Alkalinity Control
Alkalinity Control
Alkalinity Control
1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses advised against: This product is not recommended for any industrial, professional or consumer
use other than the Intended Uses above.
Company/undertaking identification
Supplier/Manufacturer:
e-mail: mail@marichem-marigases.com
Emergency Information:
Inside U.S. and Canada: (800)-424-9300 (CHEMTREC)
Outside U.S. and Canada: 1-703-527-3887 (CHEMTREC)
National Emergency Centre (Greece): ++30 210 7793777
1
2. HAZARDS IDENTIFICATION
Hazard Statement(s):
H314 Causes severe skin burns and eye damage.
SYMBOL:
Hazard Statement(s):
H314 Causes severe skin burns and eye damage.
Precautionary Statement(s):
Prevention:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
Response:
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P363 Wash contaminated clothing before re-use.
2
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see First Aid Measures on Safety Data Sheet).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do.
Continue rinsing.
P391 Collect spillage.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
The mixture does not meet the criteria for PBT or vPvB in accordance with Annex XIII of
1907/2006/EC.
Symbol: C, Corrosive
C, Corrosive
Risk Phrases
Safety Phrases
3
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition:
*
See section 16 for the full text of the Hazard Code(s) declared above.
4.1.1. In case of inhalation: Move to fresh air. Oxygen or artificial respiration if needed. Victim to
lie down in the recovery position, cover and keep him warm. Call a physician immediately.
4.1.2. In case of skin contact: Take off contaminated clothing and shoes immediately. Wash off
immediately with plenty of water. Keep warm and in a quiet place. Call a physician or poison control
centre immediately. Wash contaminated clothing before re-use.
4.1.3. In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. In the case of difficulty of opening the lids, administer an analgesic eye wash
(oxybuprocaine). Call a physician or poison control centre immediately. Take victim immediately to
hospital.
4.1.4. In case of ingestion: Call a physician or poison control centre immediately. Take victim
immediately to hospital. If swallowed, rinse mouth with water (only if the person is conscious). Do
NOT induce vomiting.
4.1.5. Information to physician: Fresh air, rest. Half-upright position. Artificial respiration may be
needed. Refer for medical attention.
4.2. Most important symptoms and effects, both acute and delayed:
Corrosive. The substance is very corrosive to the eyes, the skin and the respiratory tract. Corrosive
on ingestion. Inhalation of an aerosol of the substance may cause lung oedema. Repeated or
prolonged contact with skin may cause dermatitis.
4.3. Indication of any immediate medical attention and special treatment needed:
The symptoms of lung oedema often do not become manifest until a few hours have passed and they
are aggravated by physical effort. Rest and medical observation are therefore essential.
4
5. FIRE-FIGHTING MEASURES
The product is not flammable. Not combustible. Reacts violently with water. Gives off hydrogen by
reaction with metals. With light metal (aluminium, magnesium), zinc, led reacts releasing hydrogen,
which may form explosive mixture with air, in this case sodium hydroxide must be diluted with
plenty of water.
Should not be released into the environment. Do not flush into surface water or sanitary sewer
system. If the product contaminates rivers and lakes or drains inform respective authorities.
Spilled material shall be covered with suitable absorbing material, e.g. dry soil or sand and the
collected material shall be transported in a closed container into a safe depository for disposal. Keep
in properly labelled containers. Keep in suitable, closed containers for disposal. Treat recovered
material as described in the section "Disposal considerations”.
5
7. HANDLING AND STORAGE
Do not taste or swallow. Avoid contact with skin and avoid breathing vapor/mist. Do not eat, drink
or smoke in work area. Do not get in eyes, on skin, on clothing. When diluting, always add the
product to water. Never add water to the product. Avoid prolonged or repeated exposure. Any
protective clothing or shoes which become contaminated should be removed immediately and
thoroughly laundered before reuse.
Use only equipment and materials which are compatible with the product. Keep away from
incompatible products. Preferably transfer by pump or gravity.
Store in original pail or drum. Store in closed, properly labeled pails or drums. Keep in a well-
ventilated place. Keep in a dry place. Do not remove or deface labels or tags. Aluminum equipment
should not be used for storage and transfer.
Keep container closed. Keep away from incompatible products.
Packaging material
Suitable material:
Stainless steel, polyethylene, paper+PE
Unsuitable material:
No data available.
6
8.1. Control parameters
Substance name: Sodium hydroxide
Workers:
Acute / short-term (dermal, inhalation – local and systemic effects)/
Long term (dermal – local and systemic effects, inhalation – systemic effects):
The focus is the occurrence of local effects after acute and repeated exposure at those places where
Sodium Hydroxide is produced and/or used. This is because Sodium Hydroxide is not expected to
become systemically available in the body under normal handling and use conditions.
DNEL long-term inhalation=1.0 mg/m³ (local effects)
General population:
Acute / short-term (dermal, inhalation, oral – systemic effects; dermal, inhalation - local)/
Long term (dermal, inhalation, oral – systemic effects; dermal - local effects):
As sodium hydroxide is not expected to become systemically available in the body under normal
handling and use conditions, the focus is on possible risks from acute exposure (local effects).
DNEL long-term inhalation=1.0 mg/m³ (local effects)
PNEC aqua (freshwater, marine water, intermittent releases, STP): The toxicity of sodium hydroxide
-
can be ascribed to the pH increase due to the addition of hydroxide ion (OH ) as the sodium
concentrations are too low to explain the effects observed in acute toxicity studies. A generic PNEC
cannot be derived from single-species toxicity data for sodium hydroxide, as the pH of natural waters
as well as the buffer capacity of natural waters show considerable differences and aquatic
organisms/ecosystems are adapted to these specific natural conditions, resulting in different pH
optima and pH ranges that are tolerated.
PNEC (sediment (freshwater/marine water), soil): The high water solubility and very low vapour
pressure indicate that sodium hydroxide will be found predominantly in water. In water (including
+
soil or sediment pore water), sodium hydroxide is present as the sodium ion (Na ) and hydroxide ion
-
(OH ), as solid Sodium Hydroxide rapidly dissolves and subsequently dissociates in water.
PNEC oral: According to the EU RAR (2007) bioaccumulation in organisms is not relevant for
sodium hydroxide.
7
8.2. Exposure controls
Hand protection
Impervious gloves. Suitable material: PVC, Neoprene, Natural Rubber, butyl-rubber.
Unsuitable material: Leather.
9.1.1. Appearance
8
Color: Colorless
Odor: Odorless
pH: 13
Surface tension: Not applicable. According to the REACH Regulation, the study need only be
conducted if based on structure, surface activity is expected or can be predicted. In addition, surface
activity is not a desired property of the mixture (Annex VII, column 2 adaptation).
Granulometry: Not applicable.
Stability in organic solvents and identity of relevant degradation products: Not applicable.
According to the REACH Regulation, the study does not need to be conducted if the substance is
inorganic (Annex IX, column 2 adaptation).
Dissociation constant: Not applicable. According to the REACH Regulation, the study does not
need to be conducted if the substance is hydrolytically unstable (half-life less than 12 hours) (Annex
IX, column 2 adaptation). Alcaclean HD dissociates completely in water.
Additional physico-chemical information: Alcaclean HD is a strong alkaline substance that
+
dissociates completely in water into the sodium ion (Na ) and hydroxide ion (OH-). The
dissolution/dissociation in water is strongly exothermic, so a vigorous reaction occurs when
Alcaclean HD is added to water.
10.1. Reactivity
Potential for exothermic hazard. May be corrosive to metals.
9
Gives off hydrogen by reaction with metals. Exothermic reaction with strong acids. Risk of violent
reaction. Risk of explosion. Reacts violently with water.
Respiratory sensitization
3
Not classified. Exposure concentrations up to 1 mg/m were not considered adverse with regard to
local effects to the respiratory tract.
Skin sensitization
Not classified. Existing data do not demonstrate that Sodium Hydroxide is a skin sensitizer.
Human Not sensitizing.
Mutagenicity
Not classified. Both in vitro and in vivo genetic toxicity tests indicated no evidence for a mutagenic
activity. Furthermore Sodium Hydroxide is not expected to be systemically available in the body
10
under normal handling and use conditions and for this reason additional testing is considered
unnecessary.
Carcinogenicity
Not classified. Sodium Hydroxide did not induce carcinogenicity in in vitro and in vivo studies. No
studies were identified carcinogenicity. Product components are not listed on the IARC, NTP or
OSHA carcinogens lists.
Reproductive toxicity
Not classified. Sodium Hydroxide is not expected to be systemically available in the body under
normal handling and use conditions and for this reason it can be stated that the substance will not
reach the foetus nor reach male and female reproductive organs. It can be concluded that a specific
study to determine the developmental toxicity or the toxicity to reproduction is not necessary.
STOT-single exposure
Not classified.
STOT-repeated exposure
Not classified. No reliable studies are available for oral, inhalation and dermal repeated dose toxicity.
Aspiration hazard
Not classified.
Toxicokinetics
Sodium Hydroxide is not expected to be systemically available in the body under normal handling
and use conditions.
12.1. Toxicity
11
Toxicity to microorganisms: Data waiving.
Data waiving. The high water solubility and very low vapour pressure indicate that Sodium
Hydroxide will be found predominantly in water. In water (including soil or sediment pore water),
+ -
Sodium Hydroxide is present as the sodium ion (Na ) and hydroxide ion (OH ). If emitted to surface
water, sorption to particulate matter and sediment will be negligible and so it will not accumulate in
living tissues.
Summary of degradation
+
Abiotic degradation: NaOH is a strong alkaline substance that dissociates completely in water to Na
-
and OH . High water solubility and low vapour pressure indicate that NaOH will be found
predominantly in aquatic environment. This implies that it will not adsorb on particulate matter or
surfaces.
Biotic degradation: According to the REACH Regulation, the study does not need to be conducted if
the substance is inorganic (Annex VII, Column 2 adaption).
Data waiving. According to the REACH Regulation, the study does not need to be conducted if the
substance has a low potential for bioaccumulation (Annex IX, column 2 adaptation). The high water
solubility and very low vapour pressure indicate that Sodium Hydroxide will be found predominantly
in water. According to the EU RAR bioaccumulation in organisms is not relevant for Sodium
Hydroxide.
Adsorption/desorption: Data waiving. According to the REACH Regulation, the study does not
need to be conducted if based on the physical chemical properties the substance can be expected to
12
have a low potential for adsorption (Annex VIII, column 2 adaptation). The high water solubility and
very low vapour pressure indicate that Sodium Hydroxide will be found predominantly in water. In
+
water (including soil or sediment pore water), Sodium Hydroxide is present as the sodium ion (Na )
-
and hydroxide ion (OH ). If emitted to surface water, sorption to particulate matter and sediment will
be negligible.
Sodium Hydroxide does not fulfil the criteria for persistency, bioaccumulation and toxicity.
Therefore, Sodium Hydroxide is not considered a PBT or vPvB substance.
The product is not harmful to the marine environment as per paragraphs 1.7.4 and 1.7.5. of
Resolution MEPC. 219 (63) /Annex 24 - 2012 adoption of IMO’s MARPOL Annex V.
Do not emit directly to drains, environment. Substances with high pH value shall be neutralized prior
to discharge. It is to be diluted with plenty of water following careful neutralization with acidic
solution.
Product: The unnecessary untreated product shall be considered as hazardous waste. The generated
waste shall be treated by specialized companies in disposing in line with the local regulations and
with the hazardous waste regulations. Recovered solids or liquids may be sent to a licensed reclaimer
or disposed of in a permitted waste management facility. Consult federal, state or local disposal
authorities for approved procedures.
Packing: The uncleaned packing/container shall be handled in the same way as the product. The
packaging material may be reused after cleaning.
UN number: 1824
ADR class: 8 RID class: 8
13
14.3 SEA TRANSPORT
UN number: 1824
IATA/ICAO class: 8 Packing group: II
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture.
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
A CSA has been carried out for the raw materials in this product, from the raw materials
manufacturers (when needed to be carried out).
14
EC: European Commission.
EC50: Half maximal effective concentration.
EINECS: European Inventory of Existing Commercial Chemical Substances.
ELINCS: European List of Notified Chemical Substances.
EmS: Emergency Schedule.
ERC: Environmental Release Category.
ES: Exposure scenario.
food: oral feed.
GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
Irrit.: Irritation.
LC50: Lethal concentration, 50 %.
LD50: Median Lethal dose.
LOAEC: Lowest Observed Adverse Effect Concentration.
LOAEL: Lowest Observed Adverse Effect Level.
MK value: Maximum Concentration value.
NCO: An international corporation that provides customer service contracting.
NOAEC: No Observed Adverse Effect Concentration.
NOAEL: No Observed Adverse Effect Level.
NOEC: No Observed Effect Concentration.
OECD: Organisation for Economic Cooperation and Development.
PBT: Persistent, Bioaccumulative and Toxic.
PNEC: Predicted No Effect Concentration.
PROC: Process category.
REACH: The Registration, Evaluation, Authorisation and Restriction of Chemicals.
Resp.: Respiratory.
Sens.: Sensitization.
STEL value: Short Term Exposure Limit value.
STOT RE: Specific target organ toxicity — repeated exposure.
STOT SE: Specific target organ toxicity — single exposure.
STOT: Specific Target Organ Toxicity.
STP: Sewage Treatment Plant.
SU: Sector of use.
Tox.: Toxicity.
TWA value: Time Weighted Average value.
vPvB: Very Persistent and Very Bioaccumulative.
All information, instructions and statements contained in this Material Safety Data Sheet are
compiled in accordance with European Directives, corresponding national legislation and on the
basis of information given by our suppliers.
The information disclosed in this Material Safety Data Sheet (which supersedes all previous
versions) is believed to be correct, at the date of issue, to the best of our current knowledge and
experience. It only relates to the specific product designated herein and it may not be valid when said
product is used in combination with any other products or in any processed form, unless specified in
the text. This document aims to provide the necessary health and safety information of the product
and is not to be considered a warranty or quality specification. It is the responsibility of the recipient
of this Material Safety Data Sheet to ensure that information given here is read and understood by all
who use, handle, dispose of or in any way come in contact with the product.
Also, it is the responsibility of the user to comply with local legislation relating to safety, health,
environment and waste management. Data and information provided concerning the product are
informative, exclusively presented to the customer.
15