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    Lakshya JEE (2024) : Chemical Kinetics

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    Dev Kotecha
    This document contains a 13 question practice problem set on the topic of chemical kinetics. The questions cover various concepts related to the influence of temperature on reaction rates, including: 1) The Arrhenius equation and how it relates the temperature dependence of reaction rates to activation energy. 2) How reaction rates generally increase with rising temperature, doubling approximately every 10°C rise. 3) Temperature coefficients and how they quantify the effect of temperature changes on reaction rates. 4) Whether certain reactions are exothermic or endothermic based on comparisons of activation energies.

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    Lakshya JEE (2024) : Chemical Kinetics

    Uploaded by

    Dev Kotecha
    30 views3 pages
    This document contains a 13 question practice problem set on the topic of chemical kinetics. The questions cover various concepts related to the influence of temperature on reaction rates, including: 1) The Arrhenius equation and how it relates the temperature dependence of reaction rates to activation energy. 2) How reaction rates generally increase with rising temperature, doubling approximately every 10°C rise. 3) Temperature coefficients and how they quantify the effect of temperature changes on reaction rates. 4) Whether certain reactions are exothermic or endothermic based on comparisons of activation energies.

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    This document contains a 13 question practice problem set on the topic of chemical kinetics. The questions cover various concepts related to the influence of temperature on reaction rates, including: 1) The Arrhenius equation and how it relates the temperature dependence of reaction rates to activation energy. 2) How reaction rates generally increase with rising temperature, doubling approximately every 10°C rise. 3) Temperature coefficients and how they quantify the effect of temperature changes on reaction rates. 4) Whether certain reactions are exothermic or endothermic based on comparisons of activation energies.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    30 views3 pages

    Lakshya JEE (2024) : Chemical Kinetics

    Uploaded by

    Dev Kotecha
    This document contains a 13 question practice problem set on the topic of chemical kinetics. The questions cover various concepts related to the influence of temperature on reaction rates, including: 1) The Arrhenius equation and how it relates the temperature dependence of reaction rates to activation energy. 2) How reaction rates generally increase with rising temperature, doubling approximately every 10°C rise. 3) Temperature coefficients and how they quantify the effect of temperature changes on reaction rates. 4) Whether certain reactions are exothermic or endothermic based on comparisons of activation energies.

    Copyright:

    © All Rights Reserved
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    of 3

    1

    Lakshya JEE (2024)


    Chemical Kinetics DPP-07

    1. The influence of temperature on the rate of reaction 7. The velocity of a reaction is doubled for every 10°C
    is determined by rise in temperature. If the temperature is raised to
    (1) Nernst’s equation 50°C, the reaction velocity increases by about
    (2) Gibbs-Helmholtz equation (1) 12 times (2) 16 times
    (3) Arrhenius equation (3) 32 times (4) 50 times
    (4) Van’t Hoff equation
    1
    2. The temperature coefficient of a reaction is: 8. If we plot a graph between log k and by
    T
    (1) Ratio of rate constants at two temp. differing by Arrhenius equation, the slope is
    1°C (1) –Ea/ R (2) + Ea/ R
    (2) Ratio of rate constants at temp. 35°C and 25°C.
    Ea Ea
    (3) Ratio of rate constants at temp. 30°C and 25°C (3)  (4) 
    2.303R 2.303R
    (4) Specific reaction rate at 25°

    9. The rate constant of a reaction does not depend upon


    3. In general, with every 10°C rise in temperature, the
    (1) Temperature
    rate of reaction becomes approximately ______
    (2) Activation energy
    (1) Ten times (2) Double
    (3) Catalyst
    (3) Half (4) One tenth
    (4) Concentration of reactants and products
    4. The temperature coefficient of most of the reactions 10. For a reaction, activation energy Ea = 0 and the
    lies between rate constant at 200 K is 1.6 × 106 s-1.
    (1) 2 and 3 (2) 1 and 2 The rate constant at 400 K will be
    (3) 2 and 4 (4) 3 and 4 [Given that gas constant
    R = 8.314J K-1 mol-1]
    5. According to Arrhenius equation, rate constant of a (1) 3.2 × 104 s-1 (2) 1.6 × 106 s-1
    chemical reaction is equal to (3) 1.6 × 103 s-1 (4) 3.2 × 106 s-1
    (1) Ae–Ea/RT (2) AeEa/RT
    (3) AeRT/Ea (4) Ae–RT/Ea 11. The rate constants k1 and k2 for two different
    reactions are 1016  e–2000/T and 1015  e–1000/T,
    6. The correct expression for Arrhenius equation respectively. The temperature at which k1 = k2 is
    containing effect of temperature on the rate constant 1000
    is (T2 > T1) (1) 2000 K (2) K
    2.303
    k Ea  T1T2 
    (1) log10 2    (3) 1000 K (4)
    2000
    K
    k1 2.030R  T2  T1  2.303
    k2 R  T1  T2  12. The activation energies of the forward and
    (2) log10    backward reactions in the case of a chemical
    k1 2.030Ea  T1T2 
    reaction are 30.5 and 45.4 kJ/mol respectively.
    k 2 Ea  T2  T1 
    (3) log10    The reaction is
    k1 R  T1T2  (1) Exothermic
    k2 Ea  T2  T1  (2) Endothermic
    (4) log10    (3) Neither exothermic nor endothermic
    k1 2.303R  T2T1 
    (4) Independent of temperature
    2

    13. In a zero-order reaction, for every 10ºC rise of


    temperature, the rate is doubled. If the temperature
    is increased from 10ºC to 100ºC, the rate of the
    reaction will become
    (1) 256 times (2) 512 times
    (3) 64 times (4) 128 times
    3

    Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
    Answer Key
    1. (3) 8. (3)
    2. (2) 9. (4)
    3. (2) 10. (2)
    4. (1) 11. (2)
    5. (1) 12. (1)
    6. (4) 13. (2)
    7. (3)

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