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    Vsepr-Hl

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    Ryan Boukaa
    The document discusses molecular geometry and electron domain theory. It provides examples of different molecular geometries that result from having various combinations of bond pairs and lone pairs around a central atom, including trigonal planar, tetrahedral, trigonal bipyramidal, octahedral, square pyramidal, seesaw, T-shaped, and linear. It also discusses the bond angles that result from different electron domain geometries, such as 90°, 120°, and 180° bond angles. Key examples are provided for different molecular formulas.

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    Vsepr-Hl

    Uploaded by

    Ryan Boukaa
    122 views25 pages
    The document discusses molecular geometry and electron domain theory. It provides examples of different molecular geometries that result from having various combinations of bond pairs and lone pairs around a central atom, including trigonal planar, tetrahedral, trigonal bipyramidal, octahedral, square pyramidal, seesaw, T-shaped, and linear. It also discusses the bond angles that result from different electron domain geometries, such as 90°, 120°, and 180° bond angles. Key examples are provided for different molecular formulas.

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    IB Chemistry HL Topic 4 notes

    Original Title

    3._VSEPR-HL

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    The document discusses molecular geometry and electron domain theory. It provides examples of different molecular geometries that result from having various combinations of bond pairs and lone pairs around a central atom, including trigonal planar, tetrahedral, trigonal bipyramidal, octahedral, square pyramidal, seesaw, T-shaped, and linear. It also discusses the bond angles that result from different electron domain geometries, such as 90°, 120°, and 180° bond angles. Key examples are provided for different molecular formulas.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    122 views25 pages

    Vsepr-Hl

    Uploaded by

    Ryan Boukaa
    The document discusses molecular geometry and electron domain theory. It provides examples of different molecular geometries that result from having various combinations of bond pairs and lone pairs around a central atom, including trigonal planar, tetrahedral, trigonal bipyramidal, octahedral, square pyramidal, seesaw, T-shaped, and linear. It also discusses the bond angles that result from different electron domain geometries, such as 90°, 120°, and 180° bond angles. Key examples are provided for different molecular formulas.

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    Valence HL

    Shell
    Electron
    Pair Planar triangular
    Tetrahedral

    Repulsion
    Theory
    Trigonal
    bipyramidal Octahedral
    FIVE regions of electron domain
    AX5 molecules

    5 Bond pair, 0 lone pair

    Bond angles = 90°,120° & 180°.


    Electron domain geometry = Trigonal bipyramidal
    Molecular geometry = Trigonal bipyramidal
    Phosphorus pentachloride, PCl5
    In Trigonal bipyramidal there are two planes

    1. Equatorial plane
    2. Axial plane

    Cl-P-Cl angles:
    1.180° axial Cl-P- axial Cl
    2.120° equatorial Cl-P-equatorial Cl
    3.90° axial Cl-P-equatorial Cl

    NB- Lone pairs always occupy the equatorial positions.


    AX4E molecules

    4 Bond pair,
    1 lone pair

    Bond angles = 90 & 120°.


    Electron domain geometry = Trigonal bipyramidal
    Molecular geometry = Seesaw or distorted tetrahedral
    Sulphur tetrafluoride, SF4
    AX3E2 molecules

    3 Bond pair,
    2 lone pair

    Bond angles = 90 & 120°.


    Electron domain geometry = Trigonal bipyramidal
    Molecular geometry = T- Shape
    ClF3

    Cl

    T – shape
    90o & 120o
    AX2E3 molecules

    2 Bond pair,
    3 lone pair

    Bond angles = 180°.


    Electron domain geometry = Trigonal bipyramidal
    Molecular geometry = Linear
    2 Bond pair, 3 lone pair

    Xenon difluoride XeF2

    180o
    Tri iodide ion I3-
    SIX regions of electron domain
    AX6 molecules
    6 Bond pair, 0 lone pair

    Example - SF6, IOF5

    Bond angles = 90
    Electron domain geometry = Octahedral
    Molecular geometry = Octahedral
    AX5E molecules

    5 Bond pair, 1 lone pair

    Examples - SF5−, IF5, XeF5+, XeOF4

    Bond angles = 90°.


    Electron domain geometry = Octahedral
    Molecular geometry = Square pyramidal
    IF5 Iodine pentafluoride
    AX4E2 molecules
    4 Bond pair, 2 lone pair

    Bond angles = 90°.


    Electron domain geometry = Octahedral
    Molecular geometry = Square planer
    XeF4
    5 electron domains
    Example # of # of Electron Molecular Bond
    electron lone domain geometry angles
    domains pairs geometry
    on
    central

    5 0 trigonal trigonal 90°


    bipyramidal bipyramidal 180°
    120°

    5 1 trigonal see saw 90°


    bipyramidal 180°
    117°
    5 electron domains
    Example # of # of Electron Molecular Bond
    electron lone domain geometry angles
    domains pairs geometry
    on
    central

    5 2 trigonal T-shaped 90°


    bipyramidal 180°

    5 3 trigonal linear 180°


    bipyramidal
    6 electron domains
    Example # of # of Electron Molecular Bond
    electron lone domain geometry angles
    domains pairs on geometry
    central

    6 0 octahedral octahedral 90°

    6 1 octahedral square <90°


    pyramidal

    6 2 octahedral square 90°


    planar
    Question
    Q1 What are the molecular shapes that are considered
    planar (i.e. 2D)?

    1.Linear
    2.Bent
    3.Trigonal planar
    4.Square planar
    5.T-shaped
    Q2 Draw Lewis structure and predict the shapes and bond
    angles of the following molecules and ions: (6)

    XeF4
    PF6
    -
    -

    ..
    Xe P

    Square planar, 90°

    Octahedral, 90°
    Q3 What bond angles do you expect for the F–Kr–F
    angle in KrF4

    ..
    Kr 90°

    Q4 How many electron domains are there around the central


    atom in molecules that have the following geometry?
    (a) square planar 6
    (b) octahedral 6
    (c) square pyramidal 6
    (d) trigonal bipyramidal 5
    (e) linear 2 or 5

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