24 MAR 21 (B-1 & B-2) ASSIGNMENT CHEMISTRY

(XI) LALIT TUTORIALS (XI)

Time : Hour CHEMICAL EQUILIBIRUM Marks :
1. For the chemical equilibrium 2NO(g) + O2(g) 2NO2(g) 11. The dissociation constants for acetic acid and HCN at 25 oC
Kp = 1.3 x 10 at 1000 K. What is the value of KC at 1000 K?
‒2 are 1.5 x 10‒5 and 4.5 x 10‒10, respectively. The equilibrium
a) 0.067 b) 5.067 c) 1.067 d) 3.067 constant for the equilibrium
2. The reaction between hydrogen and iodine at 700 K is CN‒ + CH3COOH HCN + CH3COO‒ would be
described by the equilibrium a) 3.0 x 10 b) 3.0 x 105 c) 3.0 x 10‒5
4 d) 3.0 x 10‒4
H2(g) + I2(g) 2HI(g) 12. In which of the following equilibrium KC and Kp are not
In a certain experiment at 700 K, the various equal?
concentrations at equilibrium were found to be a) SO2(g) + NO2(g) SO3(g) + NO(g)
[H2] = 1.84 x 10‒3 mol dm‒3 [I2] = 3.13 x 10‒3 mol dm‒3 b) H2(g) + I2(g) 2HI(g)
[HI] = 17.7 x 10‒3 mol dm‒3 c) 2C(s) + O2(g) 2CO2(g)
Calculate KC for this equilibrium at 700 K. d) 2NO2(g) N2(g) + O2(g)
a) 30.4 b) 54.4 c) 20 d) 10.4
13. The reaction, 2A(g) + B(g) 3C(g) + D(g)
3. KC for the equilibrium A(g) B(g) + C(g) is 0.45 at 200oC.
Is begun with the concentrations of A and B both at an
1 L of a container holds 0.2 mol of A, 0.3 mol of B and 0.3
initial value of 1.00 M. When equilibrium is reached, the
mol of C at equilibrium. Calculate the new equilibrium
concentration of D is measured and found to be 0.25 M.
concentration of A, B and C if the volume of container at
The value for the equilibrium constant for this reaction is
same temperature is halved
given by the expression
a) [B] = [C] = 0.48 M, [A] = 0.52 M
a) [(0.75)3 (0.25)]  [(0.50)2 (0.75)]
b) [B] = [C] = 1.48 M, [A] = 0.25 M
b) [(0.75)3 (0.25)]  [(0.50)2 (0.25)]
c) [B] = [C] = 3.48 M, [A] = 2.52 M
c) [(0.75)3 (0.25)]  [(0.75)2 (0.25)]
d) [B] = [C] = 2.48 M, [A] = 1.23 M
d) [(0.75)3 (0.25)]  [(1.00)2 (1.00)]
4. A2(g) and B2(g) at initial partial pressure of 98.4 and 41.3
14. For the reaction N2(g) + O2(g) 2NO(g), the equilibrium
torr, respectively were allowed to react at 400 K. At
equilibrium the total pressure was 110.5 torr. Calculate the constant is K1. The equilibrium constant is K2 for the
value of Kp (atm‒1) for the following reaction at 400 K. reaction 2NO(g) + O2(g) 2NO2(g). What is K for the
2A2(g) + B2(g) → 2A2B(g) reaction?
a) 124 b) 134 c) 154 d) 174 1
NO2(g) N2(g) + O2(g)
5. The equilibrium composition for the reaction is 2
PCl3(g) + Cl2(g) → PCl5(g) 1 1 1  1 
0.20 0.05 0.40 mol L‒1 a) b) c) d)  
(K1K 2 ) (2K1K 2 ) (4K1K 2 )  K1K 2 
If 0.25 mol L‒1 of Cl2 is added at same temperature. Find
equilibrium concentration of PCl5 15. The value of ΔH for the reaction
a) 0.525 mol L‒1 b) 0.48 mol L‒1 X2(g) + 4Y2(g) 2XY4(g)
c) 0.56 mol L ‒1 d) 1.20 mol L‒1 Is less than zero. Formation of XY4(g) will be favored at
6. Equilibrium constants are given (in atm) for the following a) high pressure and low temperature
reactions at 0oC b) high temperature and high pressure
SrCl2 . 6H2O(s) SrCl2. 2H2O(s) + 4H2O(g) ; c) low pressure and low temperature
Kp = 6.89 x 10‒12 d) high temperature and low pressure
The vapor pressure of water at 0oC is 4.58 torr. Calculate 16. Given that the equilibrium constant for the reaction
the pressure of water vapour in equilibrium at 0oC 2SO2(g) + O2(g) 2SO3(g) has a value of 278 at a
a) 2.6 x 10‒3 atm b) 1.62 x 10‒3 atm particular temperature. What is the value of the
c) 1.20 x 10 atm
‒4 d) 4.28 x 10‒3 atm equilibrium constant for the following reaction at the same
7. The reaction quotient (Q) for the reaction temperature?
N2(g) + 3H2(g) 2NH3(g) SO3(g)
1
SO2(g) + O2(g)
[NH 3 ]2 2
Is given by Q = . The reaction will proceed from a) 1.8 x 10‒3 b) 3.6 x 10‒3
[N 2 ][H 2 ]3
c) 6.0 x 10 ‒2 d) 1.3 x 10‒5
right to left if 17. Given the reaction between two gases represented by A 2
a) Q = KC b) Q < KC c) Q > KC d) Q = 0 and B2 to give the compound AB(g).
8. The following equilibrium constants are given A2(g) + B2(g) 2AB(g)
N2 + 3H2 2NH3; K1 N2 + O2 2NO; K2 At equilibrium, the concentration
H2 + O2
1
H2O; K3 of A2 = 3.0 x 10‒3 M
2 of B2 = 4.2 x 10‒3 M
The equilibrium constant for the oxidation of the NH3 by of AB = 2.8 x 10‒3 M
oxygen to give NO is In the reaction takes place in a scaled vessel at 527oC, then
KK K K3 K K2 K3K the value of KC will be
a) 1 2 b) 2 3 c) 2 3 d) 2 3 a) 2.0 b) 1.9 c) 0.62 d) 4.5
K3 K1 K1 K1
18. For the reversible reaction
9. The value of equilibrium constant of the reaction N2(g) + 3H2(g) 2NH3(g) + Heat
1 1
HI(g) H2(g) + I2(g) The equilibrium shifts in forward direction
2 2 a) by increasing the concentration of NH3(g)
Is 8.0. The equilibrium constant of the reaction b) by decreasing the pressure
H2(g) + I2(g) 2HI(g) will be c) by decreasing the concentrations of N2(g) and H2(g).
a) 1/8 b) 1/16 c) 1/64 d) 16 d) by increasing pressure and decreasing temperature
10. The values of Kp1 and Kp2 for the reactions 19. For a given exothermic reaction, Kp and K 'p are the
X Y+Z (1)
equilibrium constants at temperatures T1 and T2
A 2B (2)
respectively. Assuming that heat of reaction is constant in
Are in the ratio of 9 : 1. If degree of dissociation of X and A temperatures range between T1 and T2. It is readily
be equal, then total pressure at equilibrium (1) and (2) are observed that
in the ratio
a) Kp > K 'p b) Kp < K 'p c) Kp = K 'p d) Kp = 1/ K 'p
a) 1 : 1 b) 3 : 1 c) 1 : 9 d) 36 : 1

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24 MAR 21 (B-1 & B-2) ASSIGNMENT CHEMISTRY

20. If the equilibrium constant for N2(g) + O2(g) 2NO(g) is 32. 3.1 mole of FeCl3 and 3.2 mol of NH4SCN are added to 1L of
K, then equilibrium constant for water. At equilibrium 3.0 mol of FeSCN2+ are formed. The
1 1 equilibrium constant KC of the reaction
N2(g) + O2(g) NO(g) will be Fe3+ + SCN‒ FeSCN2+ will be
2 2
a) K b) K2 c) K1/2 d) ½ K a) 6.66 x 10 ‒3 b) 0.30 c) 3.30 d) 150
21. We know that the relationship between KC and Kp is 33. One mole of N2O4 in a 1 L flask decomposes to attain the
Kp = Kc(RT) Δn equilibrium N2O4(g) 2NO2(g). At the equilibrium the
What would be the value of n for the reaction mole fraction of NO2 is 1/2. Hence KC will be
NH4Cl(s) NH3(g) + HCl(g) a) 1/3 b) 1/2 c) 2/3 d) 1
a) 1 b) 0.5 c) 1.5 d) 2 34. What is the equilibrium concentration of each of the
22. On increasing the pressure, in which direction will the gas product in the equilibrium when the initial concentration
phase reaction proceed to re-establish equilibrium, is of ICI was 0.78 M?
predicted by applying the Le Chatelier’s principle, consider 2ICl(g) I2(g) + Cl2(g); KC = 0.25
the reaction. N2(g) + 3H2(g) 2NH3(g) a) 0.195 M b) 0.42 M c) 4.2 M d) 2.1 M
Which of the following correct, if the total pressure at 35. If KC is 41 for N2(g) + 3H2(g) 2NH3(g), then for
which the equilibrium is established, is increased without NH3(g)
1 3
N2(g) + H2(g) KC will be
changing the temperature? 2 2
a) K will remain same a) 41 b) 41 c) 20.5 d) 1 / 41
b) K will decrease 36. The reaction A(g) B(g) + 2C(g) is occur by mixing of 3
c) K will increase
mol of A and 1 mol of B in 1 L container. If α of B is 1/3,
d) K will increase initially and decrease when pressure is
then KC for this reaction is
very high
a) 0.12 b) 0.25 c) 0.50 d) 0.75
23. Ratio of active masses of 22 g CO2, 3g H2 and 7g N2 in a
37. C(s) + CO2(g) 2CO(g)
gaseous mixture is
a) 22 : 3 : 7 b) 0.5 : 3 : 7 c) 1 : 3 : 1 d) 2 : 6 : 1 According to above reaction, equilibrium partial pressure
24. In a chemical equilibrium, the rate constant for the of CO2 and CO are 4 atm and 8 atm respectively. Then, find
backward reaction is 7.5 x 10‒4 and the equilibrium out Kp of the above reaction
constant is is 1.5. The rate constant for the forward a) 6 b) 2 c) 16 d) 32
reaction is 38. 4 mol of A are mixed with 4 mol of B. At equilibrium, for
a) 2 x 10‒3 b) 5 x 10‒4 c) 1.12 x 10‒3 d) 9.0 x 10‒4 the reaction A + B C + D, 2 mol of C and D are formed.
25. Assuming that the system is at equilibrium, which of the The equilibrium constant for the reaction will be
following reactions goes most nearly to 100% completion a) 1/4 b) 1/2 c) 1 d) 4
a) C(s) + H2O(g) CO(g) + H2(g); KC = 6.5 x 10‒23 39. For the following gases at equilibrium
b) CO(g) + 3H2(g) CH4(g) + H2O(g); KC = 0.176 N2O4(g) 2NO2(g)
c) 2C(s) + O2(g) 2CO(g); KC = 1 x 1016 Kp is found to be equal to KC. This is attained when
a) 0oC b) 273 K c) 1 K d) 12.18 K
d) H2(g) + I2(g) 2HI(g); KC = 54.5
40. 4 mole PCl5 is heated at constant temperature in a closed
26. When two reactants A and B are mixed to give products C container. If degree of dissociation for PCl5 is 0.5 then
and D, the reaction quotient, Q at the initial stage of the calculate the total number of moles at equilibrium
reaction a) 4.5 b) 6 c) 3 d) 4
a) is zero b) decreases with time 41. Consider the reaction PCl5(g) PCl3(g) + Cl2(g) in a
c) increases with time d) is independent of time
closed container at equilibrium at a fixed temperature.
27. A reaction mixture containing H2, N2 and NH3 has partial
What will be the effect of adding more PCl5 on the
pressures 2 atm, 1 atm and 3 atm respectively at 725 K. If
equilibrium concentration of Cl2(g)?
the value of Kp for the reaction, N2 + 3H2 2NH3 is
a) it decreases
4.28 x 10‒5 atm‒2 at 725 K, in which direction the net b) it increases
reaction will go c) it remain unaffected
a) forward d) It cannot be predicted without the value of Kp
b) reverse 42. In the system AB(s) A(g) + B(g) doubling the quantity
c) no net reaction
of AB(s) would
d) direction of reaction cannot be predicted
a) increase the amount of A to doubled its value
28. The reaction A + B C + D is studied in a 1 L vessel at
b) increases the amount B to double its value
250oC. The initial concentration of A was 3n and of B was n. c) increase the amount of both A and B to double their values
After equilibrium was attained, equilibrium concentration of d) cause no change in the amounts of A and B
C was found out to be equal to the equilibrium concentration 43. In manufacture of NO, the reaction of N2 and O2 to form NO
of B. what is the concentration of D at equilibrium? is favorable if
n n a) pressure is increased b) pressure is decreased
a) n/2 b) (3n ‒ ) c) (n + ) d) n
2 2 c) temperature is increased d) temperature is decreased
29. PCl5(g) PCl3(g) + Cl2(g). in the given reaction at 44. In which of the following equilibrium reactions, the
equilibrium condition mole fraction of PCl5 is 0.4 and mole equilibrium would shift to right side, if total pressure is
fraction of Cl2 is 0.3. Find out the mole fraction of PCl3. decreased?
a) 0.3 b) 0.7 c) 0.4 d) 0.6 a) N2(g) + 3H2(g) 2NH3(g) b) H2(g) + I2(g) 2HI(g)
30. For the following equilibrium, KC = 6.3 x 1014 at 1000 K c) N2O4(g) 2NO2(g) d) H2(g) + Cl2(g) 2HCl(g)
NO(g) + O3(g) NO2(g) + O2(g) 45. Consider the heterogeneous equilibrium in a closed
Both the forward and reverse reaction in the equilibrium container
are elementary bimolecular reactions. What is KC for the NH4HS(g) NH3(g) + H2S(g)
reverse reaction? If more NH4HS is added to the equilibrium
a) 15.9 x 10‒15 b) 1.59 X 10‒15 a) partial pressure of NH3 increases
c) 5 x 10 ‒15 d) 9 x 10‒15 b) partial pressure of H2S increases
31. One mole of H2O and one mole of CO are taken in 10 L c) total pressure in the container increases
vessel and heated to 725 K at equilibrium. 40% of water d) no effect on partial pressure of NH3 and H2S
reacts with CO according to the equation 46. Change in volume of the system does not alter the
H2O(g) + CO(g) H2(g) + CO2(g) number of moles in which of the following equilibrium
What is the value of equilibrium constant (K C) for the reaction. a) N2(g) + O2(g) 2 NO(g) b) PCl5(g) PCl3(g) + Cl2(g)
a) 44 b) 4.4 c) 0.44 d) 2.22 c) N2(g) + 3H2(g) 2 NH3(g) d) SO2Cl2(g) SO2(g) + Cl2(g)
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24 MAR 21 (B-1 & B-2) ASSIGNMENT CHEMISTRY

47. In which of the following reactions, increases in the pressure at 61. A vessel at 1000 K contains CO2 with a pressure of 0.5
constant temperature does not affect the moles at equilibrium atm. Some of the CO2 is converted into CO on the addition
a) 2NH3(g) N2(g) + 3H2(g) b) C(g) + 1/2 O2(g) CO(g) of graphite. If the total pressure at equilibrium is 0.8 atm,
c) H2(g) + 1/2 O2(g) H2O(g) d) H2(g) + I2(g) 2HI(g) the value of KP is
48. For the reaction: CO(g) + 1/2 O2(g) CO2(g) Kp/Kc is a) 1.8 atm b) 3 atm c) 0.3 atm d) 0.18 atm
62. The equailibrium constant (Kc) for the reaction
a) RT b) (RT)-1 c) (RT)-1/2 d) (RT)1/2
N2(g) + O2(g) → 2NO(g) at temperatur T is 4 x 10-4. The
49. For the reaction equilibrium:N2O4(g) 2NO2(g); the
concentration of N2O4 and NO2 at equilibrium are 4.8 x value of Kc for the reaction NO(g) → 1 N2(g) + 1 O2(g)
2 2
10-2 and 1.2 x 10-2 mol/L respectively. The value of KC for
at the same temperature is
the reaction is
a) 0.02 b) 2.5 x 102 c) 4 x 10-4 d) 50
a) 3 x 10-3 M b) 3 x 103 M c) 3.3 x 102 M d) 3 x 10-1 M
50. The conditions favorable for the reaction: 63. For the reaction SO2(g) + 1 O2(g) SO3(g),
2
2SO3(g); ΔH = -198 kJ are
o
2SO2(g) + O2(g) If KP = Kc (RT)x where the symbols have usual meaning then,
a) Low temperature, high pressure value of x is (assuming ideality).
b) Any value of T and P a) -1 b) -1/2 c) 1/2 d) 1
c) Low temperature and low pressure 64. The standard Gibbs energy change at 300 K for the reaction 2A →
d) High temperature and high pressure B + C is 2494.2 J. At a given time, the composition of the reaction
51. What is the equilibrium constant for the reaction:
mixture is [A] = 1 , [B] = 2 and (C) = 1 . The reaction proceeds in
P4(S) + 5O2(g) P4O10(S)
2 2
a) KC = 1 b) KC = [P4 O10 ] the [R = 8.314 J/K/mol, e = 2.718]
[O 2 ]5 S[P4 ][O 2 ] a) forward direction because Q > KC
b) reverse direction because Q > KC
c) KC = [O2]5 d) KC = [P4 O10 ] c) forward direction because Q < KC
[P4 ][O 2 ]5 d) reverse direction because Q < KC
52. For the reaction CO(g) + Cl2(g) COCl2(g), the KP/KC is 65. In the gaseous equilibrium A + 2B C + Heat, the forward
equal to reaction is favoured;
a) Law P, High T b) Low P, Low T
a) 1.0 b) RT c) RT d) 1/RT
c) High P, Low T d) High P, High T
53. The equilibrium constant for the reaction 66. The equilibrium, SO2Cl2(g) SO2(g) + Cl2(g) is attained at
N2(g) + O2(g) 2NO(g) at temperature T is 4 x 10-4. The 298 K in a closed container and an inert gas. He is introduced.
value of Kc for the reaction. NO(g) ½ N2(g) + 1/2 O2(g) Which of the following is/are correct?
at the temperature is a) Concentration of SO2(g), Cl2(g), and SO2Cl2(g)
a) 0.02 b) 50 c) 4 x 10-4 d) 2.5 x 10-2 remain unchanged
54. The exothermic formation of ClF3 is represented by the b) More Cl2(g) is formed
equation Cl2 + 3F2(g) 2ClF3(g); ΔH = -329 kJ/mol c) Concentration of SO2(g) is reduced
Which of the following will increase the quantity of ClF3 in an d) More SO2cl2(g) is formed
equilibrium mixture of Cl2, F2, and ClF3 67. Starting with 2 mole of PCl5 in 1 L container, 0.5 mol of
a) Increasing the temperature b) Removing Cl2 PCl3 dissociates till equilibrium at 25oC is reached.
c) Increasing the volume of container d) Adding F2 Equailibrium constant KC is
55. For the reaction: 2NO2(g) 2NO(g) + O2(g) a) 6 b) 4.5 c) 1/6 d) None
Kc = 1.8 x 10-6 at 184oC and R = 0.083 J/K.mol. When K p 68. The volume of a closed reaction vessel in which the
and Kc are compared at 184oC, it is found that equilibrium:
a) KP > KC b) KP < KC 2SO2(g) + O2(g) 2SO3(g) sets is halved, Now
c) Kp = KC d) KP x KC depends upon pressure of gases a) The rates of forward and backward reactions will
56. A definate amount of solid NH4HS is placed in a flask already remain the same
containing ammonia gas at a certain temperature and 0.50 atm b) The equilibrium will not shift
pressure. NH4HS decomposes to give NH3 and H2S and at
c) The equilibrium will shift to the right
equilibrium total pressure in flask is 0.84 atm. The equilibrium
constant for the reaction is
d) The rate of forward reaction will become double
a) 0.30 b) 0.18 c) 0.17 d) 0.11 than that of reverse reaction and the equilibrium will
57. Phosphorus pentachloride dissociates as follows, in a closed shift to the right.
reaction vessel, PCl5(g) PCl3(g) + Cl2(g) 69. In the reaction A + B C + D the inital concentration of
If total pressure at equilibrium of the reaction mixture is P and A is double the initial concentration of B. At equilibrium,
degree of dissociation of PCl5 is x, the partial pressure of PCl3 the concentration of B was found to be one-third of the
will be concentration of C. The value of equilibrium constant is
a)  x  P b)  x  P c)  2x  P d)  x  P a) 1.8 b) 1.008 c) 0.0028 d) 0.08
       
1 - x   x + 1 1 - x   x - 1 70. For the reaction PCl5(g) PCl3(g) + Cl2(g), the moles of
58. The equilibrium constant for the reaction each component PCl5, PCl3, and Cl2 at equilibrium were
SO3(g) SO2(g) + 1 O2(g) will be found to be 2. If the total pressure is 3 atm. The KP will be
2 a) 1 atm b) 2 atm c) 3 atm d) 1.5 atm
a) 4.9 x 10-2 b) 416 c) 2.40 x 10-3 d) 9.8 x 10-2 71. For the reaction H2 + I2 2HI The value of equilibrium
59. The equilibrium constant KP1 and KP2 for the reactions constant is 9.0. The degree of dissociation of HI will be
X 2Y and Z P + Q, respectively are in the ratio of a) 2 b) 2/5 c) 5/2 d) 1/2
1 : 9. If the degree of dissociation of X and Z be equal, then the 72. In a reaction vessel of 2 L capacity 3 mol of N2 reacts with 2 mol
ratio of total pressures at these equilibria is of O2 to produce 1 mol of NO. What is the molar concentration
a) 1 : 36 b) 1 : 1 c) 1 : 3 d) 1 : 9 of N2 at equilibrium?
60. For the following three reactions 1, 2 and 3, equilibrium a) 1.25 b) 1.50 c) 0.75 d) 2.0
constant are given 73. HI was heated in a sealed tube at 440oC till the equilibrium was
1) CO(g) + H2O(g) CO2(g) + H2(g); K1 established. The dissociation of HI was found to be 22%. The
equilibrium constant for dissociation is
2) CH4(g) + H2O(g) CO(g) + 3H2(g); K2 a) 0.282 b) 0.0786 c) 0.0199 d) 1.99
3) CH4(g) + 2H2O(g) CO2(g) + 4H2(g); K3 74. For the reversible system: X(g) Y(g) + Z(g), a quantity of X
Which of the following reactions is correct? was heated at constant pressure P at a certain temperature. The
a) K1 K2 = K3 b) K2 K3 = K1 equilibrium partial pressure of X was found to be P/7. What
is the value of KP at given temperature
c) K3 = K1 K2 d) K3. K 32 K12 a) 6 P/7 b) 9 P/7 c) 36 P/7 d) 6 P

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24 MAR 21 (B-1 & B-2) ASSIGNMENT CHEMISTRY

75. For the reaction: SnO2(s) + 2H2(g) 2H2O(g) + Sn(1) 87. Law of mass action was presented by
calculate KP at 900 K, where the equilibrium a) Henderson b) Lewis
steamhydrogen mixture was 45% H2 by volume c) Guldberg and Waage d) Arrehenius
a) 1.49 b) 1.22 c) 0.67 d) none of these 88. Calculate the equilibrium constant, Kc, for the following
76. For the reaction A(g) + 3B(g) 2C(g) at 27oC, 2 mol of reaction where [O2] = 2.0 M & [O3] = 1.7 M.
A, 4 mol of B, and 6 mol of C are present in 2L vessel. If K C 3O2(g) 2O3 (g)
for the reaction is 1.2, the reaction will proceed in:
a) 1 b) 2 c) 0.36 d) None of these
a) forward direction
89. 3
If K > 10 :
b) back ward direction
c) neigther direction a) products are predominate over reactants.
d) None of these b) reactants are predominate over products.
77. The equilibrium constant for the rection c) appreaciable concentrtion of both reactants and over
CO(g) + H2O(g) CO2(g) + H2(g) is 5. How many moles products are present.
of CO2 must be added to 1 liter container already d) None of these
containing 3 mol each of CO and H2O to make 2 M 90. For the decomposition calcium carbonate
equilibrium concentration CO? a) Kp = Kc b) Kp > Kc
a) 15 b) 19 c) 5 d) 20 c) Kc > Kp d) Kp =Kc = 1
78. The following equilibrium constants were determined at 91. Which of the following is not the characteristics of
chemical equilibrium
1120 K: 2CO(g) C(s) + CO2(g); K p1 = 10-14 atm-1 a) At equilibrium the forward and reverse reactions
CO(g) + Cl2(g) COCl2(g); K P2 = 6 x 10-3 atm-1 proceeds with same rate
b) A catalyst does not affect the position of equilibrium.
What is the equilibrium constatn KC for the following c) The changes in concentration, pressure, volume and
reaction at 1120 K: C(s) + CO2(g) + 2Cl2(g) 2COCl2(g) temperature can change the equilibrium position.
a) 3.31 x 1011 M-1 b) 5.5 x 1010 M-1 d) All of these are the characteristics of equilibrium
c) 5.51 x 106 M-1 d) None of these 92. The chemical equilibrium is:
79. Assuming that the decomposition of HNO3 can be a) Dynamic b) static
represented by the following equation c) may be static or dynamic d) mechanical
4HNO3(g) 4NO2(g) + 2H2O(g) + O2(g) 93. The value of equilibrium constant depends upon:
and the reaction approaches equilibrium at 400 K a) Concentration b) Pressure
temperature and 30 atm pressure. At equilibrium partial c) Volume d) Temp.
pressure of HNO3 is 2 atm. Calculate KC in (mol/L)3 at 400 94. The catalyst
K: (Use: R = 0.08 atm.L/mol.K) a) Increases the value of equilibrium constant
a) 4 b) 8 c) 16 d) 32 b) Decreases the value of equilibrium constant
80. Ammonium carbamate dissociates as c) does not affect the value of equilibrium constant
NH2COONH4(s) 2NH3(g) + CO2(g) d) None of these
In a closed vessel containing ammonium carbamate in 95. Kc and Kp are releated as:
equilibrium, ammonia is added such that partial pressure a) Kp = Kc (RT) Δn b) Kc = Kp (RT) Δn
of NH3 now equals to the original total pressure. Calculate c) Kp= Kc d) None of these
the ratio of partial pressure of CO2 now to the original 96. The law of mass action was put forth by
partial pressure of CO2: a) Arrhenius b) Lowry and Bronsted
a) 4 b) 9 c) 4/9 d) 2/9 c) Boyles and Charles d) Guldberg and Wage
81. 2NOBr(g) 2NO(g) + Br2(g). If nitrosyl bromide 97. For the reaction: CO(g) + 1/2 O2(g) CO2(g) Kp/Kc is
(NOBr) in 40% dissociated at certain temperature, and a a) RT b) (RT)-1 c) (RT)-1/2 d) (RT)1/2
total pressure of 0.30 atm. KP for the reaction 98. The conditions favorable for the reaction:
2NO(g) + Br2(g) 2NOBr(g) is 2SO2(g) + O2(g) 2SO3(g); ΔH = -198 kJ are
o

a) 45 b) 25 c) 0.022 d) 0.25 a) Low temperature, high pressure

82. Which of the following factors will enhance the amount of b) Any value of T and P
C2H4(g) present at equilibrium in the following reaction c) Low temperature and low pressure
for which the enthalpy change ΔH is negative: C2H4(g) + d) High temperature and high pressure
H2(g) C2H6(g) 99. What is the equilibrium constant for the reaction:
a) increasing temperature decreasing pressure P4(S) + 5O2(g) P4O10(S)
b) removal of some H2(g) a) KC = 1 b) KC = [P4 O10 ]
c) adding some C2H6(g) [O 2 ]5 S[P4 ][O 2 ]
d) All of these c) KC = [O2]5 d) KC = [P4 O10 ]
83. If ‘a’ is the fraction of N2O4 molecules dissociated in the [P4 ][O 2 ]5
reaction (N2O4 2NO2), then at equilibrium, the total 100. For the reaction CO(g) + Cl2(g) COCl2(g), the KP/KC is equal
number of moles of N2O4 and NO2 present will be to
a) a b) 1 + a c) 2 a d) 1 – a
84. If X is the degree of dissociation of PCl5 a) 1.0 b) RT c) RT d) 1/RT
PCl5(g) 101. The exothermic formation of ClF3 is represented by the
PCl3(g) + Cl2(g) At a given temperature and if
equation Cl2 + 3F2(g)
2 mol of PCl5 are taken in a vessel, then at equilibrium the 2ClF3(g); ΔH = -329 kJ/mol
total number of moles of various species would be Which of the following will increase the quantity of ClF 3
a) 4 b) 2 + x c) 2(1 – x) d) 2(1 + x) in an equilibrium mixture of Cl2, F2, and ClF3
85. Two males of HI was heated in a sealed tube at 440 oC tilla) Increasing the temperature b) Removing Cl2
the equilibrium was reached. HI was found to be 20% c) Increasing the volume of container d) Adding F2
decomposed. The equilibrium constant for dissociation is
102. For the reaction SO2(g) + 1 O2(g) SO3(g),
a) 16 b) 0.625 c) 0.1 d) 0.0625 2
86. For the reaction: A + B C + D, 6.0 If KP = Kc (RT)x where the symbols have usual meaning
moles of A and 5.0 moles of B are mixed together in a then, value of x is (assuming ideality).
suitable container. When equilibrium is reached, 4.0 a) -1 b) -1/2 c) 1/2 d) 1
moles of C are produced.The equilibrium constant for 103. In the gaseous equilibrium A + 2B C + Heat, the
reaction is: forward reaction is favoured;
a) K = 1/8 b) K = 8 a) Law P, High T b) Low P, Low T
c) K = 30/16 d) K = 16/30 c) High P, Low T d) High P, High T
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24 MAR 21 (B-1 & B-2) ASSIGNMENT CHEMISTRY

104. The KC for given reaction will be 116. The equilibrium constant Kp for the following
A2(g) + 2B(g) C(g) + 2D(s) equilibrium reaction is 130. H2(g) + I2(g) 2HI(g)
2 The Kc for above reaction is
a) K = [C][D] b) K = [C]
a) Zero b) 130
[A 2 ][B]2 [A 2 ][B]2
c) more than 130 d) less than 130
2 2
c) K = [A 2 ][B]2 d) K = [A 2 ][B] 117. The equilibrium constant for the following reaction can
[C][D] [C] be represented by 1/2 H2(g) + 1/2 I2(g) HI(g)
105. In which of the following does the reaction go almost to
[HI] [HI]
completion? a) K = b) K =
[H 2 ]1/2 [I 2 ]1/2 [H 2 ][I 2 ]
a) A + B C; K = 104 b) X + Y Z; K = 10-3
c) P + Q R; K=1 d) M + N O + P; K = 10-1 [H 2 ][I 2 ] [H 2 ]1/2 [I2 ]1/2
c) K = d) K =
106. For the equilibrium CO + H2O CO2 + H2. The [HI] [HI]
releation between Kp and Kc at 25oC
and at 100oC are 118. Which of the following is the correct
a) Kp = Kc, Kp = Kc b) Kp = Kc(RT)-1, Kp = Kc a) The increase in temperature favours the exothermic
c) Kp = Kc(RT), Kp = Kc(RT) d) Kp = Kc(RT), Kp = Kc reaction
107. Addition of a catalyst to the reaction system at b) Catalyst favours forward reaction only.
equilibrium c) The decrease in temperature favours the
a) increases the rate of forward reactions exothermic reaction
b) increases the rate of reverse reactions d) Catalyst favours backward reaction only
c) increases rate of forward & reverse reactions 119. The catalyst
equally a) does not change the composition of equilibrium
d) None of these mixture
108. In Haber’s process: b) does not shift the equilibrium in favour of either
reactants or products.
2NH3(g); ΔH = -92.2 kJ
o
N2(g) + 3H2(g)
c) does not modify the equilibrium constant
The pressure of equilibrium system is increased then
d) All of these
a) yield of NH3 increases b) yield of NH3
120. If Kc is very large (if Kc > 103) then the reaction is
decreases
a) in favour of products and nearly goes completion
c) yield of NH3 remains constant d) None of these
b) in favour of reactants and does not take place
109. The equilibrium is affected by
c) does not favour reactants or products
a) Change in concentration b) Change in pressure or
d) can not be predcited
volume
121. The chemical reaction in which heat is relased is known
c) Change in temperature d) All of these
as:
110. For which of the following equilibrium Kp= Kc
a) Endothermic b) Irreversible
a) N2(g) + O2(g) 2 NO(g) b) PCl5(g) PCl3(g) + Cl2(g)
c) Exothermic d) Reversible
c) N2(g) + 3H2(g) 2 NH3(g) d) Cl2 + 3F2(g) 2ClF3(g) 122. In Haber’s process:
111. If an external stress is applied to a reacting system at
2NH3(g); ΔH = -92.2 kJ
o
N2(g) + 3H2(g)
equilibrium, the system will adjust in such way that the
Suppose that H2 is added of equilibrium system then
effect of the stress is reduced. This principle is known as
a) yield of NH3 increases b) yield of NH3
a) Law of mass action b) Le-Chatlier’s principle
decreases
c) Ostwald’s principle d) Arrhenius principle
c) yield of NH3 remains constant d) None of these
112. Chemical equilibrium is defined as
123. Consider the following eqilibrium:
a) the state of chemical reaction at which the rates of
C2H4 (g) + H2(g) C2H6 (g) + 137 kJ
forward and reverse reactions are equal
b) the rate of forward reaction is greater than that of The yield of C2H6 (g) can be increases by
reverse. a) Increasing the concentration of H2 gas
c) the rate of forward reaction is smaller than that of b) Decreasing the concentration of H2 gas
reverse. d) None of these c) By introducing catalyst
113. In Haber’s process: d) None of these
124. Consider the following equilibrium:
2NH3(g); ΔH = -92.2 kJ
o
N2(g) + 3H2(g)
2NH3(g); ΔH = -92.2 kJ
o
N2(g) + 3H2(g)
Suppose that NH3 is added of equilibrium system then
a) yield of NH3 increases b) yield of NH3 By increasing the temperature
decreases a) decomposition of ammonia favoured
c) yield of NH3 remains constant d) None of these b) formation of ammonia favoured
114. The following equilibrium classify as c) No change on equilibrium position
S(Monoclinic) S(Orthorhombic) d) None of these
125. The change in pressure does not affect the concentration
a) Chemical b) Static
of
c) Mechanical d) Physical
a) solids b) Liquids
115. The following equilibrium can not be affected by
c) both solids and liquids d) only gases
H2(g) + I2(g) 2HI(g)
126. In Haber’s process:
a) Change in pressure
2NH3(g); ΔH = -92.2 kJ
o
b) Change in concentration of Hydrogen N2(g) + 3H2(g)
c) Change in concentration of Hydrogen iodide Suppose that N2 is added of equilibrium system then
d) all of these a) yield of NH3 increases b) yield of NH3 decreases
c) yield of NH3 remains constant d) None of these

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24 MAR 21 (B-1 & B-2) ASSIGNMENT CHEMISTRY

127. The pressure of gas is 138. If pressure of equilibrium mixture is decreased by

a) directly proportional to the volume of gas increasing its volume at constant temperature, the net
b) inversly proportional to the volume of gas reaction occurce in the direction of
c) independent of volume of gas a) decreasing number of moles of gases
d) none of these b) increasing number of moles of gases
128. For the equilibrium: c) No change in equilibrium
A 2B + Heat d) None of the above
the number of A molecules increases if 139. The reaction do not go to completion and occurce in
a) volume is increased b) temperature is increased either direction is called
c) catalyst is added d) Concntration of B is decresed a) Reversible b) ireversible
129. When volume of equilibrium reaction c) homogenous d) heterogeneous
C(s) + 3H2O (l) CO(g) + H2 (g) 140. For a given reaction at equilibrium n=0 , then
is increased at constant temperature, the equilibrium will a) Kc=Kp b) Kp>Kc
a) shift from left to right b) Shift from right to left c) Kp< Kc d) Cant’t determined
c) be unaffcted d) not to be predicted
130. The releation between Kc and Kp for the reaction:
A(g) + B(g) C(g) + D(g)
a) Kc =1/Kp b) Kp = Kc2 c) Kc = 1/*Kp d) Kp/Kc =1
131. For the equilibrium:
Cl2(g) + 2NO(g) 2NOCl(g)
the concentration of NOCl will increase if the equilibrium
disturbed by
a) adding Cl2 b) removing NO
c) adding NOCl d) removel of Cl2
132. An equilibrium between two phases of the same
substance is called:
a) Physical equilibrium b) chemical equlibrium
c) static equilibrium d) None
133. The equilibrium constant Kc is
a) Product of equilibrium concentration of products
divided by product of equilibrium concentrations of
reactants.
b) Product of equilibrium concentration of reactants
divided by product of equilibrium concentrations of
product.
c) Product of equilibrium concentration of products
divided by product of equilibrium concentrations of
reactants each concentration term raised to suitable
power.
d) none of above
134. If pressure of equilibrium mixture is increased by
decreasing its volume at constant temperature, the net
reaction occurce in the direction of
a) decreasing number of moles of gases
b) increasing number of moles of gases
c) No change in equilibrium
d) None of the above
135. The effect of temperature on equilibrium position is
a) The increase in temperature fours endothermic
reaction.
b) The decrese in temperature favours exothermic
reaction
c) Both a and b
d) do not affect equilibrium position
136. A catalyst
a) Increases the speed at which the system approaches
equilibrium.
b) it does not shift the equilibrium in either direction
c) there is no change in equilibrium constant
d) all of these
137. The relation between Kc and Kp for the reaction:
A(g) + B(g) 2C(g)
a) Kc =1/Kp b) Kp = Kc2
c) Kc = 1/*Kp d) Kp=Kc

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