Chemistry
Chemistry
Chemistry
B.Sc.: Elective
Outlines of Tests
4. Verification of first law of Faraday by electroplating of CuSO4, NiSO4, Cr2 (SO4)3, Ag+CN
and Au + CN.
5. Conductometeric and potentiometric titration using conductivity bridge and pH meter.
6. Measurement of reduction potential using of Zn, Cu, Ag, Al etc, by using calomet
electrode.
7. Study of first order reaction:
a) Study of hydrolysis of methytacetate
b) Measurement of rate constant.
8. Verification of Langmuir Isotherm.
9. Thin layer chromatography
10. Measurement of molecular weight by; Depression of Freezing point.
GC University, Faisalabad
Outlines of Tests and Courses of Reading BA/B Sc Pass Course 3
11. Determination of transition temperature of Na2, SO4, 10 H2O: Na2 CO3, 10 H2O: MgSO4,
7 H2O.
Recommended Books:
1. Adamson A.W. “Understanding Physical Chemistry” 3rd Ed., Benjamin Cummings
Publishing Company Inc.
2. Akhtar M.N. & Ghulam Nabi, “Textbook of Physical Chemistry” Ilmi Kutab Khana,
Lahore.
3. Bhatti H.N & K.Hussain, “Principles of Physical Chemistry” Carwan Book House, Lahore
4. Maron S.H. &B. Jerome, “Fundamentals of Physical Chemistry Macruthan publishing
Co., Inc New York.(Also Published by National Book Foundation).
5. Atikins P.W.& M.J.Clugston, “Principles of Physical Chemistry” Pitman Publishing
Company(1988)
6. Moore W.J. “Physical Chemistry” 5th Ed. Longmans Publishers.
7. Jones M. “Elements of Physical Chemistry” Additson-sesky Publishing company.
8. G.M.Barrow, International six Edition “Physical Chemistry”.
9. Ira.N.Levine fourth edition “Physical Chemistry”.
10. Alberty and Danials, Physical Chemistry”
11. Castallon “Physical Chemistry
12. Laidler & Meiser “Physical Chemistry”
13. Friemental “Chemistry in Action”
14. Francis Marion Miller “Structure and Dynamics”
15. Denbigh, “The principle of Chemical Equilibrium”
16. B.H.Mahan, “Elementry Chemical Thermodynamics”
17. E-F Caldin, “An Introduction of Chemical Thermodynamic”
18. Sample Glass Tone “Introduction of Electrochemistry”
19. Bokris and K.N. ready “Electrochemistry”
20. Milner “electrochemistry”
rd
21. Reinhold 3 Ed., “The Physical Chemistry of electrolytic Solution”
22. H.S Harned and B.B. Owen “The Physical Chemistry of Electrolytic Solution”
FOR PRACTICALS :
1. Crocleford H.D. H.W.Biard, F.W.Getzen & K.W. Nowell, “Laboratory Maual of physical
chemistry” 2nd Ed., John Wiley Sons London.
2. Das R.C. and B.Behera, “Experimental Physical Chemistry” Tata McGraw Hill
publishing Company Limited.
3. Levitt B.P., “Findlays Practical Physical Chemistry” 9th Ed., Longman Group Limited.
3. Acid-Base Concept:
General concept of acids and bases. Detail of \Lewis concept f acids and bases,soft and hard
acid-base (SHAB) concept and its applications. Relative strength of acids and bases based on
Pk values. Reactions of acids and bases relationship between redox reactions and acid base
reactions, Indicators and theory of indicators.
5. Nuclear Chemistry:
Phenomena of radioactivity ; Natural radioactivity Radioactive,disintegration series, rate of
disintegration and half like period, Mass defect and binding energy, nuclear stability ;
measurement of nuclear radiation, Wilson could chamber and Geiger-Muller counter, Carbon
dating ; Artificial radioactivity and nuclear transformations, Nclear reactions (Fission and
fusion), Uses of radioactive isotopes ; Biological effect of nuclear radiation.
8. Spectroscopy:
Electromagnetic radiation and its interaction with matter: Nature of different transitions possible
in atoms and molecules; Electronic, vibrational, rotational and other possible transitions by
absorption of radiation by molecules and atoms, Development of spectroscopic analytical
techniques employing various transition. Classification of spectroscopic techniques on the
basis of type of radiation, pehomenon occurring and the nature of the matter. Basic
introduction to atomic and molecular spectroscopic techniques including flame emission,
spectrophotometry, UV and IR spectroscopy.
9. Chemistry Industries:
Glass, Soda ash and Soap.
PREPARATIONS
1. Ferric Alum
2. Potassiun Thiosulfate
3. Sodium Thiosulfate
4. Amm. Copper (II) Sulphate
QUALITATIVE ANALYSIS
Separation & Identification of mixture of four radicals (cations and anious) by
semimicro analysis technique.
ARGENTOMETRY
MOHR’S METHOD
1. Determine the % age purity of NaCl (Rock Salt)
2. Determine the amount of NaCl in the commercial sample of soda ash.
VOLHARD’S METHOD
1. Determination of %age purity of HCL.
2. Determination of silver in the given sample, using KSCN or NH4 SCN.
IODMETRY
1. Determination of iodide and KI in the gives sample solution.
2. Standardization of Na2S2O3.5H2O solution.
3. Determination of amount/dm3 of Cu2 + and CuSO4. 5H2O using Na2S2O3 and KI.
GC University, Faisalabad
Outlines of Tests and Courses of Reading BA/B Sc Pass Course 5
COMPLEXOMETRY
1. Standardization of EDTA solution by magnesium/zinc sulfate solution.
2. Fine out the amount of Ca2+ in the given sample of marble (lime stone).
3. Determination of Ca2+ and Mg2+ in the sample by using EDTA.
Recommended Books
1. Cotton, F, Albert, Goeffrey Wilkison and Paul L. Gaus, “Basic Inorganic Chemistry”,
John, Wiley & Sons Inc, 3rd Edition (1995).
2. Lee, J.D., “Modem Inorganic Chemistry”, Champan & Hall, 5th Edition (1996).
3. Jolly, Willium, L, “Modern Inorganic Chemistry”, McGraw Hill, 2nd Edition (1991).
4. Shriver, D.F., P.W. Atkins and C.H. Langford, “Inorganic Chemisty”, Oxford, 2nd
Edition (1996).
5. Sharp, A.G. “Inorganic Chemistry”, Longman, 3rd Edition (1992).
6. Rayner Canham, Eeiof., “Descriptive Inorganic Chemistry” & Co. (1995).
7. Jefferey, G.H., j. bassett, J. Mendham and R.C. Denney, “Vogel’s text book of
Quantative Chemical Analysis”, 5th Education, Benjamin Cummings (1989).
8. Vogel, “A.I.A. Text Book of Macro and Semi-micro Qualitative Inorganic Analysis”,
Longman Green & Co. (1995).
9. Skoog, D.A., D.M. West and F.J. Holler, “Analytical Chemistry”, 6th Edition, Saunders
College Publications, (1994).
10. Javed Iqbal, Amin, “Theory and Practice of Chromatography”, Higher Education
Commission, Islamabad, (2002).
3. Hydrocarbons
a) Alkanes and Cycloalkanes
Preparation of alkanes from alkyl halides, coupling of alkyl halide and alkylboranes,
reduction of carbonyl compounds, Kolbe’s electrosynthesis, Corey-house-synthesis,
hydrogenation of alkenes and alkynes.
Reactions of alkanes with halogens, their mechanism and comparison of reactivities of
halogens; combustion, isomerization, nitration and sulfonation. Preparations of
cycloalkanes by Freud synthesis, Hydrogenation of cycle alkenes;, Structure and stability
of cycloalkanes; Reaction of cycloalkanes.
GC University, Faisalabad
Outlines of Tests and Courses of Reading BA/B Sc Pass Course 6
c) Aromatic Hydrocarbons
Structure of benzene, Resonance energy of benzene, Aromaticity, criteria for
aromaticity, Evidences of aomaticity; Natural sources of aromatic hydrocarbons:
Preparation of aromatic hydrocarbons by different methods.
Reactions of aromatic hydrocarbons; electrophilic aromatic substitution reactions, i.e.
nitration, halogenation, Friedel-Crafts reaction and its limitations, sulfonation; orientation
and reactivity of substituted benzenes;
4. Isomerism
Conformational isomerism: Conformational analysis of ethane, n-butane, cyclohexane,
mono-and di-substituted cyclohexanes.
5. Alkyl halides.
Preparation of alkyl halides from alcohols and carboxylic acids;
Chemical reactions; Aliphatic nucleophilic substitution reactions, SN1 and SN2
mechanism, effects of the nature of substrate, attacking nuclophilic, leaving group and the
nature of solvent. Elimination reactions, E1 and E2 mechanisms, orientation of elimination
(Hoffmann and Sytzeff rules).
Grignard Reagents; synthesis, structure, and reactions with active hydrogen compounds,
carbonyl compounds such as aldehydes, ketones, esters, and acid halides and CO2;
Reactions with nitriles, ethylene oxide, sulphur and oxygen.
nd
6. Chemistry of Hydroxyl Group containing Compounds 2 Ethers
GC University, Faisalabad
Outlines of Tests and Courses of Reading BA/B Sc Pass Course 7
Ethers: Physical properties; Preparation of ethers from alcohols alkyl halides and alkenes;
Reactions of ethers; Brief introduction of crown ethers and polyethers.
Physical properties of aldehydes and ketones, Structure and reactivity of carbonyl group;
Comparison of the reactivity of aldelydes and ketones; Nucleophilic additions of water,
alcohols, ammonia and its derivatives, hydrogen cyanide, bisulfite, reduction and oxidation
reactions; Aldol condensation and related reactions; Cannizaro’s reactions; Witting
reaction; Oxidation reactions, Chemical tests of aldehydes and ketones.
3. Estimations (volumetric)
1. Determination of molecular weight of a carboxylic acid.
2. Estimation of amide group and glucose.
Recommended Books
GC University, Faisalabad
Outlines of Tests and Courses of Reading BA/B Sc Pass Course 8
4. Jerry March, “Advanced Organic Chemistry. Reaction, Mechanism and Structure”, 5th
Edition Wiley Inter Science.
5. Morison and Boyd, “Organic Chemistry”, 6th Edition, Prentice Hall.
6. Seyhan N. Ege, “Organic Chemistry Structure and Reactivity”, 3rd Edition. The
University of Michigan, A.I.T.B.S. Publishers & Distributors (Regd.).
7. Thomas H. Lowry, Kathleen Schueller Richardon “Mechanism and Theory in Organic
Chemistry”, 3rd Edition, Harper and Row Publishers, New York.
8. Alder, Baker, Brown, “Mechanism in Organic Chemistry”, Wiley Publishers.
9. Atkins Carey ‘Organic Chemistry’ A brief Course, 2nd Edition.
10. Peter Sykes, “A guide book to mechanism in organic chemistry”, 6th Edition, Pearson
Education , Singapore.
11. Carruthers, “Modern Methods of Organic Synthesis”, Cambridge low Priced Edition,
Cambridge.
12. Harris, Wamser, “Fundamentals of Organic Reaction Mechanism”, Wiley Publishers.
13. G. Malcolm, Dyson, “A Manual of Organic Chemistry”, Vol. I.
14. Canat Blat, “The Chemistry of Organic Compound”, 5th Edition.
15. R. Panico, W.H. Powell, Jean-Calude Richer, “A guide to UPAC Nomenclature of
Organic Compounds”, Blackwell Sci. Publication, 1993.
16. J.G. Traynham, “Organic Nomenclature, A Programmed Introduction”, Prentice Hall.
Inc. 1997.
17. R.C. Chan and O.C. Dermer, “Introduction to Chemical Nomenclature”, 5th Edition,
Butterworths, Inc. 1979.
18. M.B. Smith and J. March “Advanced Organic Chemistry”, 5th Edition, John Wiley and
Sons, New York.
19. R.O. Norman and J.M. Coxon, “Principles of Organic Synthesis”, 3rd Edition, Chapman
and Hall, 2001.
20. G. Solomons and Craig Fryhle, “Organic Chemistry”, 7th Edition, John Willey and Sons,
2000.
21. John McMurry. “Organic Chemistry”, 5th Edition, Brooks, 2000,.
22. M. Younas, “A Text-book of Organic Chemistry”, Ilmi Kitab Khana, Lahore.
23. Noller, “Basic Principles of Organic Chemistry”.
24. Robberts, “Basic Principles of Organic Chemistry”.
25. Younas. M., “Text Book of Organic Chemistry”, Ilmi Kitab Khana, Lahore.
26. Rehman, A., “Text Book of Organic Chemistry”, Karwan Book House, Lahore.”
For Practicals
1. K.M. Ibne Raza, M.A Rehman, Abdur Rehman, “Organic Chemistry”. Karwan Book
House, Lahore.
2. B.S. Furniss, “Vogel’s E.B of Practical Organic Chemistry”, Addison Wesly Longman,
Inc 1989.
3. Frederick George Mann and Saunder, “Practical Organic Chemistry”, The English
Language Book Society, 1960.
4. Daniel R. Palleras, “Experimental Organic Chemistry”, John Willey & Sons, Inc., 2000.”
5. James A. Moore, “Experimental methods in Organic Chemistry”, Holt Saunders Inc.,
1983.
6. R.L. Shriner, R.C. Fusion, D.V. Curtin and T.C. Morrill. “The systematic identification of
th
organic compounds, 6 ed. John Willey & Sons, 1979.”
GC University, Faisalabad