Lesson 8 - Electrolysis Part 1

Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1of 13

Grade 9

CHEMISTRY
LESSON 8 – ELECTROLYSIS – PART 1

MS.DISHNA KARUNASEKARA
LYCEUM INTERNATIONAL SCHOOL,
GAMPAHA
Lesson 8 – Electrolysis – Part 1 - Page 1

ELECTROLYSIS
Objectives:
a) Describe electrolysis as the conduction of electricity by an ionic
compound (an electrolyte), when molten or dissolved in water, leading to
the decomposition of the electrolyte
(b) Describe electrolysis as evidence for the existence of ions which are
held in a lattice when solid but which are free to move when molten or in
solution
(c) Describe, in terms of the mobility of ions present and the electrode
products, the electrolysis of molten lead bromide, using inert electrodes
(d) Predict the likely products of the electrolysis of a molten compound
(e) Apply the idea of selective discharge (linked to the reactivity series for
cations, see 9.2) to deduce the electrolysis products of aqueous solutions;
describe the electrolysis of concentrated aqueous sodium chloride,
aqueous copper(II) sulfate and dilute sulfuric acid using inert electrodes
(f) Predict the likely products of the electrolysis of an aqueous electrolyte,
given relevant information
(g) Construct equations for the reactions occurring at each electrode
(anode and cathode) during electrolysis

(h) Describe the electrolysis of purified aluminium oxide dissolved in


molten cryolite as the method of extraction of aluminium (see 9.5(a))
(i) Describe the electrolysis of aqueous copper(II) sulfate with copper
electrodes as a means of purifying copper
Lesson 8 – Electrolysis – Part 1 - Page 2

(j) Describe the electroplating of metals, including copper plating, and


recall one use of electroplating
(k) Describe the production of electrical energy from simple cells (i.e. two
electrodes in an electrolyte) linked to the reactivity series

What is electrolysis?
Electrolysis is the process of breaking down a compound to its elements
using an electric current.
Lesson 8 – Electrolysis – Part 1 - Page 3

 The compound that we use is known as electrolyte.

 It should be ionic but not covalent.

 It should be molten or aqueous not solid.

 Anode and cathode are known as electrodes. These are used to send
electricity through the electrolyte.

 Electrodes are usually made up of carbon (graphite), platinum ect..

 These materials should be usually cheap and inert (unreactive).


Lesson 8 – Electrolysis – Part 1 - Page 4

 Positive electrode is known as anode.


 Negative electrode is known as cathode.

 Positive ions/cations are attracted to the negative electrode / cathode.


 Negative ions/anions are attracted to the positive electrode / anode.

 At anode, anions loose electrons (Oxidation) and at cathode, cations


gain electrons (Reduction). Ions are discharged at electrodes.
 This will produce elements.

 The reaction is a redox reaction.

ELECTROLYSIS OF IONIC COMPOUNDS


Lesson 8 – Electrolysis – Part 1 - Page 5

1. Electrolysis of molten ionic compounds

2. Electrolysis of aqueous ionic compounds

Electrolysis of molten ionic compounds

Rules:
1. Cations will be discharged at the cathode.
2. Anions will be discharged at the anode.
Lesson 8 – Electrolysis – Part 1 - Page 6

Ex: Electrolysis of molten Lead(II) bromide

Electrolytes: PbBr2(l) Pb2+(l), 2Br-(l)

Anode(+): 2Br-(l) Br2(g) + 2e-

Cathode(-): Pb2+(l) + 2e- Pb(s)

V1 https://www.youtube.com/watch?v=4x2ZCSr23Z8

Exercise 1
Predict the electrolysis of following compounds using carbon
electrodes.
1. Molten Sodium chloride
Lesson 8 – Electrolysis – Part 1 - Page 7

Electrolytes: NaCl(l) Na+(l), Cl-(l)


Anode(+): 2Cl-(l) Cl2(g) + 2e-
Cathode(-): Na+(l) + e- Na(s)

2. Molten Zinc chloride

3. Molten Magnesium iodide

4. Molten Aluminium oxide

5. Solid Lead(II) iodide

6. Molten Silver bromide

Answers

2. Molten Zinc chloride


Lesson 8 – Electrolysis – Part 1 - Page 8

Electrolytes: ZnCl2(l) Zn2+(l), 2Cl-(l)

Anode(+): 2Cl-(l) Cl2(g) + 2e-

Cathode(-):Zn2+(l) + 2e- Zn(s)

3. Molten Magnesium iodide


Lesson 8 – Electrolysis – Part 1 - Page 9

Electrolytes: MgI2(l) Mg2+(l), 2I-(l)

Anode(+): 2l-(l) l2(g) + 2e-

Cathode(-):Mg2+(l)+ 2e- Mg(s)

4. Molten Aluminium oxide


Lesson 8 – Electrolysis – Part 1 - Page 10

Electrolytes: Al2O3(l) Al3+(l), O2-(l)

Anode(+): 2O2-(l) O2(g) + 4e-

Cathode(-): Al3+(l)+ 3e- Al(s)

5. Solid Lead(II) iodide


Lesson 8 – Electrolysis – Part 1 - Page 11

No reaction

6. Molten Silver bromide

Electrolytes: AgBr2(l) Ag+(l), Br-(l)

Anode(+): 2Br-(l) Br2(g) + 2e-


Lesson 8 – Electrolysis – Part 1 - Page 12

Cathode(-): Ag+(l) + e- Ag(s)

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy