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FUNCTIONAL GROUP TABLE

o
2 –Suffix (A–Type)Common Naming
S. Functional Name o
2 –Prefix
group IUPAC Name
No. A-Type B-Type R—OH Alkyl alcohol

O R—SH Alkyl thio alcohol


1. Carboxylic acid Carboxy oic acid carboxylic Alkanoic
—C—OH acid acid R—X Alkyl halide

2. —SO3H Sulphonic acid Sulpho sulphonic X Alkane R—NH2 Alkyl amine


acid sulphonic acid
R—CN Alkyl Cynide
3. —C—O—C—
Anhydride X oic carboxylic Alkanoic Alkyl Isocynide
O O anhydride anhydride anhydride

4. (i) Alkoxy
—C—O—R Ester Alkyl---oate Alkyl--- Alkyl
carbonyl
carboxylate Alkanoate
O (ii) Alkanoyl
oxy
5. —C—X
Acid halide halo formyl oyl halide carbonyl Alkanoyl
O or halo halide halide
carbonyl (B–Type)Common Naming
6. —C—NH2
acid amide carbamoyl amide carboxamide Alkane amide
O No. of Functional
Carbonatom Prefix group Suffix
7. —CN cyanide cyano nitrile carbonitrile Alkane nitrile O
1 form ic acid
—C—OH
8. —NC iso cyanide isocyano isonitrile Alkane
isonitrile O ic
2 Acet O
9. —CH=O Aldehyde formyl, oxo al carbaldehyde Alkannal anhydride
—C—O—C—

—C— 3 Propion O
10. Alkyl....ate
ketone oxo one X Alkanone
O —C—O—R
4 butyr O
11. —OH Alcohol hydroxy ol X Alkanol yl halide
—C—X
12. —SH Thio alcohol mercapto thiol X Alkane thiol 5 Valer
—CN onitrile

13. —NH2 Amine amino amine X Alkanamine —NC oisonitrile


3C + (=) Acryl
—CH O Aldehyde
14. —O— Ether Alkoxy X X Alkoxy
4C + (=) Croton —C—NH2
alkane Ketone
15. —X Halide Halo X X Halo alkane O

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