SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

SECTION 1. IDENTIFICATION

Product name : Monoethylene Glycol, Polyester Grade

Product code : 37417-00, P3741701, E3741701, P37417BU

Manufacturer or supplier's details

Company name of supplier : Eastman Chemical Company

Address : 200 South Wilcox Drive

Kingsport TN 37660-5280
Telephone : (423) 229-2000

Emergency telephone : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321

Recommended use of the chemical and restrictions on use

Recommended use : Industrial use

Restrictions on use : None known.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200

Acute toxicity (Oral) : Category 4

Specific target organ toxicity : Category 2 (Kidney)

- repeated exposure

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : H302 Harmful if swallowed.

H373 May cause damage to organs (Kidney) through prolonged
or repeated exposure.

Precautionary Statements :
Prevention:
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
Response:

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

P301 + P312 + P330 IF SWALLOWED: Call a POISON

CENTER/doctor if you feel unwell. Rinse mouth.
P314 Get medical advice/ attention if you feel unwell.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Components
Chemical name CAS-No. Concentration (% w/w)
ethylene glycol 107-21-1 100

SECTION 4. FIRST AID MEASURES

If inhaled : Move to fresh air.

Treat symptomatically.
Get medical attention if symptoms occur.

In case of skin contact : Wash off with soap and water.

Call a physician if irritation develops or persists.

In case of eye contact : Rinse with plenty of water.

Get medical attention if symptoms occur.

If swallowed : Seek medical advice.

Most important symptoms : Harmful if swallowed.

and effects, both acute and May cause damage to organs through prolonged or repeated
delayed exposure.
Harmful if swallowed.
May cause damage to organs through prolonged or repeated
exposure.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray

Carbon dioxide (CO2)
Dry chemical
Foam

Unsuitable extinguishing : Water spray jet

media

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Specific extinguishing meth- : Use water spray to cool unopened containers.

ods

Special protective equipment : Wear an approved positive pressure self-contained breathing

for fire-fighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Wear appropriate personal protective equipment.

tive equipment and emer- Avoid release to the environment.
gency procedures

Environmental precautions : Avoid release to the environment.

Methods and materials for : Contain spillage, soak up with non-combustible absorbent
containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not taste or swallow.

Wash thoroughly after handling.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Store locked up.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
ethylene glycol 107-21-1 C 50 ppm OSHA P0
125 mg/m3
TWA (Vapor) 25 ppm ACGIH
STEL (Va- 50 ppm ACGIH
por)
STEL (Inhal- 10 mg/m3 ACGIH
able fraction,
Aerosol only)
Engineering measures : Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to
conditions. If applicable, use process enclosures, local

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

exhaust ventilation, or other engineering controls to maintain

airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne
levels to an acceptable level.

Personal protective equipment

Respiratory protection : Wear respiratory protection.

Hand protection

Remarks : Wear suitable gloves.

Eye protection : Safety glasses

Skin and body protection : Wear suitable protective clothing.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : colorless

Odor : odorless

Odor Threshold : not determined

pH : not determined

Melting point/range : -13 °C

Boiling point/boiling range : 197.4 °C (1,013 hPa)

Flash point : 232 °F / 111 °C (closed cup)

Evaporation rate : not determined

Upper explosion limit / Upper : not determined

flammability limit

Lower explosion limit / Lower : not determined

flammability limit

Vapor pressure : 0.123 hPa (25 °C)

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

Relative vapor density (air=1) : 2.1

Relative density : 1.11 (20 °C)

Solubility(ies)
Water solubility : completely soluble

Partition coefficient: n- : log Pow: -1.36

octanol/water

Autoignition temperature : 749 °F / 398 °C

Decomposition temperature : 748 °F / 398 °C

Viscosity
Viscosity, dynamic : 16.1 mPa.s (25 °C)

Viscosity, kinematic : 14.5 mm2/s (25°C)

Explosive properties : No data available

Oxidizing properties : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : None known.

tions

Conditions to avoid : Incompatible materials

Incompatible materials : Oxidizing agents

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Harmful if swallowed.
Product:
Acute oral toxicity : Remarks: No data available

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

Skin corrosion/irritation
Not classified based on available information.
Product:
Remarks : No data available

Serious eye damage/eye irritation

Not classified based on available information.
Product:
Remarks : No data available

Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Product:
Remarks : No data available

Germ cell mutagenicity

Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Product:
Remarks : This information is not available.

IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

No ingredient of this product present at levels greater than or equal to 0.1% is

identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

No component of this product present at levels greater than or equal to 0.1% is

on OSHA’s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

No ingredient of this product present at levels greater than or equal to 0.1% is

identified as a known or anticipated carcinogen by NTP.

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

Reproductive toxicity
Not classified based on available information.
Product:
Effects on fertility : Remarks: No data available

STOT-single exposure
Not classified based on available information.
Product:
Remarks : No data available

STOT-repeated exposure
May cause damage to organs (Kidney) through prolonged or repeated exposure.
Product:
Remarks : No data available

Aspiration toxicity
Not classified based on available information.
Product:
No data available

Information on likely routes of exposure

Product:
Inhalation : Remarks: None known.

Skin contact : Remarks: None known.

Eye contact : Remarks: None known.

Ingestion : Remarks: Harmful if swallowed.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
UN/ID/NA number : NA 3082
Proper shipping name : Other regulated substances, liquid, n.o.s.
(ethylene glycol)
Class : 9
Packing group : III
Labels : Class 9 - Miscellaneous dangerous substances and articles
ERG Code : 171
Marine pollutant : no
Remarks : 9, Packing Group III when material is shipped in quantities in
one package at or above the Reportable Quantity and when
no other hazard class applies; otherwise, not regulated.

Special precautions for user

The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
ethylene glycol 107-21-1 5000 5000
ethylene glycol 107-21-1 5000 5000

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity

This material does not contain any components with a section 302 EHS TPQ.

SARA 311/312 Hazards : Acute toxicity (any route of exposure)

Specific target organ toxicity (single or repeated exposure)

SARA 313 : The following components are subject to reporting levels

established by SARA Title III, Section 313:

ethylene glycol 107-21-1 >= 90 - <= 100 %

California Prop. 65
WARNING: This product can expose you to chemicals including ethylene glycol, which is/are
known to the State of California to cause birth defects or other reproductive harm. For more i n-
formation go to www.P65Warnings.ca.gov.
The ingredients of this product are reported in the following inventories:
TSCA : On TSCA Inventory

DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

ISHL : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:

Flammability
HEALTH * 1
1 FLAMMABILITY
Instability

1
Health

1 0
PHYSICAL HAZARD
0

HMIS® ratings are based on a 0-4 rating

scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
Special hazard cant hazards or risks. The "*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants -
1910.1000
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
OSHA P0 / C : Ceiling limit

AICS - Australian Inventory of Chemical S ubstances; AS TM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Canc er; IA TA - International Air Transport Association; IB C
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office

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SAFETY DATA SHEET OXYDE CHEMICALS, INC.

Monoethylene Glycol, Polyester Grade

Version Revision Date: SDS Number: Date of last issue: 07/23/2018

1.2 10/14/2019 150000106079 Date of first issue: 10/13/2016
PRD SDSUS / Z8 / 0001

of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decom position Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TS CA - Toxic Substanc es Cont rol Act (United States); UN - Unit ed Nations; UNRTDG -
United Nations Recommendations on the Trans port of Dangerous Goods; vP vB - Very Persistent
and Very Bioaccumulative

Revision Date : 10/14/2019

The information provided in this Material S afety Data S heet is correct to the best of our
knowledge, information and belief at the dat e of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designat ed and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

US / Z8

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