2365-202-01 - Electron Theory Day 1.

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Level 2 Diploma in Electrical Installations (Buildings and Structures) Unit 202 Handout 1
202: Principles of electrical science

Handout 1: Principles of electricity
Learning outcome
The learner will:
2. understand standard units of measurement used in electrical installation, maintenance and
design work
4. understand the relationship between resistance, resistivity, voltage, current and power.
Assessment criteria
The learner can:
2.1 identify and use internationally recognised base and derived (SI) units of measurement
2.2 identify and determine values of base and derived SI units which apply specifically to
electrical quantities
4.1 describe the basic principles of electron theory
4.2 identify and distinguish between materials which are good conductors and insulators
4.8 describe the chemical and thermal effects of electric currents.
Range
(SI) units of measurement: length, area, volume, mass, density, time, temperature, velocity
Electrical quantities (SI units): resistance, resistivity, power, frequency, current, voltage, energy,
impedance, inductance and inductive reactance, capacitance and capacitive reactance, power
factor
Principles of electricity
Electron theory – structure of matter
The smallest part of any material is called a molecule, yet the latter is made up of one or more
atoms. For example, water is made up of H2O (two atoms of hydrogen and one atom of oxygen).
Basically, the atom is constructed of a central core containing protons surrounded by orbiting
electrons.
Electrical nature of atoms
Protons are positively charged.

Electrons are negatively charged.
In an electrically neutral atom, the number of

protons is equal to the number of electrons.
 The simplest atom is hydrogen (1 proton and 1 electron) – see right.

 The heaviest atom is uranium (92 protons balanced by 92 electrons).
 Helium atom (two protons and two electrons).
© 2018 City and Guilds of London Institute. All rights reserved. Page 1 of 4
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Copper atom – 29 protons and 29 electrons

An electrically neutral atom has as many (+ve positive) protons
as there are (-ve negative) electrons.
The single electron in the outer orbit of the copper atom is only
loosely attached to the atom because:
 it is so far away from the core (nucleus)
 inner electrons try to push it off (like charges repel).
As a result, this electron may be easily detached. If the balance of protons and electrons is upset
and the atom becomes positively charged it will then attract any nearby electron.
This process occurs millions of times every second; at any instant in time the material has a large
number of free electrons moving in all directions.
Random free electron movement
If the material is then connected across a

battery, the positive plate (or terminal)
attracts electrons, whilst the negative
plate repels them.
The battery provides a source of
electromotive force (EMF).
The resultant electron flow around the circuit is called an electric current.
Note: even when an appropriate EMF is applied,

there must be a complete circuit for the electrons to
flow; a break in the circuit will cause the electron flow
to stop.
This aspect is useful, as we can use it to control the
flow of electricity using, for example, a switch.
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Conductors and insulators

A conductor is a material that has a loosely attached electron in its outer orbit that can be easily
dislodged, as in copper. Any external influence which moves one of them will cause a repulsion of
other electrons which spreads, ‘domino fashion’ through the conductor.
Simply stated, most metals are good electrical conductors, most non-metals are not. Metals are
also generally good heat conductors, while non-metals are not. Examples of conductors are:
 silver  sea water  iron
 gold  concrete  bronze
 copper  mercury  graphite
 aluminium  platinum  dirty water
 mercury  brass  lemon juice.
 steel
Most solid non-materials are classified as insulators because they offer very large resistance to the
flow of electric current. In an insulator, the outermost electrons are so tightly bound that there is
essentially zero electron flow through them with ordinary voltages. Examples of insulators are:
 rubber  diamond  fibreglass
 glass  dry wood  dry paper
 pure water  dry cotton  porcelain
 oil  plastic  ceramic
 air  asphalt  quartz.
Effects of an electric current
When electricity flows, one or more effects occur as follows:
 thermal
 chemical
 magnetic.
Thermal effect
When an electric current is passed through a conductor, the conductor becomes hot after some
time, and produces heat. This happens due to the conversion of some electric energy passing
through the conductor into heat energy, by the collision of electrons with each other and the atom
nuclei. This effect of electric current is called the heating effect of current.
The heating effect of current is used in various electrical heating appliances, such as electric
lamps, electric irons, room heaters, water heaters, electric fuses, etc.
Chemical effect
We can use certain chemical reactions which produce electricity, as in a battery. But, it is
interesting to note that when electric current is passed through certain liquids, a chemical reaction
takes place. This is called the chemical effect of electric current and is referred to as electrolysis.
For example, when an electric current is passed through acidified water, the water molecules split
up to form hydrogen and oxygen gases.
Electrolysis is used to electroplate objects. This is useful for coating a cheaper metal with a more
expensive one, such as copper or silver.
The negative electrode should be the object that is to be electroplated; the positive electrode
should be the metal with which you want to coat the object. The electrolyte should be a solution of
the coating metal, such as metal nitrate or sulphate.
Two examples are electroplating with silver (silver nitrate electrolyte) and electroplating with
copper (copper sulphate electrolyte).
Magnetic effect
This will be covered later in the course.
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Electrical quantities
Many different quantities are used in electrical systems and therefore need to be standardised.
These units are standardised in an international system called the Système International d’Unités
(abbreviated to SI units). SI units are based upon a small number of fundamental units from which
all other units may be derived.
The table below shows a selection of units appropriate to the electrical industry, including the
symbols used in formulae and also their abbreviation.
SI unit Measure of Symbol Abbreviation
Metre Length l m
Square metre Area a m2
Cubic metre Volume v M3
Kilogram Mass m kg
Kilogram/metre3 Density ρ kg/m3
Second Time t s
Degrees Celsius Celsius temperature t °C
Metres/second Velocity v m/s
Ohm Electrical resistance R Ω
Rho Resistivity ρ Ohm/m3
Watts Power P W
Hertz Frequency – number of cycles per second f Hz
Ampere Electric current I A
Electric potential/Potential
Volt V V
difference/Electromotive force
Joule Energy/work/quantity of heat E J
Ohm Impedance Z Ω
Henry Inductance L H
Ohm Inductive reactance XL Ω
Farad Capacitance C F
Ohm Capacitive reactance XC Ω
cos θ Power factor pf No unit

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202: Principles of electrical science

Protons are positively charged.

In an electrically neutral atom, the number of

 The simplest atom is hydrogen (1 proton and 1 electron) – see right.

Copper atom – 29 protons and 29 electrons

If the material is then connected across a

Note: even when an appropriate EMF is applied,

Conductors and insulators

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