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a series of novel white light emitting dysprosium doped Na3Ba2LaNb10O30 phosphors were successfully synthesized through conventional solid-state

reaction method.

Enhanced Internal Quantum Yield and Luminescence Properties of


Dysprosium-Doped Novel Niobate-Based Phosphor for w-LEDs
Kanishk 1
Poria , Nisha Deopa 2 and Jangvir Singh Shahi1
1Department of Physics, Panjab University, Chandigarh, India
2Department of Physics, Chaudhary Ranbir Singh University, Jind, India

Abstract Steady State Time Resolved Internal Quantum Yield


Internal quantum yield (IQE) is an important aspect of a phosphor as
A novel niobate-based phosphor doped with Dysprosium was
synthesised at 1300°C for 10 hours using hightemperature solid-state Photoluminescence Photoluminescence it gives the efficiency of conversion of electrical power to observed
optical power. The IQE of optimized dysprosium doped niobate based
reaction method. The X-ray diffraction (XRD) analysis showed that Several absorption peaks at 352, 366, 387, 428 and 453 nm were The decay curves of TRPL data fit closely with the double
the phosphors prepared were in pure phase and in the space group exponential function. The degree of fitting (χ2) was observed phosphor was measured using the reference of BaSO4 excitation line.
observed. Intense peaks observed at 387 and 453 nm correspond to
to be very close to 1 (∼0.99932). Qualitatively, IQE is the ratio of number of emitted and absorbed
P4bm of tetragonal system. Surface morphology was studied using 6H
15/2 → 4I
13/2 , 6F
7/2 and 6H
15/2 → 4I
15/2 transitions respectively[3]. The
field emission scanning electron microscopy (FESEM). Steady-state photons. IQE of dysprosium doped niobate based phosphor was
excitation spectra indicates that the synthesised phosphors have
photoluminescence luminescence (PL) characteristics were calculated as 45.35% under the excitation of 387 nm, which is
potential for applications in n-UV and blue LED chips.
significantly higher than previously reported Ca2ZnSi2O7:Dy3+, Eu3+
investigated. Three emission bands centred at 481, 575 and 666 nm The transitions 4F9/2→6H15/2 and 4F9/2→6H13/2 corresponds to the
were observed. The effect of Dy3+ concentration on luminescence (IQE:12.88%)[6], LiCaBO3:Dy3+ (IQE:25.00%)[7] and
magnetic dipole (MD) and forced electric dipole (ED) transition of
intensity was investigated. Study of CIE chromaticity diagram Ca2NaMg2V3O12:Dy3+ (IQE:25.00%)[8] phosphors.
Dy3+ ions[4]. MD transition does not get affected by surrounding
showed its potential application in w-LED. environment i.e. crystal field strength whereas ED transitions are
sensitive to surrounding environment. The intensity of the yellow
Introduction band is stronger than the blue band which illustrates that the Dy3+ ions
are located at non-centrosymmetric sites[5].
Any material that exhibit the phenomenon of luminescence when
subjected to UV light, X-rays, electron bombardment, friction, or any
other form of excitation is referred to as phosphor. A phosphor usually
consists of a host matrix and an activator ion in its lattice[1]. These
activator ions such as Eu2+, Eu3+, Dy3+, Er3+ act as the luminescent
centres i.e. the electron relaxes radiatively at these sites. Researchers
have been working to develop phosphor converted-white light
emitting diodes (pc-wled) using an appropriate host lattice. Our
current study focuses on producing white light from dysprosium
(Dy3+) doped phosphors. The visible spectrum of rare earth
dysprosium ions shows three emission bands: the blue emission (450–
490 nm) corresponding to 4F9/2→6H15/2 transition, the yellow emission Figure 4: Decay curves for 4F9/2→6H13/2 transition in niobate based dysprosium doped
(550–590 nm) corresponding to 4F9/2→6H13/2 hypersensitive transition, 1 mol%, 3 mol%, 5 mol%, 7 mol% and 10 mol% phosphors.
and the red emission (640–680 nm) corresponding to 4F9/2→6H11/2
transition, which is a feeble transition[2]. CIE Chromaticity Plot
𝑥 and 𝑦 are the chromaticity coordinates in the CIE 1931 and
Results were calculated using the given expressions:
𝑋 𝑌

X-ray Diffraction (XRD) 𝑥=


𝑋+𝑌+𝑍
,𝑦=
𝑋+𝑌+𝑍
where 𝑋,𝑌,𝑍 are the tristimulus values for each of the three
Figure 5: Excitation and emission spectra of 7 mol% Dy3+ doped phosphor and BaSO4
reference using an integerating sphere for IQE measurement. Inset: enlarged emission
spectra (400-630 nm).
The XRD analysis demonstrates that the prepared phosphors were in primary colors i.e. red, green and blue.
tetragonal tungsten bronze structure of the space group P4bm. Average
crystallite size decreases at doping concentration increases, this
Correlated color temperature (𝐶𝐶𝑇) relate its color to the color Conclusion
Figure 2. PLE spectra of 1 mol%, 3 mol%, 5 mol%, 7 mol% and 10 mol% Dy3+ doped of the light emitted by the black body at a particular A series of novel white light emitting dysprosium doped
propensity may be brought on by the mismatch between the ionic radii phosphors by fixing emission wavelength at 575 nm. temperature. The temperature is measured in Kelvins. Na3Ba2LaNb10O30 phosphors were successfully synthesized through
of Dy3+ and La3+ ions. solid-state reaction method. The optimised concentration of Dy3+ ions
is 7.0 mol% due to dipole–dipole interaction. The CIE chromaticity
coordinates, CCT, Y/B ratio and color purity indicates that the
synthesised phosphors emits warm white light. The decay time
decreases with increasing concentration of Dy3+ ions due to energy
transfer between neighbouring Dy3+ ions, as indicated by the lifetime
decay curves. The Internal Quantum Yield and Brightness calculated
for the optimised phosphor suggests that the prepared phosphor has a
potential utility in w-LED application under n-UV excitation.

References
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Figure 1. XRD pattern, Rietveld refinement and crystal structure of Na3Ba2LaNb10O30 Figure 3. PL emission spectra of 1mol%, 3 mol%, 5 mol%, 7 mol% and 10 mol% 8. Yang L, Mi X, Zhang H, Zhang X, Bai Z, Lin J. Tunable luminescence and energy transfer properties in
phosphor. Dy3+ -doped phosphors under excitation wavelength of 387 nm. Figure 5: CIE chromaticity diagram of Dy3+ doped phosphors. Ca2NaMg2V3O12: Ln3+ (Dy3+, Sm3+) phosphors. Journal of Alloys and Compounds. 2019;787:815-22.

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