1. Name the following aromatic compounds. (drocarbons — Practice Sheet for Naming and Drawing Rules mexyl bencene elfhy| benzene, propyl bentene 2. Name the following aromatic compounds, 2 ON, NO2 b. a . Da ° ie . ya | é o | cy aH Hy | S- methyl = 3- -dinitobenzene’ te beowm -2- dnloco- 3,5 - ~disdty| \3,5- imethylloenzane 3. Name the following aromatic compounds using ortho-, “peta and para- prefixes, ; yoo cH cH, b, 7 Giecii-cH, 7 Cup ener, 1 a. 2 chy CH meta-ethyl methyl benzone ara lp 4. Drawa structural diagram for each aromatic compound. CHE CH, ortho - methyl propy| benzene | ropy! bent | a. 1-ethyl-3-methylbenzene ¢. Para-dichlorobenzene c-l cl ce (33 >. 2ethy-,4-dimethylbenzene 4. 15-dibrom@#?-choro-3-ethylbenzene ¢l 's Br or OnLy 6 a y 8 CAH, oh, 5. Draw and name three aromatic isomers with the molecular formula CiHse. cH ' ost \e * aa” CEN | So 1P wl", | — ots us “ ©) a cH Cty, ucla ta=Abgfteneie= WienCRyRateeons 1 Ticacaems ||Alkane Challenge There is something wrong with each of the following IUPAC names. Identify the error, draw the correct structural formula and write the correct IUPAC name for each substance. Incorrect Name. Correct Name Structural Formula 2-methyr4-ethyldecane 4-elbyl- ze methy| decane Cc 1 C- 6-6 - E+ CHC O-C-€-¢ a Smathyl-d-methyrhexane & Cc -7 1 3,4 dimethyl hexane a re T-ethyihexane 3 -ethyloctane- octane c-c -C-C-C- Oo v 4 &-ethyloctane GS € c 3,3-methyipentane 3- methy| hexane Cc i 3)3-A mekby| pentane cea © cf 2-propylbutane © 4 c-¢-c-C Printed September 14, 2014Alkanes Worksheet 1. Identify each carbon aera organic or inorganic, put a question mark beside it. e) @ d) HCN h) Caco; 2. Indicate whether each of the following statements is true or false. ore than 2) Thenumber of organic compounds exceeds the number of inorganic compound by a factor of about 2 Eb}. Chemists now believe thatPspecial “vital force” is needed to form an organic compound ACO) Historically, the org-of the term organic was conceptually paired with the org inthe term ving organism. =F 4). Most but not all compounds found in tving organism are organic compounds { €) Over 7 million organic compounds have been characterized. ae £1) The number of organic compounds and the numberof known inorganic compounds aré%pproximately the same. TT a) Inessence, organic chemistry is the study of the compounds of one element. (<>) “Th) Numerous organic compounds are known that do not occur in living organisms, 3, Identify the three properties of carbon that allow it to form such a great variety of compounds. (Why are there ‘s0 many more organic compounds than inorganic compounds?) 44. Indicate whether each of the following situations meet or do not meet the bonding requirements for carbon atoms. 3a}. Two single bonds and a double bond. Ye-S 4d) Adouble bond anda triple bond. No b) Asingle bond and two double bonds. No e) Two double bonds. yes ) Three single bonds and a triple bond. [J 7 5. Whatis the diference between a hydrocarbon and a hydrocarbon derivative? @ 4 \) | us another 6. Whats the difference between saturated andl ungaturated hydrocprbons? element or So ee eaten aR FR Race RES Ua RSE ssc hydrocarbon? ‘8 Compare the shape around a single-bonded carbon atom with the shape around a double-bonded and triple- bonded carbon atom, Use diagrams to illustrate your answer. 9. Draw the indicated type of formula for the following alkanes. | 'a) The expanded structural formula for a straight-chain alkane with the formula C:Hiz. b). The expanded structural formula for CHs— (CHa}e— CH c) The condensed structural formula, using parentheses for the — (CH;)— groups, for the straight-chain alkane CyoHz 4) The molecular formula for the alkane CHy~ (CH2}e~ CH. 10. What general condition must be met before two compounds can be isomers? 11. Explain why two alkanes with the molecular formulas CsHy, and CeHye could not be isomers. 12, The molecular formula of CeHy«has five isomers. Draw the complete, condensed, and line structural diagrams for each of these isomers, a. CoH, (4 isomers) b. C)Myg(9 isomers) 13. Heptane has 7 carbon atoms. What is the chemical formula of heptane? 14. Nonane has 9 carbon atoms. What is its chemical formula? 15. An alkane has 4 carbon atoms, How many hydrogen atoms does it have?16. Candle wax contains an alkane with 52 hydrogen atoms. How many carbon atoms does this alkane have? Antassa z Catonran > C= 2s 29 F Nme Gack Smpound: Gi a) Of GH — CHa Ch b) Ce C= Cs A methyl pepeny methyl butane a at CHS ffs ¢ chs— Gh dy — ub 8) CH= HE — Ge Ga | zs oy ane cH” CH Ineoran' geethyl sd arn oth Q)2, 4) 4- bebrametty | hy | @) Ch Gh — CH 6 — dy Fe ‘Hy, ) CHCl; ~ CH ~ Cy — CH=CH, — CH | 1 ie oH, hep Fae, cH i | 2,2) t-timethy [-4- “Beopy! heptan-e 18. Give the correct IUPAC name for the following alkanes: Ur a CHa cH; HCH, < | (a) ome, (b) a ab deol Hs 2,3-Alimevhy (pertan 45-dimethyl octane) | SHy-CH—CH, oh oy H CH, CH, GH, dsbi-di ico be | (0 \ pentane cH, cazch, So mee 5-ethyl -2,3-dimethy| heptane cis CH>CHs~ s-CH>-CH,, ‘y ous r gr Bada Sts de Gch, oH, oH, GH, Hs e ir Gt Clk Ol, | 350" Sel bihl~ ry B i yI- -ieinranen * bn, 35 ,6;¢ 2 4y2)4-timet yl heptane Guede fi ie CH odin on, | 7 Gh be GH, cH, 06H, eb - = 3- j bu, oo ey 3 methy honane, eh re ¢ o-hutyl-3,3,5-trimethi 4 propyl deze ené-b-c-c-c-e TE = re Stal 4 po idlecane, e-ck RE OLE 2 | 20. Identify any errors in the name af each,hydypcarbon, b) 2,4-diethyloctane a) 2,2,3-dimethylbutane eter ) S-methyl-4,5-diethyfnonane 212)3- trimathy! butane |