Scribd Logo
Upload

Welcome to Scribd!

  • 20 views

    Chemical Kinetics: General Chemistry 2

    Uploaded by

    France Turda
    The document covers topics in chemical kinetics including reaction rates, factors that influence reaction rates, rate laws, reaction orders, and integrated rate laws. It discusses how to determine the rate of a reaction, rate constant, and order of reactions through experimental methods. Various aspects of reaction rates, rate laws, and rate constants are explained through examples and sample problems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Chemical Kinetics: General Chemistry 2

    Uploaded by

    France Turda
    20 views27 pages
    The document covers topics in chemical kinetics including reaction rates, factors that influence reaction rates, rate laws, reaction orders, and integrated rate laws. It discusses how to determine the rate of a reaction, rate constant, and order of reactions through experimental methods. Various aspects of reaction rates, rate laws, and rate constants are explained through examples and sample problems.

    Original Title

    Copy of Chemical Kinetics Part 2

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document covers topics in chemical kinetics including reaction rates, factors that influence reaction rates, rate laws, reaction orders, and integrated rate laws. It discusses how to determine the rate of a reaction, rate constant, and order of reactions through experimental methods. Various aspects of reaction rates, rate laws, and rate constants are explained through examples and sample problems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    20 views27 pages

    Chemical Kinetics: General Chemistry 2

    Uploaded by

    France Turda
    The document covers topics in chemical kinetics including reaction rates, factors that influence reaction rates, rate laws, reaction orders, and integrated rate laws. It discusses how to determine the rate of a reaction, rate constant, and order of reactions through experimental methods. Various aspects of reaction rates, rate laws, and rate constants are explained through examples and sample problems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 27

    General Chemistry 2

    Chemical Kinetics
    Chemical Kinetics
    Reaction Rates and Collision Theory

    Factors that Influence Reaction Rate and


    Collision Theory
    Rate of Reaction, Constant, and
    Concentration of Reactants
    Reaction Rates and Rate Law
    Learning Outcomes
    write the mathematical relationshinship
    between the rate of the reaction, rate
    constant, and concentration of the
    reactants

    give the order of the reaction with respect


    to each reactant and the overall order of
    the reaction

    write the rate law for first order reaction


    Reaction Rates
    measure of how fast a reaction takes place

    change in amount or concentration


    of a substance (reactant or product)
    per unit time
    Expressing Rates of Reactions

    rate of travel = change in position = kilometers


    time hour

    rate of reaction = change in concentration = mol/L


    time sec
    Rates of Reaction Expression

    aA + bB -> cC + dD

    Rate = -Δ[A] = -Δ[B] = Δ[C] = Δ[D]


    aΔt bΔt cΔt dΔt
    Rate Law

    aA + bB -> products
    Rate = -Δ[A] = -Δ[B]
    aΔt bΔt
    x y
    Rate = k[A] [B]

    shows the relationship between rate of a reaction,


    rate constant, and concentration of reactants
    Order of Reactions

    relationship between rate of reaction


    and concentration of reactant
    Order of Reactions

    2 NO + O2 -> 2 NO2
    2
    Rate = k[NO] [O2]

    IMPORTANT: The exponents x and y are not derived


    from the balanced chemical equation
    Order of Reactions
    Can be determined in two ways:
    Initial Rate Method
    Graphical Method
    Order of Reactions
    Initial Rate Method

    1. Measure the rate of reaction for the


    "original" trial/first experiment
    2. Vary the concentrations of reactants
    3. Compare the initial rates with the initial
    concentrations
    Order of Reactions

    2 NO + O2 -> 2 NO2
    2
    Rate = k[NO] [O2]

    2nd order with respect to NO


    1st order with respect to O2
    3rd order overall
    Order of Reactions

    2 NO + O2 -> 2 NO2
    Order of Reactions

    2 NO + O2 -> 2 NO2
    Order of Reactions

    2 NO + O2 -> 2 NO2
    Rate Constant

    2 NO + O2 -> 2 NO2
    2
    Rate = k[NO] [O2]

    k= rate
    2
    [NO] [O2]
    Rate Constant
    2 NO + O2 -> 2 NO2

    k= rate
    2
    [NO] [O2]

    0.028 M/s
    k=
    (0.020M) 2 (0.010M)
    2 2
    k = 7000 L / mol -s
    Rate Constant
    2 2
    k = 7000 L / mol -s

    How to solve for the unit:

    0.028 M/s
    k=
    (0.020M) 2 (0.010M)

    2
    M/s M/s 1/s 1 L
    (M) M)2
    M 3
    M
    2 2
    M -s mol2 - s

    M = mol/L
    Sample Problem
    Determine the rate law, rate constant, and unknown
    rate from the experimental data on the table.
    Assume constant T and P.
    Conventration-Time
    Relationship

    Zero - Order Reactions


    First-Order Reactions
    Second - Order Reactions
    Conventration-Time
    Relationship
    Zero - Order Reactions
    R -> products
    0
    Rate = -Δ[R] = k[R] [R] o - [R]t = kt
    Δt
    Integrated Rate Law
    Conventration-Time
    Relationship
    First - Order Reactions
    R -> products
    [R]t
    Rate = -Δ[R] = k[R] ln = -kt
    Δt [R]o

    Integrated Rate Law


    Conventration-Time
    Relationship
    Second - Order Reactions
    R -> products
    2 1 1
    Rate = -Δ[R] = k[R] - = kt
    Δt [R]t [R]o

    Integrated Rate Law


    Conventration-Time
    Relationship
    The decomposition of dinitrogen pentoxide is a first order
    reaction and has a decomposition constant of 0.0067/min.
    If the initial concentration of this reactant is 0.7 M, what
    will be the concentration after 5.6 minutes?

    rate = -Δ[N 2 O 5] = k[N2 O 5 ]


    Δt
    [R]t
    ln = -kt -kt
    [R] t = [R] oe
    [R]o
    Conventration-Time
    Relationship
    The decomposition of dinitrogen pentoxide is a first order
    reaction and has a decomposition constant of 0.0067/min.
    If the initial concentration of this reactant is 0.7 M, what
    will be the concentration after 5.6 minutes?

    -kt -kt
    [R] t = [R] oe [N2 O5 ]t = [N 2 O 5] o e
    Conventration-Time
    Relationship
    The decomposition of dinitrogen pentoxide is a first order
    reaction and has a decomposition constant of 0.0067/min.
    If the initial concentration of this reactant is 0.7 M, what
    will be the concentration after 5.6 minutes?

    -(0.0067/min)(5.6 min)
    [N2 O 5] t = 0.7M e

    [N2 O 5] t = 0.6742 M
    Which of the following reactions is slowest at room
    temperature?

    You might also like

    pFad - Phonifier reborn

    Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

    Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


    Alternative Proxies:

    Alternative Proxy

    pFad Proxy

    pFad v3 Proxy

    pFad v4 Proxy