ARIEL ALPINE

Safety Data Sheet

according to Regulation (EC) No. 453/2010
Date of issue: 23/01/2017 Revision date: Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Chemical type : Mixture
Trade name : ARIEL ALPINE
Product code : PA00181186
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
Function or use category : Cleaning/washing agents and additives

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
To be completed by Shipper / Person responsible for placing the product on the market

1.4. Emergency telephone number

Emergency number To be completed by Shipper / Person responsible for placing the product on the market

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Directive 67/548/EEC or 1999/45/EC
Xi; R41
Xi; R38
Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available
2.2. Label elements
Labelling according to Directive 67/548/EEC or 1999/45/EC
Hazard symbols :

Xi - Irritant
R-phrases : R38 - Irritating to skin.
R41 - Risk of serious damage to eyes.
S-phrases : S2 - Keep out of the reach of children.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S39 - Wear eye/face protection.
S46 - If swallowed, seek medical advice immediately and show this container or label.
Extra phrases : Contains Tetramethyl Acetyloctahydronaphthalenes. May produce an allergic reaction.

2.3. Other hazards

Other hazards not contributing to the : No presence of PBT and vPvB ingredients.
classification

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to
Directive 67/548/EEC
MEA-Dodecylbenzenesulfonate (CAS No.) 68910-32-7 20 - 30 Xn; R22
(EC no) 272-734-1 Xi; R41
Xi; R38

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ARIEL ALPINE
Safety Data Sheet
according to Regulation (EC) No. 453/2010

Name Product identifier % Classification according to

Directive 67/548/EEC
C12-14 Pareth-7 (CAS No.) 68439-50-9 10 - 20 Xn; R22
(EC no) polymer Xi; R41
N; R50

MEA-Laureth Sulfate (CAS No.) 162201-45-8 10 - 20 Xi; R41

(EC no) Polymer Xi; R38

PEI Ethoxylate (CAS No.) 68130-99-4 5 - 10 Xi; R36

(EC no) Polymer Xi; R38

Tetramethyl Acetyloctahydronaphthalenes (CAS No.) 54464-57-2 <1 Xi; R38

(EC no) 259-174-3 Xi; R43
N; R51/53

Peonile (CAS No.) 10461-98-0 <1 Xn; R22

(EC no) 423-740-1 N; R51/53
(EC index no) 608-044-00-8

Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
MEA-Dodecylbenzenesulfonate (CAS No.) 68910-32-7 20 - 30 Acute Tox. 4 (Oral), H302
(EC no) 272-734-1 Skin Irrit. 2, H315
Eye Dam. 1, H318
C12-14 Pareth-7 (CAS No.) 68439-50-9 10 - 20 Acute Tox. 4 (Oral), H302
(EC no) polymer Eye Dam. 1, H318
Aquatic Acute 1, H400
MEA-Laureth Sulfate (CAS No.) 162201-45-8 10 - 20 Skin Irrit. 2, H315
(EC no) Polymer Eye Irrit. 2, H319
PEI Ethoxylate (CAS No.) 68130-99-4 5 - 10 Skin Irrit. 2, H315
(EC no) Polymer Eye Irrit. 2, H319
Tetramethyl Acetyloctahydronaphthalenes (CAS No.) 54464-57-2 <1 Skin Irrit. 2, H315
(EC no) 259-174-3 Skin Sens. 1B, H317
Aquatic Chronic 2, H411
Peonile (CAS No.) 10461-98-0 <1 Acute Tox. 4 (Oral), H302
(EC no) 423-740-1 Aquatic Chronic 2, H411
(EC index no) 608-044-00-8

Full text of R-, H- and EUH-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : When symptoms occur: go into open air and ventilate suspected area. Respiratory problems:
consult a doctor/medical service.
First-aid measures after skin contact : Rinse immediately with plenty of water for 15 minutes. Take victim to a doctor if irritation persists.
Remove contaminated clothing immediately.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Take victim to a doctor if irritation persists.
First-aid measures after ingestion : Give nothing or a little water to drink. Do not induce vomiting. Consult a doctor/medical service.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms.
Symptoms/injuries after skin contact : May cause moderate irritation.
Symptoms/injuries after eye contact : May cause severe irritation.
Symptoms/injuries after ingestion : Gastrointestinal complaints.
4.3. Indication of any immediate medical attention and special treatment needed
Refer to section 4.1.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
5.2. Special hazards arising from the substance or mixture
Fire hazard : No fire hazard. Non combustible.
Explosion hazard : Product is not explosive.
Reactivity : No dangerous reactions known.
5.3. Advice for firefighters
Firefighting instructions : No specific firefighting instructions required.
Protection during firefighting : In case of inadequate ventilation wear respiratory protection.

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ARIEL ALPINE
Safety Data Sheet
according to Regulation (EC) No. 453/2010

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Wear suitable gloves and eye/face protection.

6.1.2. For emergency responders

Protective equipment : Wear suitable gloves and eye/face protection.
6.2. Environmental precautions
Consumer products ending up down the drain after use. Prevent soil and water pollution. Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning up
For containment : Scoop absorbed substance into closing containers.
Methods for cleaning up : Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into
container for disposal. Large spills: contain released substance, pump into suitable containers.
This material and its container must be disposed of in a safe way, and as per local legislation.
6.4. Reference to other sections
Refer to Sections 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin. Avoid contact with eyes. Use personal protective equipment as required.
Do not eat, drink or smoke when using this product. Do not handle until all safety precautions
have been read and understood.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in original container. Refer to section 10.
Incompatible products : Refer to section 10.
Incompatible materials : Not applicable.
Prohibitions on mixed storage : Not applicable.
Storage area : Store in a cool area. Store in a dry area.
7.3. Specific end use(s)
Cleaning/washing agents and additives.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No additional information available

8.2. Exposure controls

Personal protective equipment : Wear eye/face protection.
Hand protection : Not applicable.
Eye protection : Safety glasses.
Skin and body protection : Not applicable.
Respiratory protection : Not applicable.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : pouch.
Colour : Coloured.
Odour : pleasant (perfume).
Odour threshold : No data available
pH : 7.4
Melting point : Not measured.
Freezing point : No data available
Boiling point : Not measured.
Flash point : Not applicable
Relative evaporation rate (butylacetate=1) : Not measured.
Flammability (solid, gas) : Not flammable.
Explosive limits : Product is not explosive
Vapour pressure : Not measured.
Relative vapour density at 20 °C : Not measured.

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ARIEL ALPINE
Safety Data Sheet
according to Regulation (EC) No. 453/2010

Relative density : No data available

Density : 1078 g/l
Solubility : Soluble in water.
Log Pow : No data available
Self ignition temperature : Not measured.
Decomposition temperature : Not measured.
Viscosity : 1500 - 7000 cP
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reactions known.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Refer to section 10.1 on Reactivity.
10.4. Conditions to avoid
Not required for normal conditions of use.
10.5. Incompatible materials
Not applicable.
10.6. Hazardous decomposition products
None under normal use.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Irritation : Irritating to skin. Risk of serious damage to eyes.

Potential Adverse human health effects and : Acute Toxicity: based upon available data of the substances, classification criteria are not met.
symptoms Carcinogenicity: based upon available data of the substances, classification criteria are not met.
Corrosivity: based upon available data of the substances, classification criteria are not met.
Irritation: moderately irritating to skin. Irritation: severly irritant to eyes. Mutagenicity: based upon
available data of the substances, classification criteria are not met. Repeated Dose Toxicity:
based upon available data of the substances, classification criteria are not met. Sensitization:
based upon available data of the substances, classification criteria are not met. Toxicity for
Reproduction: based upon available data of the substances, classification criteria are not met.
Other information : Likely routes of exposure: skin and eye. Information on Effects: refer to section 4.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No known adverse effects on the functioning of water treatment plants under normal use
conditions as recommended. The product is not considered harmful to aquatic organisms nor to
cause long-term adverse effects in the environment.

12.2. Persistence and degradability

No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
ARIEL ALPINE
Results of PBT assessment No presence of PBT and vPvB ingredients

12.6. Other adverse effects

Other information : No other effects known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.

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ARIEL ALPINE
Safety Data Sheet
according to Regulation (EC) No. 453/2010

SECTION 14: Transport information

14.1. UN number
Not applicable
14.2. UN proper shipping name
Not applicable
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
Not applicable
14.6. Special precautions for user
Not applicable
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No additional information available

15.1.2. National regulations

EURLW code : 20 01 29*
CESIO recommendations : The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are
held at the disposal of the competent authorities of the Member States and will be made
available to them, at their direct request or at the request of a detergent manufacturer.

15.2. Chemical safety assessment

Not applicable

SECTION 16: Other information

Reason for the revision of the SDS :
Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging.
Salts listed in Section 3 without a REACh Registration number are exempt, based on Annex V

Full text of R-, H- and EUH-phrases::

------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1
------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
------ Eye Dam. 1 Serious eye damage/eye irritation Category 1
------ Eye Irrit. 2 Serious eye damage/eye irritation Category 2
------ Skin Irrit. 2 skin corrosion/irritation Category 2
------ Skin Sens. 1B Skin sensitisation Category 1B
------ H302 Harmful if swallowed
------ H315 Causes skin irritation
------ H317 May cause an allergic skin reaction
------ H318 Causes serious eye damage
------ H319 Causes serious eye irritation
------ H400 Very toxic to aquatic life
------ H411 Toxic to aquatic life with long lasting effects
------ R22 Harmful if swallowed.
------ R36 Irritating to eyes.
------ R38 Irritating to skin.
------ R41 Risk of serious damage to eyes.
------ R43 May cause sensitisation by skin contact.
------ R50 Very toxic to aquatic organisms.
------ R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
------ N Dangerous for the environment
------ Xi Irritant
------ Xn Harmful

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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