Interface Description USB - RS Data Export

Titration Excellence / Compact Line

1 Introduction
The Excellence Line and the Compact Line (Karl Fischer) titrators support data transfer to an external client sys­
tem. The data is transferred via the serial RS232 interface.
For the Excellence Line titrators, the COM port on the main board can be used directly for data transfer. On the
other hand, the Compact Line titrators send data via the USB Data Export Box (RS-232 adapter) to the USB
interface.
The most important data for general titration (GT) and Karl Fischer water determination (KF) is transferred such
as sample data, results or statistics, either per sample or per series.
In addition, for KF analysis automatic reports can be generated for drift, blank values and concentrations.
The data transfer is XML based. In the following there is a detailed description how the XML structure is build
up.

Introduction 3
 2 XML Based Data Export
To activate data export you have to select the following settings in the instrument's setup:
● Printer type = "RS-232 data export" (for Titration Excellence Line (T90/T70/T50)) or "USB data export" (for
Compact Line titrators (V30/V20/C30/C20), respectively.
(Navigation: Setup > Hardware > Peripherals > Printer)
● The Summary parameter in the "Record" method function (Navigation: Methods > Method  > Record):
• "Record" inside the loop: "Per sample" or "Per series"
• "Record" outside the loop: "Yes" or "No"
Note: The other parameters, which are selected in MF "Record" are ignored.
An overview per sample or per series is exported according to the settings in MF "Record".
● The Print autom. KF protocols parameter for the automatic KF data export.
Navigation: Setup > Global settings  > Analysis and resources behavior > Analysis sequence settings
(Automatic Karl Fischer reports are generated including drift, blank value and concentration.)
Not all elements are sent, if the method terminates with an error.
In the following there is an example of a printout report. It shows first the report header, the header of the analy­
sis and the summary of the analysis.
Roughly the same amount of data is sent through the RS-232 interface.

The integer values contained in brackets are used as markers, which have the following meaning:
(1) Modified (6) srel above max srel for multiple determination
(2) Excluded (7) Value out of range, not saved in setup
(3) Outside limits (8) Sample data out of range
(4) Resource expired (9) Standard evaluation used
(5) srel above max srel
Data is transferred in XML with UTF-8 format. Values are transmitted as strings such as:
[Value] [Space-Character] [Unit] (marker)1 [Space-Character] [(marker)n].
The structure of the XML files is defined by the general XML Scheme. The following XSD file defines all elements
used in the XML files for the data transfer, in what order and how often they can occur :
data_export.xsd
This XSD file is shown in "Appendix: XML Scheme".
The following examples show typical XML structures for the reports.

4 XML Based Data Export

First, a fixed report header is generated. The following example shows the typical structure of the report header:
For more information about the available report <header> elements, refer to "Appendix: Report Header".

2.1 Report Header
<?xml version=”1.0” encoding=”UTF-8”standalone=”yes”?>
<MT>
<InstrumentInfo>
<InstrumentType>T90</InstrumentType>
<CommandInterfaceFamily>Titration</CommandInterfaceFamily>
<CommandInterfaceVersion>1.0</CommandInterfaceVersion>
<InstrumentModuleInfo>
<ArrayOfInstrumentModuleInfo>
<ModuleId>0</ModuleId>
<ModuleSerialNumber>1020304050</ModuleSerialNumber>
<ModuleFirmwareVersion>Tx_3.1.16.494</ModuleFirmwareVersion>
</ArrayOfInstrumentModuleInfo>
</InstrumentModuleInfo>
</InstrumentInfo>
<analysis>
For more information about the <header> structure for <analysis> refer to "Header for Analysis" and
"Appendix: Header for Analysis".
</analysis>
</MT>.

2.2 Data Export for GT and KF Titration

The content of the exported data depends whether the value "Per sample" or Per series" is selected in MF
"Record" for the parameter "Summary". Also it depends whether MF "Record" is inside or outside of a loop.
The following examples show the different XML structures which are used for generating reports.

2.2.1 Header for Analysis

Each report contains an analysis header. The <analysis> element contains at the beginning a <header> ele­
ment. For example:
<analysis>
<header>
<instrument_id>T90</instrument_id>
<date_time>2011-03-24T14:46:56</date_time>
<user>Admin</user>
<method_id>U8000</method_id>
<sample_series_id>EQPSeries</sample_series_id>
For more information about all usable <header> elements in <analysis>, refer to "Appendix:
Header for Analysis".
</header>
</analysis>

2.2.2 Report per Sample

In the following there is an example for the XML structure to generate a report for the analysis of a sample:
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header for
Analysis and "Appendix: Header for Analysis".
</header>

XML Based Data Export 5

 <sample>
<number>1</number>
<id1>EQP ID</id1>
<size>0.2 mL</size>
Sample data depends on the analysis type, for more information all usable <sample>
elements, refer to "Appendix: Sample Elements".
<result>
<number>R1</number>
<name>Potential</name>
<result_value>0.5 mV</result_value>
For more information about all usable <result> elements, refer to
"Appendix: Result Elements".
</result>
</sample>
</analysis>
</MT>

2.2.3 Report per Series (Inside Loop)

● For the general titration (GT) with series of samples, the data are exported in MF "Record" during the last
sample of the loop.
● For the KF titration (without Stromboli), data is exported only if the user terminates the method, finishes the
series, or changes the determination type.
● Additionally, the statistic and extra statistical functions are exported (only if it is selected in MF "Calcula­
tion").
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header
for Analysis" and "Appendix: Header for Analysis".
</header>
<sample>
<number>1</number>
<id1>EQP ID</id1>
<size>0.21 mL (8)</size>
<density>1.0 g/mL
<temp>25.0 °C</temp>
Comment 2
<corr_fact>1.0</corr_fact>
<sample_start>2011-01-13T07:46:41</sample_start>
additional sample data depends on the titration typ: GT or KF,
refer to the table in "Appendix: Sample Elements".
<result>
<number> R1</number>
<name>Consumption</name>
<result_value>2.1437 mL (3)
For more information about all usable <result>
elements, refer to "Appendix: Result Elements"
</result>
<result>
<number>R2</number>
<name>Total Consumption</name>
<result_value>2.2435 mL</result_value>
</result>
<result>
repeat sequence

6 XML Based Data Export

 </result>
</sample>
<sample>
<number>2</number>
repeat sequence
<result>
repeat sequence
</result>
</sample>
<statistics>
<number> R1</number>
<name> Potential</name>
<number_of_sample> 2</number_of_sample>
<mean_value> 0.3 mV</mean_value>
For more information about all usable <statistics>
elements, refer to "Appendix: Statistic Elements"
</statistics>
<statistics>
<number> R2</number>
repeat sequence
</statistics>
<extra_stat>
<number> R2</number>
<sample_number_extr_stat> 2</sample_number_extr_stat>
For more information about all usable <extra_stat>
elements, refer to "Appendix: Extra Statistic Elements"
</extra_stat>
</analysis>
</MT>

2.2.4 Report for KF Analysis per Series

The following example shows a typical XML structure for generating a report for a KF analysis.
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header for Analysis
and "Appendix: Header for Analysis".
</header>
<sample>
<number>1</number>
<id1>KFVExtraction ID1</id1>
<id2>KFVExtraction ID2</id2>
<id3>KFVExtraction ID3</id3>
<size>11 pcs. (8)</size>
<wt_per_piece>0.0821 g/piece</wt_per_piece>
<temp>23.7 °C</temp>
<comment>Comment 1</comment>
<corr_fact>0.9999</corr_fact>
<solv_wt>60 g</solv_wt>
<wt_ext_sample>0.5 g</wt_ext_sample>
<sample_start>2011-01-12T11:19:01</sample_start>
Sample data depends on the analysis type, for more information about all usable
<sample> elements, refer to "Appendix: Sample Elements".
<result>
<number>R1</number>
<name>Consumption</name>

XML Based Data Export 7

 <result_value>0.2038 mL</result_value>
For more information about all usable <result>
elements, refer to "Appendix: Result Elements"
</result>
<result>
<number>R2</number>
repeat sequence
</result>
<result>
<number>R3</number>
repeat sequence
</result>
</sample>
<sample>
<number>2</number>
repeat sequence
<result>
<number>R1</number>
repeat sequence
</result>
<result>
repeat sequence
</result>
<result>
<number>R3</number>
repeat sequence
</result>
</sample>
<statistics>
<number>R1</number>
<name>Consumption</name>
<number_of_sample>3 </number_of_sample>
<mean_value>0.2171 mL</mean_value>
<stdev>0.0131 mL</stdev>
<s_rel>6.036 % (5)</s_rel>
For more information about all usable report <statistics> elements,
refer to "Appendix: Statistic Elements".
</statistics>
<statistics>
<number>R2</number>
repeat sequence
</statistics>
<extra_stat>
<number>R1</number>
<name>Consumption</name>
<sample_number_extr_stat>2</sample_number_extr_stat>
<mean_value>0.2169 mL</mean_value>
<stdev>0.0185 mL</stdev>
<s_rel>8.541 % (6)</s_rel>
For more information about all usable <extra_stat> elements,
refer to "Appendix: Extra Statistic Elements".
</extra_stat>
</analysis>
</MT>

2.2.5 Report Outside the Loop

For the data export outside the loop the following data are generated:

8 XML Based Data Export

● data from the preceding loop (all samples),
● results for the method functions "Calibration", "Titer" or "Sensor Test".
● all results of the method function "Calibration" between the last loop and method function "Record".

2.2.5.1 Report for the Method "Calibration"

For the method "Calibration" the method function (MF) "Calibration" is outside of the loop. To generate a suit­
able report, MF "Record" has to be placed outside of the loop after "Calibration". The following data are generat­
ed:
● data from the preceding loop,
● results of MF "Calibration"

The following example shows a typical structure for the data export of a "Calibration" method.
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header for Analysis
and "Appendix: Header for Analysis".
</header>
<sample>
<number>1</number>
<standard_list>METTLER TOLEDO (Ref. 25°C) pH</standard_list>
<standard>4.01 </standard>
<temp>25.0 °C</temp> <comment>Buffer 4</comment>
<sample_start>2011-01-12T11:56:07</sample_start>
<result>
<number>R1</number>
<name>Potential</name>
<result_value>170.9 mV</result_value>
</result>
</sample>
<sample>
<number>2</number>
repeat sequence
<result>
repeat sequence
</result>
</sample>
<sample>
<number>3</number>
repeat sequence
<result>
repeat sequence
</result>
<calibration>
<sensor_name>DGi111-SC</sensor_name>
<calib_temp>25.4 °C </calib_temp>
<no_of_seg>2 </no_of_seg>
<segment>
<number>1</number>
<slope>-57.95 mV/pH</slope>
<zero_point>6.958 pH</zero_point>
</segment>
<segment>
<number>2</number>
repeat sequence

XML Based Data Export 9

 </segment>
For more information about all usable <calibration> elements,
refer to "Appendix: Calibration Elements".
</calibration>
</sample>
</analysis>
</MT>

2.2.5.2 Report for the Method "Titer"

To generate a suitable report, the method function (MF) "Record" is outside of the loop after MF "Titer" . The fol­
lowing data are generated:
● data from the preceding loop,
● results of MF "Titer"

The following example shows a typical structure for the data export of a "Titer" method. It describes the data
export for a titer dertermination per series with four samples.
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header for Analysis
and "Appendix: Header for Analysis".
</header>
<sample>
<number>1</number>
<standard>Potassium hydrogen phthalate</standard>
<size>0.053425 g</size>
<temp>25.0 °C</temp>
<comment>Comment 1</comment>
<corr_fact>1.0</corr_fact>
<sample_start>2011-01-13T08:27:42</sample_start>
Sample data depends on the analyis type, for more information about all usable
<sample> elements, refer to "Appendix: Sample Elements".
<result>
<number>R1</number>
<name>Titer</name>
<result_value>0.982122 </result_value>
</result>
</sample>
<sample>
<number>2</number>
repeat sequenz of sample 1.
<result>
<number>R1</number>
<name>Titer</name>
<result_value>0.981315 </result_value>
</result>
</sample>
<sample>
<number>3</number>
repeat sequenz of sample 1.
<result>
<number>R1</number>
<name>Titer</name>
<result_value>0.981292</result_value>
</result>
</sample>

10 XML Based Data Export

 <statistics>
<number>R1</number>
<name>Titer</name>
<number_of_sample>4 </number_of_sample>
<mean_value>0.9832</mean_value>
<stdev>0.008215 </stdev>
<s_rel>0.836 %</s_rel>
</statistics>
<titer>
<titrant>HCL 0.1 mol/L</titrant>
<titer_value>0.9832</titer_value>
</titer>
</analysis>
</MT>

2.2.5.3 Report for the Method "Sensor Test"

For the method "Sensor Test" the method function "Calibration" is outside of the loop. To generate a suitable
report, the methode function "Record" has to be placed outside of the loop after "Calibration". The following data
are generated:
● data from the preceding loop,
● results of MF "Calibration"

The following example shows a typical structure for the related data export.
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis>
refer to "Header for Analysis and "Appendix: Header for Analysis".
</header>
<sample>
<number>1</number>
<standard_list>METTLER TOLEDO (Ref. 25°C) pH</standard_list>
<standard>4.01 </standard>
<temp>25.0 °C</temp> <comment>Buffer 4</comment>
<sample_start>2011-01-12T11:56:07</sample_start>
</sample>
<sample>
<number>2</number>
repeat sequenz of sample 1.
</sample>
<sensor_test>
<sensor_name>DGi111-SC</sensor_name>
<sens_test_result>success</sens_test_result>
<sens_test_temp>25.4 °C</sens_test_temp>
<slope>-58.43 mV/pH</slope>
<zero_point>6.938 pH</zero_point>
<drift_temp>25.4 °C</drift_temp>
<sens_test_drift>-0.1 mV/30s</sens_test_drift>
</sensor_test>
</analysis>
</MT>

2.3 Automatic Data Exports for KF Titration

For the automatic Karl Fischer (KF) data export, a report with fixed content is generated for drift, blank and con­
centration.

XML Based Data Export 11

 In order to generate an automatic data export, in the "Print autom. KF protocols" parameter is activated in:
Navigation: Setup > Global settings > Analysis and resources behavior > Analysis sequence settings.

2.3.1 Drift Determination
<MT>
<InstrumentInfo>
For more information about the report <header> elements, refer to "XML Based Data Export":
"Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header for Analysis
and "Appendix: Header for Analysis".
</header>
<drift>
<date_time>2011-01-12T10:39:42</date_time>
<drift_value>13.4 µg/min</drift_value>
For more information about all usable <drift> elements, refer to "Appendix: Drift Elements".
</drift>
</analysis>
</MT>

2.3.2 Blank Value Determination

<MT>
<InstrumentInfo>
For more information about the report <header> elements,
refer to "XML Based Data Export": "Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis>
refer to "Header for Analysis and "Appendix: Header for Analysis".
</header>
<blank>
<sample>
<number>3</number>
<size>100 mL</size>
<density>1.0 g/mL</density>
<comment></comment>
<sample_start>2011-01-12T11:38:14 </sample_start>
</sample>
<result>
<number>R1</number>
<name>Blank</name>
<result_value>0.001077 %</result_value>
For more information about <result> elements, refer to "Appendix: Result Elements".
</result>
<statistics>
<number>R1</number>
<name>Blank</name>
<number_of_sample>3 </number_of_sample>
<mean_value>0.001049 %</mean_value>
<stdev>0.000027 %</stdev>
<s_rel>2.538 %</s_rel>
For more information about statistics> elements, refer to "Appendix: Statistic Elements".
</statistics>
</blank>
For more information about <blank> elements, refer to "Appendix: Blank Elements".

12 XML Based Data Export

 </analysis>
</MT>
For the blank value determination, the statistics will be exported with every sample after the second sample.

2.3.3 Concentration determination
For the concentration determination, the statistics will be printed out with every sample after the second sample.
The structure of exports is similar to the export of the blank determination.
<MT>
<InstrumentInfo>
For more information about the report <header> elements,
refer to "XML Based Data Export": "Report Header" and "Appendix: Report Header".
</InstrumentInfo>
<analysis>
<header>
For more information about the <header> elements in <analysis> refer to "Header for Analysis
and "Appendix: Header for Analysis".
</header>
<concentration>
<sample>
<number>3</number>
<standard>Water-Standard 10.0</standard>
<size>0.1 g</size>
<comment></comment>
<sample_start>2011-01-12T10:51:52</sample_start>
</sample>
<result>
<number>R1</number>
<name>Concentration</name>
<result_value>4.735095 mg/mL</result_value>
</result>
<statistics>
<number>R1</number>
<name>Concentration</name>
<number_of_sample>3 </number_of_sample>
<mean_value>0.001049 %</mean_value>
<stdev>0.000027 %</stdev>
<s_rel>2.538 %</s_rel>
For more information about statistics> elements, refer to "Appendix: Statistic Elements".
</statistics>
For more information about the available <concentration> elements,
refer to "Appendix: Concentration Elements".
</concentration>
</analysis>
</MT>

XML Based Data Export 13

 3 Appendix
In the following section there is XSD file which defines the XML structure of the files used for the data transfer.
All available elements which can be used within the XML structure for the data transfer files are listed in the fol­
lowing tables.

3.1 Report Header
Elements for the report header
Titles in the report for <InstrumentInfo> elements Description
<InstrumentInfo>
Instrument type InstrumentType e.g. T90, V30, C30
Instrument family CommandInterfaceFamily e.g. Titration
Interface Version CommandInterfaceVersion Version of the RS data export
Module ID ModuleId 0
Serial number ModuleSerialNumber Serial number of the instrument
Firmware version ModuleFirmwareVersion Firmware version of the instrument

3.2 Header for Analysis

<header> elements within the <analysis> structure
Titles in the report for <header> <header> elements Description
Titrator ID instrument_id -
Date / Time date_time Date and time format, such as
2011-03-24T14:46:56
User user -
Method ID method_id e.g. KFVExtraction
Sample series ID sample_series_id e.g. KFVExtractionSeries

3.3 Sample Elements
The following table lists all elements used within the <sample> structure of <analysis>:
Elements for <sample> depending on the titration type
Titles in the report <sample> ele­ General Titration (GT) Karl Fischer
for <sample> ments (KF)
GT / Bromine Titer Sensor Calibra­
Index (BI) test tion
No. number x x x x x
ID1 id1 x x
ID2 id2 x1 x1
ID3 id3 x1 x1
Sample size size x x x
density density x1 x1
Temperature temp x x x x1 x
Comment comment x x x x x
Correction factor corr_fact x x x
Weight per piece wt_per_piece x1 x1
Solvent weight solv_wt x1
Wt. Extracted sam­ wt_ext_sample x1
ple
Sample Start sample_start x x x x x
List of standards / standard_list x x
pH buffer list
Buffer / Standard standard x x x
X1: This data is only exported, when it is generated by the method.

14 Appendix
3.4 Result Elements
Titles in the report for <result> <result> elements Description
Result result
Rx (x) number e.g. R1
name any name
result_value value and unit for the calculations

3.5 Sensor Test Elements

Titles in the report for <sensor_test> elements Description
<sensor_test>
Sensor sensor_name
Sensor test sens_test_result
Sensort test temperature sens_test_temp Value and unit
Slope (TSensortest) slope Value and unit
Zero point zero_point Value and unit
Drift temperature drift_temp Value and unit
Drift (Tdrift) sens_test_drift Value and unit

3.6 Calibration Elements
Titles in the report for <calibration> elements Description
<calibration>
Sensor sensor_name -
Calib. Temperature 1) calib_temp Value and unit
Number of segments2) no_of_seg -
segment (if more than one segment is required) including the following elements:
number
slope
zero_point
Slope (Tcalib)2) slope
Zero point3) zero_point
cell constant4) cell_const -
1) not for temperature calibration
2) not for pH and ISE calibration
3) not for conductivity calibration
4) only for conductivity calibration

3.7 Titer Elements
Titles in the report for <titer> <titer> elements Description
Titrant titrant -
Titer titer_value -

3.8 Statistic Elements
Titles in the report for <statistic> <statistic> elements Description
Rx (x) number Rn
name Name of the measuring method
Number of samples number_of_sample -
Mean value mean_value Value and unit
s stdev Value and unit
srel s_rel Value and unit

Appendix 15
 3.9 Extra Statistic Elements
Titles in the report for <extra_stat> elements Description
<extra_stat>
Rx (Sample x/y) (x) number number of the calculation
name sample_number_extr_stat: 2 for
sample_number_extr_stat sample 2/5, 4 for sample 4/5

Mean value mean_value value and unit

s stdev value and unit
srel s_rel value and unit

3.10 Drift Elements
Titles in the report for <drift> <drift> elements Description
date / time date_time Date and time
Drift drift_value Value and unit

3.11 Blank Elements
Titles in the report for <blank> <blank> elements Description
sample
Number number
Sample size size Value and unit
density density Value and unit
Comment comment
Sample start sample_start Date and time
result
R1 (Blank) number any number
name any name
result_value Value and unit
statistics
R1 (Blank) number number: R1
name name: Blank
Number of samples number_of_sample
Mean value mean_value Value and unit
s stdev Value and unit
srel s_rel Value and unit

16 Appendix
3.12 Concentration Elements
Titles in the report for <concentration> elements Description
<concentration>
sample
Number number
Standard standard
Sample size size Value and unit
Comment comment
Sample start sample_start Date and time
result
R1 (Concentration) number number: R1
name name: Concentration
result_value Value and unit
statistics
R1 (Blank) number number: R1
name name: Concentration
Number of samples number_of_sample
Mean value mean_value Value and unit
s stdev Value and unit
srel s_rel Value and unit

Appendix 17
 3.13 XML Scheme
XSD files define the structure of XML files. In the following there is the XSD - file "data_export.xsd" that defines
the XML-structure used for the RS data transfer:
<?xml version="1.0" encoding="UTF-8"?>
<xs:schema xmlns:xs="http://www.w3.org/2001/XMLSchema" elementFormDefault="qualified"
attributeFormDefault="unqualified">
<xs:complexType name="MT_type">
<xs:sequence>
<xs:element name="InstrumentInfo" type="InstrumentInfo_type" minOccurs="1" maxOccurs="1" />
<xs:element name="analysis" type="analysis_type" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:element name="MT" type="MT_type" />
<xs:complexType name="InstrumentInfo_type">
<xs:sequence>
<xs:element name="InstrumentType" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="CommandInterfaceFamily" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="CommandInterfaceVersion" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="InstrumentModuleInfo" type="ArrayOfInstrumentModuleInfo" minOccurs="1"
maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="ArrayOfInstrumentModuleInfo">
<xs:sequence>
<xs:element name="ArrayOfInstrumentModuleInfo" type="InstrumentModuleInfo_type" minOccurs="1"
maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="InstrumentModuleInfo_type">
<xs:sequence>
<xs:element name="ModuleId" type="xs:short" minOccurs="1" maxOccurs="1" />
<xs:element name="ModuleSerialNumber" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="ModuleFirmwareVersion" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="analysis_type">
<xs:sequence>
<xs:element name="header" type="header_type" minOccurs="1" maxOccurs="1" />
<xs:element name="sample" type="sample_type" minOccurs="0" maxOccurs="120" />
<xs:element name="statistics" type="statistics_type" minOccurs="0" maxOccurs="120" />
<xs:element name="extra_stat" type="extra_stat_type" minOccurs="0" maxOccurs="120" />
<xs:element name="concentration" type="concentration_type" minOccurs="0" maxOccurs="1" />
<xs:element name="drift" type="drift_type" minOccurs="0" maxOccurs="1" />
<xs:element name="blank" type="blank_type" minOccurs="0" maxOccurs="1" />
<xs:element name="calibration" type="calibration_type" minOccurs="0" maxOccurs="1" />
<xs:element name="sensor_test" type="sensor_test_type" minOccurs="0" maxOccurs="1" />
<xs:element name="titer" type="titer_type" minOccurs="0" maxOccurs="1" />
<xs:element name="result" type="result_type" minOccurs="0" maxOccurs="40" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="header_type">
<xs:sequence>
<xs:element name="instrument_id" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="date_time" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="user" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="method_id" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="sample_series_id" type="xs:string" minOccurs="1" maxOccurs="1" />

18 Appendix
 </xs:sequence>
</xs:complexType>
<xs:complexType name="result_type">
<xs:sequence>
<xs:element name="number" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="name" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="result_value" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="sample_type">
<xs:sequence>
<xs:element name="number" type="xs:short" minOccurs="1" maxOccurs="1" />
<xs:element name="standard_list" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="standard" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="id1" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="id2" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="id3" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="size" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="wt_per_piece" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="density" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="temp" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="comment" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="corr_fact" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="solv_wt" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="wt_ext_sample" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="sample_start" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="result" type="result_type" minOccurs="0" maxOccurs="40" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="statistics_type">
<xs:sequence>
<xs:element name="number" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="name" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="number_of_sample" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="mean_value" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="stdev" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="s_rel" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="extra_stat_type">
<xs:sequence>
<xs:element name="number" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="name" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="sample_number_extr_stat" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="mean_value" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="stdev" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="s_rel" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="concentration_type">
<xs:sequence>
<xs:element name="sample" type="concentration_sample_type" minOccurs="1" maxOccurs="1" />
<xs:element name="result" type="result_type" minOccurs="0" maxOccurs="1" />
<xs:element name="statistics" type="statistics_type" minOccurs="0" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="concentration_sample_type">
<xs:sequence>

Appendix 19
 <xs:element name="number" type="xs:short" minOccurs="1" maxOccurs="1" />
<xs:element name="standard" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="size" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="comment" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="sample_start" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="drift_type">
<xs:sequence>
<xs:element name="date_time" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="drift_value" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="blank_type">
<xs:sequence>
<xs:element name="sample" type="blank_sample_type" minOccurs="1" maxOccurs="1" />
<xs:element name="result" type="result_type" minOccurs="0" maxOccurs="1" />
<xs:element name="statistics" type="statistics_type" minOccurs="0" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="blank_sample_type">
<xs:sequence>
<xs:element name="number" type="xs:short" minOccurs="1" maxOccurs="1" />
<xs:element name="size" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="density" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="comment" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="sample_start" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="segment_type">
<xs:sequence>
<xs:element name="number" type="xs:short" minOccurs="1" maxOccurs="1" />
<xs:element name="slope" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="zero_point" type="xs:string" minOccurs="0" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="calibration_type">
<xs:sequence>
<xs:element name="sensor_name" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="calib_temp" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="no_of_seg" type="xs:short" minOccurs="0" maxOccurs="1" />
<xs:element name="segment" type="segment_type" minOccurs="0" maxOccurs="10" />
<xs:element name="slope" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="zero_point" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="cell_const" type="xs:string" minOccurs="0" maxOccurs="1" />
</xs:sequence>
</xs:complexType>
<xs:complexType name="sensor_test_type">
<xs:sequence>
<xs:element name="sensor_name" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="sens_test_result" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="sens_test_temp" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="slope" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="zero_point" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="drift_temp" type="xs:string" minOccurs="0" maxOccurs="1" />
<xs:element name="sens_test_drift" type="xs:string" minOccurs="0" maxOccurs="1" />
</xs:sequence>
</xs:complexType>

20 Appendix
<xs:complexType name="titer_type">
<xs:sequence>
<xs:element name="titrant" type="xs:string" minOccurs="1" maxOccurs="1" />
<xs:element name="titer_value" type="xs:string" minOccurs="1" maxOccurs="1" />
</xs:sequence>
</xs:complexType> </xs:schema>

Appendix 21
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