Low Corrosion Fine Point Paint Marker

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR
Date of issue: 11/08/2017 Version: 1.0

SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : Low Corrosion Fine Point Paint Marker
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Marking.
1.3. Details of the supplier of the safety data sheet
LA-CO Industries, Inc.
1201 Pratt Boulevard
Elk Grove Village, IL. 60007-5746
Phone: (847) 956-7600
Fax: (847) 956-9885
E-mail: customer_service@laco.com

1.4. Emergency telephone number

Emergency number : 24-hour emergency: CHEMTREC- U.S. : 1-800-424-9300 International: +1-703-527-3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS classification
Flammable liquids, Category 3 H226
Serious eye damage/eye irritation, Category 2 H319
Reproductive toxicity, Category 1B H360
Specific target organ toxicity — Single exposure, Category 3, Narcosis H336
Full text of H statements : see section 16

2.2. Label elements

GHS-US labelling
Hazard pictograms (GHS) :

GHS02 GHS07 GHS08

Signal word (GHS) : Danger
Hazard statements (GHS) : H226 - Flammable liquid and vapour.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
H360 - May damage fertility or the unborn child.
Precautionary statements (GHS) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical/ventilating/lighting equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P261 - Avoid breathing vapours.
P264 - Wash hands thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves.
P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 - If exposed or concerned: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.

11/08/2017 EN (English) SDS ID: LACO1711004 Page 1

Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

P370+P378 - In case of fire: Use alcohol resistant foam, carbon dioxide (CO2), Dry chemical,
Water fog to extinguish.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation

2.3. Other hazards

No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS classification
1-Methoxy-2-propanol (CAS-No.) 107-98-2 45 Flam. Liq. 3, H226
STOT SE 3, H336
diacetone alcohol (CAS-No.) 123-42-2 37 Flam. Liq. 4, H227
Eye Irrit. 2A, H319
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (CAS-No.) 872-50-4 3 Flam. Liq. 4, H227
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Repr. 1B, H360
STOT SE 3, H335

Full text of hazard classes and H-statements : see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. If skin irritation
occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes serious eye irritation. May cause drowsiness or dizziness. May damage fertility or the
unborn child.
Symptoms/effects after inhalation : May cause drowsiness or dizziness.
Symptoms/effects after skin contact : None under normal use.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : None under normal use.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : Flammable vapours heavier than air/can accumulate.
Reactivity : No dangerous reactions known.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

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Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : No open flames, no sparks, and no smoking. Do not breathe vapours. Avoid contact with skin,
eyes and clothing.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Take up liquid spill into absorbent material.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Take precautionary measures against static discharge. Flammable vapours may
accumulate in the container. Use only outdoors or in a well-ventilated area. Do not get in eyes,
on skin, or on clothing.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed.
Incompatible products : Strong oxidizers.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
1-Methoxy-2-propanol (107-98-2)
ACGIH ACGIH TWA (mg/m³) 369 mg/m³
ACGIH ACGIH TWA (ppm) 50 ppm
ACGIH ACGIH STEL (mg/m³) 553 mg/m³
ACGIH ACGIH STEL (ppm) 100 ppm
ACGIH Remark (ACGIH) Eye irr; CNS impair; A4 (Not classifiable as a Human
Carcinogen: Agents which cause concern that they
could be carcinogenic for humans but which cannot be
assessed conclusively because of a lack of data. In
vitro or animal studies do not provide indications of
carcinogenicity which are sufficient to classify the
agent into one of the other categories)
OSHA Not applicable OSHA
Canada (Quebec) VECD (mg/m³) 553 mg/m³
Canada (Quebec) VECD (ppm) 150 ppm
Canada (Quebec) VEMP (mg/m³) 369 mg/m³
Canada (Quebec) VEMP (ppm) 100 ppm
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)
Not applicable

diacetone alcohol (123-42-2)

ACGIH ACGIH TWA (mg/m³) 238 mg/m³
ACGIH ACGIH TWA (ppm) 50 ppm

11/08/2017 EN (English) SDS ID: LACO1711004 3/8

Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

diacetone alcohol (123-42-2)

ACGIH Remark (ACGIH) URT & eye irr
OSHA OSHA PEL (TWA) (mg/m³) 240 mg/m³
OSHA OSHA PEL (TWA) (ppm) 50 ppm
Canada (Quebec) VEMP (mg/m³) 238 mg/m³
Canada (Quebec) VEMP (ppm) 50 ppm

8.2. Exposure controls

Appropriate engineering controls : Ensure good ventilation of the work station.
Hand protection : Protective gloves. ( nitrile rubber). Gloves must be replaced after each use and whenever signs
of wear or perforation appear.
Eye protection : Eye protection should only be necessary where liquid could be splashed or sprayed.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : No respiratory protection needed under normal use conditions.
Environmental exposure controls : Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Solid marker containing liquid colored paint.
Colour : Various
Odour : alcohol odour
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : 97.2 °C
Flash point : 42 °C
Relative evaporation rate (butylacetate=1) : 1.3
Flammability (solid, gas) : Not applicable.
Vapour pressure : 20.8 mm Hg
Relative vapour density at 20 °C : >1
Relative density : <1
Solubility : Water: 70 - 80 %
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive limits : Lower explosive limit (LEL): 1.9 vol %
Upper explosive limit (UEL): 12.3 vol %
Explosive properties : No data available
Oxidising properties : No data available

9.2. Other information

VOC content : 77.5 %

SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reactions known.
10.2. Chemical stability
Stable under normal conditions.

11/08/2017 EN (English) SDS ID: LACO1711004 4/8

Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
Strong oxidizers.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Likely routes of exposure : Dermal; Inhalation
Acute toxicity : Not classified

1-Methoxy-2-propanol (107-98-2)
LD50 oral rat 4016 mg/kg bodyweight
LD50 dermal rat > 2000 mg/kg bodyweight
LC50 inhalation rat (ppm) > 7000 ppm 6 hr
ATE US (oral) 4016 mg/kg bodyweight
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)
LD50 oral rat 4150 mg/kg
LD50 dermal rat > 5000 mg/kg
LC50 inhalation rat (mg/l) > 5.1 mg/l/4h
ATE US (oral) 4150 mg/kg bodyweight
diacetone alcohol (123-42-2)
LD50 oral rat 4000 mg/kg
LD50 dermal rabbit 13630 mg/kg
ATE US (oral) 4000 mg/kg bodyweight
ATE US (dermal) 13630 mg/kg bodyweight
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : May damage fertility or the unborn child.
Specific target organ toxicity (single : May cause drowsiness or dizziness.
exposure)
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Symptoms/effects after inhalation : May cause drowsiness or dizziness.
Symptoms/effects after skin contact : None under normal use.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : None under normal use.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.

1-Methoxy-2-propanol (107-98-2)
LC50 fish 1 20800 mg/l
EC50 Daphnia 1 23300 mg/l
ErC50 (algae) > 1000 mg/l

11/08/2017 EN (English) SDS ID: LACO1711004 5/8

Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)

LC50 fish 1 > 500 mg/l
NOEC (acute) 495 mg/l
diacetone alcohol (123-42-2)
LC50 fish 1 420 mg/l 96 h
EC50 Daphnia 1 9000 mg/l 24 h

12.2. Persistence and degradability

Low Corrosion Fine Point Paint Marker
Persistence and degradability Not established.
1-Methoxy-2-propanol (107-98-2)
Persistence and degradability Readily biodegradable.
Biodegradation 96 % 28 d
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)
Persistence and degradability Readily biodegradable.
diacetone alcohol (123-42-2)
Persistence and degradability Readily biodegradable.
Biodegradation 100 % 14 d

12.3. Bioaccumulative potential

Low Corrosion Fine Point Paint Marker
Bioaccumulative potential Not established.
1-Methoxy-2-propanol (107-98-2)
Bioaccumulative potential Not expected to bioaccumulate.
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)
Bioaccumulative potential Not expected to bioaccumulate.
diacetone alcohol (123-42-2)
Log Pow 1.03

12.4. Mobility in soil

Low Corrosion Fine Point Paint Marker
Mobility in soil Not established

12.5. Other adverse effects

None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Additional information : Flammable vapours may accumulate in the container.

SECTION 14: Transport information

US-DOT 49-CFR / HMR / TDG / ADR / IMDG / ICAO / IATA
In accordance with DOT
Transport document description : UN1263 Paint, 3, III

UN-No.(DOT) : UN1263
Proper Shipping Name (DOT) : Paint ()
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
Hazard labels (DOT) : 3 - Flammable liquid

11/08/2017 EN (English) SDS ID: LACO1711004 6/8

Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

Transportation of Dangerous Goods

Transport document description : UN 1263 Paint, 3, III
UN-No. (TDG) : UN 1263
Proper Shipping Name (Transportation of : Paint
Dangerous Goods)
TDG Primary Hazard Classes : 3 - Class 3 - Flammable Liquids
Packing group : III - Minor Danger

Transport by sea
UN-No. (IMDG) : 1263
Proper Shipping Name (IMDG) : PAINT
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : III - substances presenting low danger
Limited quantities (IMDG) : 5L

Air transport
UN-No. (IATA) : 1263
Proper Shipping Name (IATA) : PAINT
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : III - Minor Danger

SECTION 15: Regulatory information

15.1. US Federal regulations

1-Methoxy-2-propanol (107-98-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
diacetone alcohol (123-42-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. CANADA
1-Methoxy-2-propanol (107-98-2)
Listed on the Canadian DSL (Domestic Substances List) inventory.
N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)
Listed on the Canadian DSL (Domestic Substances List) inventory.
diacetone alcohol (123-42-2)
Listed on the Canadian DSL (Domestic Substances List) inventory.
No

15.3. US State regulations

N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)

U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significant risk
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - level (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
No Yes No No 3200 µg/day

1-Methoxy-2-propanol (107-98-2)
U.S. - Idaho - Occupational Exposure Limits - Ceilings
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Minnesota - Hazardous Substance List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - New York - Right to Know List of Hazardous Chemicals
U.S. - Washington - Permissible Exposure Limits - STELs
U.S. - Washington - Permissible Exposure Limits - TWAs

11/08/2017 EN (English) SDS ID: LACO1711004 7/8

Low Corrosion Fine Point Paint Marker
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations, Canada HPR

N-methyl-2-pyrrolidone, 1-methyl-2-pyrrolidone (872-50-4)

U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities

SECTION 16: Other information

Data sources : ACGIH (American Conference of Government Industrial Hygienists).
Chemical Inspection & Regulation Service; accessed at: http://www.cirs-
reach.com/Inventory/Global_Chemical_Inventories.html.
Component Supplier SDSs.
European Chemicals Agency (ECHA) C&L Inventory database. Accessed at
http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database.
European Chemicals Agency (ECHA) Registered Substances list.
Internal Company test data.
Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing",
Fifth Edition.
National Fire Protection Association. Fire Protection Guide to Hazardous Materials; 10th
edition.
OSHA 29CFR 1910.1200 Hazard Communication Standard.
TSCA Chemical Substance Inventory. Accessed at
http://www.epa.gov/oppt/existingchemicals/pubs/tscainventory/howto.html.

Full text of H-statements:

------ H226 Flammable liquid and vapour.
------ H227 Combustible liquid
------ H315 Causes skin irritation.
------ H319 Causes serious eye irritation.
------ H335 May cause respiratory irritation.
------ H336 May cause drowsiness or dizziness.
------ H360 May damage fertility or the unborn child.
Abbreviations and acronyms:
------ ACGIH (American Conference of Government Industrial Hygienists)
------ ATE: Acute Toxicity Estimate
------ CAS (Chemical Abstracts Service) number
------ CLP: Classification, Labelling, Packaging.
------ EC50: Environmental Concentration associated with a response by 50% of the test population.
------ GHS: Globally Harmonized System (of Classification and Labeling of Chemicals).
------ LD50: Lethal Dose for 50% of the test population
------ LC50:Median lethal concentration
------ STEL: Short Term Exposure Limits
------ TSCA: Toxic Substances Control Act
------ TWA: Time Weighted Average
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and not reactive with water.

SDS Prepared by: The Redstone Group, LLC

6077 Frantz Rd.
Suite 206
Dublin, OH USA 43017
T 614-923-7472
www.redstonegrp.com

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product

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