If 25 J are required to change the temperature of 5.0 g of substance A by 2.

0 degrees Celsius,
what is the specific heat of substance A?
-2.5 J/g. C

What happens to the internal energy of the system if work is done on the system?
-Internal energy will increase

The standard enthalpy of formation for a simple substance in its most stable state must be
non-zero
-False

If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees

Celsius, what is the specific heat of substance B?
-1.76 J/g. C

___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy
change for the reaction is the sum of all changes.
-Hess's Law

Which of the following is true for a chemical reaction at equilibrium?

-The rates of the forward and reverse reactions are equal

The standard free energy is found to be zero. What is its equilibrium constant?
-1

Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from
graphite and oxygen:
C(s) + O2(g) → CO2(g)
Standard Entropy in J/mol.K for: C= 5.740 O2 = 205.14 CO2=213.74
-2.86 J/mol.K

The equilibrium constant for the reaction is 10. What will be the value of ΔG?
--5744J

Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.
-ΔS < 0

In thermodynamics, an ___process is a type of thermodynamic process in which the

pressure P of a system remains constant.
-Isobaric

A photochemical reaction is one of the examples of non-spontaneous reaction.

-True

The increased in internal energy of the system is 80 J and has 70 J of work done on it. What
is the heat change of the system?
-+10 J

What kind of thermodynamic system is coffee held in a cup?

-Open system

A chemical equilibrium may be established by starting a reaction with __________

-All the above

The ____ of a substance is the amount of energy required to raise the temperature of 1 gram
of the substance by 1 degree Celsius.
-Specific heat
____ constant tells how far the reaction has proceeded once the equilibrium is reached.
-Equilibrium

Total change in energy is equal to the sum of the heat and work transferred between the
systems and surroundings.
-First Law of Thermodynamics

A system suffers an increase in internal energy of 80 J and at the same time has 50 J of
work done on it. What is the heat change of the system?
-+30 J

An isometric process, is a thermodynamic process during which the volume of the closed
system undergoing such a process remains constant.
-True

Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum

from 45 to 65 degrees Celsius. Molar heat capacity of aluminum is 24 J/mole.K.
-1.44 KJ

Which one of the following thermodynamic quantities is not a state function?

-Work

Freezing and condensation are examples of exothermic process.

-True

Reactions in which the products can react to form back the reactants are said to be ___.
-Reversible

Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298
K.
--0.45 kJ

Non-spontaneous processes are those that do not take place by themselves or is a type of
reaction which cannot occur without the input of work from an external source.
-True

The higher the number of types of molecules, the higher is the degree of disorder.
-True

If ΔG is positive, the reaction is spontaneous in the reverse direction.

-True

Chemical equilibrium is described as a dynamic process because there is a movement in

which the forward and reverse reactions occur at the same rate to reach a point where the
amounts or concentrations of the reactants and products are unchanging with time.
-True

If the reaction quotient Q has a smaller value than the related equilibrium constant, K,
__________
-The reaction is not at equilibrium, and will make more products at the expense of reactants.

The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of 1
cm³ of water by one degree Celsius.
-Calorie

In exothermic reaction, heat is liberated into the surroundings.

-True
In thermodynamics, an ___process, also called a constant-volume process.
-Isochoric

___ is the state at which the concentration ratio of products to reactants is observed to be
constant.
-Equilibrium

In thermodynamics, an ___process is a type of thermodynamic process in which the

temperature T of a system remains constant.
-Isothermal

The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at
a certain temperature.
H2(g) + I2(s) ⇌ 2 HI(g) K = 45
Which of the following is true regarding this equilibrium?
I. The reaction is product favored.
II. The reaction is reactant favored.
III. Equilibrium lies to the right.
IV. Equilibrium lies to the left.
-I and III

The equation that relates enthalpy, temperature and entropy is

-Gibbs Free Energy

A reversible reaction has ΔG negative for forward reaction. What will be the sign for the
backward reaction?
-Positive(Wrong)
-Negative

If ΔG is 1, the system is at equilibrium.

-False

An equilibrium that strongly favors products has __________

-a value of K << 1.(Wrong)
-a value of K >> 1.

Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from
liquid at 10° C to vapor at 30° C.
-119kJ(Wrong)
-130kJ(Wrong)
-126kJ

The lower the concentration of the weak acid decreases the pH of the buffer solution.
-False

Spontaneous processes are those that can proceed with any outside intervention.
-False

Melting and vaporization are examples of exothermic process.

-False

Which phase of matter has the greatest motion and least orderly arrangement?
-Gas

What happens to the internal energy of the system if work is done by the system?
-Internal energy will increase(Wrong)
-Internal energy will decrease
Which of the following is true regarding the concentration of products, for a chemical
reaction that is already at equilibrium, assuming no disruptions to the equilibrium?
-The concentrations of products will not change because there are no more
reactants.(Wrong)
-The concentrations of products will change continually because of reversibility(Wrong)
-The concentrations of products will not change because the forward and reverse rates are
equal.

Predict the entropy change (ΔS) if the temperature of crystal is increased.

-ΔS will increase(Wrong)
-ΔS remains constant(Wrong)
-ΔS will decrease

Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a coffee
cup calorimeter and the temperature drops from 295 oC to 285 o C. Find the value of q for
the calorimeter.
(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)
--5430 J

A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of
methanol is 64.7 o C and the molar enthalpy of vaporization if 71.8 kJ/mol. The value of ΔS
when 2.15 mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.
-457