6/14/2021 Quiz 1: Attempt review

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11491001007_CHEM F111_March2021 /
Online Evaluations /
Quiz 1

Started on Saturday, 3 April 2021, 12:00 PM

State Finished
Completed on Saturday, 3 April 2021, 12:20 PM
Time taken 20 mins
Grade 19 out of 20 (95%)

Question 1
Complete

Mark 1 out of 1

Which
one of the given statements is not correct for a well-behaved
wave function?

a. The wavefunction should be continuous

b. The wavefunction should be square integrable

c. The wavefunction should be finite and single valued.

d. The wavefunction
should have non-zero values at boundaries

The correct answer is: The wavefunction

should have non-zero values at boundaries

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6/14/2021 Quiz 1: Attempt review

Question 2
Complete

Mark 1 out of 1

The
total probability of finding a particle in the whole space must be

a. zero

b. one

c. infinite

d. uncertain

The correct answer is:

one

Question 3
Complete

Mark 1 out of 1

A particle of mass m is confined to move in a square box (2D box) with each side of length L.

Initially, the particle is set to be in a state described by ψinitial . After undergoing a process the particle finally reaches
2 πx 4πy
= sin sin
L L L

another state, described by ψf inal .

2 2πx 3πy
= sin sin
L L L

Which of the given statements is correct?

a. Since the mass and the box-length are kept arbitrary, one cannot be sure about whether energy is lost or gained.

b. The energy of the particle is conserved in the process

c. Particle has gained the energy in the process

d. Particle has lost the energy in the process

The correct answer is:

Particle has lost the energy in the process

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6/14/2021 Quiz 1: Attempt review

Question 4
Complete

Mark 1 out of 1

In the given (partial) sets of the orbitals of 3d-subshell, choose the set in which the orbital are NOT arranged in the ascending order of the
square of the z-component of the angular momentum.

a. 3d0 , 3dxz , 3dx 2

−y
2

b. 3d0 , 3dyz , 3dx 2

−y
2

c. 3dz 2 , 3dyz , 3dxy

d. 3dz 2 , 3dxy , 3dxz

The correct answer is:

3dz , 3dxy , 3dxz

Question 5
Complete

Mark 1 out of 1

If a vibrator of mass 1.6 × 10−27 kg has a force constant of 854 N m−1 , its fundamental vibrational frequency must be  116.335 THz.

The correct answer is: 116.27

Question 6
Complete

Mark 1 out of 1

A particle of mass m, set to rotate in an orbit of fixed radius, r is found in a state, ψ −4iϕ
= e . The magnitude of its angular momentum in
the given state, must be  ____ ℏ .

Answer: 4

The correct answer is: 4

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6/14/2021 Quiz 1: Attempt review

Question 7
Complete

Mark 1 out of 1

When an electric bulb glows, it emits the light of various colours. If the wavelength of the most intense radiation is 605.2 nm, the
temperature of the glowing filament must be 4791.804   K.

The correct answer is: 4792

Question 8
Complete

Mark 1 out of 1

If a beam of X-ray radiations of frequency 1298 THz is flashed on the surface of a metal of workfunction 3.07 eV,  the kinetic energy of any
ejected photoelectron must not be greater than 2.28 eV

The correct answer is: 2.305

Question 9
Complete

Mark 1 out of 1

In a rigid rotor, during rotation, the distance between the center and end of the rotor is

a. infinite

b. zero

c. constant

d. variable

The correct answer is:

constant

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6/14/2021 Quiz 1: Attempt review

Question 10
Complete

Mark 1 out of 1

A hydrogen atom was found in 5d−2 state. The number of radial and angular nodes in the given wave-function are, respectively

a. 2,2

b. 4,2

c. 2,0

d. 2,4

The correct answer is:

2,2

Question 11
Complete

Mark 1 out of 1

A particle of mass 1 a.m.u. is confined to a box of length 3.3 pm. The ground state energy of the particle is 19.531 eV.

The correct answer is: 19.66

Question 12
Complete

Mark 1 out of 1

Assuming " dx
d
" as the operator and "k" as a constant, which one of the given functions is an eigen function of the given operator?

a. ex

b. kx

c. e−kx

d. cos(kx)

The correct answer is:

e

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Question 13
Complete

Mark 1 out of 1

Among
the following quantities listed in the answer choices, select the one
which is different from the others in value.

a. ground state energy of H atom.

b. (1/9)th of the ground state energy of Li2+.

c. (1/4)th of the ground state energy of Be3+.

d. (1/36)th of the ground state energy of C5+.

The correct answer is:

(1/4)th of the ground state energy of Be3+.

Question 14
Complete

Mark 1 out of 1

For
any operator A
^
and a wave function, ψ,
if A
^
ψ = aψ ,
then a is called

a. propagation constant

b. eigenvalue

c. eigen function

d. normalization constant

The correct answer is:

eigenvalue

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6/14/2021 Quiz 1: Attempt review

Question 15
Complete

Mark 1 out of 1

What
is the de Broglie wavelength of a neon atom in a container at 298K ?

Note: Assume kinetic energy of the atom to be 3

2
kT ; Relative Atomic Mass
of Neon = 20.18 ;  k −23
= 1.38 × 10 JK
−1

a. 65.31pm

b. 73.00pm

c. 32.59pm

d. 36.71pm

The correct answer is:

32.59pm

Question 16
Complete

Mark 1 out of 1

For
a black body the relation between the λmax
and the corresponding temperature is

a. exponential.

b. linear.

c. parabolic

d. hyperbolic.

The correct answer is:

hyperbolic.

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6/14/2021 Quiz 1: Attempt review

Question 17
Complete

Mark 1 out of 1

For a moving particle, the minimum uncertainty in the measurement of its position was found to be ( Δx ). The uncertainty in the
measurement of its momentum was found to be ( Δpx ).

If the uncertainties obey the relationship ΔxΔpx =

ℏ

2
, then the uncertainty in the measurement of the momentum must be __________.

a. minimum

b. maximum

The correct answer is:

minimum

Question 18
Complete

Mark 1 out of 1

The
zero point energy of a particle of mass, m, in an one
dimensional box of length, L, is

a. 0

b.

2
h
2
8πmL

c.
2
h
2

8mL

d.
2

2
h
2

4π mL

The correct answer is:

2
h
2

8mL

Question 19
Complete

Mark 1 out of 1

Find the eigenvalue of the operator, D , when it acts on the function function  f (x) 6sin(2.6x−6.1).

2
^ =
d
=
2
dx

Answer: -6.76

The correct answer is: -6.76

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6/14/2021 Quiz 1: Attempt review

Question 20
Not answered

Marked out of 1

For
an electron in a certain one-dimensional box, the lowest observed
transition frequency is 2.0 × 1014 s−1 .
What is the length of the box?
Data: h = 6.626 × 10
−34 −31
J s; me = 9.1 × 10 kg

a. 1.2nm

b. 1.6nm

c. 0.4nm

d. 0.1nm

The correct answer is:

1.2nm

◄ Tutorial Section 06 (Prashant Uday Manohar, Tuesday, 10:00-10:50 hrs)

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