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Redox Reactions 2

Chemistry

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69 views12 pages

Redox Reactions 2

Chemistry

Uploaded by

Jash Mehta
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Chapter a a eI 1 ee EOE STRAIGHT OBJECTIVE TyPE A. Oxidation Number and General Introduction 1. Which of the following reactions involve oxidation and reduetion? (a) NaBr + HCl —> NaCl + HBr (b) HBr + AgNO, —> AgBr + HNO, (©) H, + Br, —>2 HBr (@) NagO + HyS0, —+ Na,SO, + H,0 ‘2. Manganese achieves its maximum oxidation state in its compound : (a) MnO, (b) Mn,0, ( KMn0, (@) K,Mn0, 3. Oxidation number of underlined elements are N,05, $03", NHI : (@) 45, 42,-3 (b) 46,-2, 43 (0) +6, +2,-3 (@) 45,+4,-3 4, Phosphorous has the oxidation state of #3 in: (a) phosphorous acid (HsPO,) (©) ortho phosphoric acid (HPO,) (©) meta phosphoric acid (HPO,) (@) pyro phosphoric acid (H,P,07) . Which statement is wrong? (2) Oxidation number of oxygen is +1 in peroxides (6) Oxidation number of oxygen is +2 in oxygen difluoride © Oxidation number of oxygen is -1/2 in superoxides (@) Oxidation number of oxygen is (-2) in most of its compounds 10. Redox Reactions The incorrect order of decreasing oxidation number of S in compound is : (a) HyS,0; > NagS,0; > Na,S,03 > Sg (b) 80; > H,S0, > SCl, > H,S (© S0g>S0.>S,>H,S (@) H,S0, > SO, > HS > H,S,0, . The reaction 3C10-(ag) —> C105 (aq) + 2CI(aq) is an example of : (a) oxidation (b) reduction (©) disproportionation (@) decomposition reaction . Oxidizing agents are species which : (a) lose electrons (b) gain electrons (©) neither lose nor gain electrons (d) take part in solid-state reactions ). In which of the following reactions does HO, acts as a reducing agent? (a) 2 FeCl, +2 HCl +H,0, — 2 FeCl, + 2 H,0 (b) Cl, +H,0,— 2 HCl +0, (©) 2HI+H,0,— 9 2H,0+1, (@) H,S0, + H,0, —> H,S0, + H,0 ‘The oxidation number of an atom in a given species (molecule, ion or free atom) is the : (a) acutal charge of the atom (b) valency of the atom (c) formal charge of the atom (@) actual charge of the atom ifthe atom exists as 2 ‘monoatomic ion, or the hypothetical charge assigned to the atom in the species by simple rules. 11. The oxidation number of Cr is + 6 in: (a) FeCr,0, (b) Fes(CrO,). (©) Cr{$0,)0, @ (crOH),T 12. Suppose a compound contains atoms A, B and C. oxidation number of A is + 2, Bis +5 and Cis—2. Possible formula of the compound would be : (@) ABC, (b) AgBCy)y (© AJBC,), @ ABOy 18. Oxidation is a process in which : (a) oxidation number increases (b) electrons are lost (©) de-clectronation takes place (@) all the above happen 14. Which of the following is not a redox reaction? (a) Mg +N, — MgyNo (b) MnO," + C,0}° —> Mn?*+ CO. (©) CuSO, + KI —> Cugl + I + K,SO, (@) AgCl + NH — [Ag(NH,)2IC1 ‘The The 15, The average oxidation state of sulphur in sodium tetrathionate (Na,S,O,)is: (@) 0 ) 5 © 25 @ 30 16. The difference in the oxidation numbers of the types of sulphur atoms in Na,S,0, is : @ 5 ) 4 3 @2 two 17. Select the reaction which describes the existence of 1,05 (s) as (103) (103) : (a) 1,0; + HF —> HIO, + FIO, (b) 1,0; + HF — 10,F + HIO, (©) 1,0; + HF — HOI +10,F (@ 1,0; + HF— IF + HIO, 18. In FeCr,0,, the oxidation numbers of Fe and Cr. (a) +2and+3 (b) Oand+2 (c) +2and+6 (@) +3 and+6 19. The oxidation number of phosphorus in MgyP, (a) +3 (b) +2 () +5 (d) -3 20. The oxidation states of sulphur in the anions SO? S,0{° and 8,03 follow the order : (®) 8,0F < 8,0 < so? () 8,0F < SO} CaSO, +2H,0 (©) NaCl +H,80,—>NaHSO,+HO (@) 2PCl, + H,S0, —> 2POCI, + 2HC1+80! 27. Which of the following is a redox reaction? (a) NaCl+KNO, —+NaNO5+K¢l (b) CaC,0, + 2HC1— CaCl, ee _ (©) Mg(OH), +2NH,CL— Meh #28" (@) Zn-+ 2AgON —> 2g +Zn (ON) ay 28, A substance which participles FN acid-base and oxidation-reduction reat (0) KOH (@) HC ng bo, itroge 80,4045 ia (a) NaCO, (©) KMn0, pedox Reactions 29, Which of the following may act b and reducing agent? oth as an oxidizing (a) H,0, &) Mno,, (© 80, @ All of these 30, In the reaction Ca + Hy —s Cay, incorrect statement. Scleet the (a) Calcium undergoes oxidatic (b) Hydrogen undergoes reduction (0) Calcium acts as oxidising agent (@) Hydrogen acts as oxidising agent 31. Which of the following is not a redox reaction? (@) CO+NO;—+ CO, +NO ) 8SnCl, + 6HCl+2NO—43 SaCl, + 2NH,OH (© PCl,+Cl— PCI, @ Si0, +4 HF — SiF, + 24,0 42, The oxidation states of the most electronegative clement in the products of the reaction of BaO, with dilute HySO, is : (a) Oand-1 (b) -1and-2 (©) -2and0 (@) -2and 41 198. Which equation represents an oxidation-reduction reaction? (a) H,SO, + 2NH, —> (NH,),S0, (b) HySO, + NagCO, —+ Na,SO, + H,0 + CO, (¢) 2K,Cr0,+H,S0,—+ K,Crp0, +K,S0,+H,0 (a) 24,80, + Cu—s CuSO, + 2H,0 + SO, 94. For which substance is the oxidation number of vanadium the same as that in the VO3 ion? (a) VN) VCl; (@) VOSO, (@) VF, 985. Which substance participates readily in both acid-base and oxidation-reduction reactions? (2) NagCO, () KOH (© KMn0, (@) HyC,0, 36. PJs) + 30H"(ag) + 3H,O0) —> PH,(@) + 3H,PO,"(aq). For this reaction, the oxidizing and reducing agents are, respectively : (a) Py and OH- (b) OH" and Py (©) Pyand HO (@) P,and Py 37, What is the average oxidation number of tungsten in the ion, W,O,C133? @27 0) 33 @37 @) 43 38. In which case does chromium undergo reduction? (2) Cr0,—s CrOF, ©) Cr* _, CO; 5.3 (©) 210% — Cr, (@ Cr*— Gr oe 89, In which species does the underlined element have an oxidation number of +2? (@) $O,Cl, () FACM (©) HNO, (@) NCO) ¢ 40. Which transformation is an oxidation? (a) VO; — VO; () Cr0z — Cr0}" (© S0f— Sof —-(@) NO; > NO, 41. Which represents an oxidation? (a) BrO-—+ Br, (0) NO + NOx © Cr+—scx0F — @) VO; —+ VOz 42, For the balanced equation : 8H*(aq) + 5Fe**(ag) + MnO; (ag) — 5Fe(ag) + Mn?*(aq) + 4H,0() Which statement is correct? (a) Fe®(ag) undergoes oxidation (b) Fe®*(aq) is the oxidizing agent (©) H*(aq) undergoes oxidation (a) H*(aq) is the oxidizing agent, 48, Which substance can act only as a reducing agent? (@) ly ) BrCl (©) NaBr (@) HIO, 44, Which species can act as an oxidizing agent but not as a reducing agent? (@) Cl, () Cr (©) C105 (a) C10; 45, Whatis the oxidation number of Ti in the compound Nagli,0;? (a) -2 (b) +4 (© +6 (a) 412 46. Which range includes the average oxidation state of Sin NagS,0,2 (a) Less than 0 () Oto42 (©) 42to44 (@) Greater than +4 47, Which change represents an oxidation? (a) NOy —> No (b) VO* —> VO; () clo-— cr (a) Cr0F — Cr,07" 48, What is the oxidation number of Mo in Mo0,Cl,? On () +3 © +6 (a) +6 49. In which pair of substances do the nitrogen atoms have the same oxidation state? (@) HINO, andN,0, —_(b) NO and HNO, (©) NgandN,O (@) HINO, and HNO, 50. In the equation below, which species acts as the oxidizing agent? Pb(s) + PhOd(s) +2 H¥(aq) + 2 HSO; (ag) — 2 PbSO,(s) +2 HO) (a) Poe) (b) PbO,(s) (©) H*aq) (@) HSO;(aq) 51. In which species docs sulphur have the lowest oxidation state? (@) Sci, (b) OSF,, © 1,80, (@) SF, 52. Which species has an atom with an oxidation number of +3? (a) Cloz (b) PO} © $,07 (@ Nos 58. What is the oxidation number of rhenium in Ca(Re0,),? (a) +1 (b) +3 © +6 @ 47 54. When the half-reaction NO; —> NO is balanced for one NO§ in acid solution, .. (are) electron(s) is, (a) 3 gained (b) 1 gained (©) Llost (@) 8 lost 55. In the reaction C105 (aq) + 5CI(aq) + 6H*(ag) —s 3ClL,(g) + 3H,0() the oxidizing and reducing agents are, respectively : (a) Cag) and C10;(ag) () C105(ag) and CI(ag) (©) ©lO5(aq) and H*(ag) (@) Crag) and H*(aq) 56. Whatis the oxidation number of in formaldehyde, CH,O? (a) -2 ) 0 (©) 42 (@) +4 57. Which one of the following cannot act as an oxidizing agent? (a) s* (b) S03 () SO" (@) 8,03 58. What is the oxidation number of As in the compound K(NH,),As0,6H,0? Question Bank +Physical Chemisty tote (a) -3 © 43 ) 4 (a) 45 B. Balancing of Redox Reactions 1. MnO; + BI" + cH" — dMnP* els + ri.g In above balanced reaction, value of| ()ans, (@) 18 @s8 2. In the reaction, () 12 @5 aFeCly +9HS — FeCl, +8440, (@) x=2,y=1 (b) © x=4,y=3 @ x= 3, For the redox reaction sP, + yHNO, — 4 12, NO, +H,O : (@) x=1y=5 ©) (© x=1,y=20 (d@) 4, In the reaction xHI + yHNO. (a) y= 2 © ny a2 5. For the redox reaction MnO; + C,0F + Ht — Mn? 4. CO, +10 the correct stoichiometric coefficients of ln, Cf and Ht are respectively : (a) 2,5,16 (b) 16,5,2 (c) 5, 16,2 (d@) 2, 16,5, 6. In the half reaction : 2.010; — Cl, (a) 5 electrons are gained (b) 5 electrons are liberated (©) 10 electrons are gained (@) 10 electrons are liberated 7. Inthe reaction A~"? + xe” 5 A. Here, (0) ny-m (€) ny xm 8. Consider the following reaction : 3Bry+6CO% +3 H,0 —96 Br +105 +68 Which of the following statementsisiruer™™ this reaction? (a) Bromine is oxidized and the carbo is reduced. . (b) Bromine is reduced and the carbonate oxidized. (a) ny +n (©) my=ny at edoxReactions (©) Bromine is neither red ee reduced sf (@ Bromine isboth reduced end aang 9. In which of the followin in the oxidation eres a = (a) 2NOp—> N,O, . (b) NH +H,0 — NH,* + On- (©) N,05 + H,0 —s 2 HNO, (@ None of these (0, Which reaction do. 1 EE oie not represent auto redox or (a) Cly + OH" —> Ol" + C105 + H,0 ° (b) 24,0, — H,0 +0, (c) 2Cu*—> Cu +Cu (@) (NH,)gCr20, —> Np + Crg0, + 4H,0 U1. In the reaction X“ + XO; + Ht —> X, + H,0, the ‘molar ratio in which X- and XO3 react is: (a) 1:5 () 5:1 (© 2:3 @) 3:2 42, CN“is oxidised by NO3 in presence of acid : aCN-+bNO} +cH*—+(a+B)NO+aC0,+5H,0 What are the values of a, 6, c in that order : (a) 3,7,7 () 3, 10,7 (©) 3, 10,10 (@ 3,7,10 19, The following equations are balanced atomwise and chargewise. (p) Cr,0% + 8H* + 3,0, > 2Cr°* +7 H,0 + 302 (q) Crj0% + 8H* + BHO, 2Cr** + 9 H,0 + 402 (t) Cr0F + 8H* + TH,02> 2Cr5* + 11H,0 + 502, The precise equation/equations representing the oxidation of HO. is/are : (a) (P) only (© ®)only 14, During the disprop. and iodate ions, the ratio of iodate a formed in alkaline medium is : (b) (Q) only (@) all the three ortionation of iodine to iodide ind iodide ions (a) 1:5 ().5:1 3:1 (@ 1:3 15, Which of the following equations is correctly balanced? (a) 5BiO; + 22H* + Mn™* __ SBiS* + TH,0 + Mn0j 55[ 4, “3h (b) 5Bi0; + 14H* + 2Mn* — 5Bi** +7H,0 + 2Mn0; (©) 2Bi0; + 4H* + Mn?* — 2Bi** +2H,0 +Mn0; (@) 6Bi03 + 12H* + 3Mn* —+ 6Bi** + 6H,0 + 3Mn0; 16. The values of x, y and z in the reaction are respectively : 4KO, +xH1,0 + yCO, —> 4KHCO, +202 : (a) 3,6,6 ©) 2,43 © 3,25 @ 4,3,6 17. For the balanced redox reaction : aNOj + bCu,0 + cH —> NO + eCu®* +H where a, 6, c,d ande are stoichiometric coefficients if'e is 14, then the value of ‘eis : @ 2 (b) 3 @6 @7 18. Consider the balanced chemical reaction : a,0, + BBrF, —> CIF, + dO, + €Bry Calculate the value of (b ++ e)M(a). (a) 10 7 @6 @3 19, What are the values ofp, q,7 and s for the following, reaction? (p05 + gHI — rly + sH,0 (a) 1,6,3,1 ©) 1,6,3,3 (©) 1,6,6,3 (@ 1,6,3,6 20. The unbalanced equation for the reaction of P,Ss with nitrate in aqueous acidic medium is given below : P4S3 +NO3 — HPO, + so} +NO ‘The number of moles of water required per mole of P,Sy is: : (a) 18 5 @8 @ 28 21, (10; +_I'+Ht'— Cr +_h+_H0 When this equation is balanced with whole number coefficients, what is the H'/l coefficient ratio? 2 w 3 @? we @§ (@ Some other ratio [5.6 Question Bank “Physical Chemisty ley 22, MnO; +NO; + Ht —5 Mn +NO3 +H,0 29. What is the coofficient for O, when the . MnOz NH, +0, —+ NO +10 is balanced win When this equation is balanced correctly with the phe member eoefilcatsh ned With smallest integer coefficients, what is the coefficient oe ws for H*? 4 @5 8 @) 16 23, . tom ecw. 30. When the equation Sn?(aq) + 5a) + i, eel ~ a a I, H,00 i: ty What is the coefficient for OH when this equatfon Reet e 3 ee olan nig, is balanced with the smallest integer coefficients? a 1 _ 2 (@) 2 (b) 8 4 @ 6 t i 24, _Sn**(aq) + _NO3(aq) +_H*(aq) © 7 @ 5 —_Sn**(aq)+_NO@)+_H,0 What is the coefficient for H(ag) when the 91. ae teh ieromate fons in a equation above is balanced correctly with the solution gto the equation: smallest integer coefficients? O,H,OH() + 01,0 (aq) + H%(aq) (a) 2 m4 —0OsL0)+ C0909 an @s What is the coefficient for Haq) whe, iy 25, What is the coefficient for OH after the equation comtie scibeanesd with the smallest sig —Bry + OH" —> _Br- + _Br0} + _H,0 is number coefficients? balanced with the smallest integer coefficients? (@) 10 () 12 (a) 3 (b) 6 © @ 16 ©) 12 (@ 18 32. What is the coefficient for Zn when the 26, _Sn®*(aq) +_Mn0,-(aq) +_H*(aq) in*#(ag) +_Mn?*(aq) +_H,0(0) ‘When this equation for the reaction of Sn°*(ag) and. Mn0,-(aq) is balanced correctly, what is the ratio, Sn /Mn0;? 1 1 @) i (b) 3 2 5 s a 5 @s @> 27. What is the coefficient for H+ when the half equation is balanced with the smallest whole number coefficients? —S*+__H,0 —>_S0,+_H*t+_e- @2 ) 4 6 @s 28. When the reaction: CI“ + C103 — Cly + H,0 is balanced in acid solution what is the ratio of CI- to C05? Z 2 Or 2 3 5 © i @ i below is balanced with the smallest whol lemuat, coefficients? Zn + Haq) + NOj(ag) 9 En**(aq) +N, 0) 4,09 (@ 2 4 6 @s 83. What is the coefficient for O, when the fll reaction ~As,S3 +O) —> As,0, 4.80, is correctly balanced with the smallest inleet coefficients? () 5 6 ©@8 @s 34. When the equation below is balanced cometh using the simplest whole number coeficients vi! is the coefficient for CO,(@)? —Cr,0F (aq) +__H,C,0,(aq) +_H*(a9) —_cr(ag) +_COje)+_ 10! (a) 4 6. @8 wen 35. How many H* ions are required when the equ? below is balanced with the smallest whole m= coefficients? tedoxReactions Culs) + NOZ(aq) + Hea, 24 at D —> Cu (ag) + NOW) + @2 4 We @ 8 36, When this equation is balanced using the smallest possible integers, coefficients? -(NH,)PO,(aq) + CaCisfag) > ~Cag(PO,)s)+_NH{Ci(ag) © 11 (@) 12 87, Boron carbide, BC, is made by the high temperature reaction of boron oxide with graphite, yielding carbon monoxide as a by-product. " what is the sum of the (a) 8 ) 9 —B.0;+_C—s__B,c4co What is the total of the smallest coefficients for the reactants and products in the balanced equation? (a) 9 (b) 10 © 15 @ 16 38, When the equation : —Mn0j +_ SOF +__Ht —_Mn"*+_ sor +_H,0 is balanced correctly with the smallest whole number coefficients, what is the coeffi H,0? (a) 3 (b) 5 © 8 @ 10 ‘39. What is the coefficient of I, (s) when the reaction below is balanced with smallest whole number coefficients? ~Cr0F (aq) +_I-(aq) +_H*(aq) — Is) +_Cr(ag)+_H,00) @2 38 @4 @ 6 40, Ratio of stoichiometric coefficient of NjH, to Cl-in the following reaction : C10; +N,H,— NO; +C1- 8 2 6 @) = i a ®F M1 @©2F ws for C. Caleulation of Equivalent Weight 1. Equivalent weight of Brin the following reaction is: Bry +Hg0 + H,0 —+ HgBr.HgO + HBrO (Given : Br = 80) (a) 260 (b) 80 (© 160 (@ 1603 2, In the reaction, 2. CuSO, +4 KI —> Cugly + I, +2 K,S0, the equivalent weight of Cu will be : (a) 81.75 (&) 63.5 (© 127 (@ 15.88 (Atomic weight of Cu=63.5). 8, In the following reaction hydrazine is oxidized to Ny NH, + OH" +N, +H,0 +e ‘The equivalent weight of NjH, (hydrazine) is @ 8 (o) 16 © 32 (@) 64 4. The molecular weight of the compounds (I) Na,SO, (1) NagPO,-12H,O and (II) Cag(PO,), respectively are X, Y and Z the correct set of their equivalent weights will be : Zen ¥ ome Yom2 @ MFM Fas w MXM aM 4 © o< amram @ OXaDYayz 5. When one mole NOj is converted into 1 mole NO., 0.5 mole Ny and 0.5 mole N,O respectively. It accepts x, y and z mole of electrons : -x, y, z are respectively : (a) 1,5,4 @) 12,3 (© 21,3 (@) 2,8,4 6. In the equation, SnCl, + 2HgClg — Hg,Cl, + SnCl, The equivalent weight of stannous chloride (molecular weight = 190) will be : a) 190 (b) 95 © 415 (a) 1545 7. In the following change, SFe + 4H,0 —> FeO, + 4H, If the atomic weight of iron is 56, then its equivalent weight will be : (a) 42 () 21 (© 63 (a) 84 8, Which statement is correct for equivalent weight of KMn0,? (a) Baguvalent weight is 7 of molecular mass in neutral and weak basic medium "5.8 (b) Equivalent weight is : of molecular mass in basic medium (©) Equivalent weight is equal to molecular mass in acidic medium @ Equivalent weight is i of molecular mass in acidie medium 9. Equivalent weight of NH; in the change N, > NHgis: roe a " (a) $ () 1 u () a (a) 3 10. If M represents.molecular mass of MnO, then what will be its equivalent mass if it undergoes disproportionation reaetion as shown: Mn,0,—> MnO; +Mn** M M — 2 7 a ou 15M ot Oa 11. What is the equivalent mass of S,0}" ion as per the following disproportionation reaction , SO} — S,0F +S} where the charge above species represents charge on the fon and not oxidation state? (a) 182 (b) 22 (©) 130.6 (d) 113.15 12. The equivalent mass of MnSO, is half its molecular mass when it is converted to : (a) Mn,0, (b) MnO, (© MnO; (a) MnO? 18. When KMnO, acts as an oxidising agent and ultimately forms MnO{", MnO», Mn,0, and Mn2, then the number of electrons per molecular species transferred in each case is : (@) 4,3,1,5 (b) 1,5, 3,7 © 1,3,4,5 @) 3,5,7,1 14, Equivalent weight of chlorine molecule in the equation is : 3Cly + 6NaOH — 5NaCl + NaClO, + 3H,O (@) 426 (b) 35.5 (©) 59.1 (@) 71 15. In the following conversion of i f sulphi phosphorous | ” 1, How many millilitres of a 9N H,S0, Question Bank: Physical Chemisty oy ee a P,S; —>P,0, +80, Equivalent weight of P,S, (molecular Weighty, MM M Oa OR M a M © 3 Os D. Titration 1s Solution be required to neutralize completely 20 m1 0 mL ~ ‘NNaOH solution? tag @) 18.0 mL ©) 80mL (© 16.0 mL @ 80.0 mL 2. What isthe normality of the H,S0, stating ri of which neutralizes 20.0 miofa Ls5y in, solution? (@) 50N Oiee © 25N (@ 35N 3. 50 ml of 5.6% KOH (o/) is added to 50 xtc) 5.6% HC (w/v) solution. The resulting solatinss be: (a) neutral (b) alkaline (©) strongly alkaline (@) acidic 4, Calculate the normality of an NaOH solution 25 mL of which is required to convert 0240 ¢¢ NaH,PO, in a solutiin to monohydng: phosphate, (a) 1.093N () 0.093 (©) 0.048.N (@) 093N | 5. 10 mL of 0.5 N HCl, 30 mL of 0.1 N HNO, anil mL of 0.1 M H,SO, are mixed together normality of the resulting solution will be: (a) 02N ) 01N (©) 04N (@) 05N | 6. The amount of KMnO, required to prepare 101° | of a 0.1 N solution in an acidic mediumis: (a) 3.16 (b) 1.588 (©) 0.316 g (a) 316g jl 7. Volume of 0.1 M ferrous oxalate sllon to react completely with 60 ml of 0.1 KMnQ, solution. (a) 80 mL (b) 20m (© 150 mL (@ 10m) pedoxReactions g. What volume of 02(g) measured at 1 atm and 273 K will be formed by action of 200 mL of 0.4 M KMnO, of hydrogen peroxide in acidie solution? (a) 4.48 litre () 2.24 litre (©) 8.96 litre (@ 112 litre 9, The number of moles of ferrous oxalate oxidised by one mole of KMnO, in acidic medium is : 5 2 ei (b) 2 OF we 3 5 e a 5 OF @>5 10, How many moles of KMnO, are needed to oxidise a mixture of 1 mole of each FeSO, and FeC,0, in acidic medium? 4 S| (b) (a) 3 ele ale 3 OF @ 11. When Ng is converted into NHg, the equivalent ‘weight of nitrogen will be : (a) 1.67 (b) 2.67 (c) 3.67 (d) 4.67 12, In the conversion NH0H —+N,0, the equivalent weight of NH,OH will be : (Mf = molecular weight of NH,OH) M M rs py oF ws M M (co) a @ T 13. Which of the following relations is incorrect for solutions? (a) 3N Al,(SO,), = 0.5 M Al(SO,), (b) 3M H,SO, = 6 H,S0, () 1M H,PO, = 1/3 NH,PO, (@ 1MAL(SO,), = 6 N Al(SO)s 14, How many millilitres of 0.1 N H,SO, solution will be required for complete reaction with a solution containing 0,125 g of pure NagCOj : (a) 23.6 mL, (b) 25.6 mL (©) 26.3 mL (@) 82.6 mL 15, If 25 mL ofa H,SO, solution reacts completely with 1.06 g of pure NagCO,, what is the normality of this acid solution : @ iN (©) 18N (b) 0.5 (d) 0.8N 5.9 } 16. The mass of oxalic acid crystals (H,C,0,.2H,0) required to prepare 50 mL of a 0.2 N solution is : (a) 4.58 ©) 63g (©) 0.63 g (@) 0.45 g 17. 125 mL of 63% (w/v) H,C,0,.2H,0 solution is made to react with 125 mL of a 40% (w/v) NaOH solution, ‘The resulting solution is : (ignoring hyarolysis of ions) (a) neutral () acidic (©) strongly acidic (@) alkaline 18. The normality of 0.3 M phosphorus acid (HyPO,)is : a) 01 =) 09) 03 ~~ @) 06 In basic medium, I” is oxidised by MnOj. In this rrocess, I~ changes to : @10; © ©1; @ 10 20. The amount of wet NaOH containing 15% water required to prepare 70 litres of 0.5 N solution is: - (a) 1.65 kg (b) 14kg (©) 16.5 kg (@) 140 kg 21, HNO, oxidises NH ions to nitrogen and itself gets reduced to NO,, The moles of HNO, required by 1 mole of (NH,),S0, is : (@4 © 5 @6 @ 2 22, What will happen if the solution of potassium chromate reacts with excess amount of nitric acid? (a) Crreduces in the oxidation state +8 from CxO} (b) Cr oxidises in the oxidation state + 7 from Cr or (©) Cr* and Cr,07° will be formed (d) Cr,0% and H,0 will be formed 28. The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is : (+4 9b) +6 +2 A) 48 24, Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr’ salt required per mole of dichromate is : (a) 3 (b) 4 @5 @ 6 25. 0-7 g of (NH,)2S0, sample was boiled with 100 mL, of 0.2 N NaOH solution till all the NH, gas is evolved. The resulting solution was diluted to 250 mL, 25 mL of this solution was neutralized using _ 5.10 10mL of a 0.1 N H,S0, solution. The percentage Purity of the (NH,),SO, sample is : (@) 943° @) 508 (©) 474 (A) 79.8 26. 10 mL of 1 N HClis mixed with 20 mL of 1M H,SO, and 30 mL of | MNaOH. The resultant solution has: (a) 20 meq of H* ions (b) 20 meq of OH (©) 0 meq of H* or OH™ (A) 30 mili moles of H* 27, Which of the following statements are incorrect? (a) 0.2 moles of KMnO, will oxidise one mole of ferrous ions to ferric ions in acidic medium. (b) 1.5 moles of KMnO, will quantitatively oxidise mole of ferrous oxalate in acidic medium. (©) 0.6 moles KMnO, will oxidise 1 mole of ferrous oxalate to one mole of ferrie ion and carbon dioxide in acidic medium. (@) mole of K,Cr,0, will oxidise 2 moles of ferrous oxalate to ferric ions and carbon dioxide in acidic medium. 28. The valency factor of Ip when, (i) itis formed by the reaction of potassium iodide and potassium iodate in acid medium and (ii) when it reacts with hypo, are respectively : @22 0 2 (@ 5,2 29. The number of moles of oxalate ions oxidized by one mole of MnO; ion in acidic medium is : 5 2 3 5 5 2 3 @) = @> o — © @3 5 80. What volume of 0.1 M HyO, solution will be required to completely reduce 1 litre of 0.1 M KMn0, in acidic medium? (@) 2500 ml (b) 500 ml (c) 1000 ml (4) 1200 mi 81. Calculate the number of millimoles of SO,, if in the reaction, 10 mL of 0.1 M KMnO, solution are required for complete titration. ‘SO, + MnO; —> SO;? + Mn*? (b) 0.5 (a) None of these (a) 2.5 (©) 1.25 32. 10 moles of ferric oxalate is oxidised by x mole of ‘Mn0y in acidic medium, The value of ‘vis : @2 4 @4 @ 18 38. Calculate the moles of KMnO, required to react completely with 2 M and 1500 mL of K,C,0, - H,C,0, in acidic medium : (a) 08 (06 =) 16 (a) 24 Question Bank : Physical Chemisty torte, SS 34. What is the correct relation between (N) and molarity (I) of K,Cr,0; acting as o agent in acidic medium? @ © 85. Number of moles of electrons involved ig reaction during formation of 1 mole of pet according to the reaction Fe +H,0 — 42,9 . q will be: cee @.1 m 5 © 3 @s 36. 0.8 M FeSO, solution requires 160ml, 02 y Al,(Cr,07)g in acidic medium. Calculate voluge FeSO, consumed : - (a) 480 mL (b) 240 mL, (©) 720mL (@) 40 mL, 37. In alkaline medium ClO, oxidises itself gets reduced to Cl. How ane ae fa are oxidised by 1 mole of C10,? a @1 15 © 25 @ 35 38. If equal volume of IM KMn0, and IM Ke, solutions are used to react with Fe in asi, medium then amount of Fe** oxidized will be: (a) more by K,Cr,0, (b) more by KMnO, (©) equal in both cases (@ Fe’ cannot be oxidized 89, In a titration of HO, certain amount is tre with 4” mole of KMn0, in acidic medium, Themis of H,0, in solution will be : (a) 8y (b) = (©) by y ribs @) 40. In basic medium, CrO}" oxidises $,0} to fra Cx(OH)j and $03". How many mL of 0.25 MC are required to react with 40 mL of 0.3MNa,S0! (a) 16 mL. (b) 82 mL, (c) 128mL (@) 42mL 41. What is the molarity of H,0, solution whose 1008! produce the 0.5 mole of Ip, when reacted wither KI solution? @ 05M @ iM @ 25a «oH ' 42, Moles of K,Cr,0; used to oxidise 1 mol Feat Fe’ are : 1 0.92 11 (078 = =x- @ = @F © OG OG edocs 4g. In basic medium, Cr Of" oxidizes 8,03" to form soy and itself changes to Cr(OH);. How many mL of 0.154 M Cr Oj-are required to react with 40 mL. of 0.908 M S05? (a) 213 mL (b) 156.4 mL (9 1704mL (@) 190.4 mb What would be the normality of a 0.1 M K,Cr,0, ‘HU jution used as a oxidizing agent for Pb*? ( 01N (b) 0.6 (9 0AN (@ 02N 4g, In the redox reaction, MnO; +5C,0;" +16H* —>2Mn®* +1000, + 8H,0 20 mLof 0.1M. KMn0O, reacts quantitatively with: (a) 20 mL of 0.1 M oxalate (b) 40 mL of 0.1 M oxalate (@ 50 mLof 0.25 M oxalate (@) 50 mL of 0.1 M oxalate 4g, An aqueous solution of 18 gm oxalic acid (H,C,0,) jsmade up to 400 ml, Calculate the volume of 0.1 NaOH required to completely neutralize 50 mL of above solution. (@) 500 mL (© 400 mL REASONING TYPE Directior Each question has 5 choices (a), (b), (c), (4) and (e) out of which ONLY ONE is correct. (@) Statement-1 is True, Statement-2 is True; Statement-2 4 a correct explanation for Statement-1. (b) Statement-1 is True, Statement-2 is True, Statement-2 isNOT a correct explanation for Statement-1. (©) Statement-1 is True, Statement-2 is False. @) Statement-1 is False, Statement-2 is True. (©) Statement-1 and Statement-2 both are False. 1. Statement-I: Moles of KMnO, required for oxidation of Fe*? in acidic and basic medium will be different. Statement-2: Final oxidation state to which Mn‘? Will be reduced will be different in case of acidic and basic medium, (>) 50 mL, @ 200 mL Statement-2: Blue solution of CrO, is stabilised in the presence of organic solvent, e.g., ether, pyridine, te. 3. Statement-1: The oxidation state of oxygen in ‘superoxide ion in KO, Cs0y and RbO, is ~ 1/2. ‘Statement-2: Since the oxidation state of an alkali metal in any compound is always + 1, the oxidation state of oxygen is — 1/2 in the 0; ion. 4, Statement-1: In the redox reaction 8H*(ag) + 4NO3 + 6CI" + Sn(s) —> SnCl} + 4. NO, + 44,0, the reducing agent is Sits). Statement-2: In balancing half reaction, $,03° —> S(s), the number of electrons added on the left is 4. 5, Statement-I: In the reaction, ‘MnO; + 5 Fe’ + 4 H,O, MnO; acts as oxidising agent. ‘Statement-2: In the above reaction, Fe? is converted to Fe™*. 6, Statement-1: 1f 200 mL of 0.1 N NaOH is added to 200 ml, of 0.1 N H,SO, solution, then the resulting solution is acidic. Statement-2: If milliequivalents of acid is greater than milliequivalents of base, then upon mixing the solution is acidic. 7. Statement-1: Equivalent weight of FeC,0, in the reaction, FeC,0, + Oxidising agent — Fe"* + CO, is M/S, where M is molar mass of FeC,0,. Statement-2: In the above reaction total two moles of electrons are given up by 1 mole of FeC,0, to the oxidising agent. 8, Statement-1: In the titration of NaCO, with HCL using methyl orange indicator, the volume of the acid required at the equivalence point is twice that of the acid required using phenolphthalein as indicator. Statement-2: Two moles of HCl are required for the complete neutralisation of one mole of NagCO3. 2. Statement-1: Both CxO} and Cr,0* ions when PREVIOUS YEARS’ QUESTIONS treated with acidified H,O, solution gives blue solution which turns green on standing. 1. A mixture of potassium chlorate, oxalic acid and sulphuric acid is heated. During the reaction which 5.12 clement undergoes maximum change in the oxidation number? [Prelims] @) s ) H @a @e 2, When Cly gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from : [Pretims} (a) zero to +1 and zero to-5 (b) zero to -1 and zero to +5 (©) zero to -1 and zero to +3 (@) zero to +1 and zero to -8 3. In acidic medium, H,0, changes Cn0% to CrOs which has two (O—O—) bonds. Oxidation state of Crin CrO, is: [aipMT] (a) 45 (b) 43 © 46 @ -10 4. (1) H,0, +03 —>H,0+ 20. (ID) HO, + AgzO— 2Ag +H,0+02 Role of hydrogen peroxide in the above reactions is respectively : [AIPMT] (a) oxidizing in (1) and reducing in (II) (b) reducing in (1) and oxidizing in ap (c) reducing in (I) and (II) (d) oxidizing in (1) and (II) 5. The correct order of N-compounds in its decreasing order of oxidation states is : [NEET] (a) HNO3, NH4Cl, NO, No (b) HNO3, NO, NH,Cl, No (©) HNOs, NO, No, NH4Cl (@ NH,Cl, No, NO, HNOs 6. For the redox reaction MnO; +C,0}° +H* —s Mn** +CO, +H,0 ‘The correct coefficient of the reactants for the balanced equation are: [NEET] MnO; c,0}° Ht (@) 2 16 5 ) 2 5 16 © 16 5 2 @ 5 16 2 Question Bank : Physical Chemisty Hey 17. Which of the following reactions are dis ation reaction ? PP, () 2Cut —> Cu +Cu” a Gi) SMnOf" + 4H* — 2Min0j + Mind, +4, 1 (i2KMn0, —*+K_Mn0, +Mn0, +0, o |x (iv) 2Mn0j +3Mn** +2H,0— 5MnO, + 445 Select the correct option from the following. (a) (i) and (i) only be) (b) @, Gi) and Git) (©) (i), Gi) and (d) (@) (@ and Gv) only 8. ‘The method used to remove temporary h wateris: - ir (a) Calgon's method a (b) Clark's method (©) Jon-exchange method (a) Synthetic resins method 9. What is the change in oxidation number of ag in the following reaction? i= CH,(g) + 4Cl,(g) CC1,(D) + 4HCK(g) (a) Oto-4 (b) +4 to+4 (© Oto+4 (a) Ato +4 10. In the neutral or faintly alkaline medium, KN oxidises iodide into iodate. The change in oxida state of manganese in this reactions from: =) (a) +6 to +4 () 47 to48 (©) +6 to 45 (@ 47to44 11. On balancing the given redox reaction, aCr,0%" + bSO% (aq) + cH* (aq) —> 2aCr** (aq) + BSOF (a+ H0 the coefficients a, b and ¢ are found tk) respectively : wet (a) 3,8,1 - (b) 1,8,3 © 81,8 @ 1,38

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