

Other technologies

Some technology suppliers have offered gas-heated reformers (GHRs) for the
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operating in series, plants with GHRs use the hot process gas from the secondary
reformer to supply heat to the primary reformer. This reduces the size of the

primary reformer and eliminates CO2 emissions from the primary reformer stack,

making the process more environmentally friendly.

Even though some ammonia producers advocate for distributed production of

ammonia in small ammonia plants, most companies prefer to build large facilities

near cheap raw material sources and transport the product by ship, rail, or pipeline
to the consumers.

Ammonia from coal

▲Figure 9. China produces most of its ammonia from coal.

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China produces more ammonia than any other country, and produces the majority

of its ammonia from coal (Figure 9).

The basic processing units in a coal-based ammonia plant are the ASU for the

separation of O2 and N2 from air, the gasifier, the sour gas shift (SGS) unit, the acid

gas removal unit (AGRU), and the ammonia synthesis unit. Oxygen from the ASU is
fed to the gasifier to convert coal into synthesis gas (H2, CO, CO2) and CH4. There

are many gasifier designs, but most modern gasifiers are based on fluidized beds

that operate above atmospheric pressure and have the ability to utilize different coal
feeds. Depending on the design, CO levels of 30–60% by volume may be produced.

After gasification, any particulate matter in the synthesis gas is removed and steam

is added to the SGS unit. The SGS process typically utilizes a cobalt and
molybdenum (CoMo) catalyst specially designed for operation in a sulfur

environment.

After reducing the CO concentration in the synthesis gas to less than 1 vol%, the

syngas is fed to an AGRU, where a chilled methanol scrubbing solution (e.g.,

Rectisol) removes CO2 and sulfur from the synthesis gas. The CO2 overhead is either

vented or fed to a urea plant. The sulfur outlet stream is fed to a sulfur recover unit
(SRU).

Syngas that passes through the AGRU is typically purified by one of two methods:

aOur
nitrogen wash
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a PSA system for CO and CH4 removal.

Closing thoughts

During the past 60 years, ammonia process technology has improved drastically.

Plant layouts evolved from multi-train designs, often with different numbers of

trains in the front end and synthesis loop, to single-train designs. Synthesis gas
preparation in the front end of the plant increased from atmospheric pressure to

30–50 barg pressure. Capacities increased from 100 m.t./day to as much as 3,300

m.t./day in a single train.

Energy efficiencies have improved as well — from consumptions well above 60

GJ/m.t. of ammonia in coke-based plants to 40–50 GJ/m.t. in the first natural-gas-

based plants to 30–40 GJ/m.t. in the first single-train plants. Modern plants have
added heat recovery by steam production at pressures as high as 125 barg in both

the syngas preparation section and the synthesis loop.

In terms of process equipment, there has been a shift from reciprocating


compressors to centrifugal compressors. An internal heat exchanger has been

implemented in the synthesis converter to increase conversion of H2 and N2 to NH3.

Designers have tapped into hydrogen recovery from purge gas (in units such as PSA
systems) to enhance production or reduce the plant energy consumption. Designers

have also implemented hot feed gas desulfurization systems. There have been

significant improvements in the catalysts used in reforming, shift conversion,


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To improve process control and safety, distributed control systems (DCSs) for
advanced process control, as well as safety-instrumented systems (SISs), are now

standard in ammonia plants. Before any process goes online, hazard and operability

(HAZOP) studies and layer of protection analyses (LOPAs) are performed. Advances
in training simulators and education practices ensure that operators and engineers

can perform their duties safely and effectively.

These are just a few of the thousands of improvements in technology and safety that
have been implemented to make the ammonia industry one of the most productive

and safe industries in the world.

Literature Cited

1. U.S. Geological Survey, “Nitrogen (Fixed) — Ammonia Statistics,”


minerals.usgs.gov/minerals/pubs/historical-statistics/ds140-nitro.xlsx (Last

Modified: Jan. 28, 2016).

2. Slack, A. V., and G. R. James (eds.), “Ammonia,” Parts I, II, and III,

Marcel Dekker, New York, NY (1974).

3. Smil, V., “Enriching the Earth – Fritz Haber, Carl Bosch, and the

Transformation of World Food Production,” The MIT Press, Cambridge, MA


(Dec. 2000).

4. Williams, G., and V. Pattabathula, “One Hundred Years of Ammonia

Production — A Recap of Significant Contributions to Feeding the World,” 58th


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Acknowledgments

The authors acknowledge the assistance of KBR, ThyssenKrupp Industrial


Solutions, Haldor Topsøe, Linde, and Casale for providing technical literature on

their respective process technologies.

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Catalyzing Commercialization: Transparent Panels Open a New Window


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Editorial: Healthy Employees, Healthy Company


This is an expanded version of the Editorial that appeared in the print version of Chemical
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CEP: News Update


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Patent Update: Issues to Consider in Claiming Your Invention


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YPOV: Get Back on Your Feet After a Layoff


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Process Safety Beacon: Do You Recognize Change?


In 2014, a fire occurred on a passenger vessel in the Atlantic Ocean about a mile from the U.S. A
crewmember discovered the small fuel spray fire above one of the four propulsion engines during
his routine rounds. He left the area and informed the bridge. Proper emergency procedures were
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