Nitocote Et402 Hardener

Revision date: 05/05/2020 Revision: 3 Supersedes date: 13/05/2015
SAFETY DATA SHEET

NITOCOTE ET402 HARDENER
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name NITOCOTE ET402 HARDENER
Product number A1765013AE1, A1765014AE1, A1765015AE1, A1765018AE1
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hardener component of two-part protective coating.
1.3. Details of the supplier of the safety data sheet

Supplier Al Gurg Fosroc LLC
PO Box 657
Dubai
United Arab Emirates
+ 971 4 2858606
1.4. Emergency telephone number

Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Muta. 1A - H340 Carc. 1B -
H350 Repr. 1A - H360
Environmental hazards Aquatic Chronic 3 - H412
Human health Contains a substance which may be potentially carcinogenic.
Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
2.2. Label elements
Hazard pictograms
Signal word Danger
1/15
Hazard statements H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H340 May cause genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.
Contains Pitch, coal tar, high-temp., TRIETHYLENETETRAMINE, O,O'-Bis(2-

aminopropyl)polypropyleneglycol, NONYLPHENOL
Supplementary precautionary P261 Avoid breathing vapour/ spray.

statements P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Pitch, coal tar, high-temp. 30-60%

CAS number: 65996-93-2 EC number: 266-028-2
M factor (Acute) = 1 M factor (Chronic) = 1
Classification
Muta. 1B - H340
Carc. 1A - H350
Repr. 1B - H360FD
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
TRIETHYLENETETRAMINE 5-10%
Classification
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
2/15
CREOSOTE OIL, ACENAPHTHENE FRACTION 1-5%

CAS number: 90640-84-9 EC number: 292-605-3 REACH registration number: 01-
2119548393-35-0000
O,O'-Bis(2-aminopropyl)polypropyleneglycol 1-5%
CAS number: 9046-10-0
Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Eye Dam. 1 - H318
ANTHRACENE OIL 1-5%

NONYLPHENOL 1-5%
M factor (Acute) = 1 M factor (Chronic) = 1
Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318
Repr. 2 - H361
Aquatic Acute 1 - H400
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Move affected person to fresh air and keep warm
and at rest in a position comfortable for breathing. Get medical attention if any discomfort
continues.
Ingestion Get medical attention immediately. Rinse mouth thoroughly with water. Move affected person
to fresh air and keep warm and at rest in a position comfortable for breathing. Do not induce
vomiting. Never give anything by mouth to an unconscious person. Do not induce vomiting.
Skin contact Remove affected person from source of contamination. Get medical attention promptly if
symptoms occur after washing.
Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information Get medical attention promptly if symptoms occur after washing.
Inhalation May cause irritation.
3/15
Ingestion May cause chemical burns in mouth and throat.
Skin contact May cause an allergic skin reaction. May cause skin irritation.
Eye contact May cause irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Foam. Carbon dioxide (CO2). Dry chemicals, sand,
dolomite etc.
5.2. Special hazards arising from the substance or mixture

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Nitrous gases (NOx). Acrid smoke or fumes.
5.3. Advice for firefighters

Protective actions during Cool containers exposed to flames with water until well after the fire is out.
firefighting
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions

Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate. Absorb small quantities with paper towels and evaporate in
a safe place. Flush spilled material into suitable retaining areas or container with large
quantities of water.
6.4. Reference to other sections

Reference to other sections See Section 12 for additional information on ecological hazards.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions Avoid spilling. Keep away from heat, sparks and open flame. Provide adequate ventilation.
Avoid inhalation of vapours. Use approved respirator if air contamination is above an
acceptable level.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.
Storage class Chemical storage.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
4/15
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Pitch, coal tar, high-temp. (CAS: 65996-93-2)
DMEL Workers - Inhalation; Long term systemic effects: 0.0018 mg/m³
PNEC - Fresh water; 0.00001 mg/l

- marine water; 0.000044 mg/l
- STP; 3.6 mg/l
- Sediment (Freshwater); 0.84 mg/kg
- Sediment (Marinewater); 0.366 mg/kg
- Soil; 0.01 mg/kg
CREOSOTE OIL, ACENAPHTHENE FRACTION (CAS: 90640-84-9)
Biological limit values 4µmol 1-hydroxypyrene/mol creatinine in urine, 4µmol 1-hydroxypyrene/mol

creatinine in urine, 4µmol 1-hydroxypyrene/mol creatinine in urine
DNEL Professional - Inhalation; Short term systemic effects: 51 mg/m³

Professional - Dermal; Long term systemic effects: 1.06 mg/kg/day
Professional - Inhalation; Long term systemic effects: 1.2 mg/m³
Professional - Inhalation; Short term local effects: 12 mg/m³
Professional - Inhalation; Long term local effects: 1.9 mg/m³
PNEC - Fresh water; 3.8 µg/l

- marine water; 3.8 µg/l
- Intermittent release; 0.14 mg/l
- STP; 0.5 mg/l
- Sediment (Freshwater); 0.16 mg/kg
- Sediment (Marinewater); 1.6 mg/kg
- Soil; 0.19 mg/kg
O,O'-Bis(2-aminopropyl)polypropyleneglycol (CAS: 9046-10-0)
DNEL Industry/Professional, Workers - ; Long term systemic effects: 2.5 mg/kg bw/day
PNEC - Fresh water; 0.015 mg/l
ANTHRACENE OIL (CAS: 90640-80-5)
Ingredient comments No exposure limits known for ingredient(s).
DNEL Industry - Dermal; Long term : 0.63 mg/kg/day

Industry - Inhalation; Long term : 1.28 mg/m³
PNEC - Fresh water; Long term 0.0035 mg/l

- marine water; Long term 0.0035 mg/l
- Sediment; Long term 15 mg/kg
- STP; Long term 3.2 mg/l
8.2. Exposure controls
Protective equipment
5/15
Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational
controls exposure limits for the product or ingredients.
Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.
Hand protection Wear protective gauntlets made of the following material: Rubber, neoprene or PVC.
Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.
Hygiene measures Provide eyewash station. Use appropriate skin cream to prevent drying of skin. Do not eat,
drink or smoke when using this product. Wash at the end of each work shift and before eating,
smoking and using the toilet. Wash promptly with soap and water if skin becomes
contaminated. Promptly remove any clothing that becomes contaminated.
Respiratory protection Respiratory protection may be required if excessive airborne contamination occurs.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.
Colour Black.
Odour of Pitch
Odour threshold Not determined.
pH Not determined.
Melting point Not applicable.
Initial boiling point and range 200°C @
Flash point 107°C
Evaporation rate Not determined.
Evaporation factor Not determined.
Flammability (solid, gas) Not determined.
Other flammability Not determined.
Vapour pressure Not determined.
Vapour density Not determined.
Relative density 1.47 @ 20°C
Bulk density Not determined.
Solubility(ies) Insoluble in water.
Partition coefficient Not determined.
Auto-ignition temperature 400°C
Decomposition Temperature Not determined.
Viscosity 100 P @ 20°C
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
Oxidising properties Does not meet the criteria for classification as oxidising.
6/15
9.2. Other information

Other information No data available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity Stable at normal ambient temperatures and when used as recommended.
10.2. Chemical stability

Stability Stable under the prescribed storage conditions.
10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions
10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials

Materials to avoid Strong oxidising agents.
10.6. Hazardous decomposition products

Hazardous decomposition Fire creates: Thermal decomposition or combustion products may include the following
products substances: Acrid smoke or fumes. Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of
nitrogen.
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 84,353.03
Acute toxicity - dermal

ATE dermal (mg/kg) 3,922.08
Germ cell mutagenicity

Genotoxicity - in vitro may cause genetic defects
Carcinogenicity
Carcinogenicity May cause cancer.
Reproductive toxicity
Reproductive toxicity - fertility May damage fertility.
Reproductive toxicity - May damage the unborn child.

development
Inhalation Irritating to respiratory system.
Ingestion May cause chemical burns in mouth, oesophagus and stomach.
Skin contact Irritating to skin. Causes severe skin burns. May cause an allergic skin reaction.
Eye contact Irritating to eyes. Symptoms following overexposure may include the following: Redness.
Pain.
Route of exposure Ingestion. Skin and/or eye contact
7/15
Target organs Eyes Skin
Toxicological information on ingredients.
Pitch, coal tar, high-temp.
Notes (oral LD₅₀) LD₅₀ >2000 mg/kg, Oral, Rat
Notes (dermal LD₅₀) LD₅₀ >2000 mg/kg, Dermal, Rat
Carcinogenicity
IARC carcinogenicity IARC Group 1 Carcinogenic to humans.
TRIETHYLENETETRAMINE
Acute toxicity oral (LD₅₀ 2,500.0

mg/kg)
Species Rat
Acute toxicity dermal (LD₅₀ 550.0

mg/kg)
Species Rabbit
CREOSOTE OIL, ACENAPHTHENE FRACTION

mg/kg)
Species Rat
Notes (oral LD₅₀) Based on available data the classification criteria are not met.
Acute toxicity dermal (LD₅₀ 2,000.0

mg/kg)
Species Rat
Notes (dermal LD₅₀) Based on available data the classification criteria are not met.
Acute toxicity - inhalation
Acute toxicity inhalation 0.4

(LC₅₀ vapours mg/l)
Species Rat
Notes (inhalation LC₅₀) Estimated value. Based on available data the classification criteria are not met.
8/15
ATE inhalation (vapours 0.4

mg/l)
Skin corrosion/irritation
Animal data Erythema/eschar score: Well defined erythema (2). Oedema score: Moderate
oedema - raised approximately 1 mm (3). Irritating.
Serious eye damage/irritation
Serious eye Causes serious eye irritation.

damage/irritation
Respiratory sensitisation
Respiratory sensitisation There is no evidence that the material can lead to respiratory hypersensitivity.
Skin sensitisation
Skin sensitisation Local Lymph Node Assay (LLNA) - Mouse: May cause sensitisation by skin contact.
Genotoxicity - in vitro May induce heritable mutations in the germ cells of humans.
Carcinogenicity
Carcinogenicity NOAEL 140 mg/kg/day, Oral, Mouse Estimated value. May cause cancer.
Reproductive toxicity - Conclusive data but not sufficient for classification.

fertility
Specific target organ toxicity - single exposure
STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure LOAEL 50 mg/kg, Oral, Rat Estimated value.
Target organs Respiratory system, lungs
Aspiration hazard
Aspiration hazard Kinematic viscosity ≤ 20.5 mm²/s. May be fatal if swallowed and enters airways.
O,O'-Bis(2-aminopropyl)polypropyleneglycol
ATE oral (mg/kg) 500.0
ANTHRACENE OIL

mg/kg)
Species Rat
9/15

mg/kg)
Species Rat
Acute toxicity - inhalation
Notes (inhalation LC₅₀) Conclusive data but not sufficient for classification. Unlikely to be hazardous by
inhalation because of the low vapour pressure of the product at ambient
temperature.
Skin corrosion/irritation
Animal data Dose: 0.5 ml, 4 hr, Rabbit Erythema/eschar score: Well defined erythema (2).
Oedema score: Moderate oedema - raised approximately 1 mm (3). Slightly
irritating.
Serious eye damage/irritation
Serious eye Not irritating.

damage/irritation
Skin sensitisation
Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Sensitising.
Genotoxicity - in vitro Gene mutation:: Positive.
Genotoxicity - in vivo Chromosome aberration: Negative.
Carcinogenicity
Carcinogenicity Conclusive data but not sufficient for classification.
Reproductive toxicity - Two-generation study - NOAEL 25 mg/kg/day, Oral, Rat Suspected reproductive
fertility toxicant based on limited evidence.
Reproductive toxicity - Developmental toxicity: - NOAEL: 50 mg/kg/day, Oral, Rat Suspected reproductive
development toxicant based on limited evidence.
Specific target organ toxicity - single exposure
STOT - single exposure Conclusive data but not sufficient for classification. Not classified as a specific
target organ toxicant after a single exposure
Specific target organ toxicity - repeated exposure
STOT - repeated exposure NOAEC 23 mg/kg, Inhalation, Rat (NOAEC data is for inhalation for aerosol and
gas over a period of 13 weeks)
Target organs Respiratory system, lungs
Aspiration hazard
Aspiration hazard Conclusive data but not sufficient for classification.
NONYLPHENOL

mg/kg)
Species Rat
10/15

mg/kg)
Species Rat
SECTION 12: Ecological information
Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
12.1. Toxicity
Toxicity The product contains a substance which is harmful to aquatic organisms.
Ecological information on ingredients.
Pitch, coal tar, high-temp.
Acute aquatic toxicity
LE(C)₅₀ 0.1 < L(E)C50 ≤ 1
M factor (Acute) 1
Acute toxicity - fish LL₅₀, 96 hours: >100>1000 mg/l, Oryzias latipes (Red killifish)
Acute toxicity - aquatic EL50, 48 hours: >100 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EL50, 72 hours: 220 mg/l, Desmodesmus subspicatus

plants
Chronic aquatic toxicity
M factor (Chronic) 1
Acute toxicity - fish LC₅₀, 96 hours: 330 mg/l, Pimephales promelas (Fat-head Minnow)
Acute toxicity - aquatic EC₅₀, 48 hours: 31.1 mg/L, Daphnia magna

invertebrates
Acute toxicity - aquatic EC₅₀, 72 hours: 20 mg/l, Pseudokirchneriella subcapitata

plants
Acute toxicity - EC₅₀, 16 hour: 680 mg/l, Bacteria

microorganisms
Acute toxicity - fish LL50, 96 hours: 79 mg/l, Brachydanio rerio (Zebra Fish)
Acute toxicity - aquatic EL50, 48 hours: 2.7 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EL50, 72 hours: 25 mg/l, Freshwater algae

plants NOELR, 72 hours: 12 -15 mg/l, Freshwater algae
11/15
Acute toxicity - EL50, 3 hours: 670 mg/l, Activated sludge

microorganisms
Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Fish
Acute toxicity - aquatic EC₅₀, 48 hours: 15 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic IC₅₀, 72 hours: 135 mg/l, Algae

plants
ANTHRACENE OIL
Acute toxicity - fish LL₅₀, 96 hours: 100 mg/l, Brachydanio rerio (Zebra Fish)
Acute toxicity - aquatic EL50, 48 hours: 137 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EL50, 72 hours: 25 mg/l, Desmodesmus subspicatus

plants
NONYLPHENOL
LE(C)₅₀ 0.1 < L(E)C50 ≤ 1
M factor (Acute) 1
Acute toxicity - fish LC₅₀, 96 hours: 0.128 mg/l, Fish
Acute toxicity - aquatic EC₅₀, 48 hours: 0.0848 mg/l, Daphnia magna

invertebrates
Chronic aquatic toxicity
M factor (Chronic) 1
12.2. Persistence and degradability

Persistence and degradability The product is not readily biodegradable.
Persistence and The product contains persistent (not readily degradable) substances.
degradability
Stability (hydrolysis) No significant reaction in water.
Biodegradation No biodegradation observed under test conditions.
12.3. Bioaccumulative potential

Partition coefficient Not determined.
12/15
Bioaccumulative potential BCF: < 220, Freshwater fish
Partition coefficient log Pow: ~ 3.8
12.4. Mobility in soil

Mobility The product is partly soluble in water and may spread in the aquatic environment.
Mobility The product has poor water-solubility. Not considered mobile.
Adsorption/desorption Water - log Koc: ~ 3 @ °C Estimated value.

coefficient
12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
assessment
Results of PBT and vPvB The data show that the properties of the substance do not allow a direct
assessment comparison with all the criteria in Annex XIII. The substance is not considered
PBT/vPvB.
assessment
12.6. Other adverse effects

Other adverse effects None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 1760
UN No. (IMDG) 1760
UN No. (ICAO) 1760
UN No. (ADN) 1760
14.2. UN proper shipping name
13/15
Proper shipping name CORROSIVE LIQUID, N.O.S. (CONTAINS O,O'-Bis(2-aminopropyl)polypropyleneglycol,

(ADR/RID) TRIETHYLENETETRAMINE)
Proper shipping name (IMDG) CORROSIVE LIQUID, N.O.S. (CONTAINS O,O'-Bis(2-aminopropyl)polypropyleneglycol,

TRIETHYLENETETRAMINE)
Proper shipping name (ICAO) CORROSIVE LIQUID, N.O.S. (CONTAINS O,O'-Bis(2-aminopropyl)polypropyleneglycol,

Proper shipping name (ADN) CORROSIVE LIQUID, N.O.S. (CONTAINS O,O'-Bis(2-aminopropyl)polypropyleneglycol,

14.3. Transport hazard class(es)

ADR/RID class 8
ADR/RID classification code C9
ADR/RID label 8
IMDG class 8
ICAO class/division 8
ADN class 8
Transport labels
14.4. Packing group

ADR/RID packing group II
IMDG packing group II
ICAO packing group II
ADN packing group II
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant

No.
14.6. Special precautions for user

EmS F-A, S-B
ADR transport category 2
Emergency Action Code 2X
Hazard Identification Number 80

(ADR/RID)
Tunnel restriction code (E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
14/15
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations No data
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 05/05/2020
Revision 3
Supersedes date 13/05/2015
Hazard statements in full H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H340 May cause genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H360FD May damage fertility. May damage the unborn child.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
15/15

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Revision date: 05/05/2020 Revision: 3 Supersedes date: 13/05/2015

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product number A1765013AE1, A1765014AE1, A1765015AE1, A1765018AE1

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Environmental hazards Aquatic Chronic 3 - H412

Human health Contains a substance which may be potentially carcinogenic.

2.2. Label elements

Signal word Danger

Precautionary statements P273 Avoid release to the environment.

Contains Pitch, coal tar, high-temp., TRIETHYLENETETRAMINE, O,O'-Bis(2-

Supplementary precautionary P261 Avoid breathing vapour/ spray.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Pitch, coal tar, high-temp. 30-60%

NITOCOTE ET402 HARDENER

CREOSOTE OIL, ACENAPHTHENE FRACTION 1-5%

ANTHRACENE OIL 1-5%

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation May cause irritation.

NITOCOTE ET402 HARDENER

Ingestion May cause chemical burns in mouth and throat.

Eye contact May cause irritation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

Storage class Chemical storage.

7.3. Specific end use(s)

NITOCOTE ET402 HARDENER

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Pitch, coal tar, high-temp. (CAS: 65996-93-2)

DMEL Workers - Inhalation; Long term systemic effects: 0.0018 mg/m³

PNEC - Fresh water; 0.00001 mg/l

CREOSOTE OIL, ACENAPHTHENE FRACTION (CAS: 90640-84-9)

Biological limit values 4µmol 1-hydroxypyrene/mol creatinine in urine, 4µmol 1-hydroxypyrene/mol

DNEL Professional - Inhalation; Short term systemic effects: 51 mg/m³

PNEC - Fresh water; 3.8 µg/l

O,O'-Bis(2-aminopropyl)polypropyleneglycol (CAS: 9046-10-0)

PNEC - Fresh water; 0.015 mg/l

ANTHRACENE OIL (CAS: 90640-80-5)

Ingredient comments No exposure limits known for ingredient(s).

DNEL Industry - Dermal; Long term : 0.63 mg/kg/day