Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

(IE) VINYL MATT

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1. Product identifier
Product name : (IE) VINYL MATT

1.2. Relevant identified uses of the substance or mixture and uses advised against
Product use : Waterborne coating for interior use.

1.3. Details of the supplier of the safety data sheet

ICI Paints AkzoNobel,
Wexham Road,
Slough,
Berkshire,
SL2 5DS, U.K.
Tel.: +44 (0) 333 222 71 71
www.dulux.co.uk

e-mail address of person : dulux.advice@akzonobel.com

responsible for this SDS

1.4 Emergency telephone number

Telephone number : Emergency Telephone : Slough +44 (0) 1753 550000

Version : 13
Date of previous issue : 6-4-2017

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Not classified.
Ingredients of unknown : 0%
toxicity
Ingredients of unknown : 0%
ecotoxicity
See Section 16 for the full text of the H statements declared above.

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SECTION 2: Hazards identification

See Section 11 for more detailed information on health effects and symptoms.

2.2. Label elements

Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
General : P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Prevention : P262 - Do not get in eyes, on skin, or on clothing.
Response : P312 - Call a POISON CENTER or doctor if you feel unwell.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national or international regulations.
Supplemental label : Contains C(M)IT/MIT(3:1). May produce an allergic reaction.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3. Other hazards

Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture
Classification
Product/ingredient name Identifiers % (w/w) Regulation (EC) No. 1272/2008 Type
[CLP]
C(M)IT/MIT(3:1) CAS: 55965-84-9 <0.0015 Acute Tox. 3, H301 [1]
Index: Acute Tox. 3, H311
613-167-00-5 Acute Tox. 3, H331
Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 1, H410 (M=1)
See Section 16 for the full text of the H
statements declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
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SECTION 3: Composition/information on ingredients

Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1. Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

4.2. Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The product is not classified as hazardous according to Regulation
(EC) 1272/2008 as amended.

Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-
allergic contact dermatitis and absorption through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains C(M)IT/MIT(3:1). May produce an allergic reaction.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

See toxicological information (Section 11)

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2. Special hazards arising from the substance or mixture

Hazards from the : Fire will produce dense black smoke. Exposure to decomposition products may
substance or mixture cause a health hazard.
Hazardous thermal : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.

5.3. Advice for firefighters

Special protective actions : Cool closed containers exposed to fire with water. Do not release runoff from fire to
for fire-fighters drains or watercourses.
Special protective : Appropriate breathing apparatus may be required.
equipment for fire-fighters

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency : Avoid breathing vapour or mist. Refer to protective measures listed in sections 7
personnel and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2. Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.3. Methods and material : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and earth, vermiculite or diatomaceous earth and place in container for disposal
cleaning up according to local regulations (see Section 13). Preferably clean with a detergent.
Avoid using solvents.

6.4. Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe : Avoid contact with skin and eyes. Avoid inhalation of vapour, spray or mist.
handling Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or watercourses.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight.
Keep container tightly closed.
No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage.

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.

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SECTION 8: Exposure controls/personal protection

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the
effectiveness of the ventilation or other control measures and/or the necessity to
use respiratory protective equipment. Reference should be made to monitoring
standards, such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by inhalation to
chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the
application and use of procedures for the assessment of exposure to chemical
and biological agents) European Standard EN 482 (Workplace atmospheres -
General requirements for the performance of procedures for the measurement of
chemical agents) Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.
DNELs/DMELs
No DNELs/DMELs available.

PNECs
No PNECs available

8.2 Exposure controls

Appropriate engineering : Provide adequate ventilation. Where reasonably practicable, this should be
controls achieved by the use of local exhaust ventilation and good general extraction. If
these are not sufficient to maintain concentrations of particulates and solvent
vapours below the OEL, suitable respiratory protection must be worn.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period. Appropriate techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Use safety eyewear designed to protect against splash of liquids.
Skin protection
Hand protection
Gloves : For all types of exposure, a glove with protection class of 2 or higher
(breakthrough time >30 minutes according to EN374) is recommended.
Recommended gloves: Nitrile, thickness ≥ 0.12 mm.

NOTICE: The selection of a specific glove for a particular application and

duration of use in a workplace should also take into account all relevant
workplace factors such as, but not limited to: Other chemicals which may be
handled, physical requirements (cut/puncture protection, dexterity, thermal
protection), potential body reactions to glove materials, as well as the instructions/
specifications provided by the glove supplier.

The user must check that the final choice of type of glove selected for handling
this product is the most appropriate and takes into account the particular
conditions of use, as included in the user's risk assessment.

Gloves should be replaced regularly and if there is any sign of damage to the
glove material.

Always ensure that the gloves are free from defects and that they are stored and
used correctly.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.

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SECTION 8: Exposure controls/personal protection

Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators.

OLD LEAD-BASED PAINTS:

When surfaces are to be prepared for painting, account should be taken of the
age of the property and the possibility that lead-pigmented paint might be present.
There is a possibility that ingestion or inhalation of scrapings or dust arising from
the preparation work could cause health effects. As a working rule you should
assume that this will be the case if the age of the property is pre 1960.

Where possible wet sanding or chemical stripping methods should be used with
surfaces of this type to avoid the creation of dust. When dry sanding cannot be
avoided, and effective local exhaust ventilation is not available, it is recommended
that a dust respirator is worn, that is approved for use with lead dusts, and its type
selected on the basis of the COSHH assessment, taking into account the
Workplace Exposure Limit for lead in air. Furthermore, steps should be taken to
ensure containment of the dusts created, and that all practicable measures are
taken to clean up thoroughly all deposits of dusts in and around the affected area.

Respiratory protection in case of dust or spray mist formation. (particle filter

EN143 type P2) Respiratory protection in case of vapour formation. (half mask
with combination filter A2-P2 til concentrations of 0,5 Vol%.)

The current Control of Lead at Work Regulations approved code of practice

should be consulted for advice on protective clothing and personal hygiene
precautions. Care should also be taken to exclude visitors, members of the
household and especially children from the affected area, during the actual work
and the subsequent clean up operations. All scrapings, dust, etc. should be
disposed of by the professional painting contractor as Hazardous Waste.

Extra precautions will also need to be taken when burning off old lead-based
paints because fumes containing lead will be produced. It is recommended that a
respirator, approved for use with particulate fumes of lead is selected on the basis
of the COSHH assessment, taking into account the Workplace Exposure Limit for
lead in air. Similar precautions to those given above about sanding should be
taken with reference to protective clothing, disposal of scrapings and dusts, and
exclusion of other personnel and especially children from the building during
actual work and the subsequent clean up operations.

Avoid the inhalation of dust. Wear suitable face mask if dry sanding. Special
precautions should be taken during surface preparation of pre-1960s paint
surfaces over wood and metal as they may contain harmful lead.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Various: See label.
Odour : Not available.
Odour threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point and boiling : 100°C
range
Flash point : Not applicable.
Evaporation rate : Not available.

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SECTION 9: Physical and chemical properties

Upper/lower flammability or : Not available.
explosive limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : 1.395
Solubility(ies) : Easily soluble in the following materials: cold water.
Solubility in water : Not available.
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): 5.03 cm2/s
Explosive properties : Not available.
Oxidising properties : Not available.
9.2. Other information
No additional information.

SECTION 10: Stability and reactivity

10.1. Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2. Chemical stability : Stable under recommended storage and handling conditions (see Section 7).

10.3. Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4. Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.

10.5. Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.

10.6. Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
There are no data available on the mixture itself. The product is not classified as hazardous according to Regulation
(EC) 1272/2008 as amended.

Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-
allergic contact dermatitis and absorption through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains C(M)IT/MIT(3:1). May produce an allergic reaction.

Acute toxicity
Conclusion/Summary : Not available.
Acute toxicity estimates
Not available.
Irritation/Corrosion
Conclusion/Summary : Not available.
Sensitisation

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SECTION 11: Toxicological information

Conclusion/Summary : Not available.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Other information : Not available.

SECTION 12: Ecological information

12.1. Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
not classified as hazardous to the environment.
Conclusion/Summary : Not available.

12.2. Persistence and degradability

Conclusion/Summary : Not available.
12.3. Bioaccumulative potential
12.4. Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
12.5. Results of PBT and vPvB assessment
PBT : Not applicable.
P: Not available. B: Not available. T: Not available.
vPvB : Not applicable.
vP: Not available. vB: Not available.
12.6. Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product

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SECTION 13: Disposal considerations

Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as
hazardous waste, as defined by EU Directive 2008/98/EC.
Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no
longer apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from
the relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or
national legal provisions.
Special precautions : This material and its container must be disposed of in a safe way. Empty containers
or liners may retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
ADR IMDG

14.1 UN number Not regulated. Not regulated.

14.2 UN proper Not applicable. Not applicable.

shipping name
14.3 Transport
hazard class(es)
Class Not applicable. Not applicable.

Subsidiary class - -

14.4 Packing group Not applicable. Not applicable.

14.5
Environmental
hazards
Marine pollutant No. No.

Marine pollutant Not available.

substances

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Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
14.6 Special Transport within user’s premises: always
precautions for transport in closed containers that are upright
user and secure. Ensure that persons transporting
the product know what to do in the event of an
accident or spillage.
HI/Kemler number Not available.

Emergency Not applicable.

schedules (EmS)

14.7 Transport in bulk : Not applicable.

according to Annex II of
MARPOL and the IBC Code

Additional - -
information

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed, or the component present is below its threshold.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
VOC : Compliant with EU law for this product subcategory: see label
Europe inventory : At least one component is not listed.
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Seveso Directive
This product is not controlled under the Seveso Directive.

International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

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SECTION 15: Regulatory information

Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Turkey : At least one component is not listed.

15.2 Chemical safety : Not applicable.

assessment

SECTION 16: Other information

CEPE code : 8
Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Not classified.
Full text of abbreviated H statements
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Acute Tox. 3, H301 ACUTE TOXICITY (oral) - Category 3
Acute Tox. 3, H311 ACUTE TOXICITY (dermal) - Category 3
Acute Tox. 3, H331 ACUTE TOXICITY (inhalation) - Category 3
Aquatic Acute 1, H400 ACUTE AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410 LONG-TERM AQUATIC HAZARD - Category 1
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
Date of printing : 23-10-2017
Date of issue/ Date of : 22-10-2017
revision
Date of previous issue : 6-4-2017
Version : 13
Notice to reader

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SECTION 16: Other information

IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the
present state of our knowledge and on current laws: any person using the product for any purpose other than
that specifically recommended in the technical data sheet without first obtaining written confirmation from us
as to the suitability of the product for the intended purpose does so at his own risk. It is always the
responsibility of the user to take all necessary steps to fulfill the demands set out in the local rules and
legislation. Always read the Material Data Sheet and the Technical Data Sheet for this product if available. All
advice we give or any statement made about the product by us (whether in this data sheet or otherwise) is
correct to the best of our knowledge but we have no control over the quality or the condition of the substrate
or the many factors affecting the use and application of the product. Therefore, unless we specifically agree in
writing otherwise, we do not accept any liability whatsoever for the performance of the product or for any loss
or damage arising out of the use of the product. All products supplied and technical advice given are subject
to our standard terms and conditions of sale. You should request a copy of this document and review it
carefully. The information contained in this data sheet is subject to modification from time to time in the light
of experience and our policy of continuous development. It is the user's responsibility to verify that this data
sheet is current prior to using the product.

Brand names mentioned in this data sheet are trademarks of or are licensed to AkzoNobel.

Head Office
AkzoNobel Decorative Coatings BV, Christian Neefestraat 2, 1077 WW Amsterdam, The Netherlands

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