Ilovepdf Merged
Ilovepdf Merged
Ilovepdf Merged
21
Q Answer Marks
1 (a) to prevent evaporation / loss of solvent 1 7
(b)(i) solvent level above spots / hair dye samples 1
(b)(ii) dyes would mix / dissolve with solvent / wash off paper 1
(c) organic solvent / named organic solvent 1
(d) any three from:
• R contains P / Q • R is a mixture / contains 2 colours
• P is a single colour / pure substance • Q is a single colour / pure substance
• P and Q are different colours max 3
2 (a) thermometer 1 8
(round bottom) flask 1
(b) arrow to bottom entry to water jacket on condenser 1
(c)(i) flammable 1
(c)(ii) water bath / electric heater / heating mantle/ oil bath 1
(d) cools (the vapour / alcohol) 1
(e) methanol 1
lowest boiling point 1
3 (a) exothermic 1 7
(b) all volumes of distilled water completed correctly (12, 10, 8, 4, zero / 0 / none / –) 1
all times completed correctly, all five correct scores 2, four correct scores 1 (72, 45, 33, 23, 16) 2
(c) 5 1
(d) more accurate 1
(e) gas escapes (before bung inserted) / gas not collected 1
5 (a) 1 1 4
(b) carbon dioxide 1
(c)(i) hydrochloric acid / HCl
hydrogen (ions) / H+ chloride (ions) / Cl– 2
6 Any 6 from: 6
• crush / grind root
• with pestle / mortar
• with water / solvent
• place (drop of) liquid / colour on paper
• conduct chromatography
• (bottom of) paper placed in a suitable solvent / water
• number of coloured substances = number of spots
SA 1 Chemistry 0620/22 Grade 9 MCQ – P2- 2021-2022- 40 marks- 19.10.21
Q Answer Marks
1 C 1
2 D 1
3 C 1
4 C 1
5 C 1
6 B 1
7 C 1
8 C 1
9 C 1
10 D 1
11 D 1
12 B 1
13 D 1
14 B 1
15 D 1
16 D 1
17 A 1
18 C 1
19 C 1
20 C 1
21 B 1
22 B 1
23 A 1
24 A 1
25 D 1
26 B 1
27 D 1
28 D 1
29 D 1
30 B 1
31 B 1
32 A 1
33 C 1
34 C 1
35 D 1
36 B 1
37 D 1
38 D 1
39 C 1
40 C 1
CENTRE NO. IN971
CHEMISTRY 0620/22
Paper 2 Multiple Choice (Extended)
DATE: 19.10.21
You must answer on the multiple choice answer sheet. TIME: 45 mins.
INSTRUCTIONS
1
1 A crystal of purple potassium manganate(VII) was added to each of the beakers shown in the diagram.
One beaker contained hot water and the other beaker contained cold water.
In both beakers the purple colour of the potassium manganate(VII) spreads out.
Which result and explanation are correct?
2
4 The table shows the numbers of particles present in the nuclei of four atoms or ions.
3
7 When sulfur is heated it undergoes a ......1...... change as it melts.
Further heating causes the sulfur to undergo a ......2...... change and form sulfur dioxide.
Which words complete gaps 1 and 2?
4
10 Chemical compounds formed from a Group I element and a Group VII element contain ionic bonds.
How are the ionic bonds formed?
A Electrons are transferred from Group VII atoms to Group I atoms.
B Electrons are shared between Group I atoms and Group VII atoms.
C Electrons are lost by Group I atoms and Group VII atoms.
D Electrons are transferred from Group I atoms to Group VII atoms.
12 Carbon has three isotopes, 12C, 13C and 14C. Why do all three isotopes have the same chemical properties?
A act as catalysts B form coloured compounds C high melting point D low density
5
15 Which diagram represents a mixture of two different elements?
16 Which statement describes a gas which is in Group VIII of the Periodic Table?
A Only Q and R are suitable for drinking, while P could be used for irrigation.
B Only Q and R are suitable for drinking, while P is unsuitable for any purpose.
C Only Q is suitable for drinking. R could be used for washing cars and P for irrigation.
D P, Q and R are suitable for irrigation and washing cars, but are not suitable for drinking.
18 A sample of air from a town centre was analysed and found to contain mainly nitrogen and oxygen, but also
traces of the four gases below.
Which of these gases is a pollutant?
A argon B carbon dioxide C sulfur dioxide D water vapour
6
19 Which elements does an NPK fertiliser contain?
A nickel, phosphorus, potassium B nickel, potassium, calcium
C nitrogen, phosphorus, potassium D nitrogen, potassium, calcium
20 Iron reacts with dilute hydrochloric acid to form iron(II) chloride, FeCl2. Iron reacts with chlorine to form
iron(III) chloride, FeCl3.
Which property of transition elements is shown by this information?
A Transition elements have high melting points. B Transition elements can act as catalysts.
C Transition elements have variable oxidation states. D Transition elements have coloured compounds.
A Filtration removes bacteria and insoluble impurities, and chlorination removes soluble impurities.
B Filtration removes insoluble impurities, and chlorination kills the bacteria.
C Filtration removes soluble and insoluble impurities, and chlorination kills the bacteria.
D Filtration removes soluble impurities and bacteria, and chlorination removes insoluble impurities.
23 The atomic number and nucleon number of a potassium atom are shown.
7
24 The electronic structures of two atoms, P and Q, are shown.
8
26 A Group I metal (lithium, sodium or potassium) is reacted with a Group VII element (chlorine, bromine or
iodine).
Which compound is formed when the Group I metal of highest density reacts with the Group VII element of
lowest density?
A lithium chloride B potassium chloride C potassium iodide D lithium iodide
9
30 A balloon is filled with helium. Helium is a noble gas and makes the balloon rise up in the air.
The density of air is 1.23 g /dm3 .
Which gas is helium?
31 The properties of the element titanium, Ti, can be predicted from its position in the Periodic Table.
Which row identifies the properties of titanium?
10
34 When steam at 100oC condenses to water at 25 oC, what happens to the water molecules?
A They move faster and closer together. B They move faster and further apart.
C They move slower and closer together. D They move slower and further apart.
35 The diagram shows a section of the Periodic Table. Which element is described below?
‘A colourless, unreactive gas that is denser than air.’
36 The apparatus shown cannot be used to determine the melting point of sodium chloride, Na+Cl–.
Why is this?
11
37 Aqueous ammonia is added to a solution of a metal sulphate.
A green precipitate that is insoluble in excess of the aqueous ammonia forms.
Which metal ion is present?
A Ca2+ B Cu2+ C Fe3+ D Fe2+
39 When propane is burned, carbon dioxide and water are formed, as shown.
12
40 The table shows some information about elements in Group VII of the Periodic Table.
13
14
SA 1 Chemistry 0620/42 Grade 9 p-4- THEORY- 2021-2022- 80 marks- 19.10.21
Q Answer Marks
1 (a) chlorine/ argon [1] 5
(b) chlorine [1]
(c) magnesium [1]
(d) argon [1]
(e) sodium [1]
2 (a) Atoms of the same element/ atoms with same proton number/ atoms with same atomic 29
number
different neutron number/ nucleon number/ mass number [1]
(c) 3 bond pairs between N & H [1] Lone pair on N [1] [2]
(ii) K outer shell with 8 crosses (1) Cl outer shell with 7 dots and 1 cross (1) (1) + and – (1)
[3]
(e) (i) liquid (1) BOTH melting point is below –75 oC AND boiling point is above –75 oC
OR
BOTH –75 oC is higher than –101 oC / melting point AND lower than –35 oC / boiling point
OR
–75 oC is between melting point or –101 oC and boiling point or –35 oC [2]
(iii)
[2]
(iv) lilac flame [1]
(f)
[2]
(ii)
[2]
(g)
[2]
3 (a)(i) 20
1
(a) (ii) diffusion 1
(c)(i) boils at 100°C/ boiling point 100°C/ freezes at 0 °C/ freezing point 0°C/ melts at 0°C/
melting point 0oC; [1]
(ii) filtration (1)
chlorination (1) [2]
(iii) Any one from:
• manufacture of ethanol
• used in the manufacture of sulfuric acid or in the Contact process
• manufacture of hydrogen or ammonia or for the Haber process
Or any suitable point [1]
(iv) boiling or turning to steam (1)
then condensing/ condensation (1) [2]
(b) (i) to make colourless / invisible (spots) visible / coloured / seen / position made clear /
indicate [1]
(ii) distance travelled by sample / distance travelled by solvent (front) = Rf [1]
(iii) sample 1 Rf = 0.20 to 0.24 tartaric (acid) [1]
sample 2 Rf = 0.44 to 0.48 malic (acid) [1]
CENTRE NO. IN971
DIVISION: ROLL
GRADE: 9 A NUMBER
CHEMISTRY 0620/42
Paper 4 Theory (Extended)
DATE: 19.10.21
You must answer on the question paper. TIME: 1hr 15 mins.
INSTRUCTIONS
Q Marks
• Answer all questions. 1/5
• Use a black or dark blue pen.
• You may use an HB pencil for any diagrams or graphs.
• Write your name and candidate number in the boxes at the top of the page. 2/29
• Write your answer to each question in the space provided.
• Do not use an erasable pen or correction fluid. 3/20
• You may use a calculator.
• You should show all your working and use appropriate units. 4/18
INFORMATION
5/8
• The total mark for this paper is 80.
• The number of marks for each question or part question is shown in brackets [ ]. Total/80
• The Periodic Table is printed in the question paper.
1
1 For each of the following, give the name of an element from Period 3 (sodium to argon), which matches the
description.
(a) an element which is gaseous at room temperature and pressure
................................................................................................................................................................................................ [1]
................................................................................................................................................................................................ [1]
................................................................................................................................................................................................ [1]
................................................................................................................................................................................................ [1]
(e) an element that reacts vigorously with cold water to produce hydrogen
................................................................................................................................................................................................ [1]
[Total: 5]
.......................................................................................................................................................................................................
................................................................................................................................................................................................ [1]
2
[7]
(c) Draw a dot-and-cross diagram to show the arrangement of the outer (valency) electrons in one molecule of
ammonia.
[2]
(d) (i) Potassium reacts with chlorine to form potassium chloride, KCl.
Write a chemical equation for this reaction.
................................................................................................................................................................................................. [2]
(ii) Potassium chloride is an ionic compound.
Complete the diagram to show the electron arrangement in the outer shells of the ions present in potassium
chloride. Give the charges on both ions.
[3]
3
(e) The melting points and boiling points of chlorine and potassium chloride are shown.
(i) Deduce the physical state of chlorine at –75°C. Use the data in the table to explain your answer.
explanation ..................................................................................................................................................................................
..................................................................................................................................................................................................[2]
(ii) Explain, in terms of structure and bonding, why potassium chloride has a much higher melting point than
chlorine.
Your answer should refer to the:
● types of particle held together by the forces of attraction
● types of forces of attraction between particles
● relative strength of the forces of attraction.
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [3]
(iii) Solid potassium chloride is a poor conductor of electricity but when dissolved in water is a good conductor
Explain.
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
4
(iv) Flame test was conducted with a small amount of solid potassium chloride. Give the observation for a positive
test.
................................................................................................................................................................................................. [1]
(f) Diamond and graphite are two forms of the element carbon.
(i) Explain why diamond is a very hard substance.
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
Use this diagram to explain why the formula is SiO2 and not SiO4.
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
[Total: 29]
5
3 Concentrated ammonia solution gives off ammonia gas. Concentrated hydrochloric acid gives off hydrogen
chloride gas.
Ammonia, NH3, and hydrogen chloride, HCl, are both colourless gases.
Ammonia reacts with hydrogen chloride to make the white solid ammonium chloride.
Apparatus is set up as shown.
After ten minutes a white solid forms in the tube where the gases meet.
(a) (i) Write the chemical equation for the reaction of ammonia with hydrogen chloride.
................................................................................................................................................................................................. [1]
(ii) Name the process by which the ammonia and hydrogen chloride gases move in the tube.
................................................................................................................................................................................................. [1]
(iii) At which point, A, B, C or D, does the white solid form? Explain why the white solid forms at that point.
explanation ..................................................................................................................................................................................
................................................................................................................................................................................................. [2]
6
Explain your answer.
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [3]
(b) Some of the white solid is removed from the tube and dissolved in water.
Describe how the white solid could be tested to show it contains,
(i) ammonium ions,
test...................................................................................................................................................................................
.........................................................................................................................................................................................
result...............................................................................................................................................................................
.................................................................................................................................................................................... [2]
(ii) chloride ions,
test...................................................................................................................................................................................
.........................................................................................................................................................................................
result...............................................................................................................................................................................
.................................................................................................................................................................................... [2]
7
(i) Name the change that occurs in the region D to E. ...................................................................................... [1]
(ii) What would be the difference in the region B to C if an impure sample had been used?
................................................................................................................................................................................................. [1]
(iii) Sketch on the graph how the line would continue if the acid was heated to a higher temperature. [1]
(iv) Complete the following table that compares the separation and movement of the molecules in regions C to
D with those in E to F.
[5]
[Total: 20]
8
4 (a) The major gases in unpolluted air are 79% nitrogen and 20% oxygen.
(i) Name another gaseous element in unpolluted air.
..................................................................................................................................................................................................[1]
..................................................................................................................................................................................................[2]
(b) Two common pollutants in air are carbon monoxide and the oxides of nitrogen.
..................................................................................................................................................................................................[1]
..................................................................................................................................................................................................[1]
..................................................................................................................................................................................................[1]
(iv) Explain how a catalytic converter reduce the emission of these two gases?
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
..................................................................................................................................................................................................[2]
................................................................................................................................................................................................. [1]
9
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [1]
(iv) In many regions, drinking water is obtained by the distillation of sea-water. Explain how distillation separates
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
(d) (i) Plant growth is improved by the availability of essential elements, such as nitrogen, and by the soil having
a suitable pH.
Fertilisers contain nitrogen. Name the other two elements essential for plant growth commonly found in fertilisers.
.............................................................................................................................................................................................. [2]
(ii) Crops do not grow well if the soil is too acidic. One cause of acidity in soil is acid rain. Explain how acid rain
is formed.
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
[Total:18]
10
5 (a) A list of techniques used to separate mixtures is given below.
fractional distillation simple distillation crystallization
filtration diffusion
From the list choose the most suitable technique to separate the following.
(i) water from aqueous copper(II) sulphate .........................................................................................................................
[4]
(b) The following shows a chromatogram of plant acids.
An ester was used as the solvent and the chromatogram was sprayed with bromothymol blue.
(i) Suggest why it was necessary to spray the chromatogram.
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [1]
................................................................................................................................................................................................. [1]
(iii) Calculate the Rf values of the two samples and use the data in the table to identify the plant acids.
[Total:8]
12
13
CENTRE NO. IN971
CHEMISTRY 0620/62
DATE: 19.10.21
Paper 6 Alternative to Practical
TIME: 1 hr.
You must answer on the question paper.
INSTRUCTIONS Q Marks
● Answer all questions. 1 /7
● Use a black or dark blue pen.
●You may use an HB pencil for any diagrams or graphs. 2/8
● Write your name and candidate number in the boxes at the top of the page.
● Write your answer to each question in the space provided.
● Do not use an erasable pen or correction fluid. 3/7
● You may use a calculator.
● You should show all your working and use appropriate units. 4/8
INFORMATION 5/4
● The total mark for this paper is 40.
● The number of marks for each question or part question is shown in brackets [ ].
6/6
Total/
40
1
1 A student investigated the colours present in three hair dyes, P, Q and R, using chromatography. P, Q and R are
insoluble in water. The student suggested setting up the apparatus for the experiment as shown.
................................................................................................................................................................................................ [1]
............................................................................................................................................................................................... [1]
(ii) Suggest why this mistake would stop the experiment working.
......................................................................................................................................................................................................
................................................................................................................................................................................................ [1]
................................................................................................................................................................................................ [1]
(d) A separate chromatography experiment was done using the hair dyes P, Q and R. The chromatogram obtained
is shown.
2
State three conclusions about the hair dyes P, Q and R which can be deduced from the chromatogram.
1 ...................................................................................................................................................................................................
2 ...................................................................................................................................................................................................
3 ...................................................................................................................................................................................................
[3]
[Total: 7]
2 The table gives the boiling points of four alcohols.
The apparatus shown can be used to separate a mixture of the four alcohols shown in the table.
(b) Add to the diagram one arrow to show where water enters the condenser. [1]
3
(c) (i) Why is it not safe to heat the mixture of alcohols with a Bunsen burner?
................................................................................................................................................................................................. [1]
................................................................................................................................................................................................. [1]
(d) Describe how the condenser allows the alcohol to be collected as a liquid.
......................................................................................................................................................................................................
................................................................................................................................................................................................. [1]
explanation .................................................................................................................................................................................
.......................................................................................................................................................................................................
.[2]
[Total: 8]
3 A student investigated the time taken to collect 40cm3 of hydrogen gas when magnesium reacts with dilute
sulphuric acid.
Five experiments were done using the apparatus shown.
Experiment 1
● Using a measuring cylinder, 8cm3 of dilute sulphuric acid was poured into the boiling tube.
● Using a second measuring cylinder, 12cm3 of distilled water was added to the acid in the boiling tube.
4
● The apparatus was set up as shown in the diagram, ensuring the inverted measuring cylinder was full of water.
● The bung was removed from the boiling tube.
● A coiled length of magnesium ribbon was added to the boiling tube, the bung was immediately replaced and a
timer started.
● The time taken for 40cm3 of gas to be collected was measured.
● The student felt the outside of the boiling tube.
(a) The student noticed that the boiling tube was warm.
................................................................................................................................................................................................. [1]
Experiment 2
● The boiling tube was rinsed out with distilled water.
● Experiment 1 was repeated using 10cm3 of dilute sulphuric acid and 10cm3 of distilled water.
Experiment 3
● Experiment 2 was repeated using 12cm3 of dilute sulphuric acid and 8cm3 of distilled water.
Experiment 4
● Experiment 2 was repeated using 16cm3 of dilute sulphuric acid and 4cm3 of distilled water.
Experiment 5
● Experiment 2 was repeated using 20cm3 of dilute sulphuric acid and no distilled water.
5
(b) Use the information in the description of the experiments and the timer diagrams to complete the table.
Record the time in seconds.
[3]
6
(c) In which Experiment, 1, 2, 3, 4 or 5, was the rate of reaction greatest?
................................................................................................................................................................................................. [1]
(d) Why would measuring the volume of dilute sulphuric acid with a burette rather than a measuring cylinder be
an improvement?
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [1]
(e) The magnesium starts to react with the dilute sulphuric acid as soon as it is added.
................................................................................................................................................................................................. [1]
[Total: 7]
4 Two substances, solid L and solid M, were analysed. Solid L was hydrated ammonium sulphate.
Tests were done on solid L and solid M.
tests on solid L
Complete the expected observations.
(a) Describe the appearance of solid L.
................................................................................................................................................................................................ [1]
observations ..............................................................................................................................................................................
............................................................................................................................................................................................... [2]
7
The second portion of solid L was added to distilled water. The mixture was shaken to dissolve solid L and form
solution L. The solution of L was divided into two equal portions in two test-tubes.
(c) An excess of aqueous sodium hydroxide was added to the first portion of solution L.
The mixture was heated and the gas produced was tested.
observations .............................................................................................................................................................................
................................................................................................................................................................................................ [2]
(d) Dilute nitric acid and aqueous barium nitrate were added to the second portion of solution L.
tests on solid M
Some of the tests and observations are shown.
................................................................................................................................................................................................ [2]
[Total: 8]
8
5 Solution J was analysed.
tests on solution J
pH = .............................. [1]
................................................................................................................................................................................................. [1]
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [2]
[Total:4]
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
.......................................................................................................................................................................................................
................................................................................................................................................................................................. [6]
[Total:6]
10