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    Final - CEMA CC-X - Sem-IV - MSQ21

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    Subhajit Basak
    The document is a mid-semester examination for an Organic Chemistry course. It contains 8 questions divided into 4 groups (A, B, C, D) with 2 questions in each group. The questions test a variety of organic chemistry concepts like predicting products of reactions, drawing mechanisms, applying concepts like FMO theory to explain stereochemistry and photochemical reactions, identifying reagents and transformations, and purifying compounds. Students must answer 1 question from each group for a total of 4 questions out of the 8 provided.

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    Final - CEMA CC-X - Sem-IV - MSQ21

    Uploaded by

    Subhajit Basak
    27 views2 pages
    The document is a mid-semester examination for an Organic Chemistry course. It contains 8 questions divided into 4 groups (A, B, C, D) with 2 questions in each group. The questions test a variety of organic chemistry concepts like predicting products of reactions, drawing mechanisms, applying concepts like FMO theory to explain stereochemistry and photochemical reactions, identifying reagents and transformations, and purifying compounds. Students must answer 1 question from each group for a total of 4 questions out of the 8 provided.

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    Final_CEMA CC-X_Sem-IV_MSQ21

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    The document is a mid-semester examination for an Organic Chemistry course. It contains 8 questions divided into 4 groups (A, B, C, D) with 2 questions in each group. The questions test a variety of organic chemistry concepts like predicting products of reactions, drawing mechanisms, applying concepts like FMO theory to explain stereochemistry and photochemical reactions, identifying reagents and transformations, and purifying compounds. Students must answer 1 question from each group for a total of 4 questions out of the 8 provided.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    27 views2 pages

    Final - CEMA CC-X - Sem-IV - MSQ21

    Uploaded by

    Subhajit Basak
    The document is a mid-semester examination for an Organic Chemistry course. It contains 8 questions divided into 4 groups (A, B, C, D) with 2 questions in each group. The questions test a variety of organic chemistry concepts like predicting products of reactions, drawing mechanisms, applying concepts like FMO theory to explain stereochemistry and photochemical reactions, identifying reagents and transformations, and purifying compounds. Students must answer 1 question from each group for a total of 4 questions out of the 8 provided.

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    © All Rights Reserved
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    You are on page 1of 2

    Ramakrishna Mission Vivekananda Centenary College, Rahara

    B. Sc.Chemistry Hons. Semester IV


    Mid Semester Examination, 2021
    Paper CC –X (Organic Chemistry)
    Time: 1hr. Full Marks: 25
    Answer any four questions taking one from each group
    Group-A
    1. Predict the product(s) of the following reactions and explain with mechanism. 3+3

    O LiBr, HMPA, reflux


    a) ?

    OH

    O
    b)
    H
    ?
    Ph COOEt

    2. Predict the product(s) of the following reactions and provide mechanism at the rearrangement
    steps. 3+3

    a) 1. HCN
    O ?
    2. LAH
    3. H3O
    4. NaNO2 / HCl

    b) Ph Me
    H H
    Ph H O OH ?

    Group-B
    3.a) Convert: 2+2
    i) Toluene into m - bromotoluene
    ii) Benzene into 4 – bromo – 3 – chloroaniline
    b) What would be the action of nitrous acid on each of the following: PhNMe 2, PhNHMe, 2, 5 –
    Me2C6H3NH2. Give reason. 3
    4. a) What happens when o – phenylenediamine and m – phenylenediamine are separately treated
    with nitrous acid? Explain with mechanism. 2+2
    1
    b) Complete the reaction and write probable mechanism: 3
    PhN2HSO4 + CuBr + HBr

    Group-C
    1
    5. Write down the major product and explain stereochemistry using FMO theory. 2 2 × 2 = 5

    O
    O heat
    i. + O ?

    Me Me heat
    ii. ?
    H H

    6. a) Generally, [2+2] cycloaddition is photochemically possible but not thermally. Explain using
    FMO theory. 3
    b) Indentify X and Y. 2
    light H3C heat
    X Y
    CH3

    Group-D
    7. a) Carry out the following transformations: 2+2
    (i) p-Nitrotoluene to methylquinol
    (ii) m-Dinitribenzene to o-Bromobenzoic acid
    b) What product would you get when benzamide is treated with P 2O5? Write the mechanism of the
    reaction. 3
    8. a) Comment on the product distribution of nitration of 1-methoxy-2-phenylethane with
    (i) N2O5 in CH3CN; (ii) mixed acid. Explain you answer drawing appropriate structures. 5
    b) How can you purify alkyl isocyanide contaminated with trace of corresponding alkyl cyanide? 2

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