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    Organic Chemistry II Problem Set 3 Reaction of Substituted Benzene

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    ergeg64

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    Organic Chemistry II Problem Set 3 Reaction of Substituted Benzene

    Uploaded by

    kjj7760
    13 views2 pages
    ergeg64

    Original Title

    chm2211ps3

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    ergeg64

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    13 views2 pages

    Organic Chemistry II Problem Set 3 Reaction of Substituted Benzene

    Uploaded by

    kjj7760
    ergeg64

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Organic Chemistry II

    Problem Set 3
    Reaction of Substituted Benzene
    Write products for these reactions. If no reaction occurs, write N.R.

    1. HNO3
    anisole
    H2SO 4

    O
    2. Br2
    O C
    FeBr3

    O
    3. Br2
    H3C C NH
    FeBr3

    4. Cl

    CH3 C O
    Cl
    AlCl3

    5. i-Pr-Cl
    aniline
    AlCl3

    O t-Bu-Cl
    6. H3C O C
    AlCl3

    7. HCl
    CH CH CH3

    8. EtCl NBS KOH(alc) cold dilute


    AlCl3 heat KMnO 4

    Cl
    9. a. excess KMnO4 / OH- reflux
    CH3 CH CH3
    toluene
    AlCl3 b. H+
    10.
    Br2

    Light
    cumene
    Cl
    11.
    CH3 CH2 C O H2
    AlCl3 Pd

    12. a. acetyl chloride / AlCl3


    t-butylbenzene
    b. NaBH 4 in EtOH / H 2O

    CH2Cl2
    13.
    AlCl3
    excess

    14. O
    Zn(Hg)
    CH2 CH2 C AlCl3 HCl
    Cl

    15. N2H4 / OH-


    acetophenone
    heat

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