Chemistry-Deeban S

Q-1.
Calculate γ (ratio of Cp and Cv ) (ratio of Cp and Cv )  for triatomic linear gas at high temperature. Assume that the
contribution of vibrational degree of freedom is 75 % :
Subject: ChemistryAnswering Pace:Overtime
Your Answer:B)

1.121

Correct Answer:C)

1.18

Marks: 0/4

Your Pace:1 Min 54 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-2.

If one mole each of a monatomic and diatomic gases are mixed at low temperature then C p /Cv ratio for the mixture
is:

Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)

1.40

Correct Answer:C)

1.5

Marks: 0/4

Your Pace:1 Min 54 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-3.

If one mole of a mono-atomic gas (γ =5/3) is mixed with one mole of a diatomic gas (γ = 7/5), the value of γ for the
mixture is:

Subject: ChemistryAnswering Pace:Overtime
Your Answer:C)

1.53

Correct Answer:B)

1.5

Marks: 0/4

Your Pace:1 Min 54 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-4.

Out of internal energy (I), boiling point (II), pH (III) and E.M.F of the cell (IV) intensive properties are:

Subject: ChemistryAnswering Pace:Overtime
Your Answer:B)

II, III, IV

Marks: 4/4

Your Pace:1 Min 54 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-5.

Which has maximum internal energy at 290 K?

Subject: ChemistryAnswering Pace:Too Fast

Your Answer:B)

Nitrogen gas

Correct Answer:C)

Ozone gas

Marks: 0/4

Your Pace:44 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-6.

A 10 g piece of iron (C = 0.45 J/g °C) at 100°C is dropped into 25 g of water (C = 4.2 J/g °C) at 27°C. Find temperature of
the iron and water system at thermal equilibrium.

Subject: ChemistryAnswering Pace:NA
Correct Answer:A)

30°C

Marks: 0/4

Your Pace:NA | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-7.
One mole of an ideal gas at 25°C expands in volume from 1.0 L to 4.0L at constant temperature. What work (in J) is
done if the gas expands against vacuum (Pexternal=0)(Pexternal=0)?
Subject: ChemistryAnswering Pace:Overtime
Your Answer:D)

Zero
Marks: 4/4

Your Pace:1 Min 54 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-8.

At 25°C, a 0.01 mole sample of a gas is compressed from 4.0 L to 1.0 L at constant temperature. What is the work done
for this process if the external pressure is 4.0 bar? 

Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)
1.6×103J1.6×103J

Correct Answer:D)
1.2×103J1.2×103J

Marks: 0/4

Your Pace:1 Min 54 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-9.
If w1,w2,w3w1,w2,w3 andw4w4 for an ideal gas are magnitude of work done in isothermal, adiabatic, isobaric and
isochoric reversible expansion processes, the correct order will be:
Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)
w1>w2>w3>w4w1>w2>w3>w4

Correct Answer:D)
w3>w1>w2>w4w3>w1>w2>w4
Marks: 0/4

Your Pace:2 Min 2 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-10.
During an adiabatic process, the pressure of gas is found to be proportional to the cube of its absolute temperature.
The ratio of (Cp,m/Cv,m)(Cp,m/Cv,m) for gas is:
Subject: ChemistryAnswering Pace:NA
Correct Answer:A)
3232

Marks: 0/4

Your Pace:NA | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-11.
For the reaction:PCl5(g)→PCl3(g)+Cl2(g):PCl5(g)→PCl3(g)+Cl2(g):
Subject: ChemistryAnswering Pace:Too Fast
Your Answer:B)

∆H > ∆U

Marks: 4/4

Your Pace:40 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-12.
For the real gases reaction 2CO(g)+O2(g)→2CO2(g);ΔH=−560kJ2CO(g)+O2(g)→2CO2(g);ΔH=−560kJ. In 10 litre rigid
vessel at 500 K the initial pressure is 70 bar and after the reaction it becomes 40 bar. The change in internal energy is:
Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)

–557 kJ

Correct Answer:B)

–530 kJ

Marks: 0/4

Your Pace:2 Min 2 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-13.
Predict which of the following reaction(s) has a negative entropy change? I.CH4(g)+2O2(g)→CO2(g)
+2H2O(l)I.CH4(g)+2O2(g)→CO2(g)+2H2O(l) II.NH3(g)+HCl(g)→NH4Cl(s)II.NH3(g)+HCl(g)→NH4Cl(s)  III.2KClO4
(s)→2KClO3(s)+O2(g)III.2KClO4(s)→2KClO3(s)+O2(g)
Subject: ChemistryAnswering Pace:Overtime
Your Answer:C)

I and II

Correct Answer:B)

II

Marks: 0/4

Your Pace:2 Min 9 Sec | Topic:Second Law of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-14.

Mechanical work is specially important in systems that contain

Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)

gas – liquid

Marks: 4/4

Your Pace:2 Min 4 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-15.
Determine which of the following reactions taking place at constant pressure represents system that do work on the
surrounding environment I. Ag+(aq)+Cl−(aq)AgCl(s)Ag+(aq)+Cl−(aq)AgCl(s)  II. NH4Cl(s)NH3(g)
+HCl(g)NH4Cl(s)NH3(g)+HCl(g) III. 2NH3(g)N2(g)+3H2(g)2NH3(g)N2(g)+3H2(g)
Subject: ChemistryAnswering Pace:NA
Correct Answer:C)
II and III

Marks: 0/4

Your Pace:NA | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Easy
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Q-16.

The temperature of the calorimeter is increased by 6.12 K when 1 gm sample of NH 4NO3 is decomposed in a bomb
calorimeter. If The heat capacity of the system is 1.23 kJ/g/K. Calculate the molar heat of decomposition for NH 4NO3.

Subject: ChemistryAnswering Pace:Too Fast

Your Answer:A)

398.1 kJ/mol

Correct Answer:C)

602 kJ/mol

Marks: 0/4

Your Pace:18 Sec | Topic:Calorimetry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-17.

The heats of combustion of carbon and carbon monoxide are – 393.5 and – 285.5 kJ mol–1,respectively. The heat of
formation (in kJ) of carbon monoxide per mole is :

Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)

– 108

Marks: 4/4

Your Pace:2 Min 51 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-18.

A student is calculating the work during a reversible isothermal process, shown by 2 moles of an ideal gas. He by
mistake calculated the area as shown in the PV graph (Shaded area) equal to 49.26 litre atm. Calculate the correct
value of work (in litre atm) during the process.

(Given : R = 0.0821 litre atm/mol/K)

Subject: ChemistryAnswering Pace:Overtime
Your Answer:D)

–98.52

Correct Answer:B)

–34.14

Marks: 0/4

Your Pace:3 Min 33 Sec | Topic:First Law of Thermodynamics and Concept of Work | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-19.
Determine ΔU° at 300 K for the following reaction using the listed enthalpies of reaction: 4CO(g)+8H2(g)→3CH4(g)
+CO2(g)+2H2O(l)C(graphite)+1/2O2(g)→CO(g);ΔH1∘=−110.5kJCO(g)+1/2O2(g)→CO2(g);ΔH∘2=−282.9kJH2(g)
+1/2O2(g)→H2O(l);ΔH3∘=−285.8kJC(graphite)+2H2(g)→CH4(g);ΔH4∘=−74.8kJ4CO(g)+8H2(g)→3CH4(g)+CO2(g)
+2H2O(l)C(graphite)+1/2O2(g)→CO(g);ΔH1∘=−110.5kJCO(g)+1/2O2(g)→CO2(g);ΔH2∘=−282.9kJH2(g)
+1/2O2(g)→H2O(l);ΔH3∘=−285.8kJC(graphite)+2H2(g)→CH4(g);ΔH4∘=−74.8kJ
Subject: ChemistryAnswering Pace:Overtime
Your Answer:C)

–747.4 kJ

Correct Answer:D)

None of these

Marks: 0/4

Your Pace:2 Min 42 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-20.
Calculate ΔfH∘ΔfH∘ (in kJ/mol) for Cr2O3Cr2O3 from the ΔrGcΔrGc and the S° values provided at 27°C 4Cr(s)
+3O2(g)→2Cr2O3(s);ΔrG∘=−2093.4kJ/molS∘(J/Kmol):S∘(Cr,s)=24;S∘(O2,g)=205;S∘(Cr2O3,s)=814Cr(s)
+3O2(g)→2Cr2O3(s);ΔrG∘=−2093.4kJ/molS∘(J/Kmol):S∘(Cr,s)=24;S∘(O2,g)=205;S∘(Cr2O3,s)=81
Subject: ChemistryAnswering Pace:Ideal Time
Your Answer:A)

–2258.1 kJ/mol

Correct Answer:B)
–1129.05 kJ/mol

Marks: 0/4

Your Pace:1 Min 23 Sec | Topic:Third Law of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-21.
Calculate the heat produced (in kJ) when 224 gm of CaO is completely converted to CaCO3CaCO3by reaction
with CO2CO2 at 27°C  in a container of fixed volume.
Given: ΔH∘f(CaCO3,s)=−1207kJ/mol;ΔH∘f(CaO,s)=−635kJ/molΔHf∘(CaCO3,s)=−1207kJ/mol;ΔHf∘(CaO,s)=−635kJ/mol 
ΔH∘f(CO2,g)=−394kJ/mol;[UseR=8.3JK−1mol−1]ΔHf∘(CO2,g)=−394kJ/mol;[UseR=8.3JK−1mol−1]
Subject: ChemistryAnswering Pace:Overtime
Your Answer:A)

702.04 kJ

Marks: 4/4

Your Pace:1 Min 53 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-22.
When 1.0 g of oxalic acid (H2C2O4)(H2C2O4)is burned in a bomb calorimeter whose heat capacity is 8.75 kJ/K, the
temperature increases by 0.312K. The enthalpy of combustion of oxalic acid at 27°C:
Subject: ChemistryAnswering Pace:Ideal Time
Your Answer:B)

–244.452 kJ/mol

Correct Answer:D)

None of these

Marks: 0/4

Your Pace:1 Min 4 Sec | Topic:Calorimetry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-23.
Enthalpy of neutralization of H3PO3H3PO3 acid is –106.68 kJ/mol using NaOH. Enthalpy of neutralization of HCl by
NaOH is –55.84 kJ/mol. Calculate ΔHionizationΔHionization of H3PO3H3PO3 into its ions:  
Subject: ChemistryAnswering Pace:Overtime
Your Answer:B)

5 kJ/mol

Marks: 4/4

Your Pace:4 Min 7 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-24.
If enthalpy of hydrogenation of C6H6C6H6(l) into C6H12C6H12 (l) is – 205 kJ/mol and resonance energy
of C6H6C6H6 (l) is – 152 kJ/mol then enthalpy of hydrogenation of is
Assume ΔHvapofC6H6(l),C6H8(l),C6H12(l)ΔHvapofC6H6(l),C6H8(l),C6H12(l) all are equal:
Subject: ChemistryAnswering Pace:Too Fast
Your Answer:C)

–357 kJ/mol

Correct Answer:D)

–119 kJ/mol

Marks: 0/4

Your Pace:28 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-25.
The enthalpy of combustion of propane (C3H8)(C3H8)gas in terms of given data is : Bond energy
(kJ/mol) εC−H+x1εC−H+x1  εO=O+x2εO=O+x2  εC=O+x3εC=O+x3 εO−H+x4εO−H+x4 εC−Cx5εC−Cx5 Resonance
energy of CO2CO2 is –z kJ/mol and ΔHvaporization[H2O(l)]ΔHvaporization[H2O(l)] is y (kJ/mol)
Subject: ChemistryAnswering Pace:Ideal Time
Your Answer:A)
8x1+2x5+5x2−6x3−8x4−4y−3z8x1+2x5+5x2−6x3−8x4−4y−3z

Marks: 4/4

Your Pace:1 Min 21 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Medium
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Q-26.
At 5×1055×105 bar pressure density of diamond and graphite are 3g/cc and 2g/cc respectively, at certain
temperature ‘T’. Find the value of ∆U – ∆H for the conversion of 1 mole of graphite to 1 mole of diamond at
temperature ‘T’:
Subject: ChemistryAnswering Pace:Overtime
Your Answer:B)

50 kJ/mol

Correct Answer:A)

100 kJ/mol

Marks: 0/4

Your Pace:1 Min 49 Sec | Topic:Fundamentals of Thermodynamics | Chapter:Thermodynamics

Difficulty Level: Difficult
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Q-27.
From given following equations and ΔH° values, determine the enthalpy of reaction at 298 K for the
reaction: C2H4(g)+6F2(g)→2CF4(g)+4HF(g)C2H4(g)+6F2(g)→2CF4(g)+4HF(g) H2(g)
+F2(g)→2HF(g);ΔH∘1=−537kJH2(g)+F2(g)→2HF(g);ΔH1∘=−537kJ C(s)+2F2(g)→CF4(g);ΔH∘2=−680kJC(s)
+2F2(g)→CF4(g);ΔH2∘=−680kJ 2C(s)+2H2(g)→C2H4(g);ΔH∘3=52kJ2C(s)+2H2(g)→C2H4(g);ΔH3∘=52kJ
Subject: ChemistryAnswering Pace:Overtime
Your Answer:B)

–2486

Marks: 4/4

Your Pace:8 Min 6 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Difficult
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Q-28.
The standard enthalpy of formation of gaseous H2OH2O at 298 K is –241.82 kJ/mol. Calculate ΔH° at 393 K given the
following values of the molar heat capacities at constant
pressure: H2O(g)=33.58JK−1mol−1;H2(g)=29.84JK−1mol−1;O2(g)=29.37JK−1mol−1H2O(g)=33.58JK−1mol−1;H2(
g)=29.84JK−1mol−1;O2(g)=29.37JK−1mol−1 Assume that the heat capacities are independent of temperature:
Subject: ChemistryAnswering Pace:Too Fast
Your Answer:B)

–485.2 kJ/mol

Correct Answer:A)

–242.6 kJ/mol

Marks: 0/4

Your Pace:27 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Difficult
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Q-29.

The enthalpies of neutralization of a weak base AOH and a strong base BOH by HCl are –12250 cal/mol and –13000
cal/mol respectively. When one mole of HCl is added to a solution containing 1 mole of AOH and 1 mole of BOH, the
enthalpy change was –12500 cal/mol. In what ratio is the acid distribution between AOH and BOH?

Subject: ChemistryAnswering Pace:Too Fast

Your Answer:B)

2:3

Correct Answer:A)

2:1

Marks: 0/4

Your Pace:57 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Difficult
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Q-30.
Determine C – C and C – H bond enthalpy (in kJ/mol)
Given,ΔfH∘(C2H6,g)=−85kJ/mol,ΔfH∘(C3H8,g)=−104kJ/molΔfH∘(C2H6,g)=−85kJ/mol,ΔfH∘(C3H8,g)=−104kJ/mol Δsu
bH∘(C,s)=718kJ/mol B.E.(H−H)=436kJ/molΔsubH∘(C,s)=718kJ/mol B.E.(H−H)=436kJ/mol
Subject: ChemistryAnswering Pace:Overtime
Your Answer:B)

345, 414

Marks: 4/4

Your Pace:4 Min 27 Sec | Topic:Thermochemistry | Chapter:Thermodynamics

Difficulty Level: Difficult
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