3-Methylcyclobutene 1 - Methylcyclopentene 2,3-Dimethyl-2-Pentene

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TUGAS 3 KIMIA ORGANIK PERMODELAN STRUKTUR REAKSI ORGANIK

Nama : Fadilla Azhari


NPM : 3335190048
Teknik Kimia B

Jawaban tugas pertemuan ke 3:


1. Gambarkan struktur senyawa berikut
Jawab:
a) b) c)

(Z) (Z)

3- methylcyclobutene 1- methylcyclopentene 2,3-dimethyl-2-pentene

d) e) f)
Br
Br
(E)

Br
(Z)
(Z)-3-hexene (E)-2-pentene 3,3,3-tribromopropene

g) h)
Cl

(E)
(S)
(R)
(Z)
(Z,4R)-4-methyl-2-hexene (E,4S)-4-chloro-2-pentene

2. Gambarkan reaksi organic yang terjadi


Jawab:
a)
(Z) N (E) O
N (E) (E) O

N
(Z) N
(Z)
(Z)-N,N-dimethyl-N'-(3-oxocyclohexa-1,4-dien-1-
yl)acetimidamide (E)-3-((1-(dimethyliminio)ethyl)imino)cyclohexa-1,5-dien-1-olate

b)
N (E) (E) O

H3CO

N P(C6H5)3
(Z)
(methoxymethylene)triphenyl- 5-phosphane
(E)-3-((1-(dimethyliminio)ethyl)imino)cyclohexa-1,5-dien-1-olate

OCH3
(E)

60%
H3CO

(E)-1-methoxy-4-(1-methoxyprop-1-en-2-yl)benzene

H3O+/H2O

O
H3CO

2-(4-methoxyphenyl)propanal

85%
c)
OH
O

(R) H3PO4 (cat.), EtOH (R)


(S) O
(R)

(1S,5R)-1-methyl-6-oxabicyclo[3.1.0]hexane (1R,2R)-2-ethoxy-2-methylcyclopentan-1-ol

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