Landfill Gas Emissions From Landfills in
Landfill Gas Emissions From Landfills in
Vogdt, J.
Ingeniería Alemana S.A., Av. Antonio Varas 2700, Ñuñoa, Santiago de Chile, Chile
Wens, B.
RWTH Aachen University, Wüllnerstraße 2, D-52070 Aachen, Germany
Braeutigam, K.-R.*; Gonzalez, T.
Karlsruhe Institute of Technology, POB 3640, D-76021 Karlsruhe, Germany
Abstract
The German Helmholtz-Association and Karlsruhe Institute of Technology (KIT) is carrying out
an integrated research initiative on the sustainability of mega-urban developments in Latin
America, including solid waste management of the Metropolitan Region of Santiago and with the
participation of the RWTH Aachen University, Ingeniería Alemana S.A. and other associated
local institutes.
Treatment of Mixed Solid Waste (MSW) in Santiago de Chile is limited mostly to final disposal at
landfills, without any previous biological or thermal treatment, nor any recovery of biomass. Due
to the decomposition of the organic fraction of MSW leachate is produced, as well as landfill gas,
which contributes to global warming, local air pollution, odour and increased risk of fires, explo-
sions and potential exposure of workers to toxic emissions. Landfill gas emissions and their as-
sociated impacts can be mitigated by collecting the gas from the landfill to be burned or used as
a fuel source; however the quantities that can be captured are limited by the techniques applied.
Another approach is minimizing the amount of organic material disposed of at landfills, which
does not only reduce the production of landfill gas, but in addition mitigates most of the more
notorious environmental and social impacts of current waste management practices.
In this paper existing and potential CDM activities for landfills in Santiago de Chile are described.
In addition different scenarios, including “business as usual” (capture and flaring of landfill gas,
plus improved recycling), mechanical-biological treatment of MSW, as well as the separate col-
lection and composting of different shares of the organic fraction are defined. These scenarios
are evaluated with respect to their impact on reducing landfill gas emissions and overall sustai-
nability.
Palabras Clave: recolección segregada, relleno sanitario, emisiones atmosféricas, gases de invernadero,
modelación, sustentabilidad
*
Correspondence: jv@iasa.cl
1
1. The investigation project “Risk Habitat Megacity”
Urbanisation is one of the most dramatic processes of global change. Particularly in mega-urban
regions, it induces trends with both regional and global consequences that are not yet well un-
derstood. Mega-urbanization is not just connected with unprecedented growth, high population
density, and a concentration of economic and political power, but also with a complex variety of
simultaneous and interacting processes. They turn the urban habitat into a space of both risk
and opportunity.
A research initiative of the German Helmholtz-Association, which started in 2007 [1], analyses
mature and developing megacities in Latin America, one of the most urbanized regions in the
world. Its large agglomerations are of crucial socio-economic importance for the entire continent.
At the same time, urbanisation in this region is about to reach a new dimension. Subject of the
first case study is the Metropolitan Region of Santiago de Chile (MRS), which is in relative terms
one of the most centralized urban centres of Latin America (with respect to total population and
surface). Like other Latin-American urban centres, this agglomeration suffers from typical
megacity problems and offers the scope to uncover emerging trends.
Santiago de Chile offers an excellent research infrastructure and research partners with interna-
tional recognition. From Santiago, the project will be extended to other megacities in Latin Amer-
ica. The investigation initiative will:
The analytical framework of the initiative is innovative due to its integrative and interdisciplinary
character, which allows scientists, policy makers and society in general to deepen the under-
standing of megacities as a system. The sustainable development concept serves to formulate
the target dimension of the project. The risk concept assists in identifying problems and evaluat-
ing their relevance, while the governance concept focuses on the actors and options for manag-
ing megacities.
Within the project these three analytical concepts are applied to various application fields, which
are considered significant for the megacity investigation-concept. Figure 1 gives an overview of
the project structure and shows the different fields of application that will be analysed in detail
with respect to sustainability, risk and governance.
As already mentioned the work within “Risk Habitat Megacity” will among other specific objec-
tives contribute to the definition of sustainability goals for the future development of waste man-
2
agement in Santiago de Chile. In order to evaluate waste management with respect to sustain-
ability criteria, different sustainability indicators have been worked out [2], including the following:
• specific waste arising (kg/(person*day))
• amount of pre-treated waste that is sent to adequate landfills in relation to total waste
arising
• greenhouse gases (landfill gases) emitted due to waste management (CO2-equivalents
per person and year)
In addition, the investigation will contribute to design and evaluate strategies for a more sustain-
able development within the field of waste management. Keeping this in mind, the elaboration
will concentrate on the following topics:
• overview of the actual situation of waste management in Santiago de Chile (“status quo”);
• compilation of different scenarios for the future development of waste management in
Santiago de Chile, taking into consideration the separate collection of the organic fraction
of municipal solid waste;
• model calculations of greenhouse gas emissions for these scenarios and
• evaluation of the results of these scenarios
Methods
Indicators
Water resources and services
Cross-Cutting Concept:
Socio-spatial differentiation
Waste management
Transportation
Scientific training
Training of practitioners
Cross-Cutting Concept: Workshops
Governance
3
2. Waste management in Santiago de Chile
In Santiago de Chile the amount of municipal solid waste (MSW) produced increased from about
0.7 kg/(person*day) in 1990 to approximately 1.3 kg/(person*day) in 2008, with an estimated
total generation of nearly 3 million tons/year. Although the composition of MSW has changed
and the organic fraction decreased from about 68% in 1990 to about 54% in 2004, biomass still
remains the most important waste fraction (more than 1.5 million tons per year). [3],[4],[5]
Little more than 10% of the total amount of urban waste is either recycled, mainly due to informal
activity and in a lesser extent as a result of municipal solid waste recycling programs (compare
Figure 3). Treatment of MSW in the MRS is limited mostly to final disposal, without any previous
biological or thermal treatment or recovery of biomass. There are three relatively new landfills
operating in the MRS, which receive nearly 90% of total MSW of urban Santiago area.
Lomas Los Colorados landfill is the biggest and oldest of the currently operating landfills, situ-
ated in Tiltil county about 60 km north of Santiago. It began receiving waste from the respective
transfer station in Quilicura in 1996, initially by trucks and since 2003 by train (in both cases us-
ing silos with external compaction). At the moment the landfill input is at a rate of about 150,000
tons of waste per month. Although the current contract will end in 2011, it is automatically re-
newed for 16 years if none of the parties cancel the contract early. The landfill, which is operated
by KDM, an international company specialized in solid waste management, is anticipated to
reach the end of its capacity around 2045. Landfill gas is collected and flared [6]. According to
KDM energetic utilization of landfill gas will start end of 2009 [7].
Santa Marta landfill is the second biggest of the three existing disposal sites in operation. Its
operation started in 2002 and Consorcio Santa Marta (CSM) will continue landfilling until at least
2022, the year when the contract ends (however estimates of landfill capacity predict an ex-
tended operation time). The current waste disposal rate is approximately 80,000 tons per month.
The total amount of waste disposed of at Santa Marta Landfill until the end of 2008 was about
4.7 million tons. About 80% of the waste disposed is received at the transfer station (direct dis-
charge, no compaction) and subsequently transported with special containers to the landfill.
Landfill gas is flared by five flare stacks with 1.000 m3/h capacity each. [9],[10],[11]
Santiago Poniente landfill is the newest, and also smallest, of the three landfills. It started op-
eration in October 2002 and exhibits a current filling rate of about 45,000 tons per month. The
landfill is anticipated to reach final capacity around 2025. Waste is transported directly to Santi-
ago Poniente (without a transfer station) [10]. Proactiva, the operating company, has recently
received the environmental authorization for the capture of landfill-gas, treatment and utilization
in the gas system.
In addition to the operating landfills, there is a number of old, abandoned landfills in Santiago,
which still produce landfill gas and therefore require post-operative treatment. One of the first
sanitary landfill for urban residues, La Feria, started its operation in 1977 and received 60% of
the solid residues from the city of Santiago at that time. In 1978 the landfill Cerros de Renca
started its operation, receiving 30 % of the residues. 1979 a third sanitary landfill called Lepanto
began operation receiving the remaining 10 % of the residues. In 1984 La Feria reached its end
of lifetime and was replaced by Lo Errazuriz, which in turn was replaced by “Lomas Los Colora-
dos” in 1997 and partly by Lepanto, which continued to operate for the majority of municipalities
in the south of Santiago until 2001. [12]
4
According to information obtained during on-site research in 2008 in Santiago, more than 90% of
the recycled material is collected, classified and prepared by the informal sector. The amount of
people, working in the informal sector is difficult to estimate. Most informal activities are not re-
corded in official statistics and the actors are not registered and tend to change jobs when eco-
nomical or market conditions change. In a research project, carried out in 1998 (Alaniz), about
4,000 primary collectors for MRS are estimated for the informal sector. Current estimations cor-
respond to approximately 4,000 – 10,000 collectors. [13],[14]
Therefore, a promising alternative to municipal recycling programs (and subsequent elimination
of the informal sector) with a positive social impact is the inclusion of “cachureros” into formal
recycling activities and improvement of working conditions, thereby achieving higher overall re-
cycling rates at relatively low cost.
Collection costs in Santiago range between US$ 15 and 60, with an average of US$ 26 per ton.
Disposal costs are approximately US$ 10 and US$ 15, sometimes including transfer and trans-
port costs to the landfill.
Chile has no specific laws setting down the degree of biogas collection required in a sanitary
landfill, except for venting to avoid the hazardous storage of gases; so practically all of the pro-
jects for landfill capture, efficient destruction or utilization have been implemented as clean de-
velopment mechanism (CDM) measures.
Due to the decomposition of the organic fraction of MSW landfill not only leachate but biogas is
produced, contributing to global warming, local air pollution, odours and/or other nuisance. Due
to the potential for landfill gas migration outside of the landfill’s boundaries, there are not only
direct risks such as fires, explosions and exposure of workers to toxic emissions, but also poten-
tial impacts for surrounding population and/or structures. Landfill gas emissions and their asso-
ciated impacts can be mitigated by collecting the gas from the landfill, by simply burning it in high
temperature flares for methane destruction or using it as a fuel source for energy generation.
Other possible energy applications for landfill gas include use as a fuel at an industry off-site, or
purification and injection into a natural gas pipeline. Mitigating of landfill gas emissions (including
alternatives presented in this paper) can be encouraged economically by the generation of CO2
certificates in the frame of the Clean Development Mechanisms (CDM).
CDM was established under Article 12 of the Kyoto Protocol adopted by the Third Conference of
the Parties to the Framework Convention on Climate Change on December 11, 1997 [15]. The
dual goals of the CDM are to promote sustainable development in developing countries and, at
the same time, allow industrialised countries to earn emissions credits from their investments in
emission-reducing projects in developing countries. To earn credits under the CDM, the project
proponent must prove and have verified that the greenhouse gas emissions reductions are real,
measurable and additionally demonstrate would have occurred in the absence of the project. In
the following some project designs for CDM activities in the field of landfill gas emissions will be
described shortly.
5
Under the current CDM system, which is valid until the year 2012, private landfill operators have
relatively little interest in energy recovery from landfill gas, since the relatively high investment
cost for gas-to-energy plants is much less attractive than CDMs for simple methane destruction
(flares). Apart from incentives for small power plants (the so called “Ley Corta”), there is cur-
rently very little incentive in Chile for energy use of landfill gas.
Landfill Lomas Los Colorados (gas collection and flaring resp. electricity generation). The
objective of Lomas Los Colorados Landfill Gas Project is to develop a landfill gas collection and
utilization system for electric energy production. Up to now this involves only the operating a
system for landfill gas collection and flaring; however from July 2009 (end of the year according
to newer information) part of the landfill gas collected is to be put to energy use, the generation
of electricity for use at the landfill site and for sale to users elsewhere. Estimated emission re-
ductions will be about 4 million tons of CO2-equivalents in the period 2007 to 2014 [6].
According to the latest information, the company is currently installing 2 modules of gas motors
to produce electricity for the Sistema Interconectado Central (SIC); expandable in two phases to
14 MW (2011) and 27 MW (2025) [8].
Santa Marta Landfill Gas Capture Project. The project will last 16 years, from 2007 to 2022.
The purpose is to install a highly efficient landfill gas collection system. This will involve investing
in a gas collection system, airtight covering of the landfill and flaring equipment.
At the initial stage of the project, no electricity will be generated from the collected biogas. This is
due to high investment costs in power generation equipment and grid connection and the current
low price of electricity. Another reason is the uncertainty and the variation in the actual produc-
tion of biogas. The feasibility of electricity generation will be revised every three years once the
project is fully operating.
The expected efficiency of the capture system will be at least 65 %; however these are values
which have not yet been proven under practical operation conditions. The baseline emissions
until 2022 are estimated at 751,751 tons CO2-equivalents. Total burning of methane due to the
project was estimated at 6,712,426 tons CO2-equivalents [6].
The company does not consider any energy recovery from the landfill gas in the near future; it is
currently investing into a 5.000 m3/hr. flare (total capacity 10.000 m3/hr.).
Landfill Santiago Poniente (injection of landfill gas into the natural gas grid). The project
considers injection of landfill gas into to the metropolitan gas grid, displacing the use of natural
gas (as it was done previously at the Lo Errazuriz landfill). However, before biogas is fed into the
distribution grid, it has to be treated in an upgrading facility, where most of the non-methane
gases will be removed from the stream to meet the sales specifications of Metrogas S.A.
It is expected that an average of 70 million m3 of biogas per year can be injected to the distribu-
tion grid in the first 7-year crediting period, avoiding the consumption of an average of 37 million
m3 of natural gas per year.
The emission reductions estimated for the first 7-year crediting period are more than
420,000 tons CO2-equivalents [16].
Lepanto Landfill Gas Management Project. The purpose of the project at this landfill (which
was closed in 2002) is to develop works and equipment to capture and destroy the methane
produced by the Lepanto Landfill using a highly efficient controlled flaring system. However in
6
the case of Lepanto the landfill gas has been used for many years in the past in nearby indus-
tries (which provided gas cleaning system, hence practically no investment for the operator).
The basic objectives of the project include an improvement in the existing impermeabilisation
system, the implementation of new biogas extraction wells and a conveyance piping system,
assisted by suction and pressure pumps, to carry the biogas to a treatment plant where it will be
flared. The plant will be capable of treating a maximum flow of 5,000 m3/hr (an average of 2,700
m3/hr is expected).
In the future the project might also include the generation of electrical or thermal energy, how-
ever, this is not a current proposal. Because of the complexity of the system and the lack of ex-
perience in this type of project in Chile, it is commercially not attractive and difficult to implement.
Nevertheless, both possibilities are under evaluation [17].
7
2.0
1.8
emissions of methane (million tons per year)
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
0
0
9
2
19
20
20
20
Figure 2: Calculated emissions of methane from landfills in Germany (according to [20])
While waste management strategies in the 90ies focused on recycling, the paradigm of sustain-
able waste management has evolved to a more integrated approach. It is based not only on re-
cycling, but also on pre-treatment of solid waste for final disposal and reduction of CO2-
emissions.
8
notorious environmental and social impacts of current waste management practices (odours,
presence of sanitary vectors).
The base scenario (BAU = “business as usual”) was evaluated considering improvements with
respect to waste minimization at the source, separate recollection and, eventually, separation at
a centralized separation plant.
9
Landfilling: 2,522,000 Mg/a
Import: Municipal Solid Waste Fluxes [=] Mg/a
Recycling: 349,000 Mg/a
2,883,000 Mg/a Stock [=] Mg
Compost: 3,300 Mg/a
2,522,000
Mixed Waste To landfills
Collection
Informal To Production
2,847,000 Mixed Waste 325,000 325,000
Mixed Processing Companies
Mixed Waste (bin, bag) Recyclables
Recyclables
Collection
To Production
21,000 (Drop-Off 21,000 Companies
Recyclables Containers) Recyclables
Segregated
Collection To Production
4,000 4,000
Mixed Mixed Companies
Mixed
Recyclables Recyclables
Recyclables
Segregated
To be used within
Collection 11,000 Composting 3,300
the community
Biowaste Bio waste Biowaste Compost
Figure 3: Mass flow of waste in the Metropolitan Region of Santiago de Chile, 2007
These differ mainly on how the waste is collected and can be divided into “differentiated collec-
tion” and “drop-off systems”. Participation in the differentiated collection is voluntary and the par-
ticipants are encouraged to allocate their recyclable materials separately from the mixed waste,
which are then collected by the municipalities at the homes. The differentiated collection nor-
mally takes place at days different from the days when MSW is collected. These systems exist in
La Pintana (biowaste), in Ñuñoa (inorganic waste), La Florida (inorganic) and María Pinto (bio-
waste and inorganic waste).
The drop-off systems involve containers located in public places where citizens deliver their
separate recyclable materials. In general, the system is associated with charity cam-
paigns/foundations. A special example is the Clean Point of the municipality of Vitacura, where
containers are located in an area of 500 m² for the recycling of paper, cardboard, plastics, fer-
rous and non-ferrous metals, yard waste, batteries and old medicines.
For the year 2007 collection by drop-off containers, which are significantly less expensive than
separate collection systems, amounts to about 21,000 tons of recyclable materials, whereas
differentiated collection of mixed recyclables results in about 4,000 tons. Additionally, about
11,000 tons of biowaste was collected separately. Data shown in the figure is based on literature
studies, surveys in communes of Santiago de Chile with recycling programs, interviews with
people from the informal sector and own estimations ([13],[21],[22]).
10
The amount of recycling material via differentiated collection is more than 5 times smaller than
the amount collected by containers associated with charity foundations. This fact can be attrib-
uted to:
• Recycling containers are set up in the whole MRS, whereas differentiated collection
takes place in small scale in less than 10 municipalities.
• People prefer collaborating in recycling due to social reasons than to environmental
ones, possibly because of the continuous advertisement of recycling associated with
charity institutions.
CO2 saving potential. Table 1 shows estimated reduction of CO2 emissions due to waste recy-
cling. Based on current quantities of recycled materials, the average savings potential was esti-
mated in 1.150 kg CO2 per ton of waste recycled; however since most of the above potential is
based on metal recycling and the remaining content of recyclable scrap in household waste lim-
ited, a value of less than 700 kg CO2/ton appears to be more realistic. The reduction of methane
emission due to the recycling activities is rather insignificant.
Costs related to recycling activities. Costs of formal recycling programs in Santiago include
investment in recollection points, classification plants as well as operation costs for the recollec-
tion system and facilities. Two recycling facilities are currently installed in the city:
• Recycling Point of Vitacura (“Punto Limpio”), with an estimated investment cost of US$ 1
Mio. in 2005; and
• Materials recovery facility of Ñuñoa with an investment cost of US$ 227,000 in 2003.
Although detailed information on operating costs of both initiatives are not available, a range of
US$ 100 to US$ 150 for separate collection of recyclable materials and classification can be
estimated for Ñuñoa, based on the number of vehicles, equipment and personal requirements.
In the municipality of Vitacura, costs of MSW management are about 75 US$/ton, which are al-
most 43% higher than the average in Santiago. One of the reasons for the higher costs might be
the operation and maintenance of the Drop Point and separate recollection in this municipality.
In general, drop-off systems do not represent additional costs for the municipality because the
costs of collection as well as maintenance of containers are taken by the Charity Foundation
associated with the recycling program or by the recycling company itself [24],[25]. Economical
benefits of drop-off systems are associated with lower costs for transfer stations and final dis-
posal in landfills.
11
According to preliminary cost estimates, the economic impact of increasing the fraction of recy-
cled materials from currently 12 to 25% was estimated in at least US$ 10 per ton; average waste
hauling costs for a municipality like Maipú would increase to around US$ 35 per ton plus separa-
tion in a centralized plant.
This scenario requires a separate collection of organic waste and transport by trucks to a cen-
tralized composting plant. Since the current frequency for ordinary recollection of MSW is at
least three times per week, it is reasonable to assume that the minimum frequency of biomass
collection is twice a week (eventually replacing one hauling cycle for common household waste).
Waste hauling costs are expected to increase proportionally (≈ 30%). Collected biomass in-
cludes food residues, yard waste; containers may be required.
The composting process includes a range of alternatives, from very simple and inexpensive
methods for yardwaste to more expensive and high-tech methods:
Simple aerated pile composting systems are currently available technologies in Chile, turned pile
being the most common method, followed by active aeration in some of the newer plants. Figure
4 shows a flow sheet of a simple aerated pile composting plant:
< 30 mm
Emissions Residues
Gases, process water For disposal
The duration of the whole process is between 6 and 8 month, however the most frequent aera-
tion is required during the first two month, when leachate generation, nuisance potential and or
other emissions are more intense. The residual products of the process are transported to be
used within the community or spread on agricultural land. Only a very small fraction of screening
residues (estimated in 2 to 3%), is being transported to a landfill for final disposal.
12
There are air emissions from transport of collected household waste, from the composting proc-
ess itself (incomplete aeration), from the transport of residues and finally from landfilling and
application of compost.
Advantages:
Disadvantages:
Site election of a composting plant is nearly as critical as a landfill in the MRS, a fact that is un-
derlined by the re-location of several existing plants (Armony, Agroindustrial Pullihue) and the
rejection of environmental permits for a new composting plant in Maipú.
CO2 saving potential of Composting in Chile. Reduction potential of biomass and greenhouse
gas emissions of this alternative is significant: >10% green waste from public spaces; plus sepa-
rate food and garden waste from houshouls (>20%).
Treatment Costs. Based on a plant capacity of 50.000 ton/year, treatment costs for segregated
biowaste in a simple open pile composting plant are estimated at approximately US$ 20 per ton
(Source: IASA, various studies on costs of waste management alternatives, between 2001 and
present).
13
Before starting the evaluation, it has to be clear that mechanical-biological treatment is a collec-
tive term that relates to a number of alternative processes, involving both a mechanical and a
biological treatment. Whether the biological treatment is aerobic or anaerobic, or in which order
the process steps are arranged, is not defined. Therefore, an example of the quantitatively more
significant process variations existent in Germany, the combination of a mechanical and an
aerobic biological treatment, is discussed here. As displayed in the simplified flow sheet dis-
played in Figure 5, the waste is fed to the mechanical treatment prior to the biological treatment.
There, the material is separated according to the particle size, whereas the fraction > 60 mm
features the main share of unwanted components with respect to the subsequent biological
treatment. These are often higher calorific waste components, i.e. plastic foils, which may be
removed via air classifier or concentrated in fractions with greater particle sizes (> 120 mm in the
example below). Then, ferrous and non-ferrous metals are removed from the waste with mag-
nets or eddy current separators to produce pre-concentrates for subsequent purification and
application in the steel industry.
Recyclable Materials
Separation
> 120 mm High calorific fraction (~ >120mm)
Sieving, (air classification),
Ferrous metals
metal extraction
Non-ferrous metals
~ 60 - 120 mm
> 60 mm
Residues
Mechanical treatment < 60 mm Biological treatment Separation For final disposal
Mixed
Feeding, comminution, Intensive rotting, Air classification, metal on landfills or for
waste sieving biodrying extraction further thermal
treatment
Emissions
Gases, process water
The share of biodegradable organic waste components increases with decreasing particle size.
The material < 60 mm is fed to the biological step without further processing in most cases. A
separation of potential recyclables from this waste stream, akin to that of the greater sized mate-
rial described above, is more feasible after biological treatment because recyclable materials
can be separated more efficiently in the dried waste.
During aerobic biological treatment, the biodegradable organic substances are decreased, while
air is introduced into the rotting pile. Furthermore, water is added to promote the processes. The
aim of the mechanical treatment is the extraction of extraneous material (e.g. great particles like
plastic foils), which may prohibit sufficient fluctuation of air and water that is needed to provide a
stable ambience for the aerobic processes. At the end of the biological treatment, the elevated
temperatures in the piles are used to dry the waste.
Table 2 summarises the output materials from MBTs in 2006. More than 50% of the output gen-
erated was determined for energy recovery in appropriate incineration facilities. One fourth of the
output material could be landfilled without further treatment, while the low calorific fraction with a
share of 8.3% had to be treated thermally in waste incineration plants.
14
Table 2: Output of 56 German MBTs in 2006
Mass Share
Fraction Further treatment
[Mg] [%]
Landfill material 1 192 307 24.9 Final disposal
Low calorific fraction 399 454 8.3 Incineration plant; final disposal
Medium calorific fraction 1 918 928 40.0 Energy recovery; final disposal
High calorific fraction 598 825 12.5 Energy recovery; final disposal
Ferrous metals 151 589 3.2 Subsequent purification; re-use
Non-ferrous metals 10 880 0.2 Subsequent purification; re-use
Impurities 156 735 3.3 Incineration plant; final disposal
Other 363 892 7.6 Incineration plant; final disposal
Sum 4 792 610 100.0
Fractions suitable for material recycling are ferrous and non-ferrous metals, together represent-
ing a share of 3.4% of the MBT output. In comparison hereto, the generation of plastics deter-
mined for material recycling only represented 0.08% of the total output [27]. This fact is easy to
understand considering the relatively low market value, the high complexity of generating rudi-
mentary sorted plastic fractions and the organic and mineral surface contaminations on the ex-
tracted recyclables. Material recycling of clean or separately collected plastics from waste types
that are separated in origin is more feasible.
It is important to underline that the high calorific fractions produced as fuels or fuel substitutes
are not sold with a positive market value. Fuels from waste contain numerous contaminants that
require special attention. The cleaning of the exhausts and/or the application of resistant con-
struction materials as in waste incineration plants is necessary, due to the presence of aggres-
sive substances (e.g. HCl resulting from the chlorine contained; primarily in PVC). Accordingly,
the elevated operating efforts of installations designed for waste incineration or energy recovery
from waste is mirrored in the high investment and the high operational costs. The operators of
plants utilizing these alternative fuels, charge for their receipt. Considering this, it becomes clear
that the main objective of MBTs in Germany is to decrease the total mass of waste that has to
be incinerated, and the high costs associated with it. The additional recovery of materials can be
seen as a way of lowering the operational costs. Of course actual benefits result from material
recovery, but clearly MBTs should not be seen as end-of-pipe solutions but as a pre-treatment
that always involves further, but more advanced treatment of the generated output streams.
CO2 saving potential of MBTs in Chile. When evaluating the implementation of MBTs into the
Chilean waste management system, different aims have to be defined under consideration of
the existing infrastructure. The legal framework in Chile does not oblige the waste sector to fulfil
certain standards with respect to the final disposal of mixed MSW. Still, in both countries it needs
financial motivation to enforce this treatment path. The constraint to fulfil legal requirements in
Germany (which are connected to environmental benefits) is limited to a number of different so-
lutions, of which those with the lowest possible costs are generally utilised. In Chile the motiva-
tion is to enhance environmental safety, while covering the costs via generation of CDM certifi-
cates.
15
In general, MBTs offers several ways of decreasing CO2 emissions. In order to give a realistic
assessment of the possible generation of CDM certificates, only the most basic alternative, the
reduction of the content of organic waste, is evaluated in this work. The result can then be con-
sidered a minimum perspective with further optimisation potential. However, the other possibili-
ties of CO2 reduction, as well as the benefits deriving from them, will be briefly discussed:
• Reduction of the organic content of the waste that is disposed on landfills
• Substitution of fossil fuels by producing a high calorific waste fraction
• Substitution of primary raw materials (e.g. metals)
• Substitution of fossil fuels by energy recovery from biogas produced in the anaerobic
treatment
• Utilisation of stabilised fine fraction as filter material for the methane oxidation cover on
landfills
The only noteworthy pathway for energy recovery from waste in Chile is the substitution of regu-
lar fuels in cement plants. Partially, these capacities are already used to treat hazardous wastes.
Thus, there is a great uncertainty regarding the capacities available for energy recovery from
high calorific fractions. Anaerobic treatment and use of biogas will not be considered, since this
means increased process complexity and investment costs. In addition to the process complex-
ity, operating these plants has shown to be extremely sensitive, regarding the heterogeneous
characteristics of the treated materials.
Production of concentrates of ferrous and non-ferrous metals is relatively simple regarding the
technology used. However, these pre-concentrates require further cleaning in order to utilise
them as secondary raw material. In the case of ferrous metals only impurities have to be re-
moved, whereas in the case of non-ferrous metals additionally the different metals, i.e. alumin-
ium or copper, have to be sorted in order to reach purities qualifying them as secondary raw
materials. Besides the relatively high market value of the metals and the chance of establishing
or extending the recycling sector in Chile, great energy savings (and CO2 savings respectively)
are connected with the optional metal extraction. A standardised model application for savings of
greenhouse gases however, does not yet exist.
The use of some of the biological stabilised fraction as a methane oxidation layer for landfills is
not practical in Chile, because this option is adequate for landfills where the generation of landfill
gas is too low for a thermal reduction or a substitution of fossil fuels.
Costs of operation are in a range between 15 and 70 €/ton depending on the technical stan-
dard applied in the MBT [28]. The investment is in the range between 11 € and 21 € per ton [29].
For comparison, the mass specific investment for waste incineration starts at about 22 €/ton [29].
Advantages of MBTs:
• Besides the decrease of gas emissions, the potential of contamination of ground water
due to leachate from the landfills is minimised
• Recycling rates increase and waste is exploited as a resource
• Can be pursued without active participation of waste generators
16
Disadvantages of MBTs:
• The more diverse products are generated, the more complex the treatment has to be and
the more expensive it is
• Treatment costs may be higher than the benefit from emission trade / product distribution
• Downstream processing and utilisation structures must exist
• Compost products suitable for agricultural use cannot be produced
6.1 Methodology
In order to set up and evaluate different scenarios for waste management in Santiago de Chile a
set of data and boundary conditions has to be defined.
Time horizon. Due to the fact that one of the three landfills in Santiago de Chile – Santa Marta
landfill – which started its operation in 2002, will continue land filling only until 2022, model cal-
culations will take into consideration the time span from 2001 to 2022.
Population development. The last census in Chile, which was performed by the Instituto Na-
cional de Estadisticas (INE) in 2002, was taken as a basis for the population development for
the time span from 2001 to 2022 [30]. The rate of population growth was also taken from [30],
starting from 5,828,254 people for 2001 and resulting in a total population of 6,970,295 in 2022.
Waste arising. Municipal solid waste (MSW) that is disposed at to one of the three landfills in
Santiago de Chile, is weighed at the entrance of the landfill. As a result, data for total MSW de-
posited in Santiago de Chile during the last years are available [31]. For the scenario calcula-
tions this data has to be modified, because in addition to municipal solid waste from households
also waste resulting from cleaning public areas are brought to landfills and are not accounted for
separately. These amounts are not directly correlated with the amount of waste accessible from
households and businesses in Santiago and were therefore not taken into consideration.
In order to estimate the share of waste resulting from public areas, in 2007 the disposal at the
landfill “RS Santiago Poniente” has been observed on sight over a period of 2 weeks, whereas it
became clear that great parts of the waste from cleaning public areas could be identified via the
type of the vehicle delivering. These amounts have been calculated and extrapolated to the
whole region of the RM Santiago, resulting in an estimated 356,000 tons per year [10] that are
not directly linked with population growth.
With the above mentioned data specific arising of municipal solid waste (kg per person and year)
was calculated for the years 2001 to 2007. Accordingly, the generation of household waste per
capita in 2007 was estimated at 0.98 per person and day. For the years 2008 to 2022 a constant
value of 1 kg per person and year was chosen, resulting in total waste arising for the model cal-
culations of about 1.81 million tons in 2001 and about 2.54 million tons in 2022 with a total of
about 50 million tons for the time span from 2001 to 2022 (see Figure 6).
17
2.7
]
a
/ 2.5
g
M
o
i
M
[
2.3
W
S
M
f
o
n 2.1
o
it
a
r
e
n
e 1.9
G
1.7
2001 2006 2011 2016 2021
Year
Waste composition. Data for waste composition was taken from a study, performed by the Uni-
versidad Catolica de Valparaiso in 2006 [32]. Within the scenario calculations separate collec-
tion was taken into account only for food waste (share of 37.41 %) and garden waste (share of
12.08%).
Waste characteristics. Data for water content of waste and total carbon content of waste had
to be taken from literature [33],[34] due to lack of this information in [32]. Table 3 shows the
waste characteristics, used for the model calculations the share of the different waste fractions,
their water content and the content of biodegradable organic carbon of the different waste frac-
tions. In the last column, calculated values for the organic carbon content in 1 kg of MSW, result-
ing from the specified waste fraction is given; that means, that the contribution from food waste
(residuos de alimentos) to the organic carbon content of 1 kg of MSW is 65.1 g, that of garden
waste (residuos de jardín y poda) 19.79 g etc. In total, the organic carbon content of 1 kg of
MSW amounts to 156.78 g. This value changes, when different fractions of organic waste are
separated and thus are not disposed of at landfills.
18
Table 3: Waste characteristics representing mixed MSW
Biodegradable Corg Biodegradable Corg
Share in MSW Water content
Fraction in dry substance in MSW
[%] [%]
[%] [g/kgMSW]
Food waste 37.4 62 458 65.10
Garden waste 12.1 62 431 19.79
Paper 15.1 22 377 44.41
Paper board 2.8 22 397 8.74
Plastic 13.6 18 0 0.00
Tetra Pak 0.6 19 276 1.26
Diapers 6.9 63 389 9.95
Rubber 0.0 7 0 0.00
Leather 0.0 7 0 0.00
Glas 4.7 1 0 0.00
Metal 1.7 2 0 0.00
Wood 0.2 14 0 0.00
Textiles 2.0 15 314 5.39
Dirt and ashes 1.2 28 105 0.93
Batteries 0.0 1 0 0.00
Bones 0.2 2 204 0.49
Fruit stones 0.3 14 0 0.00
Ceramic 0.6 2 0 0.00
Others 0.1 28 204 0.21
Not specified 0.4 28 204 0.51
19
corg= biodegradable organic carbon content in kg/ton of waste
T= temperature within the body of the landfill in °C
20
Figure 7 shows the time dependent generation of landfill gas. Assuming a value of
corg = 156.78 g/kg (see Table 3) the decomposition of 1 ton of waste is producing a total amount
of about 240 Nm3 of landfill gas or 132 Nm³ of methane respectively. In other words, the mass
specific methane generation amounts to 95 kg CH4/ton MSW or 1995 kg CO2/ton MSW.
Considering the assumptions made with respect to the generation of MSW in Santiago in the
period from 2001 to 2022, the total methane emissions resulting are 6.67 billion Nm³ or 4.76
million tons of methane respectively. Expressed in CO2 equivalent emissions, the total methane
emissions equal 99.96 tons of CO2.
After a landfill has been closed (in Figure 7 this would be the maximum of landfill gas generation
in 2022), no fresh organic material is fed to the landfill and the generation of landfill gas de-
creases. At some point after landfill closure, not only the generation of the gas but also the share
of methane decreases. This has to be seen critical with respect to the capture of landfill gas be-
cause the effort of methane destruction (or its utilisation for energy production) rises while the
benefits per captured gas volume decreases. In the evaluation of the BAU scenario this fact is
not paid special attention to. However, when evaluating one single landfill it has to be consid-
ered that only a limited share of the total landfill gas potential stands available for capture.
70000
]
h
/³ 60000
m
N
[ 50000
s Landfill gas
a
g
lli Methane
f 40000
d
n
la
f 30000
o
n
o
it 20000
a
r
e
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e 10000
G
0
2001 2006 2011 2016 2021 2026 2031 2036 2041 2046 2051
Year
Figure 7: Emissions resulting from MSW landfilling between 2001 and 2022
BAU scenario. Due to the fact that collection and flaring has become a standard operational
measure at landfills in the RM, the baseline scenario should involve gas capture and thermal
reduction of the methane. This scenario will be taken as basis for the evaluation of the alterna-
tive scenarios “composting” and “mechanical-biological pre-treatment. As mentioned earlier,
losses of gas due to insufficient landfill gas generation or due to diffuse emissions during opera-
tion are not exclusively considered. Assuming an overall efficiency of the gas capturing system
21
of 50%, total methane emissions of 2.38 million tons (50 million CO2 equivalent tons) emerge
from the deposited MSW. Accordingly, the mass specific methane emissions also account for
50% of the mass specific methane emission when landfilling without capturing and flaring the
gas.
Compost scenario. In order to identify the impact of the different scenarios, realistic maximum
and minimum emission reductions are needed. Participation and separation efficiency of house-
holds vary considerably with geographic and demographic or social boundary conditions and
strongly influence the acquisition of organic waste. Realistic values for the relative separate ac-
quisition of the organic waste (food waste and garden waste) are seen to be in a range between
10% and 50% (for comparison, in 2003 the acquisition of biological household waste in Ger-
many was around 58% [37]). With alternating relative acquisition rates of biowaste the organic
carbon content the waste that is brought to landfills changes. This also has an impact on the
total methane potential, which is displayed in Table 4.
Table 4: Corg and CH4 emissions from deposited MSW against acquisition of biowaste
Relative acquisitions Methane Methane emissions compared to
Corg calculated
of food potential Landfilling without flares
[g/kgWaste]
and garden waste [Mg CO2] [%]
0% 156.8 1.00E+08 100.0
10 % 155.3 9.41E+07 94.2
20 % 153.9 8.84E+07 88.4
30 % 152.5 8.28E+07 82.8
40 % 151.0 7.72E+07 77.2
50 % 149.6 7.18E+07 71.8
During aerobic biological treatment with an optimal oxygen supply no CH4 is emitted. Due to
anaerobic fields that build up in real composting processes, small amounts of CH4 are emitted
during composting. A value of 0.65 kg CH4/ton of organic substance was chosen to account for
the diffuse emissions in this study [36].
MBT scenario. As discussed before, the type of treatment chosen for the estimation of the CO2-
equivalent emissions within this scenario is a mechanical-biological pre-treatment and subse-
quent final disposal of the output material. The MBT involves a mechanical treatment with the
goal of extracting material disturbing the biological process. The following biological treatment
process is anaerobic rotting of piles covered with bio-filter material. The lower content of biode-
gradable carbon in the landfill material then results in a decreased landfill gas generation.
According to Fricke et al. the degradation rate of the biodegradable waste fractions in Germany
can be estimated with a value of 65% [28]. Recent studies of the applicability of the FABER
AMBRA Process in Villa Aleman in Chile showed that this aerobic treatment is feasible. The
waste input material used for the tests exhibited an organic content of about 55% and based on
analysis, the total organic carbon (TOC) was determined to be 29.2%. The reduction of the TOC
after about 9 month, a time span that is deemed necessary in order to stabilise the waste so that
the limitations in Annex II of the German landfill directive allow final disposal, was between 70%
and 85% [38]. To include the fact that the higher content of organic waste in Chile is 15% to 20%
higher than in Germany, as a realistic approach for degradation of the biodegradable organic
carbon a range between 60% and 75% will be taken for calculations.
22
Diffuse CH4 emitted during mechanical-biological treatment is assumed to be 0.65 kg CH4/ton of
input material.
Table 5: Corg and CH4 emissions from deposited MSW against degradation rate
Methane Methane emissions compared to
Corg calculated
Degradation rate potential landfilling without flares
[g/kgWaste]
[Mg CO2] [%]
60 % 62.7 4.00E+07 40.0
75 % 39.2 2.50E+07 25.0
Of course, the values given in Table 5 relate to the total MSW generated between 2001 and
2022 under the assumption, that all the waste is processed by a MBT before final disposal.
Therefore, these values are only for comparison of the impact of this alternative.
For an integrated assessment, the emissions and emission reductions relating to the mass of
MSW generated are more important.
7. Conclusion
Collecting and flaring and/or utilizing landfill gas will improve the local environment by reducing
the amount of noxious air pollution arising from the landfill, resulting in a considerable reduction
of nuisance caused by the odours and also health risks associated to these emissions. In fact
this results in a positive effect on health and amenity in the local area. In addition, properly col-
lecting and destroying flammable landfill gas will reduce the risks of explosions in and around
the landfill. This is particularly important as the landfill gas collection system will minimise the
potential for landfill gas migration, which can infiltrate zones outside of the landfill’s boundaries
and pose dangers to the surrounding population and structures.
Regarding the organic fraction the results underline the importance of this fraction for the reduc-
tion of greenhouse gases. Separate treatment of the organic fraction yields, besides the reduc-
tion of greenhouse gas in economical chances. Taking in consideration that the disposal at land-
fills is state of the art in Chile today, the implementation of a separate collection and treatment of
the biodegradable waste fractions additionally enables the chance of generating emission certifi-
cates in the frame of the Kyoto protocol.
Based on existing Policies on Waste Management and with respect to public investment in the
waste management sector, treatment technologies should be priorized that not only reduce
waste (recyclable materials), but also have a significant effect on greenhouse gas emissiones
and other environmental impacts. The proposed strategies are not exclusive, but should be ap-
plied depending on their cost-effectiveness:
• Separation of biowaste at the source should concentrate first on yardwaste, waste from
market and public parks, which is currently transported separately but dumped at the
same landfill together with household waste.
23
• Some positive experiences exist with separate collection of household biowaste, however
the absolute impact of this measure is limited by the degree of participation by the public;
• MBT of MSW does not require separate recollection and can be cost-effective combined
with recycling and/or production of an alternative fuel, especially if landfill capacities be-
come scarce.
• Support informal sector with respect to recyclable materials (highest return in terms of eco-
nomical-social efficiency);
• In the case of Santiago where transfer stations are privately operated, reduction of biomass
through biological treatment is currently not realistic, since existing incentives (CDMs) en-
courage simple flaring; however for small or medium communities MBT may be an alterna-
tive for cost reduction in transport and disposal;
In order to meet ambitious national reduction goals (like 25% in 2025), international agreements
on greenhouse gas reduction and reduce impacts on local environment (odors, leachate produc-
tion, landfill capacities), a combination of source reduction measures (education), separate col-
lection (only where economically feasible) and mechanical-biological treatment in centralized
installations should be considered.
24
9. References
25
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of Chile), Avina, (2009). Personal contact with Alvaro Alaniz, Director from “Fundación
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26
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27