Haas Technical Documentation

Safety Data Sheet

Haas Liquid Grease

Product Number: 93-2196A Revision Date: 06/27/2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier: Haas Liquid Grease

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use See Technical Data Sheet.

1.3. Details of the supplier of the safety data sheet

Manufacturer:
Haas Automation Inc
2800 Sturgis Road
Oxnard, CA 93030
Telephone Number: (805) 278-1800

1.4. Emergency telephone number

(800) 331-6746 24hr

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Not Classified

2.2. Label elements

Using the Toxicity Data listed in section 11 & 12 the product is labeled as follows.

Not Classified
HMIS Health: 0 NFPA Health: 0
Fire: 1 Fire: 1

Physical Hazards: 0 Reactivity: 0

PPE: C Special Hazards: --

2.3. Other hazards

This product contains no PBT/vPvB chemicals.

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SECTION 3: Composition/information on ingredients

EC No. 1272/2008 / GHS

Ingredient/Chemical Designations Weight % Classification

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, Not Classified

zinc salts CAS <3
Number: 0068649-42-3

*The full texts of the phrases are shown in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General
In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.

Inhalation
If inhaled, remove person to fresh air and keep comfortable for breathing. If breathing has
stopped, give artificial respiration. If breathing is difficult, give oxygen. If unconscious, place
in the recovery position and seek medical attention immediately.

Skin
In case of contact, immediately rinse skin with plenty of water. Remove contaminated
clothing and shoes. If skin irritation occurs, seek medical attention. Launder contaminated
clothing before reuse.

Eye
In case of contact, immediately rinse eyes with plenty of fresh, clean water for at least 15
minutes. Remove contact lenses if present and continue rinsing. Seek medical attention
immediately.

Ingestion
Do not induce vomiting. Call a physician or emergency medical facility immediately.

4.2. Most important symptoms and effects, both acute and delayed
No data available

4.3. Indication of any immediate medical attention and special treatment needed No data
Available

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Use Carbon dioxide (CO2), dry chemical, or foam to extinguish flames.

5.2. Special hazards arising from the substance or mixture Hazardous

Decomposition Products: May form CO and CO2.

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5.3. Advice for fire-fighters

Self-contained full-face positive pressure breathing apparatus (SCBA) should be used. Water
can be used to cool and protect exposed material. Do not allow runoff water and
contaminants from firefighting to enter drains or water courses.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with spilled material. Use suitable personal protective equipment. Ventilate
area if spilled in confined space or other poorly ventilated areas. Evacuate personnel to safe
areas. Keep unnecessary personnel away.

6.2. Environmental precautions

Prevent entry into sewers and waterways. Report spills as required to appropriate authorities
in accordance with all applicable regulations.

6.3. Methods and material for containment and cleaning up

Ventilate the area and avoid breathing vapors. Take the personal protective measures listed
in section 8.

Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite.
Place in closed containers outside buildings and dispose of according to the Waste
Regulations. (See section 13).

Clean, preferably with a detergent. Do not use solvents.

Do not allow spills to enter drains or water courses.
If drains, sewers, streams or lakes are contaminated, inform the local water company
immediately. In the case of contamination of rivers, streams or lakes the Environmental
Protection Agency should also be informed.

Dispose of in accordance with all federal, state, and local environmental regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Handling
Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing vapor. Use with
adequate ventilation.

In Storage
Keep this container and vapors from the container away from heat and flame. Keep
container closed and maintain all original markings and labels.

7.2. Conditions for safe storage, including any incompatibilities.

Keep away from strong oxidizing and reducing agents.

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CAUTION!!! Do not use cutting or welding torches on drums, even when empty. Do not
reuse container.

Containers, even those that have been emptied will retain product residue and vapors.
Always obey hazard warnings and handle empty containers as if they were full.

7.3. Specific end use(s)

There are no exposure scenarios, see details in section 1.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

The following occupational exposure limits have been established.

CAS Number Ingredient Source Value

No Established Limit
OSHA
Phosphorodithioic acid,
O,O-diC1- No Established Limit
0068649-42-3 ACGIH
14-alkyl esters, zinc
salts No Established Limit
NIOSH

Carcinogen Data

Value
CAS No. Ingredient Source
Select Carcinogen: No
OSHA
Phosphorodithioic acid,
Group 1: No; Group 2A: No;
0068649-42-3 O,O-di-C1-14-alkyl
Group 2B: No;
esters, zinc salts IARC
Group 3: No; Group 4: No;

DNEL/PNEC values
No Data Available

8.2. Exposure controls

No special requirements under ordinary conditions of use and with adequate ventilation.

Eye/face protection
Wear safety glasses. If potential for splash or mist exists, wear chemical goggles or face
shield.

Skin protection
Wear chemical resistant gloves. Gloves should be inspected before each use and discarded
if they show tears, pinholes, or signs of wear.

Other
Gloves, overalls, apron, boots, or other suitable protective garments should be worn to
minimize contact based on the task being performed.

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Respiratory protection
Use NIOSH/OSHA approved respirator where high vapor concentrations are present.

Thermal hazards
No Data Available

SECTION 9: Physical and chemical properties

Appearance PURPLE OILY LIQUID

Odor Petroleum Odor
Odor threshold Not Determined pH Not Determined
Melting point / freezing point (C) Not Determined
Initial boiling point and boiling range (C) Not Measured
Flash point (C) > 200
Evaporation rate (H20 = 1) Not Determined
Flammability (solid, gas) Not Applicable

Upper/lower flammability or explosive limits

Lower Explosive Limit: Not Determined

Upper Explosive Limit: Not Determined

Vapor pressure (Pa) Not Determined

Vapor density Heavier than air.
Relative density 1.00
Solubility(ies) negligible
Partition coefficient n-octanol/water (Log Kow) Not Determined
Auto-ignition temperature (C) Not Determined
Decomposition temperature Not Determined

Viscosity (cSt)
@ 100 C Not Measured
@ 40 C Not Measured

Pour point temperature (C) Not Determined

SADT Not Determined

The data listed above are typical physical and chemical properties that do not constitute
product specification.

9.2. Other information

No other relevant information.

SECTION 10: Stability and reactivity

10.1. Reactivity
No data available

10.2. Chemical stability

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Material is normally stable at ambient temperature and pressure.

10.3. Possibility of hazardous reactions May react with: oxidizing agents.

10.4. Conditions to avoid

High temperature, sparks, and open flames.

10.5. Incompatible materials

Keep away from strong oxidizing and reducing agents.

10.6. Hazardous decomposition products

Hazardous Decomposition Products: May form CO and CO2.

SECTION 11: Toxicological information

INFORMATION ON TOXICOLOGICAL EFFECTS

Hazard Class Conclusion / Remarks

Inhalation
Acute Toxicity: No end point data for material. Minimally Toxic: Based on assessment of the
components.
Irritation: No end point data for material. Negligible hazard at ambient/normal handling
temperatures.
Ingestion
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the
components.
Skin
Acute Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the
components.
Skin Corrosion/Irritation: No end point data for Negligible irritation to skin at ambient temperatures.
material. Based on assessment of the components.
Eye
Serious Eye Damage/Irritation: No end point data for May cause mild, short-lasting discomfort to eyes.
material. Based on assessment of the components.
Sensitization
Respiratory Sensitization: No end point data for Not expected to be a respiratory sensitizer.
material.
Skin Sensitization: No end point data for material. Not expected to be a skin sensitizer. Based on
assessment of the components.
Aspiration: Data available. Not expected to be an aspiration hazard. Based on
physico-chemical properties of the material.
Germ Cell Mutagenicity: No end point data for Not expected to be a germ cell mutagen. Based on
material. assessment of the components.
Carcinogenicity: No end point data for material. Not expected to cause cancer. Based on
assessment of components.
Reproductive Toxicity: No end point data for Not expected to be a reproductive toxicant. Based on
material. assessment of the components.
Lactation: No end point data for material. Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for material. Not expected cause organ damage from a single
exposure.
Repeated Exposure: No end point data for material. Not expected to cause organ damage from
prolonged or repeated exposure. Based on
assessment of the components.

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Other Information

Contains:
Synthetic base oils: Not expected to cause significant health effects under conditions of
normal use, based on laboratory studies with the same or similar materials. Not mutagenic
or genotoxic. Not sensitizing in test animals and humans.

The following ingredients are cited on the lists below: None.

--Regulatory Lists Searched--
1=NTP CARC 3=IARC 1 5=IARC 2B
2=NTP SUS 4=IARC 2A 6= OSHA CARC

SECTION 12: Ecological information

The information given is based on data available for the material, the components of the
material, and similar materials.

ECOTOXICITY

Material – Not expected to be harmful to aquatic organisms.

Material –Not expected to demonstrate chronic toxicity to aquatic organisms.

MOBILITY

Base oil components –Low solubility and floats and is expected to migrate from water
to the land. Expected to partition to sediment and wastewater solids.

ECOLOGICAL DATA

Test Duration Organism Type Test Results

Aquatic – Acute 96 Hour (s) Oncorhynchus LL50 1003 mg/L:
Toxicity mykiss data for similar
materials
Aquatic – Chronic 21 day (s) Daphnia magna NOELR 1 mg/l:
Toxicity data for similar
materials

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Consult federal, state and local regulations regarding disposal methods, recycle used oil. Do
not contaminate used oil with solvents or other chemicals.

SECTION 14: Transport information

14.1. UN number Not applicable

14.2. UN proper shipping name Not regulated

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14.3. Transport hazard class(es)
US DOT Label Not regulated
ADR/RID Not regulated
IMDG Not regulated
Sub Class Not applicable

14.4. Packing group Not applicable

14.5. Environmental hazards

ADR/RID Environmentally Hazardous: No - Not regulated
IMDG Marine Pollutant: No - Not regulated

14.6. Special precautions for user

No further information

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not
Applicable

The above transport information is provided to assist in the proper classification of this
product and may not be suitable for all shipping conditions. Shipping description may vary
based on mode of transport, quantities, temperature of the material, package size, and/or
origin and destination. For information specific to your situation, consult your company's
Hazardous Materials/Dangerous Goods expert.

SECTION 15: Regulatory information

OSHA HAZARD COMMUNICATION STANDARD: This material is not considered

hazardous in accordance with OSHA HazCom 2012, 29 CFR 1910.1200

Listed or exempt from listing/ notification on the following chemical inventories: TSCA
Special Cases:

Inventory Status
AICS Restrictions Apply

PRODUCT REGISTRATION STATUS: USA

EPCRA SECTION 302: This material contains no extremely hazardous substances.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to
the supplier notification requirements of the SARA 313 Toxic Release Program.

The following ingredients are cited on the listed below:

Chemical Name CAS Number List Citations

PHENOL, 118-82-1 5

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4,4-METHYLENEBIS (2,6-
BIS (1,1-DIMETHYLETHYL)

--REGULATORY LISTS SEARCHED—

1= ACGIH ALL 6= TSCA 5a2 11= CA P65 REPRO 16= MN RTK
2= ACGIH A1 7= TSCA 5e 12= CA RTK 17= NJ RTK
3= ACGIH A2 8= TSCA 6 13= IL RTK 18= PA RTK
4= OSHA Z 9= TSCA 12b 14= LA RTK 19= RI RTK
5= TSCA 4 10= CA P65 CARC 15= MI 293

Code Key: CARC = Carcinogen; REPRO = Reproductive

SECTION 16: Other information

This information has been compiled from sources considered to be dependable and is
accurate to the best of Haas Automation Inc. knowledge. Haas Automation Inc. makes no
warranty whatsoever, expressed or implied, of MERCHANTABILITY OR FITNESS FOR THE
PARTICULAR PURPOSE, regarding the accuracy of such data or the results to be obtained
from the use thereof. Haas Automation Inc. assumes no responsibility for injury to recipient
or third persons, or for any damage to any property and recipient assumes all such risks.

The full text of the phrases appearing in section 3 is:

End of document

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