PHYSICSAccess Research Paper

ISSN Online: 2756-3898, ISSN Print: 2714-500X https://doi.org/10.47514/phyaccess.2021.1.1.005

Paleomagnetic Susceptibility Distribution and

Geochemical Analysis from the Eastern Part of
Kalambaina Formation Sokoto Basin North West,
Nigeria
Adamu Abubakar1, Faruk Usman2 and Musa M Zayyanu3
1 Department of Applied Geophysics, Federal University Birnin Kebbi, Nigeria
2 Department of Pure & Industrial Chemistry, Federal University Birnin Kebbi, Nigeria
3
National Centre for Technology Management, Ile-Ife, Osun State, Nigeria

Corresponding E-mail: adamu.abubakar35@fubk.edu.ng

Received 20-04-2021
Accepted for publication 14-05-2021
Published 21-05-2021

Abstract
Magnetic measurements, mineralogical and geochemical studies were carried out on surface
soil samples in order to delineate susceptibility distribution and to find possible relationships
based on paleomagnetic implications in some part of Kalambaina Area of Sokoto Northwestern
Nigeria. Geomorphologically, this area is generally gentle, with occasionally tabular, capped
by resistance laterites. Elevation generally decreases towards the northwest around the Nigeria
- Niger Republic boarder with an average elevation of about 215 above mean sea level. A
total of 90 sample were measured at random with DSM-10 susceptibility Kappa metre as well
20 core drilling samples were collected for further XRF geochemical analysis. Mass specific
susceptibility value ranges between 11.2 × 10 and 1.4 − 8.2 × 10 and magnetic
remanence at 1 values range between 10 × 10 and 0.5 − 9.0 × 10 as well as 0.5 −
7.4 × 10 . Chemical analysis by Xray Fluorescence analysis revealed the presence
concentration of various elements with their percentage composition (%) and the percentage
composition of calcium carbonate ( ) content between > 40% and < 70%, > 70% and
< 80%, core drilling depth and overburden thickness of a limestone Layer and Overburden.
Has also revealed low- and high-grade calcium carbonate content.

Keywords: Paleomagnetic; Susceptibility Measurement; Geochemical Analysis; Soil Samples; Kalambaina Formation

dissolution of the limestone. The maximum thickness,

I. INTRODUCTION recorded from the boreholes, is over 20 , but usually only
about 12 of section is exposed at the quarry. Near the
T he Kalambaina Formation consists of a white marine,
clayey limestone and shale. The Type Section of the
Formation is at the quarry of the cement factory of Northern
village of Dange, the Kalambaina Formation is reduced to
about 5 , but at Birnin Kebbi, further south, the Formation
Nigeria, near the village of Kalambaina, located about 6 is approximately 18 thick. The Formation is rich
to the south-west of Sokoto township. The thickness of the invertebrate fossils; mainly echinoids, corals, nautilus, and
Formation is quite variable, because of the subsurface gastropods have also been described from the formation [1-4].

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In the last 30 years, a growing number of studies using the 5° 10.398′ – 5° 10.745′ in Northwestern part of Nigeria.
techniques of magnetism of rocks has been applied to The study area covered about 59570 and is easily
environmental problems, thus creating a new branch of accessible through network of roads. Geomorphologically,
research commonly called “environmental magnetism” [5]. this area is generally gentle, with occasionally tabular hills,
This methodology is fast, economic and can be applied in capped by resistant laterites. Elevation generally decreases
various research fields, such as environmental monitoring, towards the northwest around the Nigeria – Niger Republic
pedology, paleoclimatology, limnology, archeology and boarder with an average elevation of about 215 above mean
stratigraphy. Recent studies have demonstrated the advantages sea level.
and the potential of the environmental magnetism methods as
valuable aids in the detection and delimitation of areas
affected by pollution [6-10].
One parameter often used in environmental magnetism
studies is the magnetic susceptibility. This parameter is easy
to measure and does not involve the destruction of the sample,
therefore, left available for additional analyses. The
measurement of the magnetic susceptibility of the surface soil
layers has been used as a proxy to contamination from
different pollution sources, diffuse and stationary [11-12].
Establishing a link between the concentration (and
characteristics) of ferrimagnetic minerals and the heavy metal
contents has been a challenge for a number of authors [13].
Magnetic parameters measured in soil profiles provide
information that allows us to establish a limit in depth
indicating the transition from the “polluted” to the deeper,
“unpolluted” zone in contaminated natural soil [8]. Fig. 1 Location Map of the Study Area (Adopted from
Magnetic methods should be considered as a first choice and Google Earth, 2019)
an appropriate strategy when conducting surveys [8] and they
can be a helpful indicator when targeting and selecting III. TECTONIC SETTING AND GEOLOGY OF THE STUDY AREA
sampling sites for subsequent geochemical analyses. These The Sokoto Basin of northwestern Nigeria consists
methods allow us to target the area most affected by pollution predominantly of a gentle undulating plain with an average
near roads and highways or industrial units, such as steel elevation varying from 250 − 400 above sea level. This
smelters [14-17], power plants [18-20] and cement plants [21]. monotonous plain is occasionally interrupted by steep-sided,
These are the preferred areas for sampling in order to flat-topped hills. A low escarpment, which was named as the
investigate the level of contamination by toxic elements like “Dange Scarp” by earlier workers, is the most prominent
heavy metals, with consequent benefits in saving time, feature in the basin, and is closely related to the geology (Fig.
manpower and materials. Any protective and remedial actions 2). The area to the east of this escarpment consists of
will be applied more rationally when being restricted to these predominantly of a gentle undulating, sandy plain, which
areas. In addition to the studies mentioned above, which can extends southwestwards to the Basement Complex boundary.
be described as the classic use of environmental magnetism The escarpment itself has undergone intensive erosion. The
with the aim to quantify pollution levels in air, sediments and edge is marked with a high drainage density indicating active
soils, some authors have been concerned with the stream dissection resulting in deeply incised ravines with
standardization of procedures and compatibility of numerous mesas and outliers scattered on the plains to the east
instruments used in previous research [22]. This study attempt [23]. In northwestern Nigeria the sediments of the
to (1) measure the In-situ magnetic parameters of various Iullemmeden Basin were deposited during three main phases
rocks, such as delineation of magnetic susceptibility ( ) of deposition: continental Mesozoic and Tertiary phases, with
distribution, hence the concentration of Fe-bearing mineral (2) an intervening marine Maastrichtian to Paleocene phase (Fig.
Identify magnetic minerals responsible for the Magnetization 2). Overlying the Pre-Cambrian basement unconformably, the
(3) study the magnetic parameters, the chemical contents and Illo and Gundumi Formations, made up of grifts and clays,
the mineralogical composition in order to characterize the soil; form part of the “Continental Intercalier” of West Africa. They
and (4) to find possible relationships between the measured are overlain unconformably by the Maastrichtian Rima Group,
parameters. consisting of mudstones and friable sandstones (Taloka and
Wurno Formations), separated by the fossiliferous shaly
II. LOCATION AND ACCESSIBILITY OF THE STUDY AREA Dukamaje Formation. The Paleocene Dange and Gamba
The study area lies between latitudes Formations (mainly shales) are separated by calcareous
13° 03.83′ – 13° 03.748′ and longitudes Kalambaina Formation. The overlying continental Gwandu

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Formation (Continental Terminal) is of Tertiary age. These B. Heavy Metal analysis

sediments dip gently and thicken gradually towards the In situ measurements of volume magnetic susceptibility
northwest, with a maximum thickness of over 1000 near were made in a grid of 1.12 using pocket GF Magnetic
the frontier of the Niger Republic [2]. susceptibility meter DSM-10 making access to 90% of
measuring signal e.g., concentration of ferrimagnetic material
in the top 20 of the land surface with operating frequency
of 10 and sensitivity of 1 × 10 units. In order to
check reproducibility and to avoid measurement errors, each
measurement was repeated three times and the mean accepted
as the magnetic susceptibility (MS).

C. Heavy Metal analysis

The collected soil samples were ground in a mechanical
agate grinder until fine particles (< 200 µ ) were obtained.
The prepared soil samples were analyzed for their heavy metal
concentrations using acid digestion method [24]. About
0.250 of the soil samples were weighed and placed into
Fig. 2 Generalized Geological Map of the Sokoto Basin [3] Pyrex test tubes. Concentrated nitric acid (4.0 ) and 1.0
concentrated perchloric acid were added. The mixtures were
IV. MATERIALS AND METHODS heated in an aluminum block until complete dryness. After
the test tubes were cool, 5% (0.8 ) nitric acid was added and
A. Site Description, Field work and Soil Sampling heated at 60° for 1 ℎ with occasional mixing. Upon cooling,
The study area (Fig. 1) is located in Sokoto Basin north- the mixtures were decanted into polyethylene tubes and
western Nigeria near the eastern part of Kalambaina area. The centrifuged at 3500 for 10 . Heavy metal
climate of the area immediately south of Sahara (that is concentrations of the solutions were measured using X-ray
including the Rima Basin), was becoming drier and desert Fluorescent Diffractor meter (XRF-D).
conditions were spreading southward. Mean annual
precipitation is around 650 and mean annual temperature V. RESULTS AND DISCUSSION
is 36℃. Prevailing wind direction is SE in November,
December, January and February and NW in the remaining A. Soil Magnetic Susceptibility Spatial Distribution
months. Sandstones and lime stones are the dominant Magnetic susceptibility values are about 11.2 × 10 ,
lithologies. This area is mainly occupied by the alluvial plain ranging from 1.4 − 8.2 × 10 in Site 1 and about
of the Goronyo River with numerous agricultural fields and 10 × 10 , ranging from 0.5 − 9.0 × 10 in Site 2.
drainage channels; it is also crossed by motorable road, which Site 2 shows enhancement of magnetic susceptibility
connects the cities of Gada and Goronyo. Human presence in distribution compared to the Site 1 which is far away from the
the area goes back over 2000 years [2]. Ninety samples (90)
quarry site in Kalambaina Katare. The highest values of
were randomly collected using a square grid of 500 ×
topsoil susceptibility are recorded in Site 1 with variations of
500 , distributed across site 1, 2, and 3, as well as in other
two to three orders of magnitude compared to the values
selected locations (Fig. 3). Soil material was sampled from the
recorded in Site 3. For comparison with value found in Gatere
upper 0 − 20 . For each sampling site, a composite
sample of 1 was produced from four sub samples. urban topsoil (0.5 × 10 − 7.4 × 10 ) [25], the mean
value in the lateritic topsoil is lower. In order to highlight and
delineate the trends of MS a contour map was plotted to
delineate each distribution across site 1,2, and 3. Fig. 4, 5 and
6 show the spatial map distributions of site 1, 2 and 3
respectively. Magnetic susceptibility shows inhomogeneous
repartition with probable zones of anomalies peaks at site 3.
In site 2, magnetic distribution is slightly homogeneous with
a standard value ranging from 0.5 × 10 − 9.0 × 10 .
The relatively high magnetic susceptibility values suggested
that the soil was enriched with ferrimagnetic grains probably
as a consequence of ferruginous sandstone iron deposit. In site
1, Lower susceptibility values were found and distributed
widely in all prospected surface topsoil. In respect to the same
physical characteristic of soil in both sites and remoteness to
Fig. 3 Sampling Distribution Map of the Study Area
the road edge, lower magnetic susceptibility values were also

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found in site 3 which suggest the soil is not affected by increased soil magnetic iron, bearing content [25]. In site
remanent magnetization. 1, the volume of magnetic susceptibility ranged from 1.6 ×
10 − 11.8 × 10 . Within the same area, the total
content of cobalt varied from 1.5 − 12.6, that of arsenic from
0.5 − 6.8, and copper from 6 − 62 / . On the tables,
contamination by these heavy elements is found to be
consistent with magnetic minerals of soils (through magnetic
susceptibility) and relate to the concentrations of
mineralogical composition (see Table 1, 2 & 3). Mapping of
the magnetic susceptibility enables a detailed assessment of
soil contamination with heavy metals over a large area (Fig.
7).

Fig. 4 Spatial Distribution Map of Magnetic Susceptibility at

Site 1.

Fig. 7 Spatial Distribution Map of Magnetic Susceptibility

Fig. 5 Spatial Distribution Map of Magnetic Susceptibility at across Site 1, 2 & 3
Site 2.

Fig. 8 3D Isometric View of Magnetic Susceptibility

Fig. 6 Spatial Distribution Map of Magnetic Susceptibility at Distribution Map of the Study Area
Site 3.
C. Geochemical Analysis
B. Magnetic Susceptibility Distribution Mapping Across the The XRD analysis (Table 1, 2 & 3) shows that the mineral
Areas suites consist mainly of Manganese oxide ( ), Silicates
A positive and reliable relation of magnetic susceptibility Oxide ( ), k-feldspars ( ), Sodium Oxide ( ),
with the total content of heavy metals allows us to perform a Calcium Oxide ( ), Hematite ( ), Aluminium Oxide
detailed survey of urban areas, highlighting areas with ( ), Lead Oxide ( ), Maghemite ( ), Titanium

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Oxide ( ) and Calcium Carbonate ( ). Some versus − rich) of the magnetite exert important control
samples have low quantities of magnetite/ maghemite (< on the metal fixation.
3 %). This result corroborates with the findings of other
TABLE 1. MINERAL COMPOSITION OF SOILS SAMPLES
authors [15, 26]. Other samples showed traces of Calcium ANALYSIS BY XRD OF SITE 1, HEIDELBERG TECHNOLOGY
carbonate and Hematite. Hematite and Manganese have been CENTRE, GERMANY.
found in several locations as a secondary mineral deposit
within the study area [27-28]. In this study, we consider that
the existence of this mineral which is probably related with
Sokoto cement mining site upstream of Kalambaina formation
in the village of Katere, Gatere, near Wamako [29]. The
spatial variation of the core-drilled values of Katere site 1,
Gatere site 2 and Quarry Kalambaina site 3 in soil profile
shown in (Fig. 9, 10 & 11). The core values of soils from
Katere site 1, representing the higher level of soil thickness,
ranged from (1.6 − 3.55 ) across the study area. Low
enhancement of overburden thickness of (0.9 − 3.05 ) in
Quarry Kalambaina site 3, could be reported to the process of
soil formation in the area of study. Spatial variation plot of TABLE 2. MINERAL COMPOSITION OF SOILS SAMPLES
(Fig. 10) revealed the slight increase in alluvium overburden ANALYSIS BY XRD OF SITE 2, HEIDELBERG TECHNOLOGY
CENTRE, GERMANY.
thickness (1.49 − 2.76 ) in its surface horizon and steeply
decrease from upper horizon (0.57 − 1.9 ), thus suggesting
to contribution of anthropogenic origin. The clay fraction of
the analysed soils is characterized by a rather uniform clay
mineral assemblage. The XRD analysis shows that silicates
mineral (average 28.90 %), kaolinite (average 1.5 %), calcite
(average 38 %) and irregular Hematite-magnetite mixed
layers (average 6.82 %) and Calcium carbonate
(average 69.26 %) are the major clay mineral groups
identified. These results are similar to the clay mineral suite
observed in the quarry site of Sokoto cement company [2]. No
significant correlations are found between clay mineralogy
and the magnetic data. Correlations between R index
(calculated for the main clay minerals) and the magnetic TABLE 3. MINERAL COMPOSITION OF SOILS SAMPLES
ANALYSIS BY XRD OF SITE 3, HEIDELBERG TECHNOLOGY
parameters show significant correlation between core drilling
CENTRE, GERMANY.
depth (R calculated for limestone layer) and Overburden
thickness (the correlation is negative but significant at the
8.43 level), between magnetic susceptibility distribution
parameters (R calculated for Aluminium oxide . These
correlations are significant at < 0.05 level (Table 2).
Correlations between R index and heavy metals show
significant correlation between core drill and Concentration
content, and between content (correlations are
significant at 0.05 level and at 0.01 level, respectively) (Table TABLE 4(a). CORE DRILL LOG DATA OF SOILS OF SITE 1,
1). The degree of crystallinity has an important bearing on the HEIDELBERG TECHNOLOGY CENTRE, GERMANY.

scavenging of heavy metals by secondary minerals (such as

clay minerals, sulfites, sulphates oxides and hydroxides) as
poorly crystallized minerals are more efficient sorbents than
crystalline ones. In particular, maghemite crystallochemical
characteristics show good correlations with the distribution of
some metals, pointing to a role of this mineral (in particular,
under specific crystallochemical conditions) in their fixation.
Actually, the order/disorder degree of their crystallographic
structures and the type of octahedral composition ( rich

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TABLE 4(b). CORE DRILL LOG DATA OF SOILS OF SITE 2,

HEIDELBERG TECHNOLOGY CENTRE, GERMANY. Quarry Kalambaina_Core
Drilled Log, Site 3
4

Thickness (m)
2
0
1 2 3
Sample Core Drilling

TABLE 4(c). CORE DRILL LOG DATA OF SOILS OF SITE 3,

HEIDELBERG TECHNOLOGY CENTRE, GERMANY. Fig. 11 Spatial distribution of Core-drilled log of Site 3 in
Quarry Kalambaina.

VI. CONCLUSION
Spatial variation of magnetic susceptibility shows a
characteristic distribution with higher values near the quarry
of Northern Sokoto Cement. Near the quarry, these values are
associated with ferromagnetic material produced by industrial
pollution. The analysis of in-situ magnetic susceptibility
distribution acquisition spatial plot suggests that the main
magnetic phases present in the samples are ferrimagnetic
Katere_Core Drilled Log, Site 1 structures (e.g. magnetite/maghemite). Results obtained
demonstrated that magnetic susceptibility distribution has a
4 good correlation with heavy metals so this parameter can be
Thickness (m)

3 used as a proxy for soil pollution; however, remanent

2 magnetic parameters are better indicators for heavy metal
1 pollutions than magnetic susceptibility in studied area [30].
0 The results of XRD analyses show that the most abundant
1 2 3 4 5 6 7 8 9
minerals are Hematite, Manganese, Lead oxide, plagioclases,
calcite and dolomite. They also confirm the presence of
Sample Core Drilling magnetite/maghemite although with a concentration generally
below 2 %. Some samples shown traces of calcium carbonate.
The new calculated index, R, showed good correlation with
Fig. 9 Spatial distribution of Core-drilled log of Site 1in magnetic parameters and with and contents. This
Katere Kalambaina. study revealed that magnetic mapping is a sensitive, fast and
robust method, which can be advantageously applied to
regions affected by urban and industrial pollution.
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