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Safety Data Sheet according to Regulation (EC) No 1907/2006

REMA TIP TOP AG


Revision date: 27.01.2015 Revision No: 2,01
REMA TIP TOP REPAIR PATCH
00156-0361

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


REMA TIP TOP REPAIR PATCH
Art.-No.
EC-SDS applicable for following products:
Tube-Patch, Tyre Repair Patches of series RAD100, RAD200, RAD500, PN, FRU, MTC, Radial-E,
Diagonal-E, UP, M-RCV and M-RCF
1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture


Rubberpatch for repair of radial and diagonal tyres.
1.3. Details of the supplier of the safety data sheet
Company name: REMA TIP TOP AG
Street: Gruber Strasse 63
Place: D-85586 Poing
Telephone +49 (0) 8121 / 707 - 0
Verantwortlich für das Sicherheitsdatenblatt: sds@gbk-ingelheim.de
1.4. Emergency telephone INTERNATIONAL: +49 - (0) 6132 - 84463, GBK GmbH (24h - 7d/w - 365d/a)
number: England and Wales: NHS Direct - 0845 4647; Scotland: NHS 24 - 08454 24 24
24

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
This mixture is not classified as hazardous according to Directive 1999/45/EC.
Classification according to Regulation (EC) No. 1272/2008 [CLP]
This mixture is not classified as hazardous according to Regulation (EC) No. 1272/2008.
2.2. Label elements
Additional advice on labelling
As an article the product does not need to be labelled in accordance with EC-directives or respective national laws.
2.3. Other hazards
Not known.

SECTION 3: Composition/information on ingredients


3.2. Mixtures
Chemical characterization
Vulcanized product of rubber, sulphur and other additives with tyre cord (fabric).

SECTION 4: First aid measures


4.1. Description of first aid measures
General information
No hazards which require special first aid measures.
After inhalation
Move to fresh air in case of accidental inhalation of fumes from overheating or combustion.
After contact with skin
Wash with water and soap as a precaution.
After ingestion
Ingestion is not considered a potential route of exposure.
4.2. Most important symptoms and effects, both acute and delayed
May cause sensitization of susceptible persons by skin contact.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.
Print date: 27.01.2015 GB - EN Page 1 of 6
Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
Revision date: 27.01.2015 Revision No: 2,01
REMA TIP TOP REPAIR PATCH
00156-0361

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media
Any extinguishing means and measures are acceptable. Fire-extinguishing activities according to surrounding.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Fire may produce:
Carbon monoxide, carbon dioxide and sulphur oxides.
5.3. Advice for firefighters
Use breathing apparatus with independent air supply.
Protective suit.
Additional information
Cool containers at risk with water spray jet.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
In case of vapour formation use respirator.
Avoid contact with skin, eyes and clothing.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/ground water.
6.3. Methods and material for containment and cleaning up
Take up mechanically and collect in suitable container for disposal .
Where possible recycling is preferred to disposal.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Advice on safe handling
Do not breath vapours that may be evolved during processing.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.
The product is flammable but not readily ignited.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep in a dry, cool place.
Advice on storage compatibility
Incompatible with:
Nitrous acid and other nitrosating agents.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
7.3. Specific end use(s)
Rubberpatch for repair of radial and diagonal tyres.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
8.2. Exposure controls

Print date: 27.01.2015 GB - EN Page 2 of 6


Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
Revision date: 27.01.2015 Revision No: 2,01
REMA TIP TOP REPAIR PATCH
00156-0361

Appropriate engineering controls


Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Wash hands before breaks and immediately after handling the product .
When using do not eat, drink or smoke.
Hand protection
Protective gloves resistant to chemicals made off natural -rubber latex, minimum coat thickness 0.6 mm, permeation
resistance (wear duration) approx. 480 minutes, i.e. protective glove <Lapren 706> made by www.kcl.de.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the recommendations
given by the manufacturer of protective gloves.
Skin protection
Long sleeved clothing (EN 368).
Respiratory protection
In case of respirable dust and/or fumes, use a self-contained breathing apparatus.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state: Solid
Colour: Black
Odour: Rubbery
Flash point: n.a.
Lower explosion limits: n.a.
Upper explosion limits:
Density: n.d.
Water solubility: insoluble
(at 20 °C)
Ignition temperature: n.a.
9.2. Other information
No data available.

SECTION 10: Stability and reactivity


10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reacts with:
Nitrous acid and other nitrosating agents.
10.4. Conditions to avoid
To avoid thermal decomposition, do not overheat.
10.5. Incompatible materials
Nitrous acid and other nitrosating agents.
10.6. Hazardous decomposition products
Carbon monoxide, carbon dioxide, sulphur oxides.
An inappropriate handling, for instance major amounts of product combined with strong heat and nitrosating agents, renders
possible a cleavage of nitrosamines in traces.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.
No toxicological data available.

Print date: 27.01.2015 GB - EN Page 3 of 6


Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
Revision date: 27.01.2015 Revision No: 2,01
REMA TIP TOP REPAIR PATCH
00156-0361

Irritation and corrosivity


Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
Severe effects after repeated or prolonged exposure
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
Classification in compliance with the assessment procedure specified in the Regulation (EC) no 1272/2008.
Further information
May cause sensitization of susceptible persons by skin contact.
If appropriately handled and if in accordance with the general hygienic rules, no damages to health have become known.
Product contains low quantities of cancerogenic and mutagenic components. Nevertheless it is not hazardous to health if
inhaled, swallowed or in case of contact with skin under this form.

SECTION 12: Ecological information


12.1. Toxicity
Ecological data are not available.
Because of the low solubility a toxicity to aquatic organisms is not to be expected.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this product are a PBT / vPvB
substance.
12.6. Other adverse effects
No data available.
Further information
Do not flush into surface water or sanitary sewer system.
Ecological injuries are not known or expected under normal use.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Where possible recycling is preferred to disposal.
Can be incinerated, when in compliance with local regulations.
Waste disposal number of waste from residues/unused products
080410 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and
sealants other than those mentioned in 08 04 09
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.

Print date: 27.01.2015 GB - EN Page 4 of 6


Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
Revision date: 27.01.2015 Revision No: 2,01
REMA TIP TOP REPAIR PATCH
00156-0361

SECTION 14: Transport information


Land transport (ADR/RID); Marine transport (IMDG); Air transport (ICAO); Inland waterways transport (ADN)
14.1. UN number:
No hazardous material as defined by the transport regulations.
14.2. UN proper shipping name:
No hazardous material as defined by the transport regulations.
14.3. Transport hazard class(es):
No hazardous material as defined by the transport regulations.
14.4. Packing group:
No hazardous material as defined by the transport regulations.
14.5. Environmental hazards
No hazardous material as defined by the transport regulations.
14.6. Special precautions for user
No hazardous material as defined by the transport regulations.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No hazardous material as defined by the transport regulations.

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
1999/13/EC (VOC): 0%
National regulatory information

15.2. Chemical safety assessment


For this substance a chemical safety assessment has not been carried out.

SECTION 16: Other information


Abbreviations and acronyms
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses
ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure
IMDG = International Maritime Code for Dangerous Goods
IATA/ICAO = International Air Transport Association / International Civil Aviation Organization
MARPOL = International Convention for the Prevention of Pollution from Ships
IBC-Code = International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
REACH = Registration, Evaluation, Authorization and Restriction of Chemicals
CAS = Chemical Abstract Service
EN = European norm
ISO = International Organization for Standardization
DIN = Deutsche Industrie Norm
PBT = Persistent Bioaccumulative and Toxic

LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration

Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product
(in this sense consult information on use and on product), but to liberation of major amounts in case of accidents
and irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the present
level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal warranty
regulations.
Print date: 27.01.2015 GB - EN Page 5 of 6
Safety Data Sheet according to Regulation (EC) No 1907/2006
REMA TIP TOP AG
Revision date: 27.01.2015 Revision No: 2,01
REMA TIP TOP REPAIR PATCH
00156-0361

(n.a. = not applicable; n.d. = not determined)

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Print date: 27.01.2015 GB - EN Page 6 of 6

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