UNIT-I

Latex Latexis emulsien Polyhudro-

-Caxhem dAoplet în aguLOuS Selutiom medium
Latex detme A a 'stable Cellsidal dis-_
pexsim a palymesiC- pakticl in am e8L=
-ntially AQuLdud mediuL

S peSEd phas
CPolyhy
akotarbun
o

eoplets
TS peESTOT MEatiawm
AueOus phase

ike Calloidal Seluti on.

Ttis Clleidal dis pesiom o migtiuely, Chaxge
Dati
NatuealL atexA 6htaimcekuom-Rubht
Alamt Hauea Brasiliemsis

Hea_ Bxasiliemsis Is paka ubbele tree

Amilly uhhthiac.ea.

Laex Caected
Pehningand is Sae Vike exhact-
immaky
ArCe Natuhalaftx Datuha Ruhh
 ako
sesds plaat Cakmurle and USUal
slike

gabaif in Shape
Eroaa patchis_

Arke indolia

Rubbeh plamt slc

gminat in
Rubbex Tree Seods Complytt
Lo-S_eloys-

plamfafon

tm13uddng

hashas bendling Rubbe Buddeng Rubbes

6o laex ha . T o 9a-akx

Betey kut Ru
ubbe rk0
Hauea iua ul us lanta Ht
astillga_£lhsia Pathemium ahqpatatUM
Amdalhhia

ponulas-Rosbe e
 Haeeprea.

samcs Lshen plunteha

tomtk}-

lDmes
eaves

pro(oSSmg. tm 5Am Te Am
appiang
Aiah1-
fTesh latex pH appTozimately o , Phehe
Latex- Coaguulaka eh pH ih Im.Sesed to
OLound 4 s esh lattp'ub Coaglatta
Spontameously uithin e houaj_d lesten
PhopreL Beasuae Paouctim d pH dulto
degsafien_d Casborhydalapaepemt um latey_
aBacesia amd dsaysts tha lipid
attyacid and lhHhua
SuWhstnmco T A3en
toiih _mata iehg he chie
t h i a Coagdat1
 Ompasii m o sh latex

CTSC). TotaSolid Comtnt 36

CSRC) Qty Rubbe Gmttnf 337
PoofeimS -ST

Resins T-2-5
Ash- T
SugaS
ae
Gemosa 30-35

Advamage d atx

LoS Viscedity So Fasy to Shape

light Puipmint d Simple ComatsuctHeMb
Lo êmegy Reduiromonds
No- Hea gemphatiem duking pecessimg
utra-atcele3afs Lmd tomp. lust
umbaKem ubbe Belter physial
g eing ropeiies
1lo_chaxt c field atex to 8SS sheet

HaveaBrasiliemSiS

lect atex

Tapnm itk eiklatty-

PTeserwaHm.6 Field lartx

G4 Na Satbhate

V Sieuing e mLH)_

Coaguuattd
B Htrott
 tora9

enupress 1em mde 2Roi_mil

plaio mill
Sve_milb

Wajes Rembve

Shett tex

Load c tolley

aakghause Weak

Gada
eh

Pack
35 kgBalc

ispatch to Rubbek mdusmes-

 PRSLRation_-
h e aiex 5 fo he PILS£LADEd immedey
AL Colec.iim Againat ise inaciditud
BBacakial puti,tation
Amsayhe'pTe%eLaties LLSLd hmemia
iS MestComelUSEd Dima to Cetaa
(et
Rdvantugráike Temsla loulng
Ai Reaciipm i t h HOHD

Kecetiyodium pentachlarophenae ua Beng

use alona Sth_Smna amotLmt d

emmP DSAIaves
NHa_ Dottash fmaltn__Sadeum
Slphk

Stability NR laiex
1aiex anSist s fing Daicles cSne 2o2s
_fom amd Coiered by electmical Chaded.
-Ropueln Betueosahe haticl Omd laye
dSAr hêcl NaRi 9uimq a_MLehamica
Biaieh+
RaS&n LnStability
Merhami Cal_agiatie Tmpigmim d to
paktic=CogalscomLo LHuEL- di
ecuion m electrila Cha'e du TD Dt
mapn_c mSo lubleSaah -
R in uih meialiOm.S.
**

*** ****
 -Ve

Ce

Stability Rlakx 18etju

Reaicifn_d 00SusHaCO ems
The_poiume patrcle îmBstacc

OSamd nalatity
BputtingSomo Heal SEETHING aye
C34EA)
Ohtlghtl 6und 9aes molecsl
oncoMfration latex
n thii TOr LASFliminatts M6St d th
Ne Rubhe ernstitumts Phi sQAnL

( Creamim
Cemtrijuga.ho_
elechooletamtaunm
eVaporai9n.

( Cenntikugatio h e Rutakme o94

he Cemnnugg is gemeasly Hes hat
 v****

ilh_a muanbe d metalic_deb. A the Bof

Roatea hgh 3hecol GrsO Kpm ghe ha
laicx Îs cokem up into Thin (mi(a
Shels he latx îs Ed to the machm m
Cm8tamthea d to emsuro umioimLo
TniCLeam Ceatrikug oLahds tho ayy d
Rpta m
hih 2 Cemikihugalkotco,.ag0 uSeo.
CenthiuQ Latices &o CommeHLiall Q/ai-
-lablaaS high mmia (HA mnmun o:k1
menia amdLa and Ammia yk
O13

PVapkaton_
Eva'ptatom lata oncenjae is mad b
heating Suitably. pre3tRdlates thrt Sken,
tmaien_dn thd Burhatt. he tabili3eta usedL
ah genehally KDH Sop amd s gu
Sitaeleeuabssaj' lomsSTUd a akeed
dhum_olatin 9 alLenqtho axiS Sfeam_A
adnittee in tho TkE Qmd Ho aik ins+dc
Sve fhelateoSusSuaco.asln Cylinde
Ratatmg alenq thAclkum Swsa.allotd
kin mati
ner attoLatex Åas_higo Stabilty
SE S L QdhlSive amd lotxCeoncm np
Sits
Creaming
Lata paiidoa ialk thm_SeaLmm
hichthiy-aie SusSemdea
HALN femdemty o go Lup m hi SuhalL
***
mo n-auns

e a n U m agent Ameni um alPmARe

,Tumauind
DLel aAum risb m4S2 amd Lusroern gum,
makè thu paticlea to {tm lorse aghgats
BuKtd taky Amm@niafeol to 1.

m h little Sea.

Aoht to stend

Cream SHHs ans

Am&niad urfhe
Batthes aie lede

( Alectro de.camtaftn
epends df ve_Chakaa _Om Suhaco_Rubbes
pasticlo electric irkemt u passeol, Ruhbes
pahticl move tolasds the fiod
 Sntheiiclafcy.
Nalt laey
is eceutmdlp
uhntcUqunuL
*

A dtw mute TÉSistnf du st mii itLi

a might
kdoiiontisemn
Sipotack

atkgnades
Sdurse
ype Coaglateel ield laty
Ribbec Smoke
rnrami

2atm in Snoke.
&heet inabi

loagulum } Natual latex

Pale Crepe
uid

Stafe BoDWn estate Cup lum 7e ace

Cepe
Cuplumb,wotsiab trrla7

Crepe nsno lkos8heet

***

5 hirk blanket
w

Co ***

p af B4bk tp Remi
RSS 3 3
w n errwher.s w

use 3mokiet Btanka

CLet
 X

-
 Asea tsld oise Souh enstem fsi
pnhy malesia en nSia h m a .

i lamka Viemamm Im4i tc

NGchtmiCa shrctutu
azvarwn

PomeISafwn
CHa

acH CH-
2,Methl L3 Butadiena
Pol sop1eng
nNererirarenena

unSatuhatien
Nm pola
et

methgo ulky hap

p y Gs-L4 1Sopeme Sam
May o ndeealsaMAn iStpOme
u 8tructuDa.
proitims Arrnimo Fcd phaspholi pidsn
Martomale.Cule Backhne.
htnapackim Shcei imn
Bbck im-
eA

noiyiseprem amS, poyisopheme 1S

Oncnt 1Semeh nGtia-_petha0x
ala
lCiS u 56phtm

CHo cH

1- 4 1Soprene.
Cus -

Tams -L4 1S6MAiml

c
olylm I,4 1SgprinC_

***

Physical properties 6NR

De sity 0:92 m
Rekkeive md 1S2 L0c
Molecah hleight ala -slac
O0O00-S0000

Diolectric Comstn 37
VoLume Resistiufy lo*ghnslac

Advamtag eS+
t o (uf
Poo TOSIStamco
aood WnSil& Shength.
Beltes
 gAoTh
Belte Besistonce to Cut
tack
Veh high um
Strass Tnduco-crystalizafien1S tminLLO

Chakactekiahcs Natuta Rubbes

OMolerulas LWeighi Natusa mbbek Shaus a

bimmadaa keuSLmimaediatai butm

_Stoage
Stoxage NR_

hio iduuo peARMco_daldehuditgAMp_

t h amino

phasophoS0 Gel Content Natuta rubbek *****

M e n mg 9tmgL

el enden 8terage hoslenoia"

Cstalzab in2
eohLgh huetuh.al egulakits Natukal
uunbe SAns CYStall2a tikn_

eetgeisnoieuan

-******
 ANALYSIS OF NR
Oeghl
hupberhydsocab en 9-34
maishu
Ash
Areten Estesnblon $-3
Rlty ati do -3
Skuoi des ee ).
Ninogam0 sLuS SLbsjanees S-35
5-3:s

ntesmaHn 6rado de NR-

Tp SoucQ 6 ara de Tota

RSS Caagulafe hieb I 2,

Letex 4,5,

Pol2 CrepR

Brh Estute Cuplendo T23X

Cope
Luplumm,fteage 1,2,
Cape
4
Thin Bu) Cuuplunp,etai
UnBmskot ncer

Thurk r%
BlkaCpe
Remile4 Rs Has1
ak Aaik
Crepe
 e

Lchnica lySpeced RubbeCTSR2

in 1945 i t h the
9SB a sstakfed bmalasia
Imtnductien SmR Cstadas.el malassiam Rubbek)

TSR Gua de

SmR SORGP TSNRIo

SmRWE SmR 10
SmR C Sm R 20
TSNR50
SmR V SMR 50D
Sm B S
p
Qirt Cmfni
603 ÉtTttmten

SmR L, SmR SmR SMR SMR

WF 5 10 20
Pmpei_

20
O.037
Oivtontnf
O 60
Ash lmitn
60 0 6 060
Niogim
Conionf).

Vcdarile me 80
 THER TJPES OF NATURAL BUBBER
Hevea pluß MG Rubbe
Dhose aO Chemu Call mocii ied gado oNatuseal.
Rubbek, poepaked by akt palymexizatim d
methy me thatkylakinNR Rubbe Gitonta
Thioisalailable inlade x 60 du ubbeh letm.
Ao Gade QApRpatecl i MGb0 amd MG49
mtain 30 Qmd 49 dPMMA ESpeciively.

y MG Rubb used inAclhesive

Laf MGjs lnded oith moTmal latX to
Achiere ilmL9Hh improuee modulus Hak

ENR poxielired Naura Rwhbes)

it is pmducod ay eaHON_d lattx with pekkek-
-mi acid 6tmld in Situ.
NR giveb iseto m/ed aik mpekmaability
andS tamco fo i l
ropextep_usn
NR Qlso has god adhesive
Rubbls to ma bnding
CTPNR7
Thesnonlastto Natutal Rulobek
isprebatid Hemdimg cNRamd-
paltihy d i e t neotpothos
lyephaykeme
phqushës.
o i e u b h i s fhOdilkket sfnes

n clu.cleo Lodtta petE

Pottntia alalhlitahD
and.
d Beds hees bumpess 3/2sile
Ca brdy phkelhen Sip
 Symthehie
Naheral Rubbe akt dbhekoÍ fhm Suntheh
BLut to j8 bloiao m Natukak Antt
htu g qum 9400n tack Sndhughiot 1
Creatcl fay Enz4mati nttas i niant:
NR ChAstaliene in.stucfwe _6hu Ruubbes is
nrimonncephet
ktmoaph6us1

Cis-1,4 polyiso prene.

Aue to Cis Coniaafien
sa highly Sott amd elashc
aeia

Transi,4 poly+soprena Cgutta pucha.)

Carystalliot
oriemteacrdurlly mame and pack up desely

wsienin *

e
1JRENE BDA DIE NE *

SARIS Kohld RUBAER.

eeloLd în l 9 30is_oldest
s 9mihotic
mihotíc Pulbbeit
Pubbtt, it is
16 Ccnálumahd is **

Contim 9 3.. boumdV styt0me and outa

isprepaxed Syten diend_mormalty
momaU
hyemuulsnen
1S mot hadmee Sotsuton polyrmoniaate
wi ih Stetage
1t is a Sbtt Cukkang Rubbe
G.Dd fbYaS1m TES*STAmOo
du fo hatudD

******A

Butadieme Stytmt f3}}-

Butadiena producnbn
Pm n- ButaneS
Then Butame ak0 dbtuenecl kem 3-( Shtam
Bem the Cyut kimq d peroleum (uLde_propane
TSubunl cute paialtobu Lachonafion_amd
iSobutme. îs emre ousphivn in_SLSulhhuiu
acid
Bute CH H-(H- (H_ H
CHh= CH-TH-TR

t t = t H = t H g -
1ypcally a Mixe.shcam Caniaunmq Bufan 6
wunsma

Supethtatcel Slcam ndina made 8tadicne

rodtehom d Butadiome m hri Atrho

CHa-CHo+ H

Ch C H
Ch-CH-o H-CH-CAO
Ate tuldo)

CHa-(H- CH-(Ho
(Co lenlde hyele)
CH-CH(-(Ho + oH_
CHa-H=(H-CH -oh A
CH_CHD
Cmtlalcahad
CHa-CH CH-CH-OH
C H - CH CH
Btrtrditht
Styteme 7
Shuhomais hrducod @m elh
ihducodby alkala hag btngem benaeneWhnh
ih Pthykin
 chydo pe maiikonu the Ctnzn.
r

' r
1 10
Ca 0koH 2°3
an6SD
StuAorn

Emlsm polmexíSatien df SBR

mulam polymeLisatien is dnd a t too-
at 5oCd Calles a hot_nolymeA amd he othes
dne Callee He Cold polyme
GLemekal_puhpMe SAR ÎS mamuLttukd
Y2achion_dj: uL.as emulsion d butudien0 a
Steam 1 n t hpres¢nce dSoap Solut1m
houmexiatm iniifaot amd reqlaotg to hm
higo baleculate LOeight_Conoms th
elashicnxehetes Phi Cam_oe pepaseod uih
echmißul. aljo_But h phoneAtE)__g Serdut
3AR3lightiy. Vahles iommtha dam emu lsen_
86R

OUtonmankactulch nghddesS (T.o)

T
 PTo peRhes_d SBR
53°c

Sensit =0:g4-
Marme fLstoSiby 35 5

BeH- TiistanQ to TWeS1@m

highi TisiStamcg to ahragNON_ higy Seel
u Beieh KLAEStameo to aging shecaky athg
kmpratueL

tal2nt nFimpact 8htmgth

isadvasntege ohSBR
Nece8Síy to Use TLinhocing Tte
) po0r resís tamo to 0gOne, Sun ht
11_ Yk Jifi e8is tamue to eils_ASOm
budkot acom Solvemus.

RASe d SAR Rubbe

Ht Gld palymerieo SBR Gih e
Lithac 0il aa C-Alark ahe daui late
TSRP ntezmatbmal Tntuke_o Symthek
Ruhbe rduces undek the
otiotlumg Dekies
CO HtpolymexJed Mmm_pjmeated Rubbe
500 Cto polymekise.d mm_pigmanitduubbe
Cold polymeusedCatbbn Black silRulboet
mattk atchta phr_ esS h
Cetd poly meki Sedci_Rubbei master Batthig

ISaD Celd prlymerised C-Black -ed rubbt Maoks_

barhea Comtuinira Mese than 14phs d

1900 MisceUomLrus dh polyaik eoH Iathla._

la llehtn SBR_providelo0 Rolhng TesTstanCi

*****