EPA Method 500 Series

Method 502.2 Volatile Organic Compounds by PID/ELCD

The following solutions represent a breakdown of Method 502 components into groups containing liquid and gaseous components:
54 Liquid Components
Benzene (01) 1,2-Dibromo-3-chloropropane (18) 1,1-Dichloropropene (33) Toluene (46)
Bromobenzene (02) 1,2-Dibromoethane (19) cis-1,3-Dichloropropene (34A) * 1,2,3-Trichlorobenzene (47)
Bromochloromethane (03) Dibromomethane (20) trans-1,3-Dichloropropene (34B) ** 1,2,4-Trichlorobenzene (48)
Method 502

Bromodichloromethane (04) 1,2-Dichlorobenzene (21) Ethylbenzene (35) 1,1,1-Trichloroethane (49)

Bromoform (05) 1,3-Dichlorobenzene (22) Hexachlorobutadiene (36) 1,1,2-Trichloroethane (50)
n-Butylbenzene (07) 1,4-Dichlorobenzene (23) Isopropylbenzene (Cumene) (37) Trichloroethene (51)
sec-Butylbenzene (08) 1,1-Dichloroethane (25) p-Isopropyltoluene (p-Cymene) (38) 1,2,3-Trichloropropane (53)
tert-Butylbenzene (09) 1,2-Dichloroethane (26) Methylene chloride (39) 1,2,4-Trimethylbenzene (54)
Carbon tetrachloride (10) 1,1-Dichloroethene (27) Naphthalene (40) 1,3,5-Trimethylbenzene (55)
Chlorobenzene (11) cis-1,2-Dichloroethene (28) n-Propylbenzene (41) o-Xylene (57)
Chloroform (13) trans-1,2-Dichloroethene (29) Styrene (42) m-Xylene (58)
2-Chlorotoluene (15) 1,2-Dichloropropane (30) 1,1,1,2-Tetrachloroethane (43) p-Xylene (59)
4-Chlorotoluene (16) 1,3-Dichloropropane (31) 1,1,2,2-Tetrachloroethane (44) *cis (1.06 x conc.) (34A)
Dibromochloromethane (17) 2,2-Dichloropropane (32) Tetrachloroethene (45) **trans (0.94 x conc.) (34B)

6 Gas Components Technical Note

Bromomethane (06) Dichlorodifluoromethane (24)
Solutions containing volatile components (such as gases) should be chilled
Chloroethane (12) Trichlorofluoromethane (52)
before opening to ensure gases are in the solution and not the headspace.
Chloromethane (14) Vinyl chloride (56)

54 Liquid Components All 60 liquid & gas components in One Solution

M-502A-R 0.2 mg/mL each in MeOH $ 60 / 1 x 1 mL Liquids (54 comps.) and Gases (6 comps.)
M-502A-R-PAK 0.2 mg/mL each in MeOHSAVE 20% $ 240 / 5 x 1 mL M-502 $ 75 / 1 x 1 mL
M-502A-R-10X 2.0 mg/mL each in MeOH $ 80 / 1 x 1 mL M-502-PAK SAVE 20% $ 300 / 5 x 1 mL
M-502A-R-10X-PAK 2.0 mg/mL each in MeOHSAVE 20% $ 320 / 5 x 1 mL 0.2 mg/mL each in MeOH 60 comps.
M-502-10X $ 100 / 1 x 1 mL
M-502-10X-PAK SAVE 20% $ 400 / 5 x 1 mL
2.0 mg/mL each in MeOH 60 comps.
6 Gas Components Liquids (54 comps.) & Gases (6 comps.) plus p-Isoproyltoluene
M-502B 0.2 mg/mL each in MeOH $ 25 / 1 x 1 mL M-502-R1 NEW $ 75 / 1 x 1 mL (liquid and gases)
M-502B-PAK 0.2 mg/mL each in MeOH SAVE 20% $ 100 / 5 x 1 mL M-502-R1-PAK NEW SAVE 20% $ 300 / 5 x 1 mL (liquid and gases)
M-502B-10X 2.0 mg/mL each in MeOH $ 35 / 1 x 1 mL 0.2 mg/mL each in MeOH 61 comps.
M-502B-10X-PAK 2.0 mg/mL each in MeOH SAVE 20% $ 140 / 5 x 1 mL Liquids (54 comps.) plus MtBE
M-502A-R3 NEW $ 60 / 1 x 1 mL
0.2 mg/mL each in MeOH
54 Liquid and 6 Gas Component Sets M-502A-R3-10X NEW $ 80 / 1 x 1 mL
2.0 mg/mL each in MeOH 55 comps.
M-502A-R/B-SET $ 80 / 2 x 1 mL
0.2 mg/mL each in MeOH (M-502A-R, M-502B)
M-502A-R/B-10X-SET $ 105 / 2 x 1 mL
2.0 mg/mL each in MeOH (M-502A-R-10X, M-502B-10X) 59 Component Set
As a complete set of each component in individual ampules.
M-502-SET 0.2 mg/mL in MeOH $ 300 / 59 x 1 mL
Internal & Surrogate Standard M-502-10X-SET 2.0 mg/mL in MeOH $ 350 / 59 x 1 mL
M-502-IS/SS $ 20 / 1 x 1 mL
M-502-IS/SS-PAK SAVE 20% $ 80 / 5 x 1 mL
2.0 mg/mL each in MeOH 4 comps.
Individual Component Solutions
To order, specify identity (#) and conc. (0.2 or 2.0 mg/mL)
1-Chloro-3-fluorobenzene Fluorobenzene M-502-# 0.2 mg/mL in MeOH $ 10 / 1 x 1 mL
2-Chloropropane α,α,α-Trifluorotoluene M-502-#-10X 2.0 mg/mL in MeOH $ 14 / 1 x 1 mL

M-502-34A & M-502-34B only available as mixture: M-502-34R

Technical Note M-502-34-R $ 10 / 1 x 1 mL
0.4 mg/mL each in MeOH
M-502-IS/SS is useful for DB-624/VRX analysis by GC/ELCD/PID.
M-502-34-R-10X $ 15 / 1 x 1 mL
2-Chloropropane has been included in the standard to be used as an early
4.0 mg/mL each in MeOH 2 comps.
eluting Internal Standard. The use of this Internal Standard aids in
quantitating the gaseous components in purgeable volatiles.
cis-1,3-Dichloropropene trans-1,3-Dichloropropene

Internal/Surrogate Standard
M-502-IS-ASL Alternate
$ 20 / 1 x 1 mL Individual Component Neats
M-502-IS-ASL-PAK Source SAVE 20% $ 80 / 5 x 1 mL To order, specify identity
2.0 mg/mL each in MeOH 2 comps.
M-502-#N $ 20 / 1 x 1 gram
except,
2-Bromo-1-chloropropane 1-Chloro-2-fluorobenzene
$ 40 / 1 x 1 gram $ 60 / 1 x 1 gram
o,m,p-Xylenes Mix M-502-04N M-502-31N M-502-49N
M-502-60 0.2 mg/mL in MeOH $ 10 / 1 x 1 mL M-502-08N M-502-32N
M-502-60-10X 2.0 mg/mL in MeOH $ 14 / 1 x 1 mL M-502-17N M-502-34N
3 comps. M-502-18N M-502-43N
o-Xylene (57) p-Xylene (59) M-502-28N M-502-44N
m-Xylene (58) M-502-29N

158 AccuStandard is accredited to ISO/IEC 17025 and certified to ISO 9001

 EPA Method 500 Series
Method 502.2 (Continued) VOCs by PID/ELCD Method 502.2 Volatile Organic Mixtures
The following solutions represent an alternate source formulation of Custom Unregulated VOC's
Method 502/524 components based on similar volatility groups. M-502C-09 $ 60 / 1 x 1 mL
2.0 mg/mL each in MeOH 39 comps.
Bromobenzene 1,1-Dichloropropene
M-502-K1-SET $ 150 / 6 x 1 mL
Bromochloromethane cis-1,3-Dichloropropene *
(M-502B-10X, M-502C-02, M-502C-03,
Bromodichloromethane trans-1,3-Dichloropropene **
M-502C-04, M-502C-05, M-502C-06)

Method 502
Bromoform Hexachlorobutadiene
Bromomethane Isopropylbenzene (Cumene)
M-502B-10X $ 35 / 1 x 1 mL n-Butylbenzene p-Isopropyltoluene (p-Cymene)
Alternate
M-502B-10X-PAK Source SAVE 20% $ 140 / 5 x 1 mL sec-Butylbenzene Dichloromethane (Methylene chloride)
2.0 mg/mL each in MeOH 6 comps. tert-Butylbenzene Naphthalene
Bromomethane Dichlorodifluoromethane Chloroethane n-Propylbenzene
Chloroethane Trichlorofluoromethane Chloroform 1,1,1,2-Tetrachloroethane
Chloromethane Vinyl chloride Chloromethane 1,1,2,2-Tetrachloroethane
2-Chlorotoluene 1,2,3-Trichlorobenzene
4-Chlorotoluene 1,2,4-Trichlorobenzene
M-502C-02 $ 35 / 1 x 1 mL Dibromochloromethane 1,1,2-Trichloroethane
Alternate
M-502C-02-PAK Source SAVE 20% $ 140 / 5 x 1 mL Dibromomethane Trichlorofluoromethane
2.0 mg/mL each in MeOH 6 comps. 1,3-Dichlorobenzene 1,2,3-Trichloropropane
Dichlorodifluoromethane 1,2,4-Trimethylbenzene
Bromodichloromethane cis-1,2-Dichloroethylene 1,1-Dichloroethane 1,3,5-Trimethylbenzene (Mesitylene)
Dibromochloromethane trans-1,2-Dichloroethylene 1,2-Dichloropropane
1,1,-Dichloroethylene Methylene chloride 1,3-Dichloropropane * cis (1.06 x conc.)
** trans (0.94 x conc.)
2,2-Dichloropropane
M-502C-03 $ 35 / 1 x 1 mL
Alternate
M-502C-03-PAK Source SAVE 20% $ 140 / 5 x 1 mL
2.0 mg/mL each in MeOH 9 comps. Wisconsin DNR VOC Mixture
S-989 $ 100 / 1 x 1 mL
Bromochloromethane 1,1-Dichloroethane 2.0 mg/mL each in MeOH 52 comps.
Bromoform 2,2-Dichloropropane
Carbon tetrachloride Tetrachloroethylene Benzene 1,3-Dichloropropane
Chloroform 1,1,1-Trichloroethane Bromobenzene 2,2-Dichloropropane
Dibromomethane Bromodichloromethene Diisopropyl ether
n-Butylbenzene Ethylbenzene
sec-Butylbenzene Hexachlorobutadiane
M-502C-04 Alternate $ 35 / 1 x 1 mL tert-Butylbenzene Isopropylbenzene
M-502C-04-PAK Source SAVE 20% $ 140 / 5 x 1 mL Carbon tetrachloride p-Isopropyltoluene
2.0 mg/mL each in MeOH 14 comps. Chlorobenzene Methylene chloride
Chlorodibromomethane Methyl tert-butyl ether
1,2-Dibromo-3-chloropropane Hexachlorobutadiene Chloroethane Naphthalene
1,2-Dibromoethane 1,1,1,2-Tetrachloroethane Chloroform n-Propylbenzene
1,2-Dichloroethane 1,1,2,2-Tetrachloroethane Chloromethane 1,1,2,2-Tetrachloroethane
1,2-Dichloropropane 1,1,2-Trichloroethane 2-Chlorotoluene Tetrachloroethene
1,3-Dichloropropane Trichloroethylene 4-Chlorotoluene Toluene
1,1-Dichloropropylene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2,3-Trichlorobenzene
cis-1,3-Dichloropropene * 1,2-Dibromoethane 1,2,4-Trichlorobenzene
* cis (1.06 x conc.)
trans-1,3-Dichloropropene ** ** trans (0.94 x conc.) 1,2-Dichlorobenzene 1,1,1-Trichloroethane
1,3-Dichlorobenzene 1,1,2-Trichloroethane
M-502C-05 $ 35 / 1 x 1 mL 1,4-Dichlorobenzene Trichloroethene
M-502C-05-PAK Alternate SAVE 20% $ 140 / 5 x 1 mL Dichlorodifluoromethane Trichlorofluoromethane
Source
2.0 mg/mL each in MeOH 13 comps. 1,1-Dichloroethane 1,2,4-Trimethylbenzene
1,2-Dichloroethane 1,3,5-Trimethylbenzene
Benzene Toluene 1,1-Dichloroethene Vinyl chloride
Bromobenzene 1,2,3-Trichlorobenzene cis-1,2-Dichloroethene o-Xylene
n-Butylbenzene 1,2,4-Trichlorobenzene trans-1,2-Dichloroethene m-Xylene
Ethylbenzene 1,2,4-Trimethylbenzene 1,2-Dichloropropane p-Xylene
p-Isopropyltoluene 1,3,5-Trimethylbenzene
Naphthalene m-Xylene
Styrene

M-502C-06 $ 35 / 1 x 1 mL
Technical Note
Alternate
M-502C-06-PAK Source SAVE 20% $ 140 / 5 x 1 mL Each ampule contains at least 120% of the stated volume of a solution,
2.0 mg/mL each in MeOH 12 comps. allowing easy transfer. Transfer the required amount using a clean calibration
sec-Butylbenzene 1,3-Dichlorobenzene syringe. Excess solution can be stored in a tightly capped vial, but this is not
tert-Butylbenzene 1,4-Dichlorobenzene recommended. AccuStandard cannot guarantee the integrity of the solution
Chlorobenzene Isopropylbenzene once the ampule has been opened. See the EPA method protocol for storage
2-Chlorotoluene n-Propylbenzene instructions.
4-Chlorotoluene o-Xylene
1,2-Dichlorobenzene p-Xylene

Alternate Source = Matches Competitive Product

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Source Alternate Source Line (ASL) of Analytical Standards. Use ASL’s for Independent lots to other Standard suppliers’ formulations.
We compiled a list of most requested CLP, and EPA 500, 600, 8000 series analytical Standard formulations currently offered in the marketplace.
See our complete list of ASL products in QC section of this catalog.

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