Niax* Urethane Additives Guide

Europe, Middle East, Africa & India

 A Leader in Urethane Additives
Momentive Performance Materials Inc. (Momentive) offers one of the
most trusted and diverse urethane additive (UA) product lines in the
industry, ranging from a broad array of silicone stabilizers to a full
portfolio of amine and metal based catalysts to a selection of organic-
based property modifiers.
Developed in 1962, Niax* brand additives are essential ingredients
in polyurethane formulations used to meet customers’ specialized
processing and performance needs globally. Niax grades include
a comprehensive line of silicones, catalysts and process modifiers
for polyurethane foam production. Momentive also offers Geolite*
modifiers to help flexible slabstock foam producers broaden their
offering of foam grades.
Momentive is a pioneer in the polyurethanes market and continues
to serve customers with leading innovations, creative solutions and
excellent application expertise.

2 *Niax and Geolite are trademarks of Momentive Performance Materials Inc.

Flexible Slabstock Foam

Niax* Silicones
High Resilience
Conventional Foam Polyester Foam VE
Foam

No added Nonylphenolethoxylate
Low Emission for general use

Low VOC/Low Fogging

Combustion Modified
Hydrolytic Stability
CO2 Blown Foam
Wide Processing

General Purpose

General Purpose

Cell Sturucture
Cell Opening
High Density
FR Property

FR Property
MDI Foam
Efficiency

Niax Silicones Product Description, Potential Applications

and Typical Benefits
L-570 H • High potency silicone for low density foam
L-594Plus M • Medium potency silicone for improved skin
L-580 M • • Silicone for low density formulations
L-590 • M • • Wide processing latitude for all conventional foams
L-595 M • Medium-high efficiency silicone for improved foam yield
Low viscosity, medium-high efficiency silicone for
L-595LV M •
improved foam yield
L-620 • H • Very high efficiency with wide latitude for conventional and FR
L-650 • M • • Silicone for liquid CO2 FR formulations, separate metering
L-618 • M • Wide processing FR silicone with medium efficiency
L-680 M • • FR silicone, can be considered for use in activators
L-670 • M Silicone for natural based polyol foams
L-690 H • • FR silicone, can be considered for use in activators
Standard silicone for continuous and discontinuous
SC-240 M • •
slabstock productions
Wide processing latitude, moderate efficiency for medium
L-598 • L •
to high density conventional foam
Low emission. Wide processing FR silicone with medium
L-818 • M • •
efficiency
Low emission. Wide processing FR silicone with medium
L-820 • H • •
efficiency
L-895 H • • Low emission. High efficiency silicone for improved foam yield
Low emission, wide processing medium efficiency
L-2112 • • • • •
Universal HR silicone
Low emission cell regulating additive for Viscoelastic MDI
L-500 • • • • •
foams. Can improve dimensional stability of HR/CMHR foams
L-2100 • • General Purpose silicone for HR Foam
L-2171 • • HR Silicone for PHD and SAN systems
SE-232 • • R General purpose silicone
L-530 • • R Universal ester silicone
L-537XF • • • F Universal ester silicone with fine cells and open cells
Low emission silicone for gasketing and sealing foam
L-636LE •
application
L-626 • Specialty silicone for visco-elastic foams
L-627 • Low viscosity specialty silicone for viscoelastic foams
L-629LE • Low emission cell opening silicone for visco elastic foam
L-417 • Low emission silicone for viscoelastic MDI foam
L-422 • Low emission silicone for supersoft, open cell MDI foam

VE = visco-elastic foam, VOC = volatile organic compound, FR = flame retardant, HR = high resilience
M = medium, H = high, L = low, R = regular, C = coarse, F = fine

*Niax is a trademark of Momentive Performance Materials Inc. 3

 Flexible Slabstock Foam

Niax* Catalysts
Conventional Foam High Resilience Foam Polyester Foam

Low Emissions

Low Emissions

Low Emissions
Stabilising
Balanced

Balanced

Balanced
Blow

Blow

Blow
Gel

Gel

Gel
Niax Catalysts Product Description, Potential Applications and
Typical Benefits
A-1 • • High efficiency blowing catalyst
A-133 • • Dilution of A-1 for easy metering
Balanced catalyst, optimum for square blocks, Flat
B-4 •
top or Maxfoam system
Balanced catalyst, with longer cream time for
B-18 • •
Maxfoam process
A-33 • • Gel catalyst
SA-200 • Stabilising amine for low density foams
EF-600 • • • • • Low emission gel catalyst, can reduce foam smell
EF-700 • • • • • • Low emission blow catalyst, can reduce foam smell
Low emission balanced catalyst for automotive
EF-867 • •
applications, can reduce foam smell
C-131NPF • • Blowing catalyst for low fogging polyester foam
KST-100NPF • • Balanced catalyst for low fogging polyester foam
Sn Octoate • • Stannous Octoate
D-50 • • Blowing catalyst with low DMF content

Geolite* Modifiers Typical Features

GM-206 Additive for soft foam grades at 90-100 TDI index with safe processing
Processing aid additive, can promote the production of quality foam with critical formulations,
GM-91
reduces properties gradients
Niax* Processing Additive Typical Features
DP-1022 Processing aid additive, can improve mechanical properties in filled foams and high resilience foams
Color Stabilizer CS-15 Antioxidant for low density polyether foam
Color Stabilizer CS-16 Antioxidant for polyether foam with improved UV yellowing properties
Color Stabilizer CS-22 LF Antioxidant improving light stability and enhancing flame lamination properties
Flame Lamination Additive FLE-200LF Additive for flame-laminable foam with improved bonding properties
Flame Lamination Additive FLE-500LF Low emission additive for flame lamination foam for improved bonding
Color Stabilizer CS-20LF Cost performing additive for flame lamination ether foam
Foam Hardener FH-300 Additive to enhance foam hardness - can increase tensile, elongation and tear strength
Foam Hardener FH-400 Additive to enhance foam hardness - can be blended into polyether polyol
DCF Additive to improve clickability and foam recovery after compression in polyester foam
SC-200 Additive for polyether sea sponge foam

4 *Niax is a trademark of Momentive Performance Materials Inc.

Molded Foam

Niax* Silicones

TDI / MDI

HR MDI
HR TDI

Niax Silicones Product Description, Potential Applications and Typical Benefits

L-3001 • • High cell opening silicone
L-3111 • • High cell opening silicone
L-3415 • Low emission silicone with high cell opening
L-3418 • Low emission silicone with high cell opening and finer cells
L-3002 • • Medium cell opening silicone
L-3222 • • Medium cell opening silicone
L-3416 • • Low emission silicone with medium cell opening
Very low emission, medium potency silicone providing good stabilization along with good
L-3639 • •
foam openness
L-3003 • • Stabilizing silicone
L-3417 • • Low emission; stabilizing silicone
L-2171 (Y-10366) • • • High efficiency; balanced silicone
L-3620 • Low potency, low emission silicone for TDI/MDI technology
L-3630 • Medium efficiency, low emission silicone for TDI/MDI technology
L-3636 • • Very low fogging, medium potency surfactant for TM80 technology
L-3640 • • High efficiency, low emission silicone for TDI/MDI technology
L-3170 • High efficiency balanced silicone
L-3360 • High efficiency balanced silicone
L-3350 • High stability silicone
L-3555 • High stability, low emission silicone
L-3556S • Low emission, medium potency, water soluble silicone
L-3558 • • Very low emission, medium - high potency silicone for TDI
L-3151 • • High efficiency; balanced silicone an excellent candidate to consider for TDI/MDI blends
L-3167 • • Cell regulator; co-silicone surfactant for TDI
L-5309J • High efficiency balanced silicone
L-3184 • High efficiency balanced silicone

TDI/MDI = typically 80/20 blend / TDI = toluene diisocyanate / MDI = Methylene diphenyl diisocyanate

*Niax is a trademark of Momentive Performance Materials Inc. 5

 Molded Foam

Niax* Catalysts

Balanced Amine Catalyst

Blow Amine Catalyst

Gel Amine Catalyst

Niax Catalysts Product Description, Potential Applications and Typical Benefits

A-1 • Standard blow catalyst
A-107 • Delayed action blow catalyst
A-400 • Delayed action load building (TDI); cell opening blow catalyst; improved flowability (MDI)
A-440 • Delayed action load building (TDI); cell opening blow catalyst; improved flowability (MDI)
A-4 • Catalyst for improved surface cure
C-174 • HR MDI blow catalyst
B-26 • HR MDI delayed action blow catalyst
C-225 • Delayed action catalyst; enhanced curing
A-310 • Balanced potentially cost-effective catalyst; may enhance skin cure (MDI & MDI/TDI)
A-337 • Surface curing catalyst; low mold temperature (MDI & MDI/TDI)
A-300 • Delayed action load building; cell opening gel catalyst (low corrosion)
A-33 • Key gel catalyst
Low Emission Catalyst Product Description, Potential Applications and Typical Benefits
EF-600 • • Balanced catalyst; predominantly gel
EF-602 • • Balanced delayed catalyst; predominantly gel
EF-680 • • Balanced delayed catalyst; predominantly gel can deliver improved end curing
EF-700 • • Balanced catalyst; predominantly blow
EF-705 • • Balanced cell opening delayed catalyst; predominantly blow
EF-708 • • Balanced catalyst; predominantly blow

HR = High resilience

6 *Niax is a trademark of Momentive Performance Materials Inc.

Rigid Foams

Niax* Silicones

Foam Flow / Density

Pentane solubility

Cell Stabilization
Blowing agents

Void Reduction
FR Properties
emulsification

Distribution

(DIN 4102)
Fine Cells

in Polyols

Niax Silicone Product Description, Potential Applications and Typical Benefits

High polyol/blowing agent compatibility and low lambda combined with excellent flow and
L-6895 •••• •••• •• ••• •••• •• •••• reduced voids formation, also in fast reactive systems, for refrigerators, water heaters and all
discontinuous applications
High polyol/pentane solubility - very low lambda value foam and voids reduction, for
L-6891 •••• ••• •• •••• ••• •• ••••
discontinuous applications especially refrigerators
Best polyol/pentane solubility - can provide very fine cells for discontinuous applications
L-6887 •••• •••• •• •••• ••• •• •••
especially refrigerators
Can improve polyol/pentane or HFC's compatibility - can provide very fine cells and good
L-6884 •••• ••• •• •••• ••• •• •••
flow, for refrigerators and all discontinuous applications
For pentane blown refrigerators and dis-continuous panels to reduce surface voids
L-6866 •••• •• •• •••• ••• •• ••••
formation, while still delivering excellent lambda value
Very fine cells with pentane and HFO/HC, increase froth shear stability thus reducing voids
L-6988 •••• •• ••• •••• ••• •• •••
formation, good storage stability in acidic condition
Strong emulsifier, fine cells with all blowing agents - continuous and discontinuous
L-6900 •••• •• •••• •••• •••• •• •••
applications
For Cyclopentane/HFO co-blown appliances and discontinuous panels systems, it delivers
L-6978 •••• •• ••• ••• •••• •• ••••
very fine cells and low K factor and good foam surface
Very high polyol-pentane solubility for best blend stability, good flow and
L-6889 ••• •••• ••• •••• •••• •• •••
void reduction
Low k-factor combined with excellent acid resistance and good flow, for pentane and HFO/
Y-16130 •••• ••• ••• ••• •••• •• ••••
HC blowing agents
For HCFC but also HFC's and pentane co-blown with water, good flow and dimensional
SR-321 •• •••• •• •••• ••• ••• •
stability
Combination of strong nucleation and emulsification, can resolve compatibility problems and
L-6620 •••• •• ••• •• ••• •• •••
reduce defects due to irregular mixing. Suitable also as co-silicone to improve nucleation.
Reduce foam voids formation in continuous and discontinuous application - effect increase
L-6630 •• • •• •• •••• •• •••
with higher usage level
Can reduce voids formation and excellent polyol compatibility efficiency can increase with
L-6633 ••• ••• ••• ••• ••• •• •••
usage level
Premium grade silicone to reduce foam voids and achieve excellent surface quality in metal
L-6635 •• • • •• ••• •• ••••
faced panels PUR and PIR
High performance voids reduction silicone for steel faced sandwich panels with improved
L-6638 •• •• •• •• ••• •• ••••
polyol compatibility
Balanced stabilizer with good voids control and flow for both continuous and discontinuous
L-6642 ••• •• •• •• •••• •• •••
process , suitable for all blowing agents included formic acid and HFOs
Can produce foams with good dimensional stability and improved fire properties, good liquid
L-6100 •• •• •• ••• ••• •••• ••
flow and leveling

HFC = Hydro Fluoro Carbon, HCFC = Hydro Chloro Fluoro Carbon, HFO = Hydroflouoro Olefin, PIR = Polyisocyanurate, PUR = Polyurethane,
Features: Strong = ••••, Moderate = •, FR properties = Fire Rating

*Niax is a trademark of Momentive Performance Materials Inc. 7

 Rigid Foams

Niax* Silicones

Foam Flow / Density

Pentane solubility

Cell Stabilization
Blowing agents

Void Reduction
FR Properties
emulsification

Distribution

(DIN 4102)
Fine Cells

in Polyols

Niax Silicone Product Description, Potential Applications and Typical Benefits

Improves dimensional stability and FR for spray and panels application with various
L-6265 •• ••• ••• ••• •• •••• ••
water/co-blown technologies
For boardstock fine cells with pentane blowing agents - for PIR/PUR boardstock
L-5111 •••• • ••• • ••• •• ••
lamination
For boardstock, improves mixing quality and emulsification of pentane up to high
L-5112 •••• •• •••• •• ••• •• •••
usage level. Improves foam quality and reduces laydown defects
For boardstock, strong nucleation and emulsification power, for n- and iso-
L-5162 •••• •• ••• ••• ••• •• •••
pentane and less compatible raw materials
For PIR boardstock, better processing on high speed lines. Better edge stability,
L-5158 ••• • ••• •• •••• •• ••••
reduced surface defects, reduce emulsion viscosity, increase liquid flow
For boardstock, strong nucleation and stabilization can reduce surface voids when
L-5466 •••• •• ••• ••• ••• •• ••••
using gas-tight facings, help compatibility with APP's
1K/OCF foam, good emulsification also for structural foam, blocks and phenolic
L-5345 •• •• •••• • ••• •• ••
foams
1K/OCF foam, also manufactured without HFC, high froth volume, good
L-5348 •• • ••• •• ••• • ••
compatibilization, excellent storage stability
L-5350 ••• • •••• • •• •• •• 1K/OCF foams. Multipurpose stabilizer mainly for straw foam applications
1K/OCF foam - can improve foaming at low temperature and is manufactured
L-5351 ••• • •••• • ••• •• ••
without HFC
L-5360 ••• • •••• • •• •• ••• 1K/OCF foams. High yield in gun foams allowing high propellant levels to be used
1K/OCF foams, good dimensional stability over a wide range of temperatures. PIR
L-5362 ••• • •••• • •• •• •••
boardstock and blocks, fine cells and improved side compressions
Recommended solution for low density foams like open cells spray, packaging and
L-5388 ••• ••• ••• •• •• •••
OCF. Wide compatibility with polyethers and polyesters, strong foam stabilization
L-6164 •• •• •• ••• Cell-opener, cell-regulator - very efficient cell opener, OCF/1K and 2K systems
L-6186 Open cells rigid foam - also efficient in overpacked conditions and high index -
•• •• • •• •••
L-6188 polyether and polyester based, density range 15-200 g/l
Low density Open cells rigid foams, polyethers or polyesters based, mainly water
L-6189 •••• ••• •• •• ••• •••
blown, fine and regular cells structure, good polyol solubility

1K/OCF = 1 Component foam, HFC = Hydro Fluoro Carbon, PIR = Polyisocyanurate, PUR = Polyurethane, APP = Aromatic Polyester Polyols,
Features: Strong = ••••, Moderate = •

8 *Niax is a trademark of Momentive Performance Materials Inc.

Rigid Foam - Formulation Recommendation Guidelines

Relative Scale of Niax* Silicone Contribution to Blowing Agent

Solubility in Rigid Foam System Applications

Fully soluble, pentane blown, high level

Fully soluble, low pentane level, HFO, Coblown

SR-321, L-6889
Mainly separate metering/emulsion
Y-16130, L-6891, L-6884,
L-6895, L-6887
L-6620, L-6633,
L-6900,L-6988
L-6642, L-6978

L-6638

L-6635, L-6630

Low High
Blowing agent solubilty

Niax* Catalysts for Rigid Foams Applications

Blow Gel

Niax
Niax Niax Niax Niax Niax
Pot.
A-1/A-99 C-5 C-8 A-33 C-41
Acetate

Niax Niax Niax Niax Niax Niax

C-10 DMEE PM-20plus C-27 K-ZERO MC-810
Strength

Niax Niax Niax Niax Niax Niax

DMDEE C-520 DMEA BDMA C-31 MC-710

Niax Niax
A-107 A-300

Reactive amines Best shelf life with HFO-1233zd Trimerization activity

*Niax is a trademark of Momentive Performance Materials Inc. 9

 Rigid Foams

Niax* Catalysts and Special Additives

PUR continuous lamination and block

PIR continuous lamination and block

Water blown PUR and PIR foam

PUR / PIR discontinuous block

Packaging, open cells foam

PIR discontinuous panels
PUR discontinuous

Spray

Niax Catalysts Product Description, Potential Applications and Typical Benefits

Very effective blowing catalyst, promote selectively water-NCO reactions, can improve foam
A-1 • • • • • • • •
flow and rate of expansion
C-5 • • • • General purpose blowing catalyst
C-8 • • • • • • • General purpose PUR catalyst
PM-40 • • • Blowing catalyst based on A-1, moderate odor and viscosity and may be used with direct metering
Dimethylbenzylamine, weak gel catalyst, can reduce surface friability and can improve foam
BDMA • • • • • • •
adhesion in particular with mainly water-blown foams
DMEA • • • • Moderate odour, typically cost-effective, reactive catalyst
Moderate odour, typically cost-effective, reactive catalyst, more blowing efficiency compared
DMEE • • • •
to DMEA
Moderate activity blow catalyst, excellent storage stability also in isocyanate and
DMDEE • • • • •
prepolymers, 1K/OCF foams
Blow-gel catalyst for direct in line metering in the continuous lamination of PUR or for PIR in
PM20 plus • • • •
combination with a potassium catalyst
C-27 • • • • • • • Low odor catalyst offering improved shelf life for water co-blown systems
Delayed action catalyst for PIR and PUR, improve green strength and surface curing, reduce
C-31 • • • • •
post expansion in thick panels
Strong gel catalyst promoting both PUR and PIR reaction, promote fast crosslinking, can
C-41 • • • • •
reduce demould time and improve foam adhesion
A-107 • • • Acid blocked delayed action blow catalyst
Blowing catalyst formulated for safer handling, it enables an easier balancing of the full
C-520 • •
catalysts package in PIR continuous production
Reactive amine catalyst, ideal for spray and open-cell applications. Blowing catalyst giving a
C-10 • • • • • •
smooth reaction profile, good candidate also in flexible moulded foams
Low viscosity potassium octoate to facilitate in-line metering in continuous lines. Provides
PO-10 • • •
crosslinking and cure, maintaining a smooth rise profile and an improved liquid flow.
15% K containing PIR catalyst for direct metering (2500 cPs), also good as general purpose
Potassium Octoate LV • • •
curing catalyst in PUR
Potassium Octoate • • • 15% K containing PIR catalyst, also good as general purpose curing catalyst in PUR
K-ZERO G • • • • • • • 15% Potassium content, glycol free catalyst, reduce MDI use and improve isotropy in PIR
Low viscosity (600 mPas) glycol-free Potassium octoate, to facilitate in-line metering and
K-ZERO LV • • • • • • •
reduce MDI use
Potassium Acetate • • • • 15% K containing PIR catalyst
MC-710/MC-810 • • Bismuth based catalysts, exhibiting strong gel catalytic activity.

Niax Special Additives Product Description, Potential Applications and Typical Benefits
Can speed up foam hardening and adhesion without influencing gel time, in particular for PIR
RA-1 • • •
foam made with aromatic polyester polyols
Adhesion promoter additives, reduce surface friability in high water and/or high index
AP-01 • • • • •
formulations
FRP • • • • • • • • Halogen free additives to improve fire properties in both PUR or PIR foams

NCO = Isocyanate, PU = Polyurethane, 1K/OCF = 1 Component foam, HFC = Hydro Fluoro Carbon, PIR = Polyisocyanurate,
PUR = Polyurethane, APP = Aromatic Polyester Polyols

10 *Niax is a trademark of Momentive Performance Materials Inc.

Polyurethane Coatings, Adhesives, Sealants and Elastomers (CASE)

Niax* Silicone and Modifiers

Microcellular (Polyether)

Microcellular (Polyester)

PU Leather/Coatings
Integral Skin Foam
SRIM/Composite

Niax Silicones Mechanical Froth Product Description, Potential Applications and Typical Benefits
L-1500 • • • Standard surfactant for microcellular systems
L-1501 • • Wide-processing latitude with excellent open cell for low-medium density systems
L-1507 • • For low-density polyester or polyether-based microcellular systems with excellent emulsification
L-1541 • • For high-density polyester-based microcellular systems with thick skin and SRIM applications
L-1510 • • • General purpose surfactant for polyether shoe sole and rigid foam systems, low freezing point
L-5302 • • • Medium stabilizing surfactant developed for integral skin and high-density polyether-based microcellular systems
Low surface tension silicone for Dry process PU Leather Coating, stable in pH 4-10, provides excellent
L-1128 •
wetting, leveling and dispersion
Cell stabilizer for wet process PU leather, provides good deposition, increases thickness, speeds up DMF
L-1131 •
and water exchange
L-1151 • Industry standard, provides uniform medium cell structure in wet process PU leather
Linear reactive silicone, enhance anti-sticking property, good solubility in PU system. Improves leveling in
L-1160 •
coating application
L-1169 • Linear reactive silicone, enhance anti-sticking property, good leveling, and silky hand feeling
L-5614 • Industry-standard surfactant for the mechanically frothed foam process
L-5617 • Zero VOC surfactant analog of L-5614 used in the mechanically frothed foam processes
A low VOC mechanical froth surfactant, non-hydrolysable, provides high closed cell content while reducing
L-5639 •
both froth density and shear induced cell collapse
Co-surfactant that enhances froth stability and reduce foam density when used with standard mechanical
L-5690 •
froth surfactants

Niax Catalysts
4=more
1=less
Microcellular/Shoe Sole

PU Leather/Coatings

Urethane Selectivity
Integral Skin Foam

Hydrolytic Stability
SRIM/Composite

Spray Elastomer

Urea Selectivity

Curing Speed
Elastomers

Pot Life

Niax Catalysts Product Description, Potential Applications and Typical Benefits

A-100 • • • • • • TEDA Crystals • 1 4 4
A-400 • • • Delayed-action, blowing-selective catalyst for open-mold pouring applications • 2 3 4
A-440 • • • Delayed-action, blowing-selective amine catalyst developed for microcellular foams • 2 2 4
A-533 • • • • • • Industry-standard TEDA catalyst in (mono)ethylene glycol • 1 4 4
A-525 • • • • • • Industry-standard TEDA catalyst in BDO • 1 4 4
A-534 • • • • • Delayed action, improve flow, demold and mechanical properties • 3 2 4
A-535 • • • Delayed-action gel catalyst for microcellular/SRIM/PUL applications • 3 3 4
A-537 • • • • Delayed-action TEDA-based catalyst for open-mold pouring applications • 3 2 4
A-575 • • • • DBU based Temperature-activated, delayed-action, powerful, gelling-selective catalyst • 3 2 4
A-577 • • • Delayed-action, powerful, gelling-selective catalyst • 3 2 4
MC-710/
• • • • • Tin free metal based catalysts, strong gelling, can replace DBTDL • 1 4 2
MC-810
LC-5635 • • Heat activated catalyst Sn/Hg/Ni free. • 4 1 2
LC-5636 • • • Heat activated catalyst Sn/Hg/Ni free. Lower activation temperature compared to LC-5635 • 3 2 2

*Niax is a trademark of Momentive Performance Materials Inc. 11

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*Niax, Geolite, Momentive and the Momentive logo are trademarks of Momentive Performance Materials Inc.

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