Liquid Laundry Detergent GHS SDS

Page 1 of 6 Liquid Laundry Detergent® US GHS
SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Liquid Laundry Detergent
OTHER MEANS OF IDENTIFICATION: Not applicable.
GENERAL USE: For professional laundry and wetcleaning use only.
PRODUCT DESCRIPTION: Laundry Detergent
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS

Adco Professional Products LLC Medical Emergency: 866-303-6947 (USA & Canada
1706 Ledo Rd. only) or 651-632-9272
Albany, GA 31707 Transportation Emergency: 800-424-9300 (USA &
Product Information: 800-821-7556 (USA Canada only) or 703-527-3887
& Canada only)
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
Acute Toxicity, Oral: Category 4
Eye Damage/Irritation: Category 1
Skin Corrosion/Irritation: Category 3
Carcinogenicity: Category 2
GHS LABEL ELEMENTS
Symbol(s):
Signal Word: Danger
Hazard Statements:
H302 – Harmful if swallowed.
H315 – Causes skin irritation.
H318 – Causes serious eye damage.
H351 – Suspected of causing cancer.
Precautionary Statements:
P264 – Wash thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P280 – Wear protective gloves and eye protection.
P301+P312+P330 – IF SWALLOWED: Call a POISON CENTER or doctor physician. Rinse
mouth.
P302 + P352 – IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338+P310 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/physician.
P308+P313 – If exposed or concerned: Get medical advice/attention. P332+P313 – IF SKIN irritation
occurs: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash before reuse.
Page 2 of 6 Liquid Laundry Detergent US GHS
P501 – Dispose of contents/container in accordance with local/regional/national/international

regulations.
Other Hazards: Not available.

Unknown Acute Toxicity: 49% of the ingredients in this product have unknown acute toxicity.
3. COMPOSITION / INFORMATION ON INGREDIENTS

The specific identities of one or more components of this product are withheld as a trade secret.
Chemical Name Wt.% CAS#
Trade Secret #1 - -
Trade Secret #2 - -
Diethanolamine 3-7 111-42-2
4. FIRST AID MEASURES

EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical
attention.
SKIN: Remove contaminated clothing. Wash with water. Consult a physician if irritation persists.
INGESTION: Get immediate medical attention. Do not induce vomiting unless instructed to do so by
poison center or physician.
INHALATION: Remove affected person to fresh air. If not breathing, give artificial respiration. Get
medical attention.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES: Pain, tearing, redness.
SKIN: Irritation, pain, redness, and blistering.
SKIN ABSORPTION: No data available.
INGESTION: Gastrointestinal irritation, pain, nausea, and diarrhea.
INHALATION: Respiratory tract irritation.
ADDITIONAL INFORMATION: After emergency actions, call the emergency medical information
number on page 1 or a physician immediately.
5. FIRE FIGHTING MEASURES

FLAMMABLE CLASS: Not applicable.
EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, foam, water spray or fog.
HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide, oxides of sulfur,
hydrogen sulfide, oxides of nitrogen.
FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-
demand, (MSHA/NIOSH approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES

SMALL SPILL: Clean up spill with absorbent material and water, if necessary.
LARGE SPILL: Contain spill. Clean up spills immediately with absorbent material, observing precautions
in the Exposure Controls / Personal Protection section (see section 8). Place absorbed material in closed
containers for disposal (see section 13).
7. HANDLING AND STORAGE

GENERAL PROCEDURES: Not applicable.
HANDLING: Follow all SDS/label precautions even after container is emptied because it may retain
product residues.
STORAGE: Store in labeled, tightly sealed containers.
ELECTROSTATIC ACCUMULATION HAZARD: Not applicable.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
ppm mg/m3 ppm mg/m3 ppm mg/m3
Trade Secret #1 TWA NE[1] NE
STEL NE NE
Trade Secret #2 TWA NE NE
STEL NE NE
Diethanolamine TWA NE 1[2][3]
STEL NE NE
TABLE FOOTNOTES:
1. NE=Not established.
2. A3=Confirmed animal carcinogen with unknown relevance to humans.
3. Skin notation.
The specific identities of one or more components of this product are withheld as a trade secret.
ENGINEERING CONTROLS: Not applicable.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety glasses with side shields, or goggles.
SKIN: Nitrile or Barrier™ gloves.
RESPIRATORY: None required under ordinary conditions.
PROTECTIVE CLOTHING: Where contact is likely, wear appropriate chemical resistant
equipment, which depending on circumstances may include gloves, a chemical suit, rubber boots,
and chemical safety goggles plus a face shield.
WORK HYGIENIC PRACTICES: Wash thoroughly after handling. Do not eat or drink in work area.
OTHER USE PRECAUTIONS: Have eye wash station available. Do not wear contact lenses without eye
protection.
9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Clear.
PHYSICAL STATE: Liquid.
COLOR: Light yellow.
ODOR: Lemon- citrus.
ODOR THRESHOLD: No data available.
pH: 8-9
FREEZING POINT: No data available.
INITIAL BOILING POINT: >149°C (300°F)
FLASHPOINT: >110°C (230°F) (PM)
EVAPORATION RATE: No data available.
FLAMMABILITY (Solid, Gas): Not applicable, this product is a liquid at room temperature.
FLAMMABLE LIMITS: Not available.
VAPOR PRESSURE: No data available.
VAPOR DENSITY: No data available.
RELATIVE DENSITY: 1.051
SOLUBILITY IN WATER: Miscible.
PARTITION COEFFICIENT (Log Kow): No data available.
AUTOIGNITION TEMPERATURE: Not available.
DECOMPOSITION TEMPERATURE: No data available.
VISCOSITY: 241 sec, Zahn #2
PERCENT VOLATILE: ~35
10. STABILITY AND REACTIVITY

REACTIVITY: No.
CHEMICAL STABLITY: Stable.
POSSIBILITY OF HAZARDOUS REACTIONS: Polymerization will not occur.
CONDITIONS TO AVOID: High heat.
INCOMPATIBLE MATERIALS: Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Burning produces toxic, irritating fumes.
11. TOXICOLOGICAL INFORMATION

ROUTES OF EXPOSURE: Skin.
ACUTE TOXICITY (ATE)
DERMAL LD50: Insufficient data available.
ORAL LD50: Insufficient data available.
INHALATION LC50: Insufficient data available.
CHRONIC TOXICITY
TARGET ORGANS: No data available.
SENSITIZATION: Insufficient data available.
CARCINOGENICITY
IARC: A component of this product is classified as Group 2B (Possibly carcinogenic to
humans).
NTP: Not listed as a carcinogen.
OSHA: Not listed as a carcinogen.
OTHER: ACGIH: A3. A component of this product is a confirmed animal carcinogen
with unknown relevance to humans.
OTHER: No data available.
REPRODUCTIVE EFFECTS: Insufficient data available.
MUTAGENICITY: Insufficient data available.
SYNERGISTIC MATERIALS: No data available.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye damage.

SKIN: Insufficient data available.
SKIN ABSORPTION: Insufficient data available.
INGESTION: Harmful if swallowed. May cause burns to mouth, throat and stomach.
ASPIRATION HAZARD: No.
INHALATION: Not a route of exposure under normal conditions.
MEDICAL CONDITIONS AGGRAVATED: No data available.
12. ECOLOGICAL INFORMATION

ECOTOXICITY: A component of this product has moderate aquatic toxicity.
PERSISTENCE AND DEGRADABILITY: No data available.
BIOACCUMULATIVE POTENTIAL: No data available.
MOBILITY IN SOIL: No data available.
OTHER ADVERSE EFFECTS: No data available.
13. DISPOSAL CONSIDERATIONS

DISPOSAL METHOD: Dispose of in accordance with federal, state and local regulations.
EMPTY CONTAINER: Do not cut or weld empty drums.
RCRA/EPA WASTE INFORMATION: Contains no material listed by RCRA as a hazardous waste.
14. TRANSPORT INFORMATION

DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not regulated.
OTHER SHIPPING INFORMATION: Not applicable.
CANADA TRANSPORT OF DANGEROUS GOODS
OTHER SHIPPING INFORMATION: Not applicable.
AIR (ICAO/IATA)
15. REGULATORY INFORMATION

UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES:
FIRE: No. PRESSURE GENERATING: No. REACTIVITY: No. ACUTE: Yes.
CHRONIC: Yes.
313 REPORTABLE INGREDIENTS: Not applicable.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA RQ: Not applicable.
REPORTABLE SPILL QUANTITY: Not applicable.
RCRA STATUS: See section 13.
MEXICO
Not applicable.
STATE REGULATIONS
MASSACHUSETTS
Contains one or more substances regulated by the Massachusetts Substance List.
CALIFORNIA
PROPOSITION 65 STATEMENT: This product contains a small amount of
diethanolamine, which is known to the state of California to cause cancer.
16. OTHER INFORMATION
NFPA RATINGS
HMIS RATINGS
HEALTH 1 1
FLAMMABILITY 1
1 0
REACTIVITY 0
PERSONAL PROTECTION B
SDS Revision Date: August 6, 2015

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Page 1 of 6 Liquid Laundry Detergent® US GHS

SAFETY DATA SHEET

MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS

GHS LABEL ELEMENTS

Signal Word: Danger

P501 – Dispose of contents/container in accordance with local/regional/national/international

Other Hazards: Not available.

3. COMPOSITION / INFORMATION ON INGREDIENTS

4. FIRST AID MEASURES

5. FIRE FIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

OSHA PEL ACGIH TLV Supplier OEL

ppm mg/m3 ppm mg/m3 ppm mg/m3

Trade Secret #1 TWA NE[1] NE

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

EYES: Causes serious eye damage.

12. ECOLOGICAL INFORMATION

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

15. REGULATORY INFORMATION

16. OTHER INFORMATION

SDS Revision Date: August 6, 2015

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