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    Thermodynamics Exercise 2

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    Julia Satriani
    This document contains data from various geochemical and thermodynamic calculations including: 1) Ion concentrations and log values at different temperatures and pressures. 2) Thermodynamic properties like Gibbs free energy, enthalpy and heat capacity for various minerals and compounds. 3) Calculated log K values and equilibrium constants for geochemical reactions at different temperatures. 4) Concentrations of dissolved species like SiO2, CO2, and H2 in liquids and steam at varying temperatures. 5) Enthalpy values for water, steam and other compounds involved in geothermal systems.

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    © All Rights Reserved
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    Thermodynamics Exercise 2

    Uploaded by

    Julia Satriani
    25 views7 pages
    This document contains data from various geochemical and thermodynamic calculations including: 1) Ion concentrations and log values at different temperatures and pressures. 2) Thermodynamic properties like Gibbs free energy, enthalpy and heat capacity for various minerals and compounds. 3) Calculated log K values and equilibrium constants for geochemical reactions at different temperatures. 4) Concentrations of dissolved species like SiO2, CO2, and H2 in liquids and steam at varying temperatures. 5) Enthalpy values for water, steam and other compounds involved in geothermal systems.

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    © © All Rights Reserved

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    This document contains data from various geochemical and thermodynamic calculations including: 1) Ion concentrations and log values at different temperatures and pressures. 2) Thermodynamic properties like Gibbs free energy, enthalpy and heat capacity for various minerals and compounds. 3) Calculated log K values and equilibrium constants for geochemical reactions at different temperatures. 4) Concentrations of dissolved species like SiO2, CO2, and H2 in liquids and steam at varying temperatures. 5) Enthalpy values for water, steam and other compounds involved in geothermal systems.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    25 views7 pages

    Thermodynamics Exercise 2

    Uploaded by

    Julia Satriani
    This document contains data from various geochemical and thermodynamic calculations including: 1) Ion concentrations and log values at different temperatures and pressures. 2) Thermodynamic properties like Gibbs free energy, enthalpy and heat capacity for various minerals and compounds. 3) Calculated log K values and equilibrium constants for geochemical reactions at different temperatures. 4) Concentrations of dissolved species like SiO2, CO2, and H2 in liquids and steam at varying temperatures. 5) Enthalpy values for water, steam and other compounds involved in geothermal systems.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    You are on page 1of 7

    Ca2+ Na+ Cl- A B

    I 0.001 0.01 0.7 0.5101 0.3285


    Åi 6.0 4.0 3.0

    logY -0.060737 -0.045086 -0.233913 1.00


    y 0.869486 0.901393 0.583562
    i 0.001 0.01 0.7

    I Ca2+ Na+ Cl-


    LOG 0.001 -0.060737 -0.015487 -0.015643 0.75
    0.01 -0.170445 -0.045086 -0.046434
    0.7 -0.644426 -0.20329 -0.233913

    0.001 0.87 0.96 0.96


    0.50
    0.01 0.68 0.90 0.90
    0.7 0.23 0.63 0.58

    0.25

    0.00
    0 0.25

    m HCO3 0.3038671051
    m H2CO3 0.6961193217
    m CO3 1.357325E-05
    m H2CO3 0.0004570882
    m HCO3 3.548134E-08
    m CO32- 0.0004570882

    0.25 0.5 0.75 1

    pH = 6 pH = 8
    0.000304 0.000973 0.001004347
    0.000696 0.000022298
    0.0000000135732 0.0000043478123
    Ca2+
    Na+
    Cl-

    1
    Gf Hf S Cp = a + bT + cT-2 + fT2
    J/mol J/mol J/mol/K a b c f
    SiO2 -856281 -910700 41.46 44.603 0.037754 -1001800
    H2O -237140 -285830 69.95 75.585 -0.000003576
    H4SiO4 -1309181 -1460238 178.85 298.343 -0.00065926
    2 H2O -474280 -571660 139.9

    c) Hr 22122 f) Tref TC TK

    Gr 21380 298.15 50 323.15


    Sr -2.51 100 373.15
    K 150 423.15
    e) a 102.57000 8.3144 200 473.15
    b -0.03775 250 523.15
    c 1001800.00000 300 573.15
    f -0.00065
    Log K vs T (K)
    - thermodynamics uncertainties are not the same with the 0
    lab uncertainties
    - LESSON 6: be aware that your thermodynamics -0.5
    calculations has large errors
    -1

    -1.5

    -2

    -2.5

    -3

    -3.5

    -4
    300 350 400 450 500
    Hr Sr Gr log K k (mol/kg)
    -3.5044132401993 0.00031303058
    -3.9044132401993 0.00012461972
    23076.7197202 0.571850402538177 22891.9262626187 -3.7044132401993 0.00019750894
    23999.15695395 3.27250996503433 22778.0198604951 -3.1920800287762 0.0006425693
    23510.70663273 2.08291648385121 22629.3205225903 -2.7965231468347 0.00159763238
    21479.24032634 -2.42127495492245 22624.8665712602 -2.5005090570515 0.00315857318
    17760.731843 -9.86257451692176 22920.3377015276 -2.2910577273248 0.00511613826
    12204.44686629 -19.9794664846274 23655.6780819564 -2.1582828233771 0.00694571848

    Log K vs T (K)
    0.00045
    0.0004
    0.00035
    0.0003
    0.00025
    0.0002
    0.00015
    0.0001
    0.00005
    0
    400 450 500 550 600 650 700 300 350 400
    ppm
    1.878183454E-05 19
    7.477183005E-06 7
    1.185053644E-05 12
    3.855415789E-05 39
    9.585794261E-05 96
    0.0001895143906 190
    0.0003069682957 307
    0.0004167431087 417

    ppm vs T (K)
    0.00045
    0.0004
    0.00035
    0.0003
    0.00025
    0.0002
    0.00015
    0.0001
    0.00005
    0
    300 350 400 450 500 550 600
    Htotal 1085.7 kJ/kg C 12.011 H 1.0078
    Hliquid 763.5 kJ/kg O 15.999 H2 2.0156
    Hsteam 2777.2 kJ/kg CO2 44.009
    Steam Fraction 0.160004

    SiO2 liquid 281 ppm


    CO2 liquid 74.3 ppm
    CO2 steam 51.6 mmole/kg 2270.864 ppm
    H2 1.24 mmole/kg 2.499344 ppm

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