SDS No.: US-E TG-S50 rev.

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Date of issue: 2021.9.1

SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trade designation
TG-S50
Recommended use
For welding
Restrictions on use
Do not use except for welding.
Manufacturer
Manufacturer's Name: KOBE STEEL, LTD.
Address: 5-9-12 Kitashinagawa Shinagawa-Ku Tokyo JAPAN
Phone number: +81-3-5739-6331
Fax number: +81-3-5739-6960
Emergency phone number: +81-3-5739-6331

2. HAZARDS IDENTIFICATION

Classification according to Globally harmonized system of classification and labelling of chemicals (GHS).

Hazard classification
Classification not possible as hazardous according to GHS classification.
Label elements
Symbol: Not applicable
Signal word: Not applicable
Hazard statement: Not applicable
Precautionary statement: Not applicable
Other hazards which do not classified in GHS classification
General: When this product is used in a welding process the hazards are electric shock,
fumes, gases, radiation, spatter, slag and heat. Read and understand this Safety
Data Sheets and the manufacturer’s instructions and the precautionary labels
before using this product.
Shock: Electrical Shock can kill.
Radiation: Arc rays can injure eyes and burn skin.
Fumes: Overexposure to welding fumes result in symptoms like dizziness, nausea, dryness
or irritation of the nose, throat or eyes. Chronic overexposure to welding fumes
may affect respiratory system and nervous system.
Substance(s) formed under the conditions of use
The welding fumes produced from this welding electrode may contain the listed
constituent(s) of Sec.3 and/or their complex metallic oxides as well as solid
particles or other constituents from the consumables, base metal, or base metal
coating not listed Sec.3. The welding fumes may contain Mn, Ni, Cr(VI) and
their compounds. Refer to Sec.8 and 10.
Gases: Gases may cause gas poisoning. Under conditions of use, gases may contain
carbon oxides, nitrogen oxides, ozone etc. Refer to Sec.8 and 10.
Spatter, slag: Spatter, slag can damage eyes.
Heat: Spatter, slag, melting metal, hot welds, arc rays and sparks can cause burn injuries
and ignite combustibles and flammable materials

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3. COMPOSITION / INFORMATION ON INGREDIENTS

Substance/Mixture/Article
Mixture
Chemical name CAS No. Concentration range (%)
Iron 7439-89-6 Balance
Manganese 7439-96-5 ＜3
Silicon 7440-21-3 ＜1
Copper 7440-50-8 ＜1

4. FIRST AID MEASURES

Description of first aid measures
Inhalation: Remove person to fresh air and keep comfortable for breathing and get medical
advice/attention. If breathing has stopped, perform artificial respiration and get immediate
medical advice/attention.
Skin contact: Take off contaminated clothing and rinse skin with soap and water [or shower]. If skin
irritation occurs, get medical advice/attention. For reddened or blistered skin, or thermal burns,
get medical advice/attention.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Get medical advice/attention.
Arc rays can injure eyes. If exposed to arc rays, move victim to dark room, remove contact
lenses as necessary for treatment, cover eyes with a padded dressing and rest. If symptoms
persist, get medical advice/attention.
Electric shock: Disconnect and turn off power. If the victim is semi- or unconscious, open the airway. If the
victim cannot breath, give artificial respiration. If there is no pulse, massage the chest and
apply artificial respiration.
Ingestion: Unlikely due to form of product, except for granular materials. If ingested, Rinse mouth. Do
NOT induce vomiting. Immediately call a POISON CENTER/doctor.
Most important symptoms/effects, acute and delayed
Symptoms: Short-term (acute) overexposure to welding fumes may result in discomfort such as metal
fume fever, dizziness, nausea, or dryness or irritation of nose, throat, or eyes. May aggravate
pre-existing respiratory problems (e.g. asthma, emphysema).
Long-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits in
lung), central nervous system effects, bronchitis and other pulmonary effects. Refer to Section
11 for more information.
Hazards: Welding hazards are complex and may include physical and health hazards such as but not
limited to electric shock, physical strains, radiation burns (eye flash), thermal burns due to hot
metal or spatter and potential health effects of overexposure to welding fume or dust. Refer to
Section 11 for more information.
Indication of immediate medical attention and special treatment needed Treatment
Treat Symptomatically.

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5. FIRE-FIGHTING MEASURES

General fire hazards

As shipped, this product is nonflammable. However, welding arc and sparks can ignite combustibles and
flammable products. Read and understand American National Standard Z49.1, "Safety In Welding, Cutting and
Allied Processes” before using this product.
Suitable (and unsuitable) extinguishing media
Suitable extinguishing media: As shipped, the product will not burn. In case of fire in the surroundings,
use CO2, powder or water spray.
Unsuitable extinguishing media: None known
Specific hazards arising from the chemical
None known
Special protective equipment and precautions for fire-fighters
Special protective equipment: Selection of respiratory protection for fire-fighting: follow the general fire
precautions indicated in the workplace. Self-contained breathing apparatus
and full protective clothing must be worn in case of fire.
Special precautions: Use standard firefighting procedures and consider the hazards of other
involved materials.

6. ACCIDENTAL RELEASE MEASURES

General
Unlikely due to form of product, except for granular materials. The welding fumes and slags may be released.
Personal precautions, protective equipment and emergency procedures
If airborne dust and/or fume is present, use adequate engineering controls and, if needed, personal protection to
prevent overexposure. Refer to recommendations in Section 8.
Methods and material for containment and cleaning up
Clean up spills immediately, observing precautions in the personal protective equipment in Section 8. Avoid
generating dust. Prevent product from entering any drains, sewers or water sources. Refer to Section 13 for proper
disposal.
Environmental precautions
Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

7. HANDLING AND STORAGE

Precautions for safe handling

Reduction of fumes and dusts: Keep formation of airborne dusts to a minimum. Provide appropriate
exhaust ventilation at places where dust is formed. Read and understand
the manufacturer's instruction and the precautionary label on the product.
See American National Standard Z49.1, "Safety In Welding, Cutting and
Allied Processes"
Prevention of electric shock: Do not touch live electrical parts such as the welding wire and welding
machine terminals. Wear insulated gloves and safety boots. If welding
must be performed in damp locations or with wet clothing, on metal
structures or when in cramped positions such as sitting , kneeling or
lying, or if there is a high risk of unavoidable or accidental contact with
workpiece, use the following equipment: Semiautomatic DC Welder, DC
Manual (Stick) Welder, or AC Welder with Reduced Voltage Control.
Prevention of fire and explosion: Remove flammable and combustible materials and liquids.
Prevention of harm when handling Handle with care to avoid stings and cuts. Hold the welding wire
welding consumables: manually when loosening the wire.
Conditions for safe storage, including any incompatibilities
Store welding consumables inside a room without humidity. Do not store welding consumables directly on the
ground or beside a wall. Keep welding consumables away from chemical substances like acids which could cause
chemical reactions. Store in accordance with local/regional/national regulations.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters
For substances may be included in welding fumes, gases and flux, occupational exposure values are shown in
Annex. Keep exposure below exposure limits. Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) are values published by the American Conference of Government Industrial Hygienists (ACGIH). ACGIH
Statement of Positions Regarding the TLVs and BEIs states that the TLV-TWA should be used as a guide in the
control of health hazards and should not be used to indicate a fine line between safe and dangerous exposures. See
Section 10 for information on potential fume constituents of health interest.
Appropriate engineering controls
Ventilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gases below
the exposure limits in the worker's breathing zone and the general area. Keep exposure as low
as possible.Determine the composition and quantity of fumes and gases to which workers are
exposed by taking an air sample from inside the welder's helmet if worn or in the worker's
breathing zone. Improve ventilation if exposures are not below limits. See ANSI/AWS F1.1,
F1.2, F1.3 and F1.5, available from the American Welding Society, www.aws.org.
Individual protection measures
Eye protection: Wear helmet or use face shield with filter lens. As a rule of thumb, start with a shade
which is too dark to see the weld zone. Then go to the next lighter shade which gives
sufficient view of the weld zone. Provide protective screens and flash goggles, if
necessary, to shield others.
Hand protection: Wear protective gloves. Suitable gloves can be recommended by the glove supplier.
Protective Wear hand, head, and body protection which help to prevent injury from radiation, sparks
Clothing: and electrical shock. See Z49.1. At a minimum this includes welder's gloves and a
protective face shield, and may include arm protectors, aprons, hats, shoulder protection,
as well as dark substantial clothing. Wear dry gloves free of holes or split seams. Train the
welder not to permit electrically live parts or electrodes to contact skin or clothing or
gloves if they are wet. Insulate yourself from the work piece and ground using dry
plywood, rubber mats or other dry insulation.
Respiratory Keep your head out of fumes. Use enough ventilation and local exhaust to keep fumes
protection: and gases from your breathing zone and the general area. Use respirable fume respirator
or air supplied respirator when welding in confined space or where local exhaust or
ventilation does not keep exposure below exposure limits.
Ear protection: Wear earplugs or earmuffs when using engine driven arc welding machine or pulsed arc
welding machine that generates high-level noise.
Hygiene measures: Do not eat, drink or smoke when using the product. Always observe good personal
hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Solid
Form Wire or Rod
Color: Silver or Copper
Odor: Odorless
Odor threshold: No further relevant information available
pH: Not applicable
Melting point/freezing point: No further relevant information available
Boiling point, initial boiling point and boiling range: No further relevant information available
Flash point: Not applicable
Evaporation rate: Not applicable
Flammability: No further relevant information available
Upper/lower flammability or explosive limits: No further relevant information available
Vapor pressure: Not applicable
Vapor density: Not applicable
Solubility(ies) No further relevant information available
Partition coefficient (n-octanol/water): No further relevant information available
Auto-ignition temperature: No further relevant information available
Decomposition temperature: No further relevant information available
Viscosity: Not applicable

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10. STABILITY AND REACTIVITY

Reactivity
Non-reactive under normal conditions of storage and transport.
Chemical stability
Stable under normal conditions of storage and transport.
Possibility of hazardous reactions
Contact with acids, alkalis and oxidizing agents could cause reaction and generation of gas.
Conditions to avoid
Avoid heat or contamination of acids, alkalis and oxidizing agents.
Incompatible materials
Avoid contact with acids, alkalis and oxidizing agents.
Hazardous decomposition products
Welding fumes and gases are generated as byproducts during the welding. The composition and quantity of fumes
and gases cannot be recognized simply. The composition and quantity of the fumes and gases are dependent upon
the base metal being welded (included coating such as solvent, paint, plating), the welding process, welding
procedure, welding parameter and electrodes used. Other conditions which also influence the quantity of the
fumes and gases to which workers may be exposed include the number of welding spots, the volume of the worker
area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as
well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning
and degreasing activities.)

The fumes and gases are different in percent and form from the ingredients listed in Section 3. The fumes and
gases include those originating from the volatilization, reaction, or oxidation of the materials shown in Section 3,
plus those from the base metal and coating, etc., as noted above. Reasonably expected fume constituents produced
during arc welding include the oxides of iron, manganese and other metals present in the welding consumable or
base metal. And, it is known that these metal oxides are complex oxides, not single compounds. Hexavalent
chromium compounds may be in the welding fume of consumables or base metals which contain chromium.
Nickel compounds may be in the welding fume of consumables or base metals which contain Nickel. Gaseous and
particulate fluoride may be in the welding fume of consumables which contain fluoride. Gaseous reaction products
may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation
from the arc.

11. TOXICOLOGICAL INFORMATION

General
Classification not possible as product. Refer to Sec.2. Inhalation of welding fumes and gases can be dangerous to
your health. The composition and quantity of both are dependent upon the material being worked, the process,
procedures, and consumables used. Refer to Sec.10.
Acute toxicity
Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness,
nausea, or dryness or irritation of nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g.
asthma, emphysema).
Cr: The presence of chromium/chromate in welding fumes can cause irritation of nasal membranes and
skin.
Ni: The presence of nickel compounds in fume can cause metallic taste, nausea, tightness of chest, fever.
F: Exposure to the fluoride ion in welding fumes may cause hypocalcemia-calcium deficiency in the
blood that can result in muscle cramps and inflammation and necrosis of mucous membranes.
Gases: Some toxic gases associated with welding may cause pulmonary edema, asphyxiation, and death.
Chronic toxicity
Long-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits in lung), central nervous
system effects, bronchitis, pneumoconiosis and other pulmonary effects. The severity of the change is
proportional to the length of the exposure. The changes may be caused by non-work factors such as smoking, etc.
Ni: Long term overexposure to nickel fumes may also cause pulmonary fibrosis and edema.
Cr: Chromates may cause ulceration, perforation of the nasal septum, and severe irritation of the bronchial
tubes and lungs. Liver damage have also been reported. Chromates contain the hexavalent form of
chromium.
Mn: Overexposure to manganese compounds may affect the central nervous system, symptoms of which are
languor, sleepiness, muscular weakness, emotional disturbances and spastic gait. The effect of
manganese on the nervous system is irreversible.

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Cu: Overexposure to copper fumes may lead to copper poisoning, resulting in hermolytic anemia and liver,
kidney and spleen damage.
Fe: Inhalation of too much iron oxide fume over a long time can cause siderosis, sometimes called “iron
pigmentation” of the lung, which can be seen on a chest x-ray but causes little or no disability. Chronic
overexposure to iron (>50-100mg Fe per day) can result in pathological deposition of iron in body
tissues, symptoms of which are fibrosis of the pancreas, diabetes mellitus, and liver cirrhosis.
SiO2: Respiratory exposure to the crystalline silica present in this welding electrode is not anticipated during
normal use. Respiratory overexposure to airborne crystalline silica is known to cause silicosis, a form
of disabling pulmonary fibrosis which can be progressive and may lead to death.
F: Chronic fluoride absorption can result in osseous fluorosis, increased radiographic density of the bones
and mottling of the teeth.
Carcinogenicity
Welding fumes (not otherwise specified) are possibly carcinogenic to humans. Welding fumes is on the IARC
lists as posing a cancer risk.
SiO2: Crystalline silica is on the IARC (International Agency for Research on Cancer) and NTP (National
Toxicology Program) lists as posing a cancer risk to humans.
Ni: Nickel and its compounds are on the IARC and NTP lists as posing respiratory cancer risk.
Cr: Hexavalent chromium and its compounds are on the IARC and NTP lists as posing a cancer risk to
humans.
Arc Skin cancer has been reported.
rays:
Respiratory or Skin Sensitization
Ni: Nickel and its compounds are skin sensitizers with symptoms ranging from slight itch to severe
dermatitis.
Cr: Chromates may cause allergic reactions, including skin rash. Asthma has been reported in some
sensitized individuals. Skin contact may result in irritation, ulceration, sensitization, and contact
dermatitis.
Others
Organic polymers may be used in the manufacture of various welding consumables. Overexposure to their
decomposition byproducts may result in a condition known as polymer fume fever. Polymer fume fever usually
occurs within 4 to 8 hours of exposure with the presentation of flu like symptoms, including mild pulmonary
irritation with or without an increase in body temperature. Signs of exposure can include an increase in white
blood cell count. Resolution of symptoms typically occurs quickly, usually not lasting longer than 48 hours.

12. ECOLOGICAL INFORMATION

Ecotoxicity
Product: No further relevant information available
Persistence and degradability
Product: No further relevant information available
Bioaccumulative potential
Product: No further relevant information available
Mobility in soil
Product: No further relevant information available

13. DISPOSAL CONSIDERATIONS

The generation of waste should be avoided or minimized whenever possible. When practical, recycle in an
environmentally acceptable, regulatory compliant manner. Dispose of non-recyclable products in accordance with
all applicable National, State, and Local requirements. Discharge, treatment, or disposal may be subject to
National, State, or Local laws.

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14. TRANSPORT INFORMATION

UN number: No further relevant information available

UN proper shipping name: No further relevant information available
Transport hazard class(es): No further relevant information available
Packing group: No further relevant information available
Environmental hazards: No further relevant information available
Transport in bulk (according to Annex II of MARPOL73/78 No further relevant information available
and the IBC Code):
Special precautions for user: No further relevant information available
Classification for SEA transport (IMO-IMDG): No further relevant information available
Classification for AIR transport (IATA/ICAO): No further relevant information available

15. REGULATORY INFORMATION

Regulations of each country are applied to substance/mixtures/article.

16. OTHER INFORMATION

This SDS is prepared in accordance with ISO 11014, OSHA Hazard Communication Standard (29 CFR
1910.1200) and the Canadian Controlled Products Regulations.
Reference
American National Standard (ANSI) Z49.1 “Safety in Welding, Cutting, and Allied Processes”
ISO 11014:2009 “Safety data sheet for chemical product - Content and order of sections”
United Nations (UN) “Globally harmonized system of classification and labelling of chemicals (GHS)”
Date of issue
2021.9.1
Disclaimer
The information given in this SDS is based on the present level of our knowledge and experience. This
information is believed to be accurate as of the revision date shown above. However, no warranty, expressed or
implied, is given. Because the conditions or methods of use are beyond KOBE STEEL, LTD.’s control, we assume
no liability resulting from the use of this product. Regulatory requirements are subject to change and may differ
between various locations. Compliance with all applicable Federal, State, Provincial, and local laws and
regulations remain the responsibility of the user. If necessary, consult an industrial hygienist or other expert to
understand this information and safeguard the environment and protect workers from potential hazards associated
with the handling or use of this product.