SAFETY DATA SHEET

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II (453/2010) - Europe

Sanichlor Version : 2

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : Sanichlor
Product code : 111337E
Product use : disinfectant
Product is for professional use only

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Surface disinfectant. Manual process

Uses advised against

None known.

1.3 Details of the supplier of the safety data sheet

Manufacturer/ Distributor/ : Ecolab Ltd.
Importer David Murray John Building
UK-SN1 1NH Swindon, Wiltshire
England
Tel +44 (0)1793 511221
Fax +44 (0)1793 618552
CCS@ecolab.com
1.4 Emergency telephone number
National advisory body/Poison Centre
Telephone number : 0870 600 6266 (This service is only available to health professionals)
Manufacturer/ Distributor/ Importer
Telephone number : 01793 511221
Food & Beverage, Institutional, Agri - 01793 548888
Healthcare Leeds - 0113 2322480
Healthcare Swansea - 01252 717616

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Eye Irrit. 2, H319
STOT SE 3, H335
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
The classification of this product is based on the results of testing.
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Xn; R22
Xi; R36/37
R31
N; R50/53
Human health hazards : Harmful if swallowed. Irritating to eyes and respiratory system. Contact with acids
liberates toxic gas.

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SECTION 2: Hazards identification

Environmental hazards : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Contains : Troclosene sodium
Hazard statements : H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements
Prevention : P273 - Avoid release to the environment.
P280 - Wear eye protection.
Ingredients of unknown : Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 20%
toxicity
Supplemental label : EUH031 - Contact with acids liberates toxic gas.
elements

2.3 Other hazards

Other hazards which do : Not applicable.
not result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
Troclosene sodium EC: 220-767-7 35 - E; R2 Ox. Sol. 2, H272 [1]
CAS: 2893-78-9 <50 O; R8 Acute Tox. 4, H302
Index: 613-030-00-X Xn; R22 Eye Irrit. 2, H319
Xi; R36/37 STOT SE 3, H335
R31 Aquatic Acute 1, H400
N; R50/53 Aquatic Chronic 1, H410
Organic acids EC: 204-673-3 20 - Xi; R36 Eye Irrit. 2, H319 [1]
CAS: 124-04-9 <25 Aquatic Chronic 3, H412
Index: 607-144-00-9
Sodium Carbonate REACH #: 1 - <5 Xi; R36 Eye Irrit. 2, H319 [1]
(soda) 01-2119485498-19
EC: 207-838-8
CAS: 497-19-8
Index: 011-005-00-2

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SECTION 3: Composition/information on ingredients

See Section 16 for See Section 16 for the
the full text of the R- full text of the H
phrases declared statements declared
above. above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this
section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15
minutes. Get medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If it is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. Get medical attention. If necessary, call a poison
center or physician.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get
medical attention if symptoms occur.
Ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : May cause respiratory irritation. Exposure to decomposition products may cause a
health hazard. Serious effects may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

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SECTION 4: First aid measures

Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : No specific data.
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : In case of fire, use water spray (fog), foam, dry chemical, or CO2.
media
Unsuitable extinguishing : None known.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : This material is very toxic to aquatic life with long lasting effects. Fire water
substance or mixture contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
metal oxide/oxides

5.3 Advice for firefighters

Special precautions for : Promptly isolate the scene by removing all persons from the vicinity of the incident if
fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Keep unnecessary and unprotected personnel from entering. Try to avoid touching
or walking through spilt material. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Water polluting material. May be harmful to the environment if released in large
precautions quantities. Collect spillage.

6.3 Methods and materials for containment and cleaning up

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SECTION 6: Accidental release measures

Small spill: : Move containers from spill area. Vacuum or sweep up material and place in a
designated, labelled waste container.
Large spill : Move containers from spill area. Prevent entry into sewers, water courses,
basements or confined areas. Vacuum or sweep up material and place in a
designated, labelled waste container.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Avoid release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Keep away from acids.
Advice on general : Workers should wash hands and face before eating, drinking and smoking. See
occupational hygiene also Section 8 for additional information on hygiene measures.

7.2 Conditions for safe : Store between the following temperatures: 0 to 40°C (32 to 104°F). Store in
storage, including any accordance with local regulations. Separate from acids.
incompatibilities

7.3 Specific end use(s)

Recommendations : Not applicable until Exposure Scenarios for substances become available.
Industrial sector specific : Not applicable until Exposure Scenarios for substances become available.
solutions

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
No exposure limit value known.

Derived effect levels

No DNELs available for the mixture.
Predicted effect concentrations
No PNECs available for the mixture.

8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas,
controls vapour or mist, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. Engineering controls may be required to control
the primary or secondary risks associated with this product.
Individual protection measures

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SECTION 8: Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Recommended : Safety glasses.
(EN 166)
Skin protection
Hand protection : No special recommendations.
(EN 374)
Body protection : Personal protective equipment for the body should be selected based on the task
(EN 14605) being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
(EN 143, 14387) standard if a risk assessment indicates this is necessary. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Thermal hazards : Not applicable.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to
controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Tablet
Colour : White
Odour : chlorine
Odour threshold : Not applicable and/or not determined for the mixture.
pH : 5 to 6 [Conc. (% w/w): 1%]
Melting point/freezing point : Not applicable and/or not determined for the mixture.
Initial boiling point and : Not applicable and/or not determined for the mixture.
boiling range
Flash point : > 100°C
Evaporation rate : Not applicable and/or not determined for the mixture.
Flammability (solid, gas) : Not applicable and/or not determined for the mixture.
Burning time : Not applicable and/or not determined for the mixture.
Burning rate : Not applicable and/or not determined for the mixture.
Upper/lower flammability or : Not applicable and/or not determined for the mixture.
explosive limits
Vapour pressure : Not applicable and/or not determined for the mixture.
Vapour density : Not applicable and/or not determined for the mixture.
Relative density : Not available.
Solubility(ies) : Easily soluble in the following materials: cold water and hot water.
Partition coefficient: n-octanol/ : Not applicable and/or not determined for the mixture.
water

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SECTION 9: Physical and chemical properties

Auto-ignition temperature : Not applicable and/or not determined for the mixture.
Decomposition temperature : Not applicable and/or not determined for the mixture.
Viscosity : Not applicable and/or not determined for the mixture.
Explosive properties : Not applicable.
Oxidising properties : Yes.

9.2 Other information

No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Hazardous reactions or instability may occur under certain conditions of storage or
hazardous reactions use.
Conditions may include the following:
contact with acids
Reactions may include the following:
liberation of toxic gas

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : Extremely reactive or incompatible with the following materials: acids and moisture.

10.6 Hazardous : Contact with acids liberates toxic gas.

decomposition products

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Troclosene sodium LD50 Dermal Rabbit >10000 mg/kg -
LD50 Oral Rat 1500 mg/kg -
Sodium Carbonate(soda) LC50 Inhalation Dusts and Rat 1.15 mg/l 4 hours
mists
LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat 2800 mg/kg -
Conclusion/Summary : No known significant effects or critical hazards.
Acute toxicity estimates
Route ATE value
Oral 2666.7 mg/kg
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Organic acids Eyes - Mild irritant Rabbit - 10 milligrams -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Mild irritant Rabbit - 0.25 Grams -

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SECTION 11: Toxicological information

Conclusion/Summary : No known significant effects or critical hazards.
Sensitiser
Conclusion/Summary : No known significant effects or critical hazards.
Mutagenicity
Conclusion/Summary : No known significant effects or critical hazards.
Carcinogenicity
Conclusion/Summary : No known significant effects or critical hazards.
Reproductive toxicity
Conclusion/Summary : No known significant effects or critical hazards.
Teratogenicity
Conclusion/Summary : No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
Troclosene sodium Category 3 Not applicable. Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
No known significant effects or critical hazards.
Aspiration hazard
No known significant effects or critical hazards.
Information on the likely : No known significant effects or critical hazards.
routes of exposure
Potential acute health effects
Inhalation : May cause respiratory irritation. Exposure to decomposition products may cause a
health hazard. Serious effects may be delayed following exposure.
Ingestion : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Eye contact : Causes serious eye irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : No known significant effects or critical hazards.
effects
Potential delayed effects : No known significant effects or critical hazards.
Long term exposure
Potential immediate : No known significant effects or critical hazards.
effects

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SECTION 11: Toxicological information

Potential delayed effects : No known significant effects or critical hazards.
Potential chronic health effects
Conclusion/Summary : No known significant effects or critical hazards.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Other information : No known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
Troclosene sodium Acute EC50 0.11 mg/l Daphnia 48 hours
Acute LC50 0.217 mg/l Fish 96 hours
Organic acids Acute LC50 97000 μg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling) - 4 to 8 weeks - 1.1
to 3.1 cm
Sodium Carbonate(soda) Acute EC50 200 mg/l Daphnia 48 hours
Conclusion/Summary : No known significant effects or critical hazards.

12.2 Persistence and degradability

Conclusion/Summary : The total of the organic components contained in the product achieve > 60% BOD/
COD or CO2 liberation, or > 70% DOC reduction in tests for ease of degradability -
threshold values for 'readily degradable' (e.g. to OECD method 301).

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
Organic acids 0.08 - low

12.4 Mobility in soil

Soil/water partition : Not determined for the mixture.
coefficient (KOC)
Mobility : Not determined for the mixture.

12.5 Results of PBT and vPvB assessment

PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects : No known significant effects or critical hazards.

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SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Empty
containers or liners may retain some product residues. This material and its
container must be disposed of in a safe way. Significant quantities of waste product
residues should not be disposed of via the foul sewer but processed in a suitable
effluent treatment plant. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority
requirements.
Hazardous waste : Yes.
European waste catalogue (EWC)
Waste code Waste designation
20 01 14* acids
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled.
Special precautions : This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues.

SECTION 14: Transport information

ADR/RID ADN/ADNR IMDG IATA
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.

14.2 UN proper - - - -
shipping name
14.3 Transport - - - -
hazard class(es)

14.4 Packing - - - -
group
14.5 No. No. No. No.
Environmental
hazards
14.6 Special None. None. None. None.
precautions for
user

14.7 Transport in bulk : Not applicable.

according to Annex II of
MARPOL 73/78 and the IBC
Code

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SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
Ingredient declaration according to detergent regulation 648/2004/EC:

≥ 30% chlorine-based bleaching agents

National regulations
United Kingdom (UK)
The Chemicals (Hazard Information and Packaging for Supply) Regulations.
The Control of Substances Hazardous to Health Regulations.
Health and Safety at Work Act.

15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ADN = European Provisions concerning the International Carriage of Dangerous
acronyms Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
DPD = Dangerous Preparations Directive [1999/45/EC]
EC = European Commission
EUH statement = CLP-specific Hazard statement
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
OEL = Occupational Exposure Limit
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation [Regulation (EC) No. 1907/2006]
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
REACH # = REACH Registration Number

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SECTION 16: Other information

vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Eye Irrit. 2, H319 Calculation method
STOT SE 3, H335 Calculation method
Aquatic Acute 1, H400 Calculation method
Aquatic Chronic 1, H410 Calculation method
Full text of abbreviated H : H272 May intensify fire; oxidiser.
statements H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications : Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4
[CLP/GHS] Aquatic Acute 1, H400 AQUATIC TOXICITY (ACUTE) - Category 1
Aquatic Chronic 1, H410 AQUATIC TOXICITY (CHRONIC) - Category 1
Aquatic Chronic 3, H412 AQUATIC TOXICITY (CHRONIC) - Category 3
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Ox. Sol. 2, H272 OXIDIZING SOLIDS - Category 2
STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE
EXPOSURE) [Respiratory tract irritation] - Category 3
Full text of abbreviated R : R2- Risk of explosion by shock, friction, fire or other sources of ignition.
phrases R8- Contact with combustible material may cause fire.
R22- Harmful if swallowed.
R36- Irritating to eyes.
R36/37- Irritating to eyes and respiratory system.
R31- Contact with acids liberates toxic gas.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Full text of classifications : E - Explosive
[DSD/DPD] O - Oxidising
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
Date of printing : 18 November 2013
Date of issue/ Date of : 18 November 2013
revision
Date of previous issue : No previous validation
Version : 2
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.

Date of issue/Date of revision : 18 November 2013 12/12