ChemQuest 26

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ChemQuest 25

Advanced Name: ____________________________

Ionic Bonding
Date: _______________
Hour: _____

Information: Polyatomic Ions


The word, “polyatomic” means “many atoms”. A polyatomic ion, therefore, is an ion that is
made of more than one atom. An example of a polyatomic ion is the sulfate ion, SO42-. Sulfate
is composed of one sulfur atom and four oxygen atoms and overall sulfate has a negative two
charge.
Some polyatomic ions are listed below.

Many polyatomic ions end in “-ate”:


Acetate: C2H3O2-1
Carbonate: CO32-
Chlorate: ClO3-1
Nitrate: NO3-1
Phosphate: PO43-
Sulfate: SO42-

Some other polyatomic ions:


Ammonium: NH4+1
Cyanide: CN-1
Hydroxide: OH-1

Critical Thinking Questions

1. What do all of the polyatomic ions that have the suffix “-ate” have in common? (ie,
What atom exists in all of the polyatomic ions that end in “-ate”?)

2. Which two atoms do you think compose the polyatomic ion called “silicate”?

3. What is the difference between calcium nitride and calcium nitrate?


Information: Writing Formulas With Polyatomic Ions
First of all, you must remember that you can never change the formula for a polyatomic ion.
Sulfate is always SO42- and never S2O84- or something else. Following are some examples of
chemical formulas that contain polyatomic ions.

Sodium sulfate, Na2SO4:

Magnesium nitrate, Mg(NO3)2:

Consider calcium hydroxide. Calcium has a positive two charge (Ca2+) and hydroxide has a
negative one charge (OH-). We need two hydroxide ions to combine with one calcium ion so
that the overall charge ends up being zero. We write calcium hydroxide like Ca(OH)2.
Following are some more examples:
potassium acetate: KC2H3O2 magnesium nitrate: Mg(NO3)2
barium phosphate: Ba3(PO4)2 calcium carbonate: CaCO3
Critical Thinking Questions
4. In the expression Mg(CN)2, there is one magnesium atom, two carbon atoms, and ______
nitrogen atoms. how many?

5. In the expression MgCN2, there is ______ magnesium atom, _____ carbon atom, and
_____ nitrogen atoms? how many? how many? how
many?

6. As mentioned above, calcium hydroxide is written like Ca(OH)2. Why can’t it be written
like CaOH2?

7. As mentioned above, magnesium nitrate is written as Mg(NO3)2. Why can’t it be written


like MgNO32?

8. Name the following compounds. Each includes at least one polyatomic ion.
a) Na3PO4 b) (NH4)2SO4 c) Mg(C2H3O2)2

d) (NH4)2S e) CaCO3 f) Ba(NO3)2

9. Write formulas for the following ionic compounds. Note that each includes a polyatomic
ion.
a) lithium phosphate b) ammonium oxide c) barium hydroxide

d) calcium cyanide e) sodium chlorate f) potassium sulfate

10. In question 3, you were asked the difference between calcium nitride and calcium nitrate.
Now write the formula for each of them.

calcium nitride: calcium nitrate:

Information: Formulas for Acids


Acids are compounds that contain positive hydrogen ions (H+) bonded to a negative ion. For
example, carbonic acid is formed when the carbonate ion (CO32-) bonds with two hydrogen ions
(H+) to give H2CO3. Other common acids are listed below:
Hydrochloric acid: HCl
Sulfuric acid: H2SO4
Nitric Acid: HNO3
Acetic Acid: HC2H3O2

Critical Thinking Questions


11. Why do carbonic and sulfuric acid require two H+ ions to bond, but HCl and HNO3 only
have one H+?

12. Phosphoric acid is made from the phosphate ion and H+ ions. Write the formula for
phosphoric acid.

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