Datos

Qg 25 MMpcnd L 0.034445
T° de entrada (G 100 °F V 0.965555
P° de entrada (G 500 Lpca
T° de salida(GN) -15 °F
P° de salida (GN) 500 Lpca

CORIENTE 1 Xi=𝑍𝑖/(𝐿+𝑉∗𝐾𝑖)

COMPONETE %Moles Zi (gas conndKi(3000 psia) Zi/ki Zi*Ki Xi

C1 73 0.73 6.12 0.1192810458 4.4676 0.12282033
C2 11 0.11 1.4 0.0785714286 0.154 0.07935237
C3 8 0.08 0.51 0.1568627451 0.0408 0.15183779
nC4 4 0.04 0.18 0.2222222222 0.0072 0.19208153
nC5 3 0.03 0.071 0.4225352113 0.00213 0.29126382
nC6 1 0.01 0.028 0.3571428571 0.00028 0.16265309
TOTAL 100 1 1.3566155101 4.67201 1.00000893

PARA EL LIQUIDO
COMPONENTES Xi=Zi/(L+V*KiPM PC TC PM*Xi PC*Xi
C1 0.12282033 16.043 667 343.34 1.97040649 81.9211576
C2 0.07935237 30.07 707.8 550.07 2.38612574 56.165607
C3 0.15183779 44.097 615 665.92 6.69559113 93.3802424
nC4 0.19208153 58.123 548.123 765.51 11.164355 105.284307
nC5 0.29126382 72.15 488.1 845.7 21.0146845 142.16587
nC6 0.16265309 86.177 439.5 911.8 14.0169556 71.4860344
TOTAL 1.00000893 306.66 57.2481185 550.403218

152,557𝐵𝑇𝑈/𝑙𝑏𝑚∗57,248
Pr 0.90842492
𝑙𝑏𝑚/𝑙𝑏𝑚𝑜𝑙=8733,613 𝐵𝑇𝑈/𝑙𝑏𝑚𝑜𝑙
Tr 0.79604771

Conversion de unidades de Hoi * mi = s°=78,15273-(1,986*(-1,716416)

entalpia real de la mezcla = S°-S=R*(4,56+0,1711317*6)+Ln(500/14,7)

H° 152.557211 8733.61328 (BTU/Lbmol) S 63.4620196

[((𝐻^𝑂−𝐻))/ 〖𝑅𝑇〗 _𝑐 ]^𝑂=4,5

(𝐻°−𝐻)=𝑅𝑇𝑐([(𝐻^𝑂−𝐻)/𝑅𝑇𝑐]^𝑂+ ∗[((𝐻°−𝐻))/𝑅𝑇𝑐])
4.5

[((𝐻^𝑂−𝐻))/ 〖𝑅𝑇〗
6.1 _𝑐 ]^𝑂=6,1 (𝐻^𝑂−𝐻)=1,986∗728,59955∗((4,5)+0,1711317∗(6,1))

(Ho-H)= 8022.02097
H= 711.592313 711.59231342

PARA GAS
COMPONENTES Yi PM PC TC PM*Yi Pc*Yi
C1 0.7516604 16.043 667 343.34 12.0588877 501.357484
C2 0.11109332 30.07 707.8 550.07 3.34057604 78.6318497
C3 0.07743727 44.097 615 665.92 3.41475148 47.6239236
nC4 0.03457468 58.123 548.123 765.51 2.00958391 18.9511753
nC5 0.02067973 72.15 488.1 845.7 1.4920426 10.0937768
nC6 0.00455429 86.177 439.5 911.8 0.39247476 2.00160896
TOTAL 0.99999968 22.7083165 658.659819

ENTALPIAS

225,918𝐵𝑇𝑈/𝑙𝑏𝑚∗22,708 Pr
𝑙𝑏𝑚/𝑙𝑏𝑚𝑜𝑙=5130,221 𝐵𝑇𝑈/𝑙𝑏𝑚𝑜𝑙 Tc

ENTALPIA DE 5130.21745 BTU/lbmol (Ho)

(𝐻^𝑂−𝐻)=1,986∗418,8599118∗(4,5)+(0,03349096∗0,152)
[((𝐻^𝑂−𝐻))/ 〖𝑅𝑇〗 _𝑐 ]^𝑂=0,45
(H°-H)= 374.3402 0.45

[((𝐻^𝑂−𝐻))/ 〖𝑅𝑇〗 _𝑐 ]^𝑂=0,152

H=H° - (H° - H) 0.152

H= 4755.87725 BTU/lbmol entalpia real

PARA LA CORRIENTE 2

T2= 48 °F
P2= 500 psia
𝑋𝑖=𝑍𝑖/(𝐿+𝑉∗𝐾𝑖)

COMPONETE %Moles Zi (gas condeK tbla GPSA Zi*K Zi/K Xi

C1 73 0.73 4.85 3.5405 0.15051546 0.16533591
C2 11 0.11 0.95 0.1045 0.11578947 0.11510538
C3 8 0.08 0.29 0.0232 0.27586207 0.2161146
nC4 4 0.04 0.09 0.0036 0.44444444 0.20751387
nC5 3 0.03 0.03 0.0009 1 0.21500218
nC6 1 0.01 0.012 0.00012 0.83333333 0.08092838
TOTAL 100 1 3.67282 2.81994478 1.00000031
L= 0.1129211 L+V 1
V= 0.8870789

fact.acentrico
COMPONETE Xi PM PC TC Wi PM*Xi
C1 0.16533591 16.043 667 343.34 0.0108 2.65248401
C2 0.11510538 30.07 707.8 550.07 0.0972 3.4612187
C3 0.2161146 44.097 615 665.92 0.01515 9.5300053
nC4 0.20751387 58.123 548.123 765.51 0.1981 12.0613286
nC5 0.21500218 72.15 488.1 845.7 0.251 15.5124075
nC6 0.08092838 86.177 439.5 911.8 0.299 6.97416501
TOTAL 1.00000031 50.1916091

Calculo de la entalpia
H°=ENTALPIA IDEAL LECTURA DE PROPIEDADES FISICAS FIG 4-10
H°la sumatoria de (mi*H°) 133.258092 BTU/LB
Correccion de uniades a BTU/LB-mol
[((𝐻^𝑂−𝐻))/ 〖𝑅𝑇〗
H°= S(H°*mi)*SPM*xi _𝑐 ]^𝑂=0,455
H°= 6688.43804
[((𝐻^𝑂−𝐻))/ 〖𝑅
(𝐻°−𝐻)=𝑅𝑇𝑐([(𝐻^𝑂−𝐻)/𝑅𝑇𝑐]^𝑂+[((𝐻°−𝐻))/𝑅𝑇𝑐])
𝑇〗 _𝑐 ]^ =6,38

FIG 4-11 FIG4-12 (H^O-H)=1,986∗728,59955∗((4,5)

TEMPERATURA PSEUDORREDUCIDA=TEMPERATURA DATO/S (TC*Xi (H°-H)=

Tsr= 0.74874431 H=

PRECION PSEUDOREDUCIDA= PRESION DATO /S(PC*Xi)

Psr= 0.86368491

PARA EL VAPOR
COMPONETE Yi=(Xi*Ki) TC Yi*TC PC Yi*PC Wi
C1 0.80187916 343.34 275.317192 667 534.853403 0.0108
C2 0.10935011 550.07 60.1502143 707.8 77.3980069 0.0972
C3 0.06267323 665.92 41.735359 615 38.544038 0.01515
nC4 0.01867625 765.51 14.2968547 548.123 10.2368812 0.1981
nC5 0.00645007 845.7 5.45482038 488.1 3.14827696 0.251
nC6 0.00097114 911.8 0.88548596 439.5 0.42681628 0.299
TOTAL 0.99999996 397.839927 664.607422

ENTALPIA
H° ENTALPIA IDEAL (𝑆°−𝑆)=𝑅([(𝑆^°−𝑆)/𝑅]^𝑂+∗[((𝑆°−
H°=(°-)
S(H°-H)211.244177 BTU/Lb +𝑙𝑛𝑃)
 CRORRECCION DE UNIDADES
H°=S(H°*mi)*S(PM*X) 4341.27667 BTU/Lb-mol
(𝐻°−𝐻)=𝑅𝑇𝑐([(𝐻^𝑂−𝐻)/𝑅𝑇𝑐]^𝑂+[((𝐻°−𝐻))/𝑅
𝑇𝑐])

[((𝐻^𝑂−𝐻))/ [((𝐻^𝑂−𝐻))/ 〖𝑅
〖𝑅𝑇〗 _𝑐 ]^𝑂=0,49 𝑇〗 _𝑐 ]^ =1,4

Psr= 0.75
Tsr= 1.28
(H° - H) 415.745517
H° 3925.53115
CORRIENTE 3
T -15 °F Xi=𝑍𝑖/(𝐿+𝑉∗𝐾𝑖)
P 500 psia
COMPONETE Zi (gas condeK Zi*Ki Zi/Ki Xi Yi=(Xi*Ki)
C1 0.73 4.4 3.212 0.1659090909 0.1987412 0.87446127
C2 0.11 0.49 0.0539 0.2244897959 0.18362953 0.08997847
C3 0.08 0.11 0.0088 0.7272727273 0.26642521 0.02930677
nC4 0.04 0.03 0.0012 1.3333333333 0.16850976 0.00505529
nC5 0.03 0.008 0.00024 3.75 0.13631511 0.00109052
nC6 0.01 0.0022 2.2E-05 4.5454545455 0.04639977 0.00010208
TOTAL 1 3.276162 10.746459493 1.00002058 0.9999944

L= 0.21378863 1
V= 0.78621137

PARA EL LIQUIDO
COMPONETE Xi PM PC TC Wi PM*Xi
C1 0.1987412 16.043 667 343.34 0.0108 3.18840503
C2 0.18362953 30.07 707.8 550.07 0.0972 5.52173989
C3 0.26642521 44.097 615 665.92 0.01515 11.7485527
nC4 0.16850976 58.123 548.123 765.51 0.1981 9.79429292
nC5 0.13631511 72.15 488.1 845.7 0.251 9.83513501
nC6 0.04639977 86.177 439.5 911.8 0.299 3.99859325
TOTAL 1.00002058 44.0867188

CALCULO DE ENTALPIA
H° Entalpia real
H°la sumatoria de (mi*H°) 112.053276 BTU/LB

Correccion de uniades a BTU/LB-mol

H°= S(H°*mi)*SPM*xi
H°= 4940.06127
(𝐻°−𝐻)=𝑅𝑇𝑐([(𝐻^𝑂−𝐻)/𝑅𝑇𝑐]^𝑂+[((𝐻°−𝐻))/𝑅 [((𝐻^𝑂−𝐻))/ [((𝐻^𝑂−𝐻))/ 〖𝑅
𝑇𝑐]) 〖𝑅𝑇〗 _𝑐 ]^𝑂=0,475 𝑇〗 _𝑐 ]^ =6,8
 [((𝐻^𝑂−𝐻))/ [((𝐻^𝑂−𝐻))/ 〖𝑅
〖𝑅𝑇〗 _𝑐 ]^𝑂=0,475 𝑇〗 _𝑐 ]^ =6,8

Psr 0.83 (H°-H) 1499.61453

Tsr 0.70 H° 3440.44674

VAPOR

COMPONETE Yi=(Xi*Ki) PM PC TC Wi PM*Yi

C1 0.87446127 16.043 667 343.34 0.0108 14.0289821
C2 0.08997847 30.07 707.8 550.07 0.0972 2.70565255
C3 0.02930677 44.097 615 665.92 0.01515 1.29234079
nC4 0.00505529 58.123 548.123 765.51 0.1981 0.29382879
nC5 0.00109052 72.15 488.1 845.7 0.251 0.07868108
nC6 0.00010208 86.177 439.5 911.8 0.299 0.00879691
TOTAL 0.9999944 18.4082822

CALCULO DE ENTALPIA
H° Entalpia real
H°la sumatoria de (mi*H°) 197.427102 BTU/LB

Correccion de uniades a BTU/LB-mol

H°= S(H°*mi)*SPM*xi
H°= 3634.29381

(𝐻°−𝐻)=𝑅𝑇𝑐([(𝐻^𝑂−𝐻)/𝑅𝑇𝑐]^𝑂+[((𝐻°−𝐻))/𝑅
𝑇𝑐]) [((𝐻^𝑂−𝐻))/
〖𝑅𝑇〗 _𝑐 ]^𝑂=0,59
Psr 0.75
Tsr 1.19
(H°-H) 465.203435
H° 3169.09038
Xi=𝑍𝑖/(𝐿+𝑉∗𝐾𝑖)

yi=Ki*Xi
0.7516604
0.11109332
0.07743727
0.03457468
0.02067973
0.00455429
0.99999968

TC*Xi wi wi*Xi mi Hoi Hoi*mi S°i S°i*mi

42.1691308 0.0108 0.00132646 0.03441871 282.5 9.72328608 3.13 0.10773057
43.6493578 0.0972 0.00771305 0.04168042 182 7.58583682 2.02 0.08419445
101.111823 0.01515 0.00230034 0.1169574 155 18.1283971 1.51 0.17660567
147.040336 0.1981 0.03805135 0.19501698 155 30.2276315 1.32 0.25742241
246.321811 0.251 0.07310722 0.36708079 150 55.0621183 1.22 0.44783856
148.30709 0.299 0.04863327 0.2448457 130 31.8299409 1.19 0.29136638
728.599549 0.1711317 1 152.557211 1.36515805

48
𝐵𝑇𝑈/𝑙𝑏𝑚𝑜𝑙

1,986*(-1,716416) 81.5615315 BTU/Lbmol°R

(𝑆°−𝑆)=𝑅([(𝑆^°−𝑆)/𝑅]^𝑂+∗[((𝑆°−𝑆))/𝑅]
+𝑙𝑛𝑃)
0,1711317*6)+Ln(500/14,7) 18.0995119

BTU/Lbmol°R

0,1711317∗(6,1))

𝑚𝑖=(𝑃𝑀𝑖∗𝑌𝑖)/(𝑃𝑀∗𝑌𝑖)
 Tc*Yi Wi Wi*Yi mi Hoi Hoi*mi Si° Si°*mi
258.07508 0.0108 0.00811793 0.53103398 282.5 150.0171 3.13 1.66213636
61.1091009 0.0972 0.01079827 0.14710804 182 26.7736641 2.02 0.29715825
51.5670296 0.01515 0.00117317 0.15037449 155 23.3080457 1.51 0.22706548
26.4672604 0.1981 0.00684924 0.0884955 155 13.7168031 1.32 0.11681406
17.4888486 0.251 0.00519061 0.06570468 155 10.1842249 1.22 0.08015971
4.15259853 0.299 0.00136173 0.0172833 130 2.24682963 1.19 0.02056713
418.859918 0.03349096 1 226.246667 2.40390099

ENTROPIA

0.75909023 So=PM*Xi*Sio-R*lnXi*Xi
1.33696249
S° =  (PM*yi*Si°) - R*  (ln (yi) * yi)

S°= 56.3320409

(𝑆°−𝑆)=𝑅([(𝑆^°−𝑆)/𝑅]^𝑂+[((𝑆°−𝑆))/𝑅]+𝑙𝑛𝑃)

0.235 0.11

(S° - S) 3.99715461
S=S° - (S° - S) 52.3348862

𝑍𝑖/(𝐿+𝑉∗𝐾𝑖)

Yi=(Xi*Ki)
0.80187916
0.10935011
0.06267323
0.01867625
0.00645007
0.00097114
0.99999996
 mi=(Pmi*Xi/suma(PM*Xi)
PC*Xi TC*Xi Wi*Xi mi H° H°*mi
110.279052 56.7664314 0.00178563 0.05284716 250 13.2117901
81.4715863 63.316015 0.01118824 0.06896011 168 11.5852979
132.910476 143.915031 0.00327414 0.18987248 132 25.0631674
113.743124 158.853942 0.0411085 0.24030568 132 31.7203493
104.942565 181.827346 0.05396555 0.30906376 120 37.0876514
35.568023 73.790497 0.02419759 0.13895082 105 14.5898356
578.914827 678.469262 0.13551964 1 133.258092

(𝐻^𝑂−𝐻))/ 〖𝑅𝑇〗 0.455

𝑐 ]^𝑂=0,455

(𝐻^𝑂−𝐻))/ 〖𝑅
〗 _𝑐 ]^ =6,38
6.38

H^O-H)=1,986∗728,59955∗((4,5)+0,1711317∗(6,1))

7295.866

-607.43022

Yi*Wi PM PM*Yi mi Ho Ho*mi

0.00866029 16.043 12.8645474 0.62598193 250 156.495482
0.01062883 30.07 3.28815777 0.15999998 168 26.8799968
0.0009495 44.097 2.76370154 0.13448022 132 17.7513895
0.00369976 58.123 1.08551957 0.0528208 132 6.97234508
0.00161897 72.15 0.46537223 0.02264476 120 2.71737133
0.00029037 86.177 0.08368998 0.00407231 105 0.42759247
0.02584773 20.5509885 1 211.244177

ENTROPIA
−𝑆)=𝑅([(𝑆^°−𝑆)/𝑅]^𝑂+∗[((𝑆°−𝑆))/𝑅]
𝑛𝑃)
 s=

PC*Xi TC*Xi wi*Xi mi H° H°*mi

132.560379 68.2358027 0.0021464 0.07232121 220 15.9106671
129.972979 101.009094 0.01784879 0.12524724 135 16.9083775
163.851506 177.417878 0.00403634 0.26648735 110 29.313608
92.3640765 128.995908 0.03338178 0.22215972 110 24.4375688
66.535404 115.281686 0.03421509 0.22308612 100 22.308612
20.3927003 42.3073132 0.01387353 0.09069836 35 3.17444273
605.677045 633.247683 0.10550195 1 112.053276

[((𝐻^𝑂−𝐻))/ 〖𝑅
𝑇〗 _𝑐 ]^ =6,8
 [((𝐻^𝑂−𝐻))/ 〖𝑅
𝑇〗 _𝑐 ]^ =6,8

PC*Yi TC*Yi Wi*Yi mi H° H°*mi

583.265666 300.237532 0.00944418 0.76210164 220 167.662361
63.6867599 49.4944561 0.00874591 0.14698018 135 19.8423236
18.0236657 19.5159666 0.000444 0.07020431 110 7.72247433
2.7709223 3.86987725 0.00100145 0.01596177 110 1.75579482
0.53228323 0.92225349 0.00027372 0.00427422 100 0.42742217
0.04486394 0.09307609 3.05218E-05 0.00047788 35 0.01672571
668.324161 374.133161 0.01993978 1 197.427102

((𝐻^𝑂−𝐻))/ [((𝐻^𝑂−𝐻))/ 〖𝑅
〖𝑅𝑇〗 _𝑐 ]^𝑂=0,59 𝑇〗 _𝑐 ]^ =1,81
ln(Xi)*Xi (Xi*PM)*S°i
-0.25755825 6.16737232
-0.20106755 4.819974
-0.28620551 10.1103426
-0.3169029 14.7369487
-0.35928144 25.6379151
-0.29540007 16.6801772
-1.71641573 78.1527299
ln(Yi)*Yi PM*Yi*Si°
-0.21457699 37.7443186
-0.24411476 6.7479636
-0.19810677 5.15627473
-0.11633112 2.65265076
-0.08020843 1.82029197
-0.02455529 0.46704496
-0.87789336 54.5885446