Material Safety Data Sheet: 1. Chemical Product and Company Identification

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Product name: KF-96-100CS 1/7

Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

MATERIAL SAFETY DATA SHEET

1. Chemical product and company identification


A: Product name KF-96-100CS
B. Recommended use and Limitations on use
Recommended use Fluids,Modified silicone fluids
Resin modifier ,
Defoaming agent ,
Polishing agent ,
Powder processing agent ,
Water repellent ,
Textile treatment ,
Heating medium ,
Release agent ,
Cutting oil ,
Lubricating oil ,
Hydraulic oil ,
Damper oil ,
Cosmetic additive
Limitations on use Industrial use only.
C. Supplier information
MANUFACTURER
COMPANY NAME Shin-Etsu Silicones (Thailand) Limited
CONTACT Customer Services Department
ADDRESS 7th Floor, Harindhorn Tower, 54 North Sathorn Road, Bangkok 10500, Thailand
TELEPHONE NUMBER +66-2632-2941
FAX NUMBER +66-3868-9070
SUPPLIER
COMPANY NAME Shin-Etsu Silicone Korea Co., Ltd.
CONTACT Business Operation Dept.
ADDRESS GT TOWER 15F, 411, SEOCHO-DAERO, SEOCHO-GU, SEOUL, KOREA
TELEPHONE NUMBER +82(0)2-590-2500
FAX NUMBER +82(0)2-590-2501
EMERGENCY +82(0)2-590-2500
E-MAIL msds@shinetsu.net

2. Hazards identification
A. Hazard category/Classification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.

B. Warning label items including precautionary statement


• Pictogram None.
• Signal word None.
• Hazard statement None.
• Precautionary statement None.
C. Other hazards not included None known.
in the hazard category criteria
(e.g. dust explosion hazard)
Supplemental information None.

MSDS Korea (English)


Product name: KF-96-100CS 2/7
Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

3. Composition/information on ingredients
Chemical identity Common and CAS number ID number Content in
alternative names percent (%)
Dimethylpolysiloxane ; No hazardous component 63148-62-9 KE-31068 100
Common and alternative name ; No data

4. First aid measures


A. In case of eye contact Rinse immediately with plenty of water for at least 15 minutes. Get medical attention if irritation
develops and persists.
B. In case of skin contact Wash skin with soap and water.
C. In case of inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
D. In case of swallowing Rinse mouth. Get medical attention immediately.
E. Note to physician Treat symptomatically.
General advice Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
A. Suitable (and unsuitable) extinguishing media
Suitable extinguishing Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
media
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
B. Specific hazards arising By heating and fire, harmful vapors/gases may be formed.
from the chemical (example:
hazardous combustion
products)
C. Specific methods of fire-fighting
Special protective Firefighters must use standard protective equipment including flame retardant coat, helmet,
equipment for firefighters gloves, rubber boots, and self-contained breathing apparatus.
Special fire fighting Move containers from fire area if you can do so without risk.
procedures

6. Accidental release measures


A. Personal precautions, Wear appropriate personal protective equipment.
protective equipment and
emergency measures
B. Environmental precautions Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or
onto the ground.
C. Methods and materials for Eliminate sources of ignition.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills in original containers for re-use.

7. Handling and storage


A. Precautions for safe Provide adequate ventilation. Use adequate ventilation when this product is heated at
handling approximately 150 degrees C(300'F) and above in the presence of air. Use care in
handling/storage. Do not breathe mist or vapor.
B. Conditions for safe storage Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Keep in original
(including any container. Store away from incompatible materials (see Section 10 of the MSDS).
incompatibilities)

8. Exposure controls/personal protection


A. Exposure limit values, biological limit values, etc
No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).

MSDS Korea (English)


Product name: KF-96-100CS 3/7
Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

Exposure guidelines Other components are not applicable


B. Appropriate engineering Provide adequate general and local exhaust ventilation. Provide eyewash station.
controls
C. Personal protective equipment
• Respiratory protection If ventilation is insufficient when heating use chemical respirator with organic vapor cartridge.
• Eye protection Wear safety glasses with side shields (or goggles).
• Hand protection Wear protective gloves.
• Body protection Wear suitable protective clothing.
Hygiene measures Wash hands before breaks and immediately after handling the product. Handle in accordance with
good industrial hygiene and safety practice. This product can generate formaldehyde at
approximately 150 °C (300 °F) and above in the presence of air. Formaldehyde is a skin and
respiratory sensitizer, eye and throat irritant, acute toxicant and potential cancer hazard. So, use
adequate ventilation or wear protective equipment such as gloves, goggles, organic vapor
respirator or protective clothing when this product is heated at approximately 150 °C (300 °F) and
above in the presence of air.

9. Physical and chemical properties


A. Appearance
Form Liquid.
Color Colorless. Clear.
B. Odor Odorless
C. Odor threshold Not available.
D. pH Not measurable (Refer to water solubility)
E. Melting point/freezing point
Melting point No data
F. Boiling point, initial boiling No data
point, and boiling range
G. Flash point > 201.2 °F (> 94 °C) Closed Cup
> 572 °F (> 300 °C) Open Cup
H. Evaporation rate Negligible (Butyl Acetate=1)
I. Flammability (solid, gas) Not applicable.
J. Upper/lower limit on flammability or explosive limits
Flammability limit - lower No data
(%)
Flammability limit - upper No data
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
K. Vapor pressure Negligible ( 25 °C )
L. Solubility
Solubility (water) Not soluble (<1 ppm)
M. Vapor density Not applicable
N. Specific gravity 0.96 ( 25 °C )
O. n-octanol/water partition Not available.
coefficient
P. Auto-ignition temperature ca.400°C (752°F)
Q. Decomposition temperature Not available.
R. Viscosity 100 mm2/s ( 25 °C )
S. Molecular weight No data

10. Stability and reactivity


A. Stability and hazardous reaction potential
Stability Stable at normal conditions.
Hazardous reaction Hazardous polymerization does not occur.
potential

MSDS Korea (English)


Product name: KF-96-100CS 4/7
Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

B. Conditions to avoid (e.g. Not available.


static discharge, shock or
vibration, etc)
C. Incompatible materials Strong oxidizing agents.
D. Hazardous decomposition Thermal breakdown of this product during fire or very high heat condition may evolve the following
products hazardous decomposition product:
Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde .

11. Toxicological information


A. Information on likely routes of exposure
• Respiratory organs No adverse effects due to inhalation are expected.
• Skin No adverse effects due to skin contact are expected.
• Eyes Direct contact with eyes may cause temporary irritation.
• Mouth Expected to be a low ingestion hazard.
B. Information on health hazards
• Acute toxicity (list all
possible routes of
exposure)
Components Species Test Results
Dimethylpolysiloxane ; No hazardous component Common and alternative name ; No data (CAS 63148-62-9)
Acute
Oral
LD50 Rat > 5 g/kg (Estimated by similar product)

• Corrosivity or irritation to SKIN-RABBIT :No skin irritation (Estimated by similar product)


the skin
• Serious eye damage/eye EYE-RABBIT : No eye irritation (Estimated by similar product)
irritation
• Respiratory sensitization Not available.
• Skin sensitization Not available.
• Carcinogenic properties No carcinogenicity (Estimated by similar product)
/Carcinogenicity
• Mutagenic properties Negative(Bacteria) (Estimated by similar product)
/Mutagenicity
• Reproductive toxicity Not available.
• Specific target organ Not available.
toxicity - single exposure
• Specific target organ Not available.
toxicity - repeated
exposure
• Aspiration hazard Not available.
C. Other information This product can generate formaldehyde at approximately 150 °C (300 °F) and above in the
presence of air. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute
toxicant and potential cancer hazard. So, use adequate ventilation or wear protective equipment
such as gloves, goggles,organic vapor respirator or protective clothing when this product is
heated at approximately 150 °C (300 °F) and above in the presence of air.

Other components are no data.

12. Ecological information


A. Ecotoxicity No data available.
Hazardous to the aquatic Not available.
environment, acute hazard
Hazardous to the aquatic Not available.
environment, long-term
hazard
B. Persistence/degradability May cause decomposition in dry soils. (Estimated by similar product)
C. Bioaccumulative potential No bioaccumulation (Estimated by similar product)

MSDS Korea (English)


Product name: KF-96-100CS 5/7
Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

D. Mobility in soil No data available.


E. Hazardous to the ozone No data available.
layer
F. Other adverse effects Other components are no data.

13. Disposal considerations


A. Method of disposal Incinerate. Incinerator should be appropriately equipped for silica and other fine powder which the
product will generate in incineration. Workers should wear appropriate personal protective
equipment(s) such as respirator. Contract with a disposal operator licensed by the Law on
Disposal and Cleaning. Dispose of contents/container in accordance with
local/regional/national/international regulations.
B. Disposal considerations Since emptied containers may retain product residue, follow label warnings even after container is
(including disposal of emptied.
contaminated containers or
packaging)
Waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.

14. Transport information


IATA
A. UN number Not applicable.
B. UN proper shipping name Not applicable.
C. Transport hazard class(es)
Class Not applicable.
Subsidiary risk -
D. Packing group Not applicable.
E. Environmental hazards No.
F. Special precautions for Not applicable.
user
IMDG
A. UN number Not applicable.
B. UN proper shipping name Not applicable.
C. Transport hazard class(es)
Class Not applicable.
Subsidiary risk -
D. Packing group Not applicable.
E. Environmental hazards
Marine pollutant No.
EmS Not applicable.
F. Special precautions for Not applicable.
user
Transport in bulk according to This product is not intended to be transported in bulk.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information


A. Restriction under the Occupational Safety and Health Act
Harmful Substances Prohibited from Manufacturing
Not regulated.
Harmful Substances Requiring Permission for Manufacture or Use
Not regulated.
Controlled Hazardous Substances
Not regulated.
Harmful Substances Requiring Special Medical Examination
Not regulated.
Workplace Environmental Monitoring Harmful Materials
Not regulated.
Occupational Exposure Limit
Not regulated.

MSDS Korea (English)


Product name: KF-96-100CS 6/7
Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

B. Restrictions under the Toxic Chemicals Control Act


Accidental Release Prevention Substances
Not regulated.
Banned Toxic Chemicals
Not regulated.
Observational Chemicals
Not regulated.
Restricted Chemical Substances
Not regulated.
Toxic Chemicals
Not regulated.
C. Restrictions under the Safety Control of Dangerous Substances Act
Not regulated.
D. Restrictions under the Wastes Control Act
Halogenated Materials in Waste Organic Solvents
Not regulated.
Hazardous Substances
Not regulated.
E. Restrictions under other foreign or domestic laws
Clean Air Conservation Act
Air Pollutants
Not regulated.
Specific Air Pollutants
Not regulated.
Further information This material safety data sheet was prepared in accordance with Article 41 of the Industrial Safety
and Health Law.
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Korea Existing Chemicals List (ECL) Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information


A. Source of information ACGIH
EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
Korea. Accidental Release Prevention Substances (Presidential Decree of Toxic Chemical Control
Law, Executive Order No. 19203)
Korea. Dangerous Substances Threshold Quantity (Presidential Decree of Dangerous Substances
Safety Management Act No. 18406, Schedule 1)
Korea. Harmful Substances Prohibited from Manufacturing (Presidential Decree on the Industrial
Safety and Health Act (No. 13053), Article 29)
Korea. Harmful Substances Requiring Permission for Manufacture or Use (Presidential Decree on
the Industrial Safety and Health Act (No. 13053), Article 30)
Korea. Non-Toxic Chemicals List (National Institute of Environment Research (NIER) Public Notice
No. 1997-10, as amended)
Korea. Observational Chemicals (Ministerial Decree of TCCL Article 6)
Korea. OELs. Regulation for Permitted Concentration of Hazardous Substances (Ministry of Labor
(MOL) Public Notice No. 1986-45, as amended)
Korea. Prohibited Chemical Substances (TCCL Article 11)
Korea. Regulated volatile organic compounds (VOCs) (MOE Notice No. 2001-36, March 8, 2001,
as amended)
Korea. Restricted Chemical Substances (TCCL Article 11)
Korea. Toxic Chemical Control Law (TCCL), Existing Chemicals Inventory (KECI)
Korea. Toxic Chemical Control Law (TCCL), pre-1997 List
Korea. Toxic Chemicals (TCCL Article 10)
Korea. Toxic Release Inventory (TRI) Chemicals (TCCL Article 14)
Korea. Employment Labor Department Notification No. 2016-19
B. Issue date 02-04-2014
C. Number of revisions and 04-24-2017 (02 revision)
date of most recent revision

MSDS Korea (English)


Product name: KF-96-100CS 7/7
Company name: Shin-Etsu Silicones (Thailand) Limited Reference #: GJNSS1 / 03 Version #: 02 Revision date:
04-24-2017

D. Other Not available.


Disclaimer A number of potentially serious health effects can result from aerosol inhalation of this product.
Take preventive measures such as controlling size of generated particle, ventilation, and
respiratory protection when using this product in spray application. Please contact nearby sales
representative for further information. This information is offered in good faith as typical values
and not as a product specification. No warranty, expressed or implied, is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of
the intended use and determine whether they are appropriate.
This product has been designed, manufactured and developed solely for general industrial use
only. This product is not designed for, intended for use as, or suitable for, medical, surgical or
other particular purposes. Users have the sole responsibility and obligation to determine the
suitability of this product for any application, to make preliminary tests, and to confirm the safety of
this product for their use. Users must never use this product for the purpose of implantation into
the human body and/or injection into humans.
Revision information This document has undergone significant changes and should be reviewed in its entirety.

MSDS Korea (English)

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