Structure of Atom
Structure of Atom
Class-11th, Assignment-1st
Structure of atom
I. Thomson, Rutherford atomic model and electromagnetism based questions
1. Define anode and cathode ray.
2. Write the drawback of Thomson model of an atom.
3. What is the basic difference between Thomson and Rutherford model of an atom.
4. What happened when Rutherford allowed to pass beta particle through the thin gold foil in
alpha-particle scattering experiment?
5. Write the observation and conclusion made by Rutherford after performing alpha particle
scattering experiment.
6. What is the similarity between Rutherford and bohr's model of an atom.
7. What is electromagnetic spectrum.
8. A radiation has wavelength of 4650 A°. Calculate it’s wave number and frequency.
9. One of the spectral lines of caesium has a wavelength of 456 nm. Calculate the frequency of
this line.
10. Calculate the wavelength, frequency and wavenumber of a light wave whose period is
2.5×10¹² s.
II. Plank quantum theory and photoelectric effect based question.
11. Electrons are emitted with zero velocity from the surface of metal when it is exposed to
radiation of wavelength 6000 A°. Calculate the frequency require to eject the electron and work
function of metal.
12. The kinetic energy of electron ejected from the surface is 6.25×105 J. Calculate the frequency
of radiation falling on the surface of metal, if the work function of metal is 3.4×10-¹9.
13. Calculate the velocity of ejected electron from the surface of caesium, If the radiation of
wavelength falling on surface is 400 nm. (The work function of metal is 3.95×10-¹9 J)
14. What is the ratio between the energy of two radiation of wavelength 6000 A° and 2000 A°.
15. How many photons of light having a wavelength of 4000 A° are necessary to provide 1.00 J
of energy?
16. Electromagnetic radiation of wavelength 400 nm is just sufficient to ionise sodium atom.
Calculate the ionization energy of sodium in KJ mol-¹.
17. A bulb emit a light of wavelength 4500 A°. The bulb is rated as 150 watt and 8% of energy is
emitted as light. How many photon are emitted by the bulb per second.
18. Calculate the wavelength of the radiation which would cause the photo dissociation of
Chlorine molecule if the Cl-Cl bond energy is 243 kj mol-¹.
I. Bohr’s model of an atom based Question.
19 Write the postulates of bohr’s model of an atom.
20. Write the merit and demerits of bohr’s model of an atom.
21. Define planck’s quantum theory.
22. Calculate the energy associated with one photon of the radiation of frequency 2.5×10-⁴ hertz.
23. Mention the main points of difference between the emission and absorption spectra of an
atom.
24. Calculate the wavenumber and energy of the spectral line emitted by an excited hydrogen
atom corresponding to n1=3 and n2 =5.
25. A spectral line in the balmer series of hydrogen spectrum corresponds to wavelength 6561
A°.
Find the energy levels involved in the transition responsible for the origin of this line.
26. Calculate the ionisation energy of He+ if that of H atom is 13.6 eV.
27. Calculate the shortest and longest wavelengths in hydrogen spectrum of paschen series.
28. Show that the balmer series occur between 3647 A° and 6563 A°.
29. Light of wavelength 12818 A° is emitted when the electron of hydrogen atom drop from 5th
to 3rd orbit. Find the wavelength of photon emitted when the electron fall from 3rd to 2nd orbit.
30. Calculate the longest wavelength of light required to remove electron from 3rd orbit of He+
ion
31. Calculate the ratio of velocity of light to the velocity of electron in the 1st orbit of hydrogen
atom
32. The wavelength of a certain line in balmer series is observed to be 4341 A°. To what value of
n does this correspond ?
33. What transition in the hydrogen spectrum have the same wavelength as balmer transition n=4
to n=2 of He+ spectrum.?
34. Calculate the wavelength of radiations emitted produced in a line in lyman series, when an
electron falls from fourth stationary state of hydrogen atom.
35. A hydrogen atom is in ground state. To which level will it get excited on absorbing a photon
of energy 12.75 eV. ( 1 eV=1.6×10-¹9).
36. Calculate the wavelength for the emission transition if it starts from the orbit having radius
1.3225 nm and ends at 211.6 pm. Name the series to which this transition belongs and the region
of spectrum.
37. The longest wavelength doublet absorption transition is observed at 589 and 589.6 nm.
Calculate frequency of each transition and energy difference between two excited states.
I. De-Broglie hypothesis and Heisenberg uncertainty principle questions
38. An electron is moving with a velocity of 5×10³ ms-¹. Calculate it’s De-Broglie wavelength.
39. An electron is moving with a kinetic energy of 4.55×10-²³J. Calculate it’s De-Broglie
wavelength.
40. State Heisenberg uncertainty principle and it’s consequences in relation to an electron.
41. The mass of an electron is 9×10-³¹ kg. If it’s K. E is 3×10-²5 J. Calculate it’s wavelength.
42. Calculate the uncertainty in position of an electron whose velocity is 3×10⁴ cms-¹ accurate up
to 0.001%.
43. The uncertainty in the position and velocity of a particle are 10-¹0 m and 5.24×10-²⁴ ms-¹
respectively. Calculate the mass of the particle.
44. Calculate the uncertainty in momentum of an electron if uncertainty in its position is 1 A°.
45. Calculate the momentum of a particle which has a De-Broglie wavelength of 2.5×10-¹0.
46. What is the mass of photon of sodium light with a wavelength of 5890 A°.
47. Find the no. of wave made by a bohr’s electron in one complete revolution in the 3rd orbit.
48. The speed of Ferrari racing car are recorded to ±4.5×10-⁴ ms-¹. Assuming the track distance
to be known within ±16 m, is the uncertainty principle violated for 3500 kg car.
49. Alveoli are tiny sacs in the lungs whose average diameter is 5×10-³ m. Consider an oxygen
molecule 5.3×10-²³ kg trapped within a sec. Calculate the uncertainty in the velocity of oxygen
molecule.
50. How the De-broglie wavelength change if the velocity of moving electron become twice?
51. How the De-broglie wavelength change if the kinetic energy of electron increased by twice
of its
Initial value.