Equilibrium Doc 2

1.
Determine the equilibrium constant (Kc) for the following reaction if the equilibrium concentrations
of
[N2O4] = 0.00150 and [NO2] = 0.571. Write the equilibrium expression and solve for the value of
Kc.
N2O4(g) ⇌ 2NO2(g)
2. For the reaction CH4(g) + H2O(g) ⇌ CO(g) + 3H2 (g) at 1500°C, an equilibrium mixture of these
gasses was found to have the following concentrations [CO] = 0.300M, [H2] = 0.800M and [CH4] =
0.400M. Kc at 1500°C = 5.67. Determine the equilibrium concentration of H2O in this mixture.
3. Nitrogen and hydrogen react together in a 4.00 liter container at 450°C. At equilibrium, [N2] =
0.130,
[H2] = 0.220, and [NH3] = 0.650. Calculate the equilibrium constant (Kc) for this reaction.
4. A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular
hydrogen and iodine according to the equation:
2HI (g) ⇌ H2(g) + I2(g)
When the system comes to equilibrium at 425 °C, PHI = 0.708 atm, and PH2 = PI2 = 0.0960 atm.
Calculate the value of Kp.
5. Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular

chlorine according to the reaction: PCl3 (g) + Cl2 (g) ⇌ PCl5 (g). If an equilibrium mixture at 450 K
contains P(PCl3) = 0.124 atm, P(Cl2) = 0.157 atm and Kp = 16.5, then what is the equilibrium
pressure of PCl5?
6. An equilibrium mixture of O2, SO2 and SO3 contains equal concentrations of SO2 and SO3.
Calculate
the concentration of O2 if Kc = 270. for the reaction: 2 SO2(g) + O2(g) ⇌2 SO3(g)
7. The value of Kc for the equilibrium N2O4 (g) ⇌ 2NO2 (g) is 4.64 x 10–3 at 25ºC. If the initial
concentration of N2O4 is 0.0367M, what will be the concentration of both gasses at equilibrium?
8. At 650°C, the reaction below has a Kc value of 0.771. If 2.00 mol of both hydrogen and carbon
dioxide are placed in a 4.00 L container and allowed to react, what will be the equilibrium
concentrations of all four gasses?
H2(g) + CO2(g) ⇌ CO(g) + H2O(g)
9. Find the equilibrium constant, Kc, for the following equilibrium. The initial concentrations of AB
and
A2D are 0.30 M before they are mixed and when equilibrium is reached, the equilibrium
concentration of A2D is 0.20 M.
2AB(g) + C2D(s) ⇌ A2D(g) + 2CB(s)
10. A 5.00 L reaction vessel is filled with 1.00 mol of H2, 1.00 mol of I2 and 2.50 mol of HI. Kc (at 500K)
is
129. Calculate the equilibrium concentrations of H2, I2 and HI at 500K given the reaction:
H2 (g) + I2 (g) ⇌2HI (g).
11. For the reaction H2 (g) + Cl2 (g) ⇌ 2HCl (g), Kc = 3500. A reaction vessel initially containing [HCl] =
0.95 M is allowed to achieve equilibrium. What is the equilibrium concentration of HCl?
12.. Consider the equilibrium expression for the reaction: N2 (g) + O2 (g) ⇌ 2NO (g). When 0.50 atm
of
nitrogen and 0.40 atm of oxygen are placed in a container, 40.0% of the nitrogen gas reacts to
reach equilibrium. Calculate Kp.
13. The Kc for the equilibrium of 2NO (g) + O2 (g) ⇌ 2NO2 (g) is 5.4 × 1013 at 480.0°C. What is the Kp?
14. 4CuO (s) + CH4 (g) ⇌ CO2 (g) + 4Cu (s) + 2H2O (g).
When 1.00 atm of methane(CH4) is exposed to copper(II) oxide, equilibrium is established with a
TOTAL equilibrium pressure of 2.40 atm. Determine Kp and Kc.
15. Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution:
HCHO (aq) ⇌ CHO-(aq) + H+(aq) Kc = 2.00
At 25 °C a 0.100 M solution of acetic acid reacts until equilibrium. What is the hydrogen ion
concentration at equilibrium?
16. Dinitrogen tetroxide partially decomposes according to the equilibrium: N2O4 (g) ⇌ 2NO2 (g). A
1.000-L flask is loaded with 3.00 × 10–2 mol of N2O4. At equilibrium, 2.36 × 10–2 mol of N2O4
remains.
Kc for this reaction is:
17. Carbonyl bromide, COBr2, can be formed by reacting CO with Br2. A mixture of 0.400 mol CO,
0.300
mol Br2, and 0.0200 mol COBr2 is sealed in a 5.00L flask. Calculate equilibrium concentrations for
all
gasses. Kc = 0.680
CO(g) + Br2(g) ⇌ COBr2(g)
18. When wine spoils, ethanol is oxidized to acetic acid as O2 from the air dissolves in the wine:
C2H5OH (aq) + O2 (aq) ⇌ CH3COOH(aq) + H2O(l) The value of Kc for this reaction at 25ºC is
1.2 x 108. If a 10.0 L barrel contains 300.0 mol C2H5OH, 750.0 mol oxygen gas, and 250.0 mol
CH3COOH in liquid water, which way will the reaction shift? Explain
19. Sn(s) + 2CO2 (g) ⇌ SnO2 (g) + 2CO(g). A container with both solids, 0.60 atm of carbon dioxide
and
0.80 atm of carbon monoxide is allowed to react to equilibrium. Kp = 64.0. What is the equilibrium
pressure of carbon dioxide?
20. __NO (g) + __Cl2 (g) ⇌ __NOCl (g). Balance the equation using whole number coefficients. The
Kc
for the reaction is 0.00555. If a solution has 0.10 mol of each substance at equilibrium, which way
will the reaction shift? Explain
21. What does a large Keq imply?
a. The reaction always proceeds in the forward direction toward products

b. The reaction always proceeds in the reverse direction toward reactants
c. The reaction is endothermic
d. The reaction is exothermic
e. The equilibrium mixture has a higher concentration of products than reactants
22. Which of the following regarding Q and K is FALSE?
a. When Q > K, the reverse reaction rate is higher than the forward reaction rate
b. When K < Q, the reaction will shift left
c. When Q < K, the reverse reaction rate is lower than the forward reaction rate
d. When K > Q, the reaction will shift right
e. When K = Q, the reaction stops occurring
23. Which of the following is NOT part of the RICE method for determining equilibrium
Concentrations?
a. “I” = initial concentrations

b. “C” = changing stoichiometric concentrations
c. “R” = rate of reaction
d. “E” = equilibrium/ending concentrations
e. “R” = balanced reaction
24. Consider the following graph, showing 3 gasses reaching equilibrium. Which of the
following is true?
a. The Keq is likely greater than 1.

b. There are two products and one reactant
c. Kp is smaller than Kc
d. The reaction is endothermic
e. Addition of a catalyst would increase the equilibrium concentrations

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1.

2HI (g) ⇌ H2(g) + I2(g)

5. Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular

2AB(g) + C2D(s) ⇌ A2D(g) + 2CB(s)

21. What does a large Keq imply?

a. The reaction always proceeds in the forward direction toward products

a. “I” = initial concentrations

a. The Keq is likely greater than 1.

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