D. Data Hasil Praktikum 1. Pembuatan Larutan Standar HCL 0,1 M

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D.

DATA HASIL PRAKTIKUM


1. Pembuatan Larutan Standar HCL 0,1 M
BJ HCl : 1,16 kg/m3

Kadar HC : 32 %

Volume HCl yang dibutuhkan : 0,49 mL

Perhitungan:
Molaritas HCl
ρ ×10 ×%
M=
Mr
1,16× 10× 32
¿
36,5
M =10,17 M

Volume HCl yang dibutuhkan


M 1 × V 1=M 2 ×V 2
10,17 ×V 1=0,1× 50
0,1 ×50
V 1=
10,17
V 1=0,49 mL
2. Standarisasi larutan HCl 0.1 M
Volume HCl : 12,25 mL (Vrata-rata)

Molaritas HCl : 0,1 M

Berat boraks : 10 mL

Molaritas larutan HCl hasil standarisasi : 0,08 M

Perhitungan:
Na2B4O7.10H2O + 2 HCl  2NaCl + 4H3BO3 + 5H2
mol HCl 2
=
mol boraks 1
1 grammol HCl = 2 grammol boraks
Normalitas asam boraks
N=M × ekuivalen boraks
1
N=
2 ()
0,1× 2

N=0,1
Molaritas HCl
M HCl × V HCl =2 × M boraks ×V boraks
M HCl × 12,25=2 ×0,05 ×10
M HCl =0,08 M
3. Pembuatan larutan standar NaOH 0.1 M
Berat NaOH : 0,4 gram

Volume larutan NaOH : 100 ml

Molaritas larutan NaOH : 0,1 M

Perhitungan:
gram 1000
M= ×
Mr V
gram 1000
0,01= ×
40 100
0,1× 40 ×100
gram= =0,4 gram
1000
4. Standarisasi larutan standar NaOH 0,1 M
Volume Na-oksalat : 20 ml

Volume akuades : 100 ml

Volume larutan NaOH 0,1 M : 21,3 ml (V1) dan 20,8 ml (V2)

Molaritas larutan NaOH : 0,095 M

Perhitungan:
H2C2O4 + 2 NaOH  Na2C2O4 + 2 H2O
mol NaOH 2
=
mol oksalat 1
1 grammol NaOH = 2 grammol oksalat
Normalitas oksalat
N=M × ekuivalen oksalat
N=0,05× 2
N=0,1
Volume rata-rata NaOH
21,3 mL+20,8 mL
V NaOH = =21,05 mL
2
Molaritas NaOH
M NaOH ×V NaOH =2 × M oksalat ×V oksalat
M NaOH ×21,05=2× 0,05 ×20
M NaOH =0,095 M
5. Penetapan kadar asam asetat pada cuka
Volume larutan asam cuka : 20 ml

Volume NaOH (titrasi) : 23,8 mL (Vrata-rata)

Molaritas NaOH : 0,095 M

Persamaan reaksi : NaOH + CH3COOH  CH3COONa + H2O

Kadar total asam (%b/v) : 13,57 % b/v

Perhitungan:
Molaritas asam cuka
V NaOH × M NaOH standarisasi × F p=V asam cuka erlenmeyer × M asam cuka
V NaOH × M NaOH standarisasi × F p
M asamcuka =
V asamcuka erlenmeyer
0,095× 23,8 ×10
¿ M asamcuka =1,1305 M
20
Berat asam cuka
gram 1000
M= ×
Mr V
M × Mr × V
gram=
1000
1,1305× 60× 20
gram= =1,357 gram
1000

Kadar total asam (% b/v)


Terdapat 1,357 gram asetat dalam 10 mL asam cuka, maka dalam 100 mL
gram
% b/v = ×100 %
V
¿ 1,357 ×10
% b/v =13,57 % b /v

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