General Instructions : Read the following instructions carefully and strictly follow them : @ This question paper contains 35 questions. All questions are compulsory. (ii) This question paper is divided into five Sections ~ A, B, C, D and E. (iii) In Section A - Questions no. 1 to 18 are multiple choice (MCQ) type questions, carrying 1 mark each. (iv) In Section B - Questions no. 19 to 25 very short answer (VSA) type questions, carrying 2 marks each. (») In Section C ~ Questions no. 26 to 30 are short answer (SA) type questions, carrying 8 marks each. (vi) In Section D - Questions no. 31 and 32 are case-based questions carrying 4 marks each. (vii) In Section E - Questions no. 38 to 35 are long answer (LA) type questions carrying 5 marks each. (viii) There is no overall choice. However, an internal choice has been provided in 2 questions in Section B, 2 questions in Section O, 2 questions in Section D and 2 questions in Section E. (ix) Use of calculators is not allowed. SECTION A Questions no. 1 to 18 are Multiple Choice (MCQ) type Questions, carrying 1 mark each. 18x1=18 L Which of the following is not true about enantiomers ? (a) They have the same density. (b) They have the same melting or boiling point. (©) They have the same specific rotation. (a) They have the same chemical reactivity. 2. Aspirin is obtained by the acetylation of which of the following compounds ? (a) Salicylaldehyde (b) Salicylic acid (©) Acetyl salicylie acid (4) Phenol 56/3/1

I>1 (ob) I>I>U0 (©) I>MI>I (@) I>TM>1 Among the following, which is the strongest base ? © € S-sn, @ & S-on,-sn, On hydrolysis, which of the following carbohydrates gives only glucose ? (a) Starch (b) Fructose (©) Lactose (d) Sucrose NH, Which of the following vitamins is water soluble ? (a) Vitamin A (b) Vitamin D (c) Vitamin E (d) Vitamin C The unit of the rate of reaction is the same as that of the rate constant for a: (a) _ first order reaction (b) second order reaction (c) zero order reaction (d) it cannot be same Kohlrausch gave the following relation for strong electrolyte A=A.-AVC Which of the following equality holds true ? (a) A=A,asC —>VA by N=, asC —>0 © A=A,asC —>% @ A=A,asC——+1 <> we PTO.10. wd 12, 13. 14, 56/3/1 An azeotropic mixture of two liquids has a boiling point higher than cither of the two liquids when it (a) shows large negative deviation from Raoult’s law. (b) shows no deviation from Raoult’s law. (©) _ shows large positive deviation from Raoult’s law. (d) obeys Raoult’s law. Which of the following colligative property is used to find the molar mass of proteins ? (a) Osmotic pressure (b) Elevation in boiling point (©) Depression in freezing point (@)_, Relative lowering of vapour pressure Among the following outermost configurations of transition metals which one shows the highest oxidation state ? (a) 3d°4s? (b) 34°4st () 3d°4s? (@) 3d°4s? How many ions are produced in the solution from the complex [Ni(NH,),]Cl, ? @ 4 ) (c) 2 (d) Which of the following species is not expected to be a ligand ? (a) co (b) NEY @ NH; @ 4,0 Which of the following is the most stable complex species ? (a) (Fe(C,0,),1*° (b) [Fe(CN),| (©) [Fe(CO),) @ — (FetH,0),1* <7 wi P.T.O.For Questions number 15 to 18, two statements are given — one labelled as Assertion (A) and the other labelled as Reason (R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as given below. (a) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A). 15. 16. i. 18. 56/3/14 (b) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A). (c) Assertion (A) is true, but Reason (R) is false. (d) Assertion (A) is false, but Reason (R) is true. Assertion (A) Reason (R) : Assertion (A): Reason (R): Assertion (A): Reason (R): Assertion (A): Reason (R): Order and molecularity of a reaction are always same. Complex reactions involve a sequence of elementary reactions and the slowest step is rate determining. Electrolysis of aqueous solution of NaCl gives chlorine gas at anode instead of oxygen gas. Formation of oxygen gas at anode requires overpotential. Nucleophilic substitution of iodoethane is easier than chloroethane. Bond energy of C — Cl bond is less than C — I bond. Zinc is not regarded as a transition element. In zinc, 3d orbitals are completely filled in its ground state as well as in its oxidised state. <2 ae19, 20. 21. 22. 56/3/1 SECTION B Write the structures and IUPAC names of the products expected from the following reactions : 2 (a) Reaction of methanal with (CH,),CHMgBr followed by hydrolysis. (b) Reaction of phenol with cone. HNO3. ‘A chemical reaction 2N,05 (g) —> 4NOg (g) + Oo(g) in gas phase was carried out in a closed vessel. The concentration of NO2 was found to increase by 5 x 10~? mol L” in 10 seconds. Calculate 2 (a) the rate of formation of NO», and ° ® ~ (b) the rate of consumption of No! (a) Define fuel cell and write its two advantages. 2 OR (b) Using E* values of X and Y given below, predict which is better for coating the surface of Iron to prevent corrosion and why ? 2 Given : yx 77236 Eyorjy 27014 EL .2tspe 7 OHV (a) G) How are carbohydrates stored in animal body ? Mention any one organ where they are present. (ii) What is the kasie structural difference between starch and cellulose ? 2 oR (b) Differentiate between : 2 (i) Peptide linkage and Glycosidic linkage (ii) Nucleoside and Nucleotide Pe] P.T.O.23, Give reasons for the following: > 2 _ fa) Carboxylic carbon is less electrophilic than Carbonyl carbon of \’ aldehydes and ketones. (>) Propanal is more reactive than Propanone towards addition of HCN. p HONS 24, Write the chemical equation involved in the following reactions : 2 _s@) Carbylamine reaction | (b) Gabriel phthalimide synthesis 25, Give reasons for the following : 2 (a) Aquatic animals are more comfortable in cold water in comparison: to warm water. (by Sprinkling of salt helps in clearing the snow-covered roads in hilly areas. SECTION C 26. (a) Write the mechanism of the following reaction He : CHy- CH, ~ OH Ti ¢> CHy = CH + H20 (b) Write the equation of the reaction for the preparation of phenol from cumene. 27. (a) Write the structures of A, B and C in the following reactions: 2x1 Z =3 @ és coon—NHs_, q —Br+Ne0H , 5 és NaNO» +HCl, ¢ orc Gi) OH,CHyBr —KCN_, 4 Lidl, p HNO2 , ¢ he orc OR (b) . How will you convert the following : 3x1=3 (Aniline to p-bromoaniline Gi) Ethanoic acid to methanamine (ii) Butanenitrile to 1-aminobutane 56/3/1 w PTO.28. 29. 30. 0:3 g of acetic acid (M = 60 g mol”) dissolved in 30 g of benzene shows a depression in freezing point equal to 0:45°C. Calculate the percentage association of acid if it forms a dimer in the solution, 3 (Given : K; for benzene = 5-12 K kg mol) The rate of a reaction doubles when temperature changes from 27°C to 37°C. Caleulate energy of activation for the reaction, (R=83143 Kt mor) 3 (Given : log 2 = 0-3010, log 3 = 0-4771, log 4 = 0.6021) Write the structure of product when D-Glucose reacts with the following : (any three) Bx1=8 (a) HI () Cone. HNO, (©) Bry water (d) HCN SECTION D The following questions are case-based questions. Read the case carefully and answer the questions that follow. 31. 56/3/14 The polarity of C - X bond of alkyl halides is responsible for their nucleophilic substitution, elimination and their reaction with metal atoms to form organometallic compounds. Alkyl halides are prepared by the free radical halogenation of alkanes, addition of halogen acids to alkenes, replacement of -OH group of alcohols with halogens using phosphorus halides, thionyl chloride or halogen acids. Aryl halides are prepared by electrophilic substitution of arenes. Nucleophilic substitution reactions are categorised into Sy! and Sy? on the basis of their kinetic properties. Chirality has a profound role in understanding the Sy) and Sy? mechanism, eS P.T.OAnswer the following questions : ( What happens when bromobenzene is treated with Mg in the presence of dry ether ? 1 (i) Which compound in each of the following pairs will react faster in Sy! reaction with OH ? 1 (1) CH, =CH-CHy~Cl or CH3~CH,~CH,-Cl (2) (CH)sC-Cl or CH3Cl (ii) Write the equations for the preparation of 1-iodobutane from (1) 1-chlorobutane (2) but-1-ene. 2x1=2 OR (ii), Write the structure of the major products in each of the following reactions : 2x1=2 Ethanol L CH; - CH - CH; + KOH @ OHs- ¢ at heat Br cl @) oO +cH,coc: —Anhyd-AICls _, 32. Coordination compounds are widely present in the minerals, plant and animal worlds and are‘known to play many important functions in the area of analytical chemistry, metallurgy, biological systems and medicine. Alfred Werner's theory postulated the use of two types of linkages (primary and secondary), by a metal atom/ion in a coordination compound. He predicted the geometrical shapes of a large number of coordination entities using the property of isomerism. The Valence Bond Theory (VBT) explains the formation, magnetic behaviour and geometrical’ shapes of coordination compounds. It, however, fails to describe the optical properties of these compounds. The Crystal Field Theory (CFT) explains the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion, 56/3/1